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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Implications of Aerosol Physicochemical Properties Including Ice Nucleation at ARM Mega Sites for Improved Understanding of Microphysical Atmospheric Cloud Processes (Final Technical Report)

Continuous, long-term measurements of atmospheric ice-nucleating particles (INPs) that influence clouds and precipitation were conducted to investigate the abundance and variability of ground-level INPs across the world. Three field campaigns were organized by the DOE Atmospheric Radiation Measurement (ARM) program, including Examining INP from Southern Great Plains (ExINP-SGP, 2019), Examining INP from Eastern North Atlantic (ExINP-ENA, 2020 – 2021), and Examining INP from North Slope of Alaska (ExINP-NSA, 2021 – 2024). Additional small-scale supporting field experiments were performed in 2019 and 2021 to collect airborne particulate matter at SGP for complementary laboratory characterization of the particles’ physical and chemical properties [Aerosol-Ice Formation Closure Pilot Study (AEROICESTUDY), 2019; ExINP-SGP II, 2021]. In these studies, the PI’s team measured INP concentration with both real-time and laboratory measurements in a wide range of freezing temperatures ($T$ from 0 °C to about –30 °C). This project elucidated spatial variability and seasonality in the abundance of immersion mode active INPs across three ARM sites using a single instrument, a Portable Ice Nucleation Experiment (PINE) chamber version 03 (PINE-03 hereafter). Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient INP abundance, air mass origin region, and meteorological variability. Our findings suggest very high freezing efficiency of INPs at the NSA site across the measured temperatures (ice nucleation active surface site density, $n_s(T)$, $\approx 2 \times 10^{8} - 10^{10}$ m -2 for from –16 to –31 °C), which is a factor of 10 – 1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in autumn using the same instrument; surprisingly high INP abundance ($\ge 1 \text{ L}^{-1}$ at –25 °C) for the examined temperatures throughout the year that PINE-03 did not measure at other sites; and high INP concentration in spring, possibly related to arctic haze episodes.

58 GEOSCIENCES↗
DOE OSTI2025

Back Trajectories during SAIL

This data set contains air mass back trajectories generated during the Surface Atmosphere Integrated Field Laboratory (SAIL) campaign using the Hybrid Single-Particle Lagrangian Integrated Trajectory model (HYSPLIT, Stein et al. 2015, Rolph et al. 2017). For each hour from January 1, 2021 to June 30, 2023, a 96-hour back trajectory was initiated at the SAIL sampling site, starting 100 m above ground level. The calculations used the GDAS meteorological data set with model vertical velocity. The files within this dataset show location and meteorological parameters of the back trajectory analysis. There are 21 columns within each data file. The first 2 columns pertain to back trajectory parameters: the trajectory number (which is always 1) and the meteorological grid number. The next 9 columns pertain to spatiotemporal information: the year, month, day, hour (0-23), and minute of the trajectory, the previous time of the trajectory (in negative hours), and the airmass location (latitude, longitude, and height in m AGL). The rest of the parameters within each file pertains to surface and meteorological characteristics of the airmass: pressure (in hPa), potential temperature (in K), temperature (in K), precipitation rate (in mm/hr), mixing depth (in m), relative humidity (in % relative to liquid water), specific humidity (in g/kg), H2O mixing ratio (in g/kg), underlying terrain height (in meters above sea level), and incoming radiation (in W/m^2).

back trajectory↗
DOE OSTI2025

PV Degradation Modeling: Applying Geospatial Workflows with "PVDeg"

Accurate degradation modeling is essential for predicting photovoltaic (PV) module performance, estimating longevity and informing design decisions. With degradation rates varying significantly by location, geospatial analysis is critical for PV and broader applications, such as agrivoltaics, weathering and environmental data analysis. This work presents PVDeg, an open-source tool designed for geospatial degradation analysis. PVDeg integrates meteorological data from global sources, including the National Solar Radiation Database (NSRDB) and Photovoltaic Geographical Information System (PVGIS), with degradation models. The toolkit enables users to customize geospatial workflows by integrating weather data, material parameters, and user-defined Python functions. It facilitates accelerated downloads of NSRDB and PVGIS datasets and optimizes geospatial point selection to preserve data density in regions of interest. Additionally, PVDeg provides a local database for storage and spatial queries, supporting large-scale analyses without the need for high-performance computing (HPC) resources. PVDeg provides a foundational workflow that extends its utility beyond PV applications, enabling researchers to analyze geospatial processes across discipline.

14 SOLAR ENERGY↗
DOE OSTI2024

National Climate Database (NCDB)

The National Climate Database (NCDB) is a high resolution, bias-corrected climate dataset consisting of the three most widely used variables of solar radiation- global horizontal (GHI), direct normal (DNI), and diffuse horizontal irradiance (DHI)- as well as other meteorological data. The goal of the NCDB is to provide unbiased high temporal and spatial resolution climate data needed for renewable energy modeling. The NCDB is modeled using a statistical downscaling approach with Regional Climate Model (RCM)-based climate projections obtained from the North American Coordinated Regional Climate Downscaling Experiment (NA-CORDEX; linked below). Daily climate projections simulated by the Canadian Regional Climate Model 4 (CanRCM4) forced by the second-generation Canadian Earth System Model (CanESM2) for two Representative Concentration Pathways (RCP4.5 or moderate emissions scenario and RCP8.5 or highest baseline emission scenario) are selected as inputs to the statistical downscaling models. The National Solar Radiation Database (NSRDB) is used to build and calibrate statistical models.

Array↗
DOE OSTI2026

Near-Real-Time Statistical Analysis and Visualization of Streamflow from a Deep-Learning Rainfall-Runoff Model

Near-real-time (NRT) streamflow data are critical importance for timely water resources management. Here, we developed an open-source tool, FlowStats, for NRT streamflow analysis and visualization in Germany, based on NRT meteorological data from the German Weather Service and simulated streamflow from a long short-term memory neural network (LSTM). The LSTM model achieved very good overall performance, median NSE of 0.80 for the test period across 1,479 catchments. FlowStats provides options for deriving various streamflow statistics, from normal and abnormal streamflow detection to drought and flood analyses. An example analysis from FlowStats revealed widespread below-normal to extreme low-flow conditions across Germany from March to May 2025, which weakened from June to September 2025. Drought analysis for September 2025 highlighted severe to extreme drought conditions in northwestern Germany, while flood classifications indicated that high-flow events occurred in southwestern Germany. FlowStats can be used for various hydrological assessments to support water resources management.

Hydrological modeling↗
DOE OSTI2025

Multi-seasonal measurements of the ground-level atmospheric ice-nucleating particle abundance on the North Slope of Alaska

Atmospheric ice-nucleating particles (INPs) are an important subset of aerosol particles that are responsible for the heterogeneous formation of ice crystals. INPs modulate the arctic cloud phase (liquid vs. ice), resulting in implications for radiative feedbacks. The number of arctic INP studies investigating specific INP episodes or sources increased recently. However, existing studies are based on short-duration field data, and long-term datasets are lacking. Continuous, long-term measurements are key to determining the abundance and variability of ambient arctic INPs and constraining aerosol–cloud interactions, e.g., to verify and/or improve simulations of mixed-phase clouds. Here, we present a new long-duration INP dataset from the Arctic: 2 years of predominantly immersion-mode INP concentrations (n INP ) measured continuously at the National Oceanic and Atmospheric Administration's Barrow Atmospheric Baseline Observatory (BRW) on the North Slope of Alaska. A portable ice nucleation experiment chamber (PINE-03), which simulates adiabatic expansion cooling, was used to directly measure the ground-level INP abundance with an approximately 12 min time resolution from October 2021 to December 2023. We document PINE-03 n INP measurements as well as estimated ice nucleation active surface site density (n s ) over a wide range of heterogeneous freezing temperatures from −16 to −31 °C from which we introduce new season-specific parameterizations suitable for modeling mixed-phase clouds. Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient n INP , air mass origin region, and meteorological variability. Our findings suggest (1) very high freezing efficiency of INPs across the measured temperatures (n s ≈ 2×10 8 –10 10 m −2 for −16 to −31 °C), which is a factor of 10–1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in fall using the same instrument; (2) surprisingly high n INP (≥ 1 L −1 at −25 °C) for the examined temperatures throughout the year that were not measured by PINE-03 at other sites; and (3) high n INP in spring, possibly related to arctic haze episodes. Relatively low concentrations of aerosol surface area and contrasting high-INP concentrations at BRW relative to mid-latitude sites are the possible reasons for the observed high freezing efficiency.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Assessing Photovoltaic Capacity Factor Variability Using Long-Term Satellite Derived Solar Resource Data Under Brazilian Climate

Accurate estimation of photovoltaic (PV) energy yield and its variability is essential for reducing financial risk and supporting reliable system planning for rapidly expanding PV markets. In Brazil, high solar adoption and increasing levels of distributed energy resources are beginning to introduce operational challenges such as curtailment and evolving grid requirements. Understanding how natural variability in solar resource propagates into PV system performance is therefore increasingly important for both project design and grid integration. Modern PV yield assessments commonly rely on multi-year meteorological datasets and probabilistic exceedance metrics (e.g., P50/P90) to quantify energy yield uncertainty for project financing. However, the implications of long-term solar resource variability for PV system design choices and high-adoption grid conditions remain less well characterized for rapidly expanding markets such as Brazil. In particular, understanding how weather-driven variability propagates into PV production distributions and capacity factor expectations is important for evaluating curtailment exposure, deployment strategies, and storage requirements in regions experiencing rapid growth of distributed and utility-scale PV. Seasonal and interannual variability in atmospheric conditions can produce substantial fluctuations in monthly PV energy production, which propagate into uncertainty in annual energy yield and capacity factor expectations. Characterizing this variability using long-term meteorological datasets allows probabilistic estimation of PV system performance and provides improved insight into the range of expected PV energy outcomes. This study explores the use of long-term satellite-derived meteorological data from the National Solar Radiation Database (NSRDB) to evaluate the variability of photovoltaic system performance across multiple locations in Brazil. Using a 27-year dataset (1998-2024), PV system simulations are performed to characterize the distribution of annual and seasonal capacity factors and energy yield outcomes, while propagating key sources of meteorological variability and model uncertainty through the PV modeling chain. The analysis also investigates the sensitivity of PV performance outcomes to key system design assumptions within the PV modeling chain, including tracking configuration and system sizing parameters. The resulting probabilistic performance characterization provides insight into how weather-driven variability influences PV production expectations and capacity factor distributions. These results provide a foundation for evaluating how weather-driven variability interacts with high PV adoption and potential storage or curtailment mitigation strategies.

14 SOLAR ENERGY↗
DOE OSTI2025

U.S. Agrivoltaics Irradiance Database

This is a foundational data set for research and deployment of agrivoltaics, which is the co-location of agriculture and solar power plants on the same land. This irradiance and shading dataset can be utilized to determine the suitability of agrivoltaics configurations for a given region and crop-type. The data is hourly, 4x4 km resolution across the contiguous United States and Hawaii. It is calculated from the National Solar Radiation Database sites, using the System Advisor Model (SAM) to simulate the shading patterns for 10 common agrivoltaics configurations. Sunlight availability data is reported for 10 locations on the ground between adjacent rows of solar panels, as well as averaged across areas of interest such as the average irradiance in the edge-to-edge open area or across 3-6 planting beds. Other available metrics include the input meteorological data from the NSRDB (e.g. global horizontal irradiance, wind speed, etc.) and estimates for comparing energy and agricultural characteristic across the 10 configurations, including power output per acre or per kW installed capacity and farmable land area per acre.

14 SOLAR ENERGY↗
DOE OSTI2024

NDVI and Multispectral Images, UAS Flights, Council Road Site, Seward Peninsula, Alaska, June 2022

The dataset contains Normalized Difference Vegetation Index (NDVI) and multispectral images collected on June 18, 2022 using an UAS (Unmanned Aerial System) Yuneec H520, Mapir Survey 3, and Parrot Sequoia cameras. This data was created to accompany the following datasets:- NGEE Arctic CO2, CH4 and Energy Eddy-Covariance (EC) Flux Tower Auxiliary Measurements, Council Road Mile Marker 71, Seward Peninsula, Alaska (https://doi.org/10.5440/1526749)- Sun-induced chlorophyll fluorescence/eddy covariance measurements at NGEE Arctic Council site, Seward Peninsula, Alaska, 2022 (https://doi.org/10.15485/2466175)- NGEE Arctic Meteorological Data from Instrumented PCDC Stations, Council Site, Seward Peninsula, Alaska, 2018 - 2023 (https://doi.org/10.5440/1529604)Survey 3 is RGN (Red, Greeen, Near Infra Red) camera with 87° Horizontal Field of View (HFOV) (19mm) f/2.8 Aperture, 550nm/660nm/850nm (Red+Green+NIR) filter transmission and produced geo referenced jpg and raw format images. Parrot Sequoia is a camera with 16 megapixel RGB (Red, Green, Blue) sensor and 1.2 megapixel monochrome sensors in discrete spectral bands: Green (550nm - 40Nm Bandwidth), Red (660nm - 40nm Bandwidth), Red Edge (735nm - 10nm Bandwidth) and Near Infrared (790nm - 40nm Bandwidth).The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

AmeriFlux US-GL2 Granite Island

This is the AmeriFlux version of the carbon flux data for the site US-GL2 Granite Island. Site Description - Granite Island is a small island on Lake Superior approximately 10 miles due north of Marquette, Michigan. It is roughly 6.5 miles from shore and is occupied by a lighthouse, bell tower, Coast Guard light tower, and other small structures. A flux tower to measure H, LE, and meteorological data was installed atop the bell tower in July of 2009 and has been in continuous operation since then (aside from occasional power outages or other sources of data loss). CO2 measurements were added to the flux tower in October of 2010.

Lenters, John [University of Michigan Biological S↗
DOE OSTI2026

Outdoor Deployment Data for a Four-Terminal GaAs//Si Tandem Solar Mini-Module

This dataset contains the complete outdoor measurement and analysis data for a mechanically stacked, four-terminal (4T) gallium arsenide (GaAs)//silicon (Si) tandem solar mini-module deployed from October 2019 to January 2021 at the Solar Radiation Research Laboratory (SRRL) in Golden, Colorado, USA. The data support a performance modeling and degradation analysis framework for tandem photovoltaic devices, as described in the accompanying publication. The dataset includes: (1) current–voltage (J–V) characteristics of each sub-cell measured approximately every five minutes, with extracted performance parameters; (2) spectral irradiance from an EKO MS-710 WISER spectroradiometer, along with derived spectral mismatch ratios (SMR) and average photon energy (APE); (3) one-minute resolution meteorological data from the co-located SRRL weather station and GPS-derived precipitable water vapor (PWV); (4) pre-deployment laboratory characterization (external quantum efficiency, J–V curves, standard test conditions parameters); (5) outdoor-extracted temperature and PWV correction coefficients; and (6) PVcircuit equivalent-circuit simulation outputs used for model validation. Degradation rates of −4.1 ± 0.2 %/year (GaAs) and −2.5 ± 0.9 %/year (Si) were determined using a filtering and normalization methodology adapted for fixed-tilt tandem modules. All data are provided in open, portable formats (Apache Parquet, CSV, JSON) to enable full reproducibility of the published analysis.

14 SOLAR ENERGY↗
DOE OSTI2025

Development of a Digital Twin for Hydrogen Dispersion and Safety Assessment in an Electrolyzer Based Hydrogen Production Facility

Digital twin models are virtual representations of physical systems that use real-time data to simulate and optimize performance. This study presents the development and initial implementation of a digital twin (DT) for the electrolyzer-based hydrogen production facility at NREL's Advanced Research on Integrated Energy Systems (ARIES), focused on enhancing safety and optimizing sensor placement through physics-based simulations and metadata integration. The DT incorporates detailed facility-specific information, including component layout, leak locations, and controlled release parameters, to model hydrogen dispersion under varying environmental conditions. Using steady-state computational fluid dynamics (CFD) simulations informed by real meteorological data, such as wind speed, direction, and vertical wind profiles, the DT enables visualization of hydrogen plume behavior and spatial concentration distributions. Comparative analysis between high and low wind speed scenarios illustrates the significant influence of wind dynamics on plume shape and extent, with horizontal momentum dominating dispersion at higher speeds, while buoyancy effects become more prominent under low wind conditions. These simulations generate a rich dataset embedded within the DT, allowing users to assess potential leak outcomes and identify optimal sensor locations based on concentration thresholds. The model supports scenario-based analysis to guide safety strategies and equipment deployment for open-area hydrogen infrastructure. The digital twin thus serves as a dynamic platform for virtual prototyping, providing predictive insight into hydrogen behavior and enhancing risk-informed decision-making. This initial phase establishes a validated foundation for future integration of transient, uncontrolled leak scenarios and real-time sensor feedback, positioning the DT as a critical tool for safety design, operational planning, and adaptive monitoring in hydrogen systems. Overall, the approach demonstrates the value of combining environmental data with digital simulations to inform safer and more efficient deployment of hydrogen technologies.

08 HYDROGEN↗
DOE OSTI2026

Development of a Digital Twin for Hydrogen Dispersion and Safety Assessment in an Electrolyzer-Based Hydrogen Production Facility: Preprint

Digital twin models are virtual representations of physical systems that use real-time data to simulate and optimize performance. This study presents the development and initial implementation of a digital twin (DT) for the electrolyzer-based hydrogen production facility at the National Renewable Energy Laboratory (NREL)'s Advanced Research on Integrated Energy Systems (ARIES), focused on enhancing safety and optimizing sensor placement through physics-based simulations and metadata integration. The DT incorporates detailed facility-specific information, including component layout, leak locations, and controlled release parameters, to model hydrogen dispersion under varying environmental conditions. Using steady-state computational fluid dynamics (CFD) simulations informed by real meteorological data, such as wind speed, direction, and vertical wind profiles, the DT enables visualization of hydrogen plume behavior and spatial concentration distributions. Comparative analysis between high and low wind speed scenarios illustrates the significant influence of wind dynamics on plume shape and extent, with horizontal momentum dominating dispersion at higher speeds, while buoyancy effects become more prominent under low wind conditions. These simulations generate a rich dataset embedded within the DT, allowing users to assess potential leak outcomes and identify optimal sensor locations based on concentration thresholds. The model supports scenario-based analysis to guide safety strategies and equipment deployment for open-area hydrogen infrastructure. The digital twin thus serves as a dynamic platform for virtual prototyping, providing predictive insight into hydrogen behavior and enhancing risk-informed decision-making. This initial phase establishes a validated foundation for future integration of transient, uncontrolled leak scenarios and real-time sensor feedback, positioning the DT as a critical tool for safety design, operational planning, and adaptive monitoring in hydrogen systems. Overall, the approach demonstrates the value of combining environmental data with digital simulations to inform safer and more efficient deployment of hydrogen technologies.

08 HYDROGEN↗
DOE OSTI2024

Statistically Resolved Planetary Boundary Layer Height Diurnal Variability Using Spaceborne Lidar Data

The Planetary Boundary Layer Height (PBLH) significantly impacts weather, climate, and air quality. Understanding the global diurnal variation of the PBLH is particularly challenging due to the necessity of extensive observations and suitable retrieval algorithms that can adapt to diverse thermodynamic and dynamic conditions. This study utilized data from the Cloud-Aerosol Transport System (CATS) to analyze the diurnal variation of PBLH in both continental and marine regions. By leveraging CATS data and a modified version of the Different Thermo-Dynamics Stability (DTDS) algorithm, along with machine learning denoising, the study determined the diurnal variation of the PBLH in continental mid-latitude and marine regions. The CATS DTDS-PBLH closely matches ground-based lidar and radiosonde measurements at the continental sites, with correlation coefficients above 0.6 and well-aligned diurnal variability, although slightly overestimated at nighttime. In contrast, PBLH at the marine site was consistently overestimated due to the viewing geometry of CATS and complex cloud structures. The study emphasizes the importance of integrating meteorological data with lidar signals for accurate and robust PBLH estimations, which are essential for effective boundary layer assessment from satellite observations.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Daily water stable isotopes, transpiration, and matrix potential data for an aspen and engelmann stand in the East River Watershed (version 2)

We provide daily stable isotope (2H & 18O) ratios in soil water and xylem (plant stem) water, as well as the sap flow (transpiration) and the soil's matric potential at a forested site near Gothic, Colorado, in the East River catchment. We measured the stable isotopic composition of the transpiration and the daily transpiration flux sum of three aspen and three engelmann spruce. In both forest stands, we installed a soil profile and measured the soil matric potential at 15, 30, and 60 cm depth as well as the stable isotopes of soil pore water at 5, 10, 30, 60, and 90 cm depths. All isotope measurements were done in situ via vapor probes connected to a cavity ring down spectrometer (Picarro L1240i).We further report the daily meteorological data observed at billy barr near our study site. We also provide for each tree the relative share of root water uptake derived from the isotope measurements via a Bayesian mixing model (MixSIAR).The daily data is provided as a time series in "Iso_MP_Sap_DataDaily_ESSDiveUpload.csv" and the units are provided in "dd.csv"; the location of the instrumented trees and soil profiles are given as latitude and longitude coordinates saved as CSV and KMZ files; and a file-level metadata (flmd.csv) file that lists each file contained in the dataset with associated metadata.The data was gathered to investigate the short-term changes of the water sources (i.e., variation of root water uptake from different soil depths) of the studied subalpine trees.Update 07/16/2025: The relative and absolute plant water uptake depths were grouped to ensure that the MixSIAR model was applied with endmembers that differed in their d2H value by at least 3 permill and at least 1 permill for d18O. Whenever the difference between observed d2H values for two or more probes at neighboring depths was less than 3 permill, we used the average value for the source water endmember. For days at which probes that were not next to each other measurements did not differ at least 3 permill, the average of all probes between these two depths was used as the water source endmember representing the depth range between these two probes.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

AmeriFlux FLUXNET-1F US-GL1 Stannard Rock

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-GL1 Stannard Rock. This is the FLUXNET version of the carbon flux data for the site US-GL1 Stannard Rock produced by applying the standard ONEFlux (1F) software. Site Description - Stannard Rock is located 39 km from the nearest shore (Keweenaw Peninsula) in Lake Superior, 44 miles NNE of Marquette, Michigan, and 24 miles ESE of Manitou Island. The site is located on the historic Stannard Rock Lighthouse, which was completed in 1882. Eddy covariance instrumentation was installed in 2008 by a network of scientists from both US and Canada, eventually to be called the Great Lakes Evaporation Network (GLEN). The intent of GLEN has been to provide observations of over-lake meteorology and evaporation, improve forecasting of Great Lakes water levels, and support a wide variety of stakeholders, including the National Weather Service (NWS), Environment and Climate Change Canada, National Oceanic and Atmospheric Administration, U.S. Coast Guard, recreational boaters and commercial shipping, emergency management officials, and the Great Lakes research community. The eddy covariance station along with other ancillary meteorological instrumentation is located at an approximate elevation of 39.2 meters above mean lake water level. Meteorological data from the lighthouse are sent to the National Data Buoy Center, where they can be viewed in real-time at http://www.ndbc.noaa.gov/station_page.php?station=stdm4 Uncorrected half-hour fluxes were computed directly on the logger using a 30-minute block averaging period as high-frequency data were not available. The half hour flux measurements downloaded from the datalogger were post-processed with the following filters and corrections. Latent and sensible heat and carbon dioxide fluxes were corrected with 2-D coordinate rotation. Although the primary objective of data collection at Stannard Rock was to quantify the evaporative flux, additional preliminary measurements of the carbon dioxide concentration and flux from the LI-7500 are also included in this dataset but it is advised to use the carbon data with caution. Carbon data reported in this dataset includes turbulent fluxes of CO2 with no storage correction (FC, µmol m-2 s-1) and CO2 density in mole fraction of wet air (CO2), which was originally output on the datalogger as average CO2 density (mg m-2 s-1) and converted into µmol mol-1 using air temperature and pressure in post-processing. Webb, Pearman, and Leuning terms were applied to account for density fluctuations for water vapor and CO2. Sonic path length, high-frequency attenuation and sensor separation were accounted for according to Horst and Massman, and the oxygen absorption correction for the KH2O hygrometer was also applied. Latent and sensible heat fluxes were assumed to be unrealistic above an absolute value of 1000 W m-2 and were removed. Both carbon flux (FC) and carbon dioxide mole fraction in wet air (CO2) and were assumed to be unrealistic above 1000 µmol m-2 s-1 and 1000 µmol mol-1 respectively. Spikes in latent and sensible heat and carbon fluxes and densities (often due to periods of precipitation) were identified by computing the mean and standard deviation over a moving, overlapping window of 336 half-hours (7 days), similar to Shao et al., and were removed when the flux was more than 1.5 standard deviations from the moving window’s mean. While Vickers and Mahrt use a threshold of 3.5 standard deviations from the mean, a conservative value of 1.5 was chosen due to the noisy nature of over-lake data at this particular site. This process was repeated twice for latent and sensible heat, and carbon dioxide fluxes and densities and therefore it is possible that some real, realistic data was filtered out in this process. No detrending was performed. As per AmeriFlux standards, no friction velocity (USTAR, m s-1) filtering was performed.

Spence, Chris [Environment and Climate Change Cana↗
DOE OSTI2024

Modeling Diurnal and Annual Ethylene Generation from Solar-Driven Electrochemical CO 2 Reduction Devices

Integrated solar fuels devices for CO 2 reduction (CO 2 R) are a promising technology class towards achieving net-negative carbon emissions. Designing integrated CO 2 R solar fuels devices requires careful co-design of electrochemical and photovoltaic components as well as consideration of the diurnal and seasonal effects of solar irradiance, temperature, and other meteorological factors expected for ‘on-sun’ deployment. Here, using a photovoltaic-electrochemical (PV-EC) platform, we developed a temperature and potential-dependent diurnal and annual model using experimental CO 2 R performance of Cu-based electrocatalysts, local meteorological data from the National Solar Radiation Database (NSRD), and modeled performance of commercial c-Si PVs. We simulated diurnal product outputs with and without the effects of ambient temperature to determine gaseous product temperature sensitivity. From these outputs, we observed seasonal variation in gaseous product generation, with up to two-fold increases in ethylene productivity between the Winter and Summer, analyzed the consequences of dynamic cloud coverage, and identified periods where device cooling/heating mechanisms could be implemented to maximize ethylene generation. Finally, we modeled the annual ethylene generation for a scaled 1 MW solar farm at three different locations (Beijing, CN; Sydney, AUS; Barstow, CA) to determine the consequences of local meteorological climates on PV-EC CO 2 R product output, recording a maximum ethylene output of 18.5 tonne/yr at Barstow. Overall, this model presents a critical tool for streamlining the translation of experimental solar-driven electrochemical research to real-world implementation.

Yap, Kyra M. K.↗
DOE OSTI2024

The "PVLib" of Degradation: PVDeg

The Photovoltaic (PV) industry constantly aims for lower costs through higher-efficiency cells, improved module designs, and improvements in durability. This leads to the use of new materials, designs, and manufacturing processes, and not always with a sufficient amount of durability testing. To help drive down costs there is a desire to create modules that will last for up to 50 years of service life. To accomplish this, every degradation mode and mechanism must be identified and either eliminated or otherwise mitigated. This involves the extrapolation of laboratory results to the field conditions. There is a need to organize the existing degradation data into an accessible format and to provide industry relevant tools for extrapolation from laboratory to field conditions. While the basic equations used to model degradation are sometimes very simple, the full analysis involves calculations are cumbersome but ubiquitous for many degradation processes. A simplified, modeling framework to accomplish these repetitive processes will facilitate the analysis to help researchers keep up with the rapid pace of technological changes. In this talk, we will describe our progress creating the open-source tool PVDeg. This tool can be used to search for and analyze degradation information and extrapolate PV module performance and durability to field exposure. PVDeg simplifies many of the common foundational computational operations for obtaining meteorological data and using it to generate a model of the PV deployment. This prediction tool repository also contains various degradation models as well as a library of material parameters suitable for estimating the durability assessment of materials and components. We use an integration pipeline approach that allows us to leverage weather data from the National Solar Radiation Database, and other weather sources, to perform geospatial degradation analysis in the US and worldwide. We hope to become a repository that can be used for weathering and degradation analysis for various applications beyond the PV industry. During the talk, we will provide the PVPMC attendees the opportunity to interact with the tool via a Google Collab tutorial they can run on their phones or laptops.

durability↗