Search NASA⌕ Search

SEARCH · Search NASA

Results for “midinfrared”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Linear dichroism infrared resonance in overdoped, underdoped, and optimally doped cuprate superconductors

By measuring the polarization changes in terahertz, infrared, and visible radiation over an extended energy range (3–2330 meV), we observe symmetry breaking in cuprate high-temperature superconductors over wide energy, doping, and temperature ranges. We measure the polarization rotation (Re[$θ_F$]) and ellipticity (Im[$θ_F$]) of transmitted radiation through thin films as the sample is rotated. We observe a twofold rotational symmetry in $θ_F$, which is associated with linear dichroism (LD) and occurs when electromagnetic radiation polarized along one direction is absorbed more strongly than radiation polarized in the perpendicular direction. Such polarization anisotropies can be generally associated with symmetry breakings. We measure the amplitude of the LD signal and study its temperature, energy, and doping dependence. The LD signal shows a resonant behavior with a peak in the few hundred meV range, which is coincident with the midinfrared optical feature that has been associated with the formation of the pseudogap state. In this work, the strongest LD signal is found in underdoped films, although it is also observed in optimally and overdoped samples. The LD signal is consistent with an electronic nematic order which is decoupled from the crystallographic axes as well as novel magnetoelectric effects.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Tunable plasmon-enhanced second-order optical nonlinearity in transition metal dichalcogenide nanotriangles

The development of nanomaterials with a large nonlinear susceptibility is essential for nonlinear nanophotonics. Here we show that transition metal dichalcogenide (TMD) nanotriangles have a large effective second-order susceptibility [χ (2) ] at midinfrared to near-infrared frequencies owing to their broken centrosymmetry. χ (2) is calculated within the density-matrix formalism that accounts for dissipation and screening. χ (2) peaks in the vicinity of both two-photon resonances (specified by the geometry) and plasmon resonances (tunable via the carrier density). Aligning the resonances yields the values of χ (2) as high as 10 –6 m/V. These findings underscore the potential of TMD nanotriangles for nonlinear nanophotonics, particularly second-harmonic generation.

0-dimensional systems↗
DOE OSTI2021

Probing nanoparticle substrate interactions with synchrotron infrared nanospectroscopy: Coupling gold nanorod Fabry-Pérot resonances with SiO 2 and $h$-BN phonons

Spectroscopic interrogation of materials in the midinfrared with nanometer spatial resolution is inherently difficult due to the long wavelengths involved, reduced detector efficiencies, and limited availability of spectrally bright, coherent light sources. Technological advances are driving techniques that overcome these challenges, enabling material characterization in this relatively unexplored spectral regime. Synchrotron infrared nanospectroscopy (SINS) is an imaging technique that provides local sample information of nanoscale target specimens in an experimental energy window between 330 and 5000 cm -1 . Here, using SINS, we analyzed a series of individual gold nanorods patterned on a SiO 2 substrate and on a flake of hexagonal boron nitride. The SINS spectra reveal interactions between the nanorod photonic Fabry-Pérot resonances and the surface phonon polaritons of each substrate, which are characterized as avoided crossings. A coupled oscillator model of the hybrid system provides a deeper understanding of the coupling and provides a theoretical framework for future exploration.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

Light-induced anomalous Hall conductivity in the massive three-dimensional Dirac semimetal Co 3 ⁢Sn 2 ⁢S 2

Weyl semimetals can emerge from Dirac semimetals when the time-reversal or spatial-inversion symmetries are broken. Recently, it has been proposed based on Floquet theory that Dirac semimetals can be converted into Weyl semimetals even by shining circularly polarized light (CPL). Here we have investigated the possibility of such a Dirac-Weyl conversion by measuring the CPL-induced anomalous Hall conductivity (AHC) in a massive 3D Dirac semimetal Co 3 ⁢Sn 2 ⁢S 2 in the paramagnetic phase using ultrafast midinfrared pump-terahertz Faraday rotation probe spectroscopy. We find that the field-strength and driving frequency dependence of the observed AHC is well accounted for by CPL-induced nonzero Berry curvature associated with the splitting of the Dirac bands as predicted by the Floquet theory. As a result, the estimated splitting of the Dirac bands reaches about 60% of the mass gap and the calculated CPL-induced AHC quantitatively reproduces the experimental observation, demonstrating a promising route toward the realization of Floquet-Weyl states from massive Dirac semimetals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Polarization Flipping of Even-Order Harmonics in Monolayer Transition-Metal Dichalcogenides

We present a systematic study of the crystal-orientation dependence of high-harmonic generation in monolayer transition-metal dichalcogenides, WS 2 and MoSe 2 , subjected to intense linearly polarized midinfrared laser fields. The measured spectra consist of both odd- and even-order harmonics, with a high-energy cutoff extending beyond the 15th order for a laser-field strength around ~1 V/nm. In WS 2 , we find that the polarization direction of the odd-order harmonics smoothly follows that of the laser field irrespective of the crystal orientation, whereas the direction of the even-order harmonics is fixed by the crystal mirror planes. Furthermore, the polarization of the even-order harmonics shows a flip in the course of crystal rotation when the laser field lies between two of the crystal mirror planes. By numerically solving the semiconductor Bloch equations for a gapped-graphene model, we qualitatively reproduce these experimental features and find the polarization flipping to be associated with a significant contribution from interband polarization. In contrast, high-harmonic signals from MoSe 2 exhibit deviations from the laser-field following of odd-order harmonics and crystal-mirror-plane following of even-order harmonics. We attribute these differences to the competing roles of the intraband and interband contributions, including the deflection of the electron-hole trajectories by nonparabolic crystal bands.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Thermophysical Modeling of 20 Themis Family Asteroids with WISE/NEOWISE Observations

Themis family is one of the largest and oldest asteroid populations in the main belt. Water ice may widely exist on the parent body (24) Themis. In this work, we employ the Advanced Thermophysical Model as well as midinfrared measurements from NASA’s Wide-field Infrared Survey Explorer to explore thermal parameters of 20 Themis family members. Here we show that the average thermal inertia and geometric albedo are 39.5 ± 26.0 J m{sup −2} s{sup −1/2} K{sup −1} and 0.067 ± 0.018, respectively. The family members have a relatively moderate roughness fraction on their surfaces. We find that the relatively low albedos of Themis members are consistent with the typical values of B-type and C-type asteroids. As mentioned, the Themis family bears a very low thermal inertia, which indicates a fine and mature regolith on their surfaces. The resemblance of thermal inertia and geometric albedo of Themis members may reveal their close connection in origin and evolution. In addition, we present the compared results of thermal parameters for several prominent families.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1977

A high-resolution far-infrared survey of the W31 region

A 1-m balloon-borne telescope was used to conduct a far-infrared survey of the W31 region at an effective wavelength of 69 microns with a resolution of 1 arcmin. Within this region seven far-infrared sources were observed. Five of these sources were associated with thermal radio emission. For each of these sources the infrared luminosity is much greater than the Ly-alpha luminosity, a situation requiring either dust absorption of Lyman-continuum photons or a large nonionizing stellar luminosity. Two faint infrared sources had no radio counterparts. Far-infrared radiation was not detected from two known radio sources and from one midinfrared source in this region.

Wright, E. L.↗
NASA NTRS1983

Balloon-borne remote sensing of stratospheric constituents

Data on species of interest in the photochemistry of the ozone layer obtained from balloon flights are presented. The flights made use of remote-sensing instruments that took measurements in the wavelength region from the ultraviolet to millimeter wavelengths. Most of the data were obtained with instruments whose readings were in the midinfrared wavelengths. Descriptions are given of the two techniques generally used in this type of research, namely solar absorption and atmospheric emission. The promise that these techniques hold for providing data on the photochemistry of the ozone layer is discussed.

Murcray, D. G.↗
NASA NTRS1987

Reflectance- and radiance-based methods for the in-flight absolute calibration of multispectral sensors

Variations reported in the in-flight absolute radiometric calibration of the Coastal Zone Color Scanner (CZCS) and the Thematic Mapper (TM) on Landsat 4 are reviewed. At short wavelengths these sensors exhibited a gradual reduction in response, while in the midinfrared the TM showed oscillatory variations, according to the results of TM internal calibration. The methodology and results are presented for five reflectance-based calibrations of the Landsat 5 TM at White Sands, NM, in the period July 1984 to November 1985. These show a + or - 2.8 percent standard deviation for the six solar-reflective bands. Analysis and preliminary results of a second, independent calibration method, based on radiance measurements from a helicopter at White Sands, indicate that this is potentially an accurate method for corroborating the results from the reflectance-based method.

Slater, P. N.↗
NASA NTRS1988

Radio properties of the highly polarized, quiescent quasar OI 287

The highly polarized, quiescent quasar OI 287 has been observed with high resolution at 2 cm and 6 cm in an effort to determine the origin of some of the object's peculiar properties. The results seem to rule out the classification of OI 287 as a blazar. Extrapolation of the radio core spectrum to midinfrared wavelengths fails to predict the infrared flux by at least an order of magnitude. This supports the conclusion that the infrared emission and the radio emission do not originate in the same synchrotron-emitting component. The high optical polarization could be related to possible broad absorption lines in the unobserved UV regime, or it could be caused by reflection into the line of sight by scattering agents distributed in a thin disk.

Ulvestad, James S.↗
NASA NTRS1988

Luminous extranuclear star formation in the interacting galaxy Arp 118 - NGC 1143/44

The interacting system Arp 118 (NGC 1143/44) has been observed at infrared and radio wavelengths. The interaction has produced a pair of distorted loops and several luminous radio and infrared sources in NGC 1144 which emit a total power of 2.5 x 10 to the 11th lunar masses, 80 percent of which is reradiated in the thermal infrared. Remarkably, the present observations reveal that much of the midinfrared emission originates in an extra-nuclear star-forming region. Arp 118 has many of the same characteristics as the well-studied interacting system Arp 299 (NGC 3690), including luminous extranuclear activity; the main difference between the two systems is that the nuclei of NGC 1143/44 are much less luminous at 10 microns than their counterparts in NGC 3690.

Joy, Marshall↗
NASA NTRS1988

Investigation of stimulated Brillouin scattering switching in mid infrared fibers

Backward stimulated Brillouin scattering (SBS) has been experimentally studied in midinfrared transparent AgCl and KRS-5 fibers. In the present scheme, pump transmission through the fibers and acoustooptic radiative effects are simultaneously observed. The SBS shifted scattered light spectrum is investigated by laser heterodyne spectroscopy using HgCdTe and very fast metal-oxide-metal diode broadband mixers. The results suggest that reflection under high incident laser power departs from simple Fresnel surface reflection.

Yu, Chung↗
NASA NTRS1991

Data space volumes and classification optimization of SPOT and Landsat TM data

In order to compare the data space volume of SPOT XS and Landsat TM images, three data sets, i.e., a wetlands/agricultural data set, an agricultural data set, and a forest data set, are examined. The comparisons are made for the same geographic area. The data space volumes for Landsat TM (2, 3, and 4) are found to be 70 to 100 percent larger than the volumes for the SPOT XS images. It is suggested that the additional midinfrared bands contribute to the difference in data space volumes between Landsat TM and SPOT XS. The data space volumes for Landsat TM bands 3, 4, and 5 are more than an order of magnitude greater than the volumes for the three band SPOT XS data sets. The volumes of the six-band Landsat TM images are four orders of magnitude greater than the SPOT XS. The analysis of the data space volumes is used to optimize the computation time and minimize the storage requirements of a maximum-likelihood classification based on a look-up table.

Ahearn, Sean C.↗
NASA NTRS1991

Satellite remote sensing of surface energy and mass balance - Results from FIFE

Results obtained from the FIFE experiments conducted in 1987 and 1989 are summarized. Data analyses indicate that the hypotheses linking energy balance components to surface biology and remote sensing are reasonable at a point level, and that satellite remote sensing can potentially provide useful estimates of the surface energy budget. An investigation of atmospheric scattering and absorption effects on satellite remote sensing of surface radiance shows that the magnitude of atmospheric opacity variations within the FIFE site and with season can have a large effect on satellite measured values of surface radiances. Comparisons of atmospherically corrected TM radiances with surface measured radiances agreed to within about two percent at the visible and near-infrared wavelengths and to 6 percent in the midinfrared.

Hall, F. G.↗
NASA NTRS1991

The particle size of Martian aeolian dunes

The effective particle size of unconsolidated materials on the Martian surface can be determined from thermal inertia, due to a pore size dependence of thermal conductivity at Martian atmospheric pressures. Because dunes consist of a narrow range of well-sorted, unconsolidated particles, they provide for a test of the relationship between particle size and thermal inertia calculated from midinfrared emission data for the Martian surface. Two independent approaches are used. First, thermal inertia data indicate that Martian dunes have an average particle size of about 500 +/-100 microns, or medium to coarse sand. Second, expected dune particle sizes are determined from grain trajectory calculations and the particle size transition from suspension to saltation. On earth, the transition occurs for a grain when the ratio of the terminal fall velocity to the wind friction speed, u*(t) is near unity; for grains at u*(t) this occurs at about 52 microns. Terrrestrial dune sands have a mean of 250 microns and are composed entirely of grains greater than 52 microns. The corresponding Martian transition grain size is about 210 microns, suggesting that Martian dunes should be significantly coarser than terrestrial dunes. Grain saltation path length as a function of particle size also shows that, under Martian conditions, larger grains than on earth will become suspended. Both approaches indicate that Martian dune sand should be coarser than terrestrial dune sand. These results closely match the grain sizes determined from thermal inertia models, providing the first direct test of the validity of these models for actual Martian surface materials.

Edgett, Kenneth S.↗
NASA NTRS1992

High-resolution 12.4 micron images of the starburst region in M82

We present 12.4 micron images, made with 1" resolution, of the intense star-forming region in the galaxy M82. Considerable small-scale structure is evident, including several bright clumps less than about 20 pc in size which may be embedded with giant star clusters more massive than 3 x 100,000 solar mass. No correlation is seen between the infrared emission and the bright radio/X-ray point sources which are thought to be very young supernova remnants. We propose that high values of the ratio of nonthermal and infrared emission near the nucleus, and of the ratio LIR/LCO at one of the starburst lobes, can be attributed to disruption of the central region by supernova activity. However, we argue that the midinfrared-emitting dust is heated by young stars and not, as recently proposed, by supernova shocks.

Telesco, C. M.↗
NASA NTRS1995

Low-temperature and low atmospheric pressure infrared reflectance spectroscopy of Mars soil analog materials

Infrared reflectance spectra of carefully selected Mars soil analog materials have been measured under low atmospheric pressures and temperatures. Chemically altered montmorillonites containing ferrihydrite and hydrated ferric sulfate complexes are examined, as well as synthetic ferrihydrate and a palagonitic soil from Haleakala, Maui. Reflectance spectra of these analog materials exhibit subtle visible to near-infrared features, which are indicative of nanophase ferric oxides or oxyhydroxides and are similar to features observed in the spectra of the bright regions of Mars. Infrared reflectance spectra of these analogs include hydration features due to structural OH, bound H2O and adsorbed H2O. The spectal character of these hydration features is highly dependent on the sample environment and on the nature of the H2O/OH in the analogs. The behavior of the hydration features near 1.9 micrometers, 2.2 micrometers, 2.7 micrometers, 3 micrometers, and 6 micrometers are reported here in spetra measured under Marslike atmospheric environment. In spectra of these analogs measured under dry Earth atmospheric conditions the 1.9-micrometer band depth is 8-17%; this band is much stonger under moist conditions. Under Marslike atmospheric conditions the 1.9-micrometer feature is broad and barely discernible (1-3% band depth) in spectra of the ferrihydrite and palagonitic soil samples. In comparable spectra of the ferric sulfate-bearing montmorillonite the 1.9-micrometer feature is also broad, but stronger (6% band depth). In the low atmospheric pressure and temperature spectra of the ferrihydrite-bearing montmorillonite this feature is sharper than the other analogs and relatively stronger (6% band depth). Although the intensity of the 3- micrometer band is weaker in spectra of each of the analogs when measured under Marslike conditions, the 3-micromter band remains a dominant feature and is especially broad in spectra of the ferrihydrite and palagonitic soil. The structural OH features observed in these materials at 2.2-2.3 micrometers and 2.27 micrometers remain largely unaffected by the environmental conditions. A shift in the Christiansen feature towards shorter wavelengths has also been observed with decreasing atmospheric pressure and temperature in the midinfrared spectra of these samples.

Bishop, Janice L.↗
NASA NTRS1995

Thermal emission from particulate surfaces: A comparison of scattering models with measured spectra

Emissivity spectra of particulate mineral samples are highly dependent on particle size when that size is comparable to the wavelength of light emitted (5-50 micrometers for the midinfrared). Proper geologic interpretation of data from planetary infrared spectrometers will require that these particle size effects be well understood. To address this issue, samples of quartz powders were produced with narrow, well-characterized particle size distributions. Mean particle diameters in these samples ranged from 15 to 227 micrometers. Emission spectra of these powders allow the first detailed comparison of the complex spectral variations with particle size observed in laboratory data with the predictions of radiative transfer models. Four such models are considered here. Hapke's relectance theory (converted to emissivity via Kirchoff's law) is the first model tested. Hapke's more recently published emission theory is also employed. The third model, the 'Mie/Conel' model, uses Mie single scattering with a two-stream approximation for multiple scattering. This model, like the first, is a converted reflec- tance model. Mie scattering assumes particles are both spherical and well separated, which is not true for the quartz powders, but includes diffraction effects. The fourth model uses the Mie solution for single scattering by spheres and inputs those results into the multiple scattering formalism of Hapke's emission theory. The results of the four models are considered in relation to the values of the optical constants n and k. We have grouped these as class 1 (k large), class 2 (k moderate, n is approximately 2), class 3 (k small, n is approximately 2), and class 4 (k small, n is approximately 1). In general, the Mie/Hapke hybrid model does best at predicting variations with grain size. In particular, it predicts changes of the correct pattern, although incorrect magnitude, for class 1 bands, where large increases in emissivity with decreasing grain size are observed. This model also does an excellent job on moderate (class 2) and very weak and intraband (class 3) regions, and correctly predicts the emission maximum and its invariance with grain size near the Christiansen frequency (class 4). The Mie/Hapke hybrid model also has the fewest free parameters of the four models examined, while maintaining the most physical treatment of the radiative transfer. The Mie/Conel model performs as well as the Mie/Hapke hybrid model in strong bands (class 1) but does not accurately model the behavior of moderate (class 2) and very weak (class 3) bands.

Moersch, J. E.↗