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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Ultraviolet and optical spectroscopy of NGC 5548 and the nature of the broad-line region

The structure of the broad-line region in NGC 5548 is investigated by analysis of the integrated flux and profile variations observed in optical and ultraviolet emission lines. It is shown that the observations do not appear to be consistent with models which identify the variable part of the emission lines with a simple rotating disk structure. The variable continuum, and integrated emission-line fluxes are highly correlated and suggest a small broad-line region (18 light days = 5 x 10 to the 16th cm), although the size of the line-emitting region is not well-determined. At least some of the broad emission arises in a component which at times appears very prominently and distinctly in difference spectra. This emission component appears to arise in a region which is physically distinct from the rest of the broad-line region. Although the integrated fluxes in the various optical and ultraviolet emission lines seem to vary together, there clearly are differences between the profiles of various lines, which suggests that there is at least some ionization stratification within the broad-line region.

Peterson, Bradley M.↗
NASA NTRS1997

Modulated FT- Raman Fiber-Optic Spectroscopy: A technique for Remotely Monitoring High-Temperature Reactions in Real-Time

A modification to a commercial FT-Raman spectrometer is presented for the elimination of thermal backgrounds in FT-Raman spectra. The modification involves the use of a mechanical chopper to modulate the CW laser, remote collection of the signal via fiber optics, and connection of a dual-phase digital signal processor lock-in amplifier between the detector and the spectrometer's collection electronics to demodulate and filter the optical signals. The resulting modulated FT-Raman fiber-optic spectrometer is capable of completely eliminating thermal backgrounds at temperatures exceeding 370 C. In addition, the signal/noise of generated Raman spectra is greater than for spectra collected with the conventional FT-Raman under identical conditions and incident laser power. This is true for both room-temperature and hot samples. The method allows collection of data using preexisting spectrometer software. The total cost of the modification (excluding fiber optics) is approximately $3000 and requires less than 2 h to implement. This is the first report of Fr-Raman spectra collected at temperatures in excess of 300 C in the absence of thermal backgrounds.

Cooper, John B.↗
NASA NTRS1991

Ultraviolet and optical spectroscopy of the R Aquarii symmetrical jet

The first ultraviolet spectrum of the southwest (SW) component of the symmetrical jet in the R Aquarii binary system has been obtained in the range 1200-2000 A with the IUE. These results are compared to more encompassing spectra of the central H II region taken at the same time and also similar spectra of the northeast (NE) jet component obtained six months earlier. Moreover, optical spectra of both the NE and SW jet components in the range 3400-9800 A were obtained within about 6 months and about 1 month, respectively, of the ultraviolet spectra. These highly complementary observations argue that excitation of the symmetrical jet may be due to shock excitation as the jet components overtake and impact the previously ionized material associated with the expanding inner nebulosity. The problems with this shock model as well as problems with competing photoionization models are discussed. It is suggested that the jet components were ejected less than 90 years ago.

Hollis, J. M.↗
NASA NTRS1993

Optical spectroscopy of a highly fluorescent aggregate of bacteriochlorophyll c

Bacteriochlorophyll (BChl) c and a similar model compound, Mg-methyl bacteriopheophorbide d, form several types of aggregates in nonpolar solvents. One of these aggregates is highly fluorescent, with a quantum yield higher than that of the monomer. This aggregate is also unusual in that it shows a rise time in its fluorescence emission decay at certain wavelengths, which is ascribed to a change in conformation of the aggregate. An analysis of fluorescence depolarization data is consistent with either a linear aggregate of four or five monomers or preferably a cyclic arrangement of three dimers.

NASA Discipline Exobiology↗
DOE OSTI2025

Investigating Np(VI) Nitrate Speciation Control through Temperature and Optical Spectroscopy

Numerous areas of nuclear processing, such as radioisotope production, nuclear waste remediation, and separations, depend upon the speciation of f-elements in the solution state. However, fundamental knowledge of the actinides─particularly Np─lags behind most of the elements on the periodic table. Despite the importance of Np(VI) chemistry in separations and nuclear processing, its speciation in HNO 3 remains uncertain. This work addresses some of these gaps by investigating the effect of HNO 3 concentration and temperature on the spectra and speciation of the Np(VI) nitrate system. Six samples of Np in 1 to 10 M HNO 3 were prepared and treated with (NH 4 ) 2 [Ce(NO 3 ) 6 ] to stabilize the hexavalent oxidation state. The absorbance spectrum of the 10 M HNO 3 is drastically different from the spectra of the other samples; the 10 M spectrum indicates coordination of nitrate ligands to the Np(VI)O 2 2+ ion to form a complex with high symmetry. Additionally, absorbance spectra were recorded over the temperature range of 15 to 40 °C, and systematic increases and decreases in certain spectral features of the ultraviolet–visible (UV–vis)–near-infrared (NIR) spectra are present in the spectra. The difference in spectral features suggests that Np(VI) nitrate speciation depends on temperature. Dilution studies of this sample were monitored with UV–vis–NIR and Raman spectroscopies. Spectral data indicate the presence of multiple complexes with different symmetries, including a high-symmetry complex with an inversion center. As samples are diluted and aquo ligands replace nitrate ligands bound to the Np(VI) neptunyl cation, changes in spectroscopic signals indicate a decrease in the high-symmetry nitrate complex and an increase in the lower-symmetry aquo complex. Additionally, the Raman band associated with the Np(VI)O 2 2+ symmetric stretch broadens with dilution and is fitted with two peaks. These peaks are assigned to Np(VI) aquo and nitrato complexes, indicating that this vibrational mode is sensitive to the coordination environment of the Np(VI) neptunyl cation and that contributions from these two Np(VI) complexes can be distinguished. This unique experimental data could be used to advance computational models describing the electronic transitions of complex actinyl ions.

Absorption↗
NASA NTRS1978

Optical spectroscopy of BL Lacertae objects and their relatives

Absorption lines from intervening gas along the line of sight to BL Lac objects are examined. The absorption line systems observed in several such objects are discussed, and detailed attention is given to the objects PKS 0735+178 and AO 0235+164. Random observations relevant to the nature of BL Lac objects are reviewed, including observations of steep-spectrum 3C QSOs and the peculiar object PKS 0528-250. The nature of the absorbing material is considered.

Smith, H. E.↗
NASA NTRS1984

Optical matching for fiber optic spectroscopy

Single silica fibers of the type developed for communications are useful in the design of astronomical spectrographs. They can be used to couple light from many objects over a wide field to a single spectrograph, or to eliminate wavelength errors from image motion and gravitational flexure. For many applications it will be advantageous to use small lenses to make the most efficient coupling into and out of a fiber. If the telescope pupil is imaged on the fiber core, an efficient coupling can be made that preserves image size over a certain range. This method is demonstrated by a laboratory test using sapphire spheres as coupling lenses.

Hill, J. M.↗
NASA NTRS1995

Optical spectroscopy of carbon-rich proto-planetary nebulae

In this paper, we present a medium-resolution (3 A) spectroscopic study of six proto-planetary nebulae (PPN), post-asymptotic giant branch (AGB) objects with large infrared excesses. All six are found to display the spectra of G supergiants. However, they also show molecular carbon features, C2 and in most cases C3, and strong absorption lines due to s-process elements. Other evidences of a carbon-rich nature are found in published molecular-line millimeter emissions (CO and HCN) and 3.3 micrometer features attributed to polycyclic aromatic hydrocarbons. These properties are all in accord with what one would expect in a post-AGB star in which carbon-rich materials formed in thermal pulses is dredged up to the surface of a mass-losing object. A correlation is found between the presence of molecular C2 absorption and the presence of the unidentified 21 micrometer emission feature. This strengthens the suggestion that carbon is a major component of the molecule producing this unidentified feature. Four additional proto-planetary nebulae which share some of these properties are also discussed.

Hrivnak, Bruce J.↗
NASA NTRS2004

FUV and Optical Spectroscopy of Hot Post-AGB Stars in Globular Clusters

The goal of this program was to determine the atmospheric parameters (effective temperature and surface gravity) and abundances of the hot, post-AGB (PAGB) stars in globular clusters observed with the Hopkins Ultraviolet Telescope (HUT) on the Astro-l and 2 missions.

Dixon, William V.↗
NASA NTRS2006

Optical Spectroscopy of Stardust Samples

The Stardust spacecraft collected dust samples of the Kuiper belt comet 81P Wild-2 in aerogel and returned them to Earth January 15, 2006. Preliminary examination (PE) of the collected dust includes teams focused on mineralogy, chemical composition, isotopic measurements, organic analysis, cratering and spectroscopic properties. The main PE science goals are to provide an initial characterization of the returned samples with an emphasis on the capture process and its effects on the samples, a comparison of Stardust samples to other meteoritic materials, and the abundance of presolar materials in the Stardust samples. The science objectives of the Spectroscopy team are to obtain spectroscopic data on Stardust particles through infrared (IR), UV/Vis and Raman measurements of particles in aerogel, extracted particles, keystones, and microtome thin sections. These data will be used to answer fundamental science questions about the nature of the samples, but will also serve as preliminary mineralogical data to guide follow-on measurements that will be performed in the other preliminary examination teams. The IR characteristics of Stardust particles are measured to determine: 1) the nature of the indigenous 3.4 micron organic feature, is it detected and can it be differentiated/deconvolved from the contaminated aerogel? How does it compare to features observed in interplanetary dust particles (IDPs) and to astronomical measurements of comets and interstellar dust? 2) the shape and fine structure within the 10 micron silicate feature. Overlap with the strong Si-O stretching vibration from the aerogel complicates this analysis, but we hope to determine if the feature is dominated by amorphous silicates such as those observed in IDPs and comets and whether or not crystalline silicates (e.g. olivine, pyroxene, clays) are present, 3) the presence of secondary (alteration) phases. Deep Impact results suggest that IR observations of Stardust particles should be evaluated for the presence of hydrated materials (water bands at 3 and 6 microns) and carbonates (6.8 microns and other resonances) and 4) the detection of crystalline features in the far-IR (20-100 microns) region where crystalline silicates and other minerals have strong bands that can be used both for phase analysis and phase chemistry. It has been demonstrated that these far-IR measurements can be obtained in situ on particles in aerogel keystones.

Keller, Lindsay P.↗
NASA NTRS1998

Optical Spectroscopy of V635 Cassiopeiae/4U 0115+63

In this paper we present two data sets that can be used to constrain the physical and geometric models for the circumstellar disk. The companion's spectral type is a critical parameter for modelling the disk.

stars circumstellar matter emission line binary ne↗