Auxiliary electrode charge control.
Signal electrode charge control of sealed Ni-Cd batteries, discussing signal voltage for overcharge control
Ford, F. E.↗
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Evaluation program for secondary spacecraft cells - Acceptance test of General Electric Company 6.0 ampere hour nickel cadmium cells /ceramic seals with nickel braze/
Acceptance tests including capacity, cell short, high vacuum leak, overcharge, and internal resistance of nickel-cadmium secondary cells with nickel braze ceramic seals for spacecraft
Thomas, R. E.↗
Study of process variables associated with manufacturing hermetically sealed nickel-cadmium cells
Formation time, specific gravity of solution, and overcharge amount associated with electrochemical cleaning or formation operation in manufacturing nickel cadmium cells
Miller, L.↗
Evaluation program for secondary spacecraft cells: Acceptance tests of Eagle-Picher 12.0 ampere-hour nickel-cadmium cells with auxiliary electrodes
An acceptance test program was conducted on 24 cells to insure that all cells put into the life cycle program were of high quality by the removal of cells found to have electrolyte leakage, internal shorts, low capacity, or inability of any cell to recover its open circuit voltage above 1.150 volts after the cell short test. The cells were rated at 12.0 ampere-hours and equipped with auxiliary electrodes. Test results were: (1) The capacity of the 24 cells ranged from 14.6 to 16.8 ah. All the cells exceeded the rated capacity on all three capacity checks. (2) One cell failed to recover to 1.150 volts after the cell short test. (3) During the overcharge tests, all cells but one failed the test at the c/10 rate after the first minute. (4) A special resistance test was conducted on the auxiliary electrodes of these cells to establish the resistance value necessary which would provide maximum signal power across the auxiliary electrode. The resistance value established was 10 ohms. (5) No electrolyte leakage was observed.
Christy, D. E.↗
Development of uniform and predictable battery materials for nickel-cadmium aerospace cells
Battery materials and manufacturing methods were analyzed with the aim of developing uniform and predictable battery plates for nickel cadmium aerospace cells. A study is presented for the high temperature electrochemical impregnation process for the preparation of nickel cadmium battery plates. This comparative study is set up as a factorially designed experiment to examine both manufacturing and operational variables and any interaction that might exist between them. The manufacturing variables in the factorial design include plaque preparative method, plaque porosity and thickness, impregnation method, and loading, The operational variables are type of duty cycle, charge and discharge rate, extent of overcharge, and depth of discharge.
Source record↗
Evaluation program for secondary spacecraft cells: Acceptance test of Eagle-Picher 100 ampere-hour nickel-cadmium cells with auxiliary electrodes
Tests were conducted on a group of 29 cells for the purpose of removing from the life cycle program all cells found to have electrolyte leakage, internal shorts, low capacity, or inability to recover open circuit voltage above 1.150 volts after the cell short test. The test findings include the following: (1) All the cells exceeded the rated capacity of 103.5 to 119.0 ampere-hours on all three capacity checks. (2) All cells recovered above the 1.150 volt requirement after the cell short test. (3) The cells cannot be overcharged at the c/10 rate without exceeding 1.500 volts after approximately 12 to 13 hours of charge. (4) The resistance value necessary to provide maximum signal power across the auxiliary electrode was found to be 10 ohms. (5) One cell revealed a definite leak at the negative terminal.
Christy, D. E.↗
Evaluation program for secondary spacecraft cells: Acceptance tests of Eagle-Picher 20.0 ampere-hour nickel-cadmium cells with auxiliary electrodes
A group of 29 cells with capacities ranging from 21.7 to 28.8 ampere-hours were tested. A summary of the results indicates: (1) All cells exceeded the rated capacity on all three capacity checks. (2) Five cells failed to recover to 1.150 volts. (3) During the overcharge tests, 15 of the 29 cells had to be removed from charge before completion of the respective tests due to high pressure.
Christy, D. E.↗
The electrical power subsystem of the Pioneer F/G spacecraft.
The Pioneer F/G spacecraft is the first to use radioisotope thermoelectric generators (RTG's) for a long duration interplanetary mission. This paper describes the design of the spacecraft power subsystem which meets the unique requirements of such a mission. The primary power source consists of four SNAP 19 RTG's. The 4.2 volt dc outputs of the RTG's are inverted to higher voltage ac by four inverters which are connected in parallel at their outputs. A power control unit (PCU) regulates the ac output of the inverters such that the RTG's are operated at near maximum power voltage throughout the mission. The PCU also contains charge and discharge controls for a silver cadmium battery which supplements the RTG's if load requirements temporarily exceed RTG power output. Battery reliability is enhanced by overcharge and cell reversal protection electronics which are provided for each cell. Multiple, low voltage, regulated dc outputs which supply power to the spacecraft subsystems are provided by a central transformer-rectifier-filter unit (CTRF). The CTRF operates directly from the regulated ac bus.
Reppucci, G. M.↗
The Atmosphere Explorer power subsystem
The design and operation of the power subsystem for the Atmospheric Explorer spacecraft are discussed. The additional functional redundancy which was added in several component areas to improve the overall subsystem reliability is analyzed. The battery charging technique has been modified to include third electrode overcharge control. The automatic removal of all battery charge is provided to correct abnormally high battery voltages. An undervoltage detector has been added which removes all nonessential spacecraft loads when the battery voltage falls below a given level. All automatic functions can be over-ridden by ground command.
Obenschain, A.↗
Evaluation program for secondary spacecraft cells: Initial evaluation tests of General Electric Company 12.0 ampere-hour, nickel-cadmium spacecraft cells for the international ultraviolet Explorer satellite
Evaluation tests are reported for 20 cells to be put into the life cycle program. Leak, capacity, internal resistance, internal short, and overcharge tests are described.
Harkness, J. D.↗
Fabrication and testing of negative limited sealed nickel-cadmium cells
A number of 20 Ah and 3 Ah negative limited nickel-cadmium cells were fabricated and assembled in hermetically sealed stainless steel containers. The cells exhibit a large voltage rise signal, in excess of 250 mA, at the end of each charge period. They also exhibit lower self discharge rates than conventional sealed nickel-cadmium cells and do not require overcharge. The cells are capable of operating at charge and discharge rates up to 5C and can deliver at least 1000 cycles on a 30 minute regime at 25% DOD. A small amount of gassing occurs, but is not deemed critical or detrimental in view of the facts that, (1) operating pressures are in the range of 7 to 20 psig and (2) the cells are operated in the flooded condition so therefore contain little internal void volume. The cells were found to exhibit somewhat higher capacity loss rates during cycling than conventional sealed nickel-cadmium batteries.
Gordy, D. J.↗
Development of single cell protectors for sealed silver-zinc cells, phase 1
A single cell protector (SCP) assembly capable of protecting a single silver-zinc (Ag Zn) battery cell was designed, fabricated, and tested. The SCP provides cell-level protection against overcharge and overdischarge by a bypass circuit. The bypass circuit consists of a magnetic-latching relay that is controlled by the high and low-voltage limit comparators. Although designed specifically for secondary Ag-Zn cells, the SCP is flexible enough to be adapted to other rechargeable cells. Eighteen SCPs were used in life testing of an 18-cell battery. The cells were sealed Ag-Zn system with inorganic separators. For comparison, another 18-cell battery was subjected to identical life test conditions, but with battery-level protection rather than cell-level. An alternative approach to the SCP design in the form of a microprocessor-based system was conceptually designed. The comparison of SCP and microprocessor approaches is also presented and a preferred approach for Ag-Zn battery protection is discussed.
Imamura, M. S.↗
Multiplexed battery-bypass control system
Cell-bypass control system senses low capacity cells before they overcharge or discharge. Relay automatically removes defective cell (when it is detected) from battery circuit. System shows promise for improving batteries in computer standby power systems, electric vehicles, and energy storage systems.
Bennett, J. C.↗
Initial evaluation tests of Eagle-Picher Industries 9.0 ampere-hour nickel-cadmium spacecraft cells for the heat capacity mapping mission satellite and the stratospheric aerosol and gas experiment satellite
The results of tests to insure that all cells put into the life cycle program are of high quality are reported. The tests consisted of the following: phenolptalein leak tests, internal short test, charge efficiency test, and overcharge tests. The results of tests for 10 cells are tabulated.
Harkness, J. D.↗
Storage effects on cells
The results of an experiment to test storage effects on electric cells of a battery are presented and discussed. The type of cells were the 20 amp-hour OAO type. The various modes that were tested were the integration type mode, the trickle charge, the discharge shorted and the discharged OCV (open current voltage). Every six months the cells were reconditioned and approximately two weeks of tests were performed. The tests included three capacity checks, two zero-degree overcharge tests and an internal short test (the cells are shunted for 16 hours, the shunt removed and allowed to stand on local circuit recovery for 24 hours). The integration pack was discontinued after three years and the trickle charge shorted packs after five years.
Harkness, J. M.↗
The characteristics of sealed nickel-cadmium cells during voltage reversal
A mechanism which allows a cell voltage reversal in a nickel cadmium battery are discussed. The effects of reconditioning and the characteristics of Ni-Cd cells during voltage reversal at low overdischarge rates are outlined. Graphs are presented for: (1) hydrogen pressure decay-effect of state of charge (open circuit stand); (2) hydrogen pressure increase during overdischarge; (3) hydrogen pressure decay-effect of temperature (cells terminals connected through resistors); (4) cell, positive and negative electrode voltage during reversal when reconditioning a 13 cell-24-Ah battery pack through a 40 Omega resistor; (5) pressure discharge current and recombination current during voltage reversal when reconditioning a 13 cell-24-Ah battery pack through a 40 Omega resistor; (6) theoretical hydrogen gas pressure if there were no recombination; and (7) effect of hydrogen pressure on recombination rate during overcharge.
Ritterman, P. F.↗
Evaluation of positive plates with various loading levels
The effects of overcharge and total cycling rate on one electrochemically impregnated and four chemically impregnated nickel electrodes are examined. Topics discussed include porosity distribution, electrode corrosion, electrolyte absorption and positive electrode involvement in the decrease in the amount of electrolyte in the separator. The electrochemically impregnated electrode is shown to be superior to all types of conventionally impregnated electrodes regardless of the loading level.
Vanommering, G.↗
Microprocessor controlled advanced battery management systems
The advanced battery management system described uses the capabilities of an on-board microprocessor to: (1) monitor the state of the battery on a cell by cell basis; (2) compute the state of charge of each cell; (3) protect each cell from reversal; (4) prevent overcharge on each individual cell; and (5) control dual rate reconditioning to zero volts per cell.
W. T. Payne↗