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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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44 records · Page 3

Phase Change Material Heat Sink for an ISS Flight Experiment

A flight experiment is being constructed to utilize the persistent microgravity environment of the International Space Station (ISS) to prove out operation of a microgravity compatible phase change material (PCM) heat sink. A PCM heat sink can help to reduce the overall mass and volume of future exploration spacecraft thermal control systems (TCS). The program is characterizing a new PCM heat sink that incorporates a novel phase management approach to prevent high pressures and structural deformation that often occur with PCM heat sinks undergoing cyclic operation in microgravity. The PCM unit was made using brazed aluminum construction with paraffin wax as the fusible material. It is designed to be installed into a propylene glycol and water cooling loop, with scaling consistent with the conceptual designs for the Orion Multipurpose Crew Vehicle. This paper reports on the construction of the PCM heat sink and on initial ground test results conducted at UTC Aerospace Systems prior to delivery to NASA. The prototype will be tested later on the ground and in orbit via a self‐contained experiment package developed by NASA Johnson Space Center to operate in an ISS EXPRESS rack.

Quinn, Gregory↗

Using Paraffin with -10 deg C to 10 deg C Melting Point for Payload Thermal Energy Storage in SpaceX Dragon Trunk

A concept of using paraffin wax phase change material (PCM) with a melting point between -10 deg C and 10 deg C for payload thermal energy storage in a Space Exploration Technologies (SpaceX) Dragon trunk is presented. It overcomes the problem of limited heater power available to a payload with significant radiators when the Dragon is berthed to the International Space Station (ISS). It stores adequate thermal energy to keep a payload warm without power for 6 hours during the transfer from the Dragon to an ExPRESS logistics carrier (ELC) on the ISS.

Choi, Michael K.↗

Development and Validation of Resistance-Capacitance Model (RCM) for Phase Change Material (PCM) Embedded in 3D Periodic Structures

The low thermal conductivity of Phase Change Materials (PCM) can be improved with extended surfaces such as additively manufactured 3D periodic lattice structures. Three different aluminum alloy-based lattices (base sizes 10, 20, and 40 mm) with average porosity of 0.95 filled with paraffin wax, with a nominal phase change temperature of 55°C, were experimentally investigated. In this work, a computationally efficient 2D Resistance Capacitance-based model (RCM) was developed for predicting the thermal characteristics of these geometries. Non-uniform porosity in the PCM-metal domain was estimated using image processing and served as model input. The solver does not solve for higher-order physics as in CFD but still can provide a good prediction of thermal resistance and energy storage at a very low computational cost. The simulation-to-real-time factor for this geometry is of the order of 10-4, while CFD simulations typically have a real-time factor greater than 1. The model was validated against the experimental data for melting under three different heat fluxes (6250 W/m2, 12500 W/m2, and 18750 W/m2). The mean deviation of the predicted average PCM temperature was between 1.34 K-2.81 K for different cases. The maximum average temperature deviation of 5.45 K was observed for the 20 mm geometry at the highest heat flux test condition. The effects of natural convection were neglected in the model, but the predicted PCM temperature and energy storage still showed good agreement with the experimental data.

25 ENERGY STORAGE↗

Critical transverse compressive stresses of straight and bent CORC® wires with and without impregnation

CORC® wires are a promising superconductor for accelerator magnet applications. While their excellent uniaxial tensile properties have been well established, potential degradation under transverse compression remains a concern for accelerator magnets, in which transverse compression is a primary stress experienced by superconductors. To evaluate the critical transverse compressive stresses of rare-earth barium copper oxide conductors, we developed an experimental system that enables testing of samples both with and without impregnation in liquid nitrogen. Furthermore, because bending strain induced during coil winding may influence the critical compressive response of CORC® wires, the apparatus was also modified to allow testing under the bending condition. In this study wires were tested for five configurations: (1) straight, non-impregnated, (2) bent, non-impregnated, (3) straight, Stycast 2850 FT-impregnated, (4) bent, Stycast 2850 FT-impregnated, and (5) bent, paraffin wax-impregnated. The transverse pressures corresponding to 3% and 5% reductions in the critical current are reported. In conclusion, the effects of wire bending and impregnation on the critical transverse pressure are analyzed, and the implications for transverse stress levels in accelerator magnet conductors are discussed.

CORC® wire↗

Improved ceramic slip casting technique

A primary concern in modern fluid dynamics research is the experimental verification of computational aerothermodynamic codes. This research requires high precision and detail in the test model employed. Ceramic materials are used for these models because of their low heat conductivity and their survivability at high temperatures. To fabricate such models, slip casting techniques were developed to provide net-form, precision casting capability for high-purity ceramic materials in aqueous solutions. In previous slip casting techniques, block, or flask molds made of plaster-of-paris were used to draw liquid from the slip material. Upon setting, parts were removed from the flask mold and cured in a kiln at high temperatures. Casting detail was usually limited with this technique -- detailed parts were frequently damaged upon separation from the flask mold, as the molded parts are extremely delicate in the uncured state, and the flask mold is inflexible. Ceramic surfaces were also marred by 'parting lines' caused by mold separation. This adversely affected the aerodynamic surface quality of the model as well. (Parting lines are invariably necessary on or near the leading edges of wings, nosetips, and fins for mold separation. These areas are also critical for flow boundary layer control.) Parting agents used in the casting process also affected surface quality. These agents eventually soaked into the mold, the model, or flaked off when releasing the case model. Different materials were tried, such as oils, paraffin, and even an algae. The algae released best, but some of it remained on the model and imparted an uneven texture and discoloration on the model surface when cured. According to the present invention, a wax pattern for a shell mold is provided, and an aqueous mixture of a calcium sulfate-bonded investment material is applied as a coating to the wax pattern. The coated wax pattern is then dried, followed by curing to vaporize the wax pattern and leave a shell mold of the calcium sulfate-bonded investment material. The shell mold is cooled to room temperature, and a ceramic slip is poured therein. After a ceramic shell of desired thickness has set up in the shell mold, excess ceramic slip is poured out. While still wet, the shell mold is peeled from the ceramic shell to expose any delicate or detailed parts, after which the ceramic shell is cured to provide a complete, detailed, precision ceramic article without parting lines.

Buck, Gregory M.↗

Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins

Catalytic hydrogenolysis of polyolefins into valuable liquid, oil, or wax-like hydrocarbon chains for second-life applications is typically accompanied by the hydrogen-wasting co-formation of low value volatiles, notably methane, that increase greenhouse gas emissions. Catalytic sites confined at the bottom of mesoporous wells, under conditions in which the pore exerts the greatest influence over the mechanism, are capable of producing less gases than unconfined sites. A new architecture was designed to emphasize this pore effect, with the active platinum nanoparticles embedded between linear, hexagonal mesoporous silica and gyroidal cubic MCM-48 silica (mSiO 2 /Pt/MCM-48). This catalyst deconstructs polyolefins selectively into ~C 20 –C 40 paraffins and cleaves C–C bonds at a rate (TOF = 4.2 ± 0.3 s –1 ) exceeding that of materials lacking these combined features while generating negligible volatile side products including methane. The time-independent product distribution is consistent with a processive mechanism for polymer deconstruction. In contrast to time- and polymer length-dependent products obtained from non-porous catalysts, mSiO 2 /Pt/MCM-48 yields a C 28 -centered Gaussian distribution of waxy hydrocarbons from polyolefins of varying molecular weight, composition, and physical properties, including low-density polyethylene, isotactic polypropylene, ultrahigh-molecular-weight polyethylene, and mixtures of multiple, post-industrial polyolefins. Here, coarse-grained simulation reveals that the porous-core architecture enables the paraffins to diffuse away from the active platinum site, preventing secondary reactions that produce gases.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Hybrid Propulsion In-Situ Resource Utilization Test Facility Results for Performance Characterization

Hybrid propulsion presents a promising alternative to conventional systems for in-space propulsion applications using In-Situ Propellant Production (ISPP). A hybrid propulsion test facility has been built at the NASA Jet Propulsion Laboratory (JPL) with the capability of evaluating ISPP oxidizers (gaseous mixtures of O2 and CO2) and modifying fuel type and chamber geometry. This work is the result of a continuing e ort at JPL to characterize the burn characteristics and performance of different propellant combinations and motor configurations in order to re ne and support preliminary designs. Twelve tests using gaseous oxygen and two paraffin based fuels (Black Paraffin and SP1X) from the 2015 campaign are presented. Different reduction techniques are compared in an e ort to determine the uncertainty associated with deriving a regression rate law and evaluating c* efficiency with the collected data.Hybrid motors are mechanically and chemically simple propulsion systems that have the potential forlong-term storability with low gross mass. The oxidizer (such as gaseous O2) can be produced in-situ,signicantly reducing the landed mass. The solid, inert fuel is stored in the combustion chamber in its most dense state, further reducing the total structural mass and volume. Considerable eorts have been focusedon ISPP for Environmental Control and Life Support Systems (ECLSS) and human exploration of Mars.At optimum oxidizer to fuel ratio (O/F), about 70% of the total propellant mass could be produced in-situ.Paran based fuels exhibit a fast regression rate behavior due to the formation of a thin liquid layer on thefuel surface.1 A high burn rate is necessary in order to reach a medium to high thrust range. In order toachieve an O/F ratio close to optimum performance (between 2.1 and 2.7 for the O2/Paran combination),the fuel mass ow needs to be suciently large compared to the oxidizer ow. The slow regression rateof classical hybrid rocket fuels leads to long fuel grain designs or complicated multi-port structures. Singleport, high regression rate fuels have the potential to reduce residual propellant mass and have a grainlength to diameter ratio (L/D) more favorable for packaging. However, hybrid motors remain at a fairly lowTechnology Readiness Level (TRL), and solutions to accurately measure and increase performance are stilllacking, especially for small-scale motors that are constrained to tight packaging.A total of 12 hotres were performed and analyzed in this campaign. All of these tests were conductedat pressures above the critical pressure of paran wax, approximately 6.7 bar (97 psi).2 Three dierentmotor congurations were explored while conserving a single cylindrical port fuel grain. Additionally, sincethrottling is a crucial advantage of hybrid rocket propulsion systems, low oxidizer mass ows (60 - 100 g/s)and uxes (5 - 30 g/cm2/s) were investigated to determine the performance impact in this regime.

Mechentel, F. S.↗