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Lunar and Planetary Science XXXVI, Part 10

The Problem of Incomplete Mixing of Interstellar Components in the Solar Nebula: Very High Precision Isotopic Measurements with Isoprobes P and T. Finally: Presolar Graphite Grains Identified in Orgueil. Basaltic Ring Structures as an Analog for Ring Features in Athabasca Valles, Mars. Experimental Studies of the Water Sorption Properties of Mars-Relevant Porous Minerals and Sulfates. Silicon Isotope Ratio Variations in CAI Evaporation Residues Measured by Laser Ablation Multicollector ICPMS. Crater Count Chronology and Timing of Ridged Plains Emplacement at Schiaparelli Basin, Mars. Martian Valley Networks and Associated Fluvial Features as Seen by the Mars Express High Resolution Stereo Camera (HRSC). Fast-Turnoff Transient Electromagnetic (TEM) Field Study at the Mars Analog Site of Rio Tinto, Spain. Time Domain Electromagnetics for Mapping Mineralized and Deep Groundwater in Mars Analog Environments. Mineralogical and Seismological Models of the Lunar Mantle. Photometric Observations of Soils and Rocks at the Mars Exploration Rover Landing Sites. Thermal Infrared Spectral Deconvolution of Experimentally Shocked Basaltic Rocks Using Experimentally Shocked Plagioclase Endmembers.

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Estimating Mixing Heights Using Microwave Temperature Profiler

A paper describes the Microwave Temperature Profiler (MTP) for making measurements of the planetary boundary layer thermal structure data necessary for air quality forecasting as the Mixing Layer (ML) height determines the volume in which daytime pollution is primarily concentrated. This is the first time that an airborne temperature profiler has been used to measure the mixing layer height. Normally, this is done using a radar wind profiler, which is both noisy and large. The MTP was deployed during the Texas 2000 Air Quality Study (TexAQS-2000). An objective technique was developed and tested for estimating the ML height from the MTP vertical temperature profiles. In order to calibrate the technique and evaluate the usefulness of this approach, estimates from a variety of measurements during the TexAQS-2000 were compared. Estimates of ML height were used from radiosondes, radar wind profilers, an aerosol backscatter lidar, and in-situ aircraft measurements in addition to those from the MTP.

Nielson-Gammon, John↗

Silicon-On-Insulator (SOI) Devices and Mixed-Signal Circuits for Extreme Temperature Applications

Electronic systems in planetary exploration missions and in aerospace applications are expected to encounter extreme temperatures and wide thermal swings in their operational environments. Electronics designed for such applications must, therefore, be able to withstand exposure to extreme temperatures and to perform properly for the duration of the missions. Electronic parts based on silicon-on-insulator (SOI) technology are known, based on device structure, to provide faster switching, consume less power, and offer better radiation-tolerance compared to their silicon counterparts. They also exhibit reduced current leakage and are often tailored for high temperature operation. However, little is known about their performance at low temperature. The performance of several SOI devices and mixed-signal circuits was determined under extreme temperatures, cold-restart, and thermal cycling. The investigations were carried out to establish a baseline on the functionality and to determine suitability of these devices for use in space exploration missions under extreme temperatures. The experimental results obtained on selected SOI devices are presented and discussed in this paper.

Patterson, Richard↗

Buoyant production and consumption of turbulence kinetic energy in cloud-topped mixed layers

It is pointed out that studies of the entraining planetary boundary layer (PBL) have generally emphasized the role of buoyancy fluxes in driving entrainment. The buoyancy flux is proportional to the rate of conversion of the potential energy of the mean flow into the kinetic energy of the turbulence. It is not unusual for conversion to proceed in both directions simultaneously. This occurs, for instance, in both clear and cloudy convective mixed layers which are capped by inversions. A partitioning of the net conversion into positive parts, generating turbulence kinetic energy (TKE), and negative parts (TKE-consuming), would make it possible to include the positive part in the gross production rate, and closure would be achieved. Three different approaches to partitioning have been proposed. The present investigation is concerned with a comparison of the three partitioning theories. Particular attention is given to the cloud-topped mixed layer because in this case the differences between two partitioning approaches are most apparent.

Randall, D. A.↗

The covariance of temperature and ozone due to planetary-wave forcing

The cross-spectra of temperature and ozone mass mixing ratio at 42 km and 28 km has been determined for spring (1971) and summer (1971-2) over Christchurch, New Zealand (44 S, 172 E). The sources of data are the SCR and BUV experiments on Nimbus 4. The observed covariances are compared with a model in which the temperature and ozone perturbations are forced by an upward propagating planetary wave. The agreement between the observations and the model is reasonable. It is suggested that this cross-spectral method permits an estimate of the meridional gradient of ozone mass mixing ratio from measurements of the vertical profile of ozone mass mixing ratio at one location, supported by temperature profiles from at least two locations.

Fraser, G. J.↗

Infrared laboratory studies of synthetic planetary atmospheres

Research involving a test of multiplicative transmittance for mixed absorbing gases when their lines are broadened by H2 and He, which are constituents of the atmospheres of the major planets was conducted. The results indicate that the multiplicative law as originally formulated can be applied with confidence. The broadening of individual lines in the CO fundamental by various gases has been investigated. The results indicate that the ratio of the self-broadening ability of CO to the line-broadening ability of foreign gases is greater for lines in the band wings than for lines near the band center when the molecular mass of the broadener is less than that of CO. The results have been interpreted in terms of a phenomenological theory. Studies of the relative line broadening abilities of foreign gases have provided information that can be used to provide optical collision cross sections for individual lines in the CO fundamental.

Williams, D.↗

Ultraviolet photochemistry of cyanoacetylene: Application to Titan

Cyanoacetylene is believed to have had a central role in the formation of the pyrimidines essential for RNA synthesis leading to the origin of life on Earth. Cyanoacetylene has also been detected on Titan, Saturn's largest moon, and the only moon in the solar system that possesses a dense atmosphere. It is generally accepted that photochemistry plays a major role in the formation of the complex organic molecules and aerosols found in Titan's atmosphere. Because of its long wavelength absorption and low dissociation threshold it is expected that cyanoacetylene is an important part of these photochemical processes. Since cyanoacetylene would also have been subject to ultraviolet light in the atmosphere of early Earth, an investigation of cyanoacetylene photochemistry on Titan might lead to a better understanding of both the photochemical reactions occurring on primitive earth and the processes of chemical evolution as they occur in planetary atmospheres. The effects of irradiation wavelength, mixing with Titan's atmospheric gases, reducing the temperature and lowering cyanoacetylene partial pressures on product formation and polymer composition have been determined with the ultimate goal of understanding the chemical transformations taking place in Titan's atmosphere.

Clarke, D. W.↗

The rocket-ultraviolet spectrum and models of the planetary nebula NGC 7662

Ultraviolet spectral analysis of NGC 7662 has revealed a Balmer line distribution indicating a C/O ratio of unity. This abundance of carbon is characteristic of mixing between the central star and the outer envelope of the planetary nebula. A continuum spectrum is observed from the star and the nebula, radiating its energy via the two photon process through neutral hydrogen. Spectral lines were fitted to apply to the predictions of three models of the nebular structure. UV observations were compared with visible, IR, and radio observations.

Bohlin, R. C.↗

New isotopic clues to solar system formation

The presence of two new extinct nuclides Al-26 and Pd-107 with half lives of approximately one million years in the early solar system implies that there were nucleosynthetic activities involving a great many elements almost at the instant of solar system formation. Rate gas and oxygen isotopic abundance variations ('anomalies') relative to the 'cosmic' composition were observed in a variety of planetary objects, which indicates that isotopic heterogeneities caused by the incomplete mixing of distinct nucleosynthesis components permeate the entire solar system. These new results have major implications for cosmochronology, nucleosynthesis theory, star formation, planetary heating, and the genetic relationship between different planetary bodies

Lee, T.↗

Catching Constrains on the Parent Body Genesis of Mesosiderites and a Possible Link to HED (Howardite-Eucrite-Diogenite) Meteorites - A New Hope?

Mesosiderites (MES) are a group of enigmatic stony-iron meteorites exhibiting fragmental matrix breccias and irregular textures; e.g. [1-3]. Mesosiderites contain roughly equal volumes metal (Fe-Ni) and silicates often intimately mixed together (Fig.1). The silicates mostly consist of basaltic, gabbroic, and pyroxenitic components, and appear similar to eucrites and howardites; [4-8]. But unlike HEDs - and other differentiated parent body meteorite groups e.g. ureilites - mesosiderites contain high metal abundances. Several studies have been published to reveal the processes leading to the formation of mesosiderites and attempt to classifiy them [1], [2], [10-15]. Because the silicate inclusions in mesosiderites are often strongly metamorphosed after formation, it is difficult to assess the origin of the silicates and implications for the differentiation process of their parent body [15-17]. Several workers have advanced a formation hypothesis for the mesosiderites where an impact between differentiated bodies occurred prior to 4.47 Ga ago (e.g. [13,18], which could explain the possible incomplete dispersal of the colliding bodies due to their low cosmic ray exposure ages and their special thermal history. However, [13] discuss and favor the model for formation of mesosiderites with the collision of two differentiated bodies, along with disruption events and gravitational re-assembly. The mesosiderites have numerous gabbroid melt clasts with anomalous rare-earth- element (REE) - especially positive Eu - values [19, 20]. HEDs do not show the same. However, the heating mechanisms of both mesosiderites and HED's are puzzling. Mesosiderites are remarkable, they consist of a mix of basalts, which are only found on or near planetary surfaces and undifferentiated metal [1,2]. The probable model is that an asteroid containing a metallic magma impacted onto a second asteroid covered with basalt [18,21]. The mix was then buried under an insulating regolith, and cooled slowly. During cooling and at low temperatures the redox reactions continued to occur and proceed (J.T. Wasson; in pers. comm. 2015).

Eucrite↗

Effusion rate, length, and area relationships for some lava flows on Hawaii and Mount Etna with planetary implications

A model for the radiative cooling of thermally well mixed lava flows is presented and the relationship between effusion rate and length and area is analyzed. If radiative cooling is the prime mode of heat loss for a lava flow, one should expect to see a stronger correlation between the effusion rate and the plan area of the flow, than between effusion rate and just flow length. Different flows on a single volcano with differing initial temperatures, volatile content, and gross compositions should yield different areas for a given effusion rate. Likewise, a range of slopes for the relationship between effusion rate and flow area should result from comparisons between different volcanoes. As a test of these ideas, available data on the effusion rates, lengths, and areas of Hawaiian and Etnean flow is studied. It was found that: (1) the effusion rate/area correlation was statistically more significant than the correlation between effusion rate and length for four out of the five eruption episodes which met the necessary criteria of more than three individual flows with area, length, and effusion rate independently measured; (2) that there exists a minimum length and area for a given effusion rate, reflecting competition between overall characteristic proportionality between effusion rate and flow length, width, and area.

Pieri, D.↗

Lunar and Planetary Science XXXV: Lunar Sample Analysis

The titles in this section include: 1) Global Mixing as a Mechanism for Compositional Anomalies of Agglutinitic Glasses; 2) Electron Microscopy of Apollo 12 Glass Spherules; 3) 40Ar-39Ar Geochronology on Apollo 12 Regolith; 4) LSCC Apollo and Luna Soil Analyses: Update of Soil Evolution Model; 5) Planetary Regolith Microstructure: An Unexpected Opposition Effect Result; 6) Infrared Spectroscopy on a Microscopic Scale: Investigating the Technique of Microspectroscopy and Its Application to a Lunar Breccia; 7) The Most Reduced Rock from the Moon - Apollo 14 Basalt 14053: Extreme Reduction Entirely from a Re-Heating Event.

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Meteorological and air pollution modeling for an urban airport

Results are presented of numerical experiments modeling meteorology, multiple pollutant sources, and nonlinear photochemical reactions for the case of an airport in a large urban area with complex terrain. A planetary boundary-layer model which predicts the mixing depth and generates wind, moisture, and temperature fields was used; it utilizes only surface and synoptic boundary conditions as input data. A version of the Hecht-Seinfeld-Dodge chemical kinetics model is integrated with a new, rapid numerical technique; both the San Francisco Bay Area Air Quality Management District source inventory and the San Jose Airport aircraft inventory are utilized. The air quality model results are presented in contour plots; the combined results illustrate that the highly nonlinear interactions which are present require that the chemistry and meteorology be considered simultaneously to make a valid assessment of the effects of individual sources on regional air quality.

Swan, P. R.↗

Photochemistry of biogenic emissions over the Amazon forest

The boundary layer chemistry over the Amazon forest during the dry season is simulated with a photochemical model. Results are in good agreement with measurements of isoprene, NO, ozone, and organic acids. Photochemical reactions of biogenic isoprene and NOx can supply most of the ozone observed in the boundary layer. Production of ozone is very sensitive to the availability of NOx, but is insensitive to the isoprene source strength. High concentrations of total odd nitrogen (NOy) are predicted for the planetary boundary layer, about 1 ppb in the mixed layer and 0.75 ppb in the convective cloud layer. Most of the odd nitrogen is present as PAN-type species, which are removed by dry deposition to the forest. The observed daytime variations of isoprene are explained by a strong dependence of the isoprene emission flux on sun angle. Nighttime losses of isoprene exceed rates of reaction with NO3 and O3 and appear to reflect dry-deposition processes. The 24-hour averaged isoprene emission flux is calculated to be 38 mg/sq m per day. Photooxidation of isoprene could account for a large fraction of the CO enrichment observed in the boundary layer under unpolluted conditions and could constitute an important atmospheric source of formic acid, methacrylic acid, and pyruvic acid.

Jacob, Daniel J.↗

A Procedure to Simultaneously Determine the Calcium, Chromium, and Titanium Isotopic Compositions of Astromaterials

Many elements display both linear (mass-dependent) and non-linear (mass-independent) isotope anomalies (relative to a common reservoir). In early Solar System objects, with the exception of oxygen, mass-dependent isotope anomalies are most commonly thought to result from phase separation processes such as evaporation and condensation, whereas many mass-independent isotope anomalies likely reflect radiogenic ingrowth or incomplete mixing of presolar components in the proto-planetary disk. Coupling the isotopic characterization of multiple elements with differing volatilities in single objects may provide information regarding the location, source material, and/or processes involved in the formation of early Solar System solids. Here, we follow up on the work presented in, and detail new procedures developed to make high-precision multi-isotope measurements of Calcium, Chromium, and Titanium with small or limited amounts of sample using thermal ionization mass spectrometry and multi-collector ICP-MS, and characterize a suite of chondritic and terrestrial standards.

Tappa, M. J.↗

Impact melting and vaporization in planetary regoliths

The thermal phenomena attending high-velocity impact have profound effects on virtually every aspect of the physical, chemical, and optical evolution of planetary regoliths. Not only do impacts pulverize, redistribute, and mix the various components of a regolith, but they also fuse and vaporize them - changing crystalline material to glass, releasing trapped or implanted gases, and spreading vaporized products across the planet's surface, among many other things. Those wishing to understand the details of regolith evolution must incorporate the effects of impact into their approach to the problem. Derived from a more extensive contribution, a short summary of the thermal processes accompanying impact into planetary regoliths, with the immediate acknowledgment that it is neither exhaustive in its consideration of the existing literature nor exact in any of its treatments, is presented. The reader desiring more information is directed to the relevant papers cited at the end; should they fail to provide satisfaction, he or she is then heartily encouraged to attack the problem immediately.

Cintala, Mark J.↗

Entrainment and Optical Properties of an Elevated Canadian Forest Fire Plume Transported into the Planetary Boundary Layer near Washington, D.C.

Smoke and pollutants from Canadian forest fires were transported over the northeastern United States in July 2002. Lidar observations at the NASA Goddard Space Flight Center show the smoke from these fires arriving in an elevated plume that was subsequently mixed to the surface. Trajectory and three-dimensional model calculations confirm the origin of the smoke and show that it mixed to the surface after it was intercepted by the turbulent planetary boundary layer. Modeled smoke optical properties agreed well with aircraft and remote sensing observations provided coagulation of smoke particles was accounted for in the model. Our results have important implications for the long-range transport of pollutants and their subsequent entrainment to the surface, as well as the evolving optical properties of smoke from boreal forest fires.

Colarco, P. R.↗

On planetary nebulae as sources of carbon dust: Infrared emission from planetary nebulae of the galactic halo

Planetary nebulae of the galactic disk are generally seen to emit a thermal continuum due to dust grains heated by stellar and nebular photons. This continuum typically peaks between 25 and 60 micron m, so that the total power emitted by the dust is sampled well by the broad-band measurements made by IRAS. Researchers examine here the characteristics of the infrared emission from the four planetary nebulae which are believed on the basis of their low overall metallicities to belong to the halo population. These nebulae are of particular interest because they are the most metal-poor ionized nebulae known in our Galaxy, and offer the opportunity to probe possible dependences of the dust properties on nebular composition. Researchers present fluxes extracted from co-addition of the IRAS data, as well as ground-based near infrared measurements. Each of the four halo objects, including the planetary nebula in the globular cluster M15, is detected in at least one infrared band. Researchers compare the estimated infrared excesses of these nebulae (IRE, the ratio of measured infrared power to the power available in the form of resonantly-trapped Lyman alpha photons) to those of disk planetary nebulae with similar densities but more normal abundances. Three of the halo planetaries have IRE values similar to those of the disk nebulae, despite the fact that their Fe- and Si-peak gas phase abundances are factors of 10 to 100 lower. However, these halo nebulae have normal or elevated C/H ratios, due to nuclear processing and mixing in their red giant progenitors. Unlike the other halo planetaries, DDDM1 is deficient in carbon as well as in the other light metals. This nebula has a substantially lower IRE than the other halo planetaries, and may be truly dust efficient. Researchers suggest that the deficiency is due to a lack of the raw material for producing carbon-based grains, and that the main bulk constituent of the dust in these planetary nebulae is carbon.

Dinerstein, Harriet L.↗