Results for “plasma crystals” — Page 3

NASA NTRS1993

Thermal spray forming of refractory sample ampoule cartridges for single crystal growth space furnaces

A thermal spray process is being used to build up refractory metals and ceramics into a containment cartridge for high temperature, single crystal semiconductor growth experiments. This process uses high energy plasma inside a low pressure (100-200 torr) inert environment to apply layers of material onto a removable mandrel. A variety of materials are being characterized and evaluated against a demanding set of requirements, including high service temperature (1700 C), oxidation resistance, and resistance to liquid metal attack. Techniques to spray form refractory metals (tungsten, molybdenum, niobium, tantalum) and ceramics (alumina, boron nitride) are being developed in the Plasma Spray Cell at Marshall Space Flight Center. These plasma spray formed materials have been evaluated for mechanical properties, density, microstructure, and resistance to liquid metal attack. Forming techniques and the resultant mechanical and metallurgical properties will be presented.

Zimmerman, Frank↗

NASA NTRS1993

Thermal spray forming of refractory sample ampoule cartridges for single crystal growth space furnaces

A thermal spray process is being used to build up refractory metals and ceramics into a containment cartridge for high temperature, single crystal semiconductor growth experiments. This process uses high energy plasma inside a low pressure (100-200 torr) inert environment to apply layers of material onto a removable mandrel. A variety of materials are being characterized and evaluated against a demanding set of requirements, including high service temperature (1700 C), oxidation resistance, and resistance to liquid metal attack. Techniques to spray form refractory metals (tungsten, molybdenum, niobium, tantalum) and ceramics (alumina, boron nitride) are being developed in the Plasma Spray Cell at Marshall Space Flight Center. These plasma spray formed materials have been evaluated for mechanical properties, density, microstructure, and resistance to liquid metal attack. Forming techniques and the resultant mechanical and metallurgical properties are presented.

Zimmerman, Frank↗

NASA NTRS1989

Study of indium tin oxide films exposed to atomic axygen

A qualitative simulation of the effects of atomic oxygen has been conducted on indium tin oxide (ITO) films prepared by dc sputtering onto room-temperature substrates, by exposing them to an RF-excited oxygen plasma and characterizing the resulting changes in optical, electrical, and structural properties as functions of exposure time with ellipsometry, spectrophotometry, resistivity, and X-ray measurements. While the films thus exposed exhibit reduced resistivity and optical transmission; both of these effects, as well as partial crystallization of the films, may be due to sample heating by the plasma. Film resistivity is found to stabilize after a period of exposure.

Snyder, Paul G.↗

NASA NTRS1980

Thermal fatigue and oxidation data for directionally solidified MAR-M 246 turbine blades

Thermal fatigue and oxidation data were obtained for 11 plasma spray coated and 13 uncoated directionally solidified and single crystal MAR-M 246 blades. Blade coatings on the airfoil included several metal-oxide thermal barrier layers based on Al2O3, Cr2O3, or ZrO2. The 24 turbine blades were tested simultaneously for 3000 cycles in fluidized beds maintained at 950 and 25 C using a symmetrical 360 set thermal cycle. In 3000 cycles, only uncoated turbine blades exhibited cracking on the trailing edge near the platform; 3 of the 13 uncoated blades did not crack. Cracking occurred over the range 400 to 2750 cycles, with single crystal blades indicating the poorest thermal fatigue resistance. Oxidation of the uncoated blades was limited in 3000 cycles. All coatings indicated microscopically visible spalling at the trailing edge radius after 3000 cycles. Severe general spalling on the airfoil was observed for two multilayered coatings.

Hill, V. L.↗

NASA NTRS1993

High-resolution measurements, line identification, and spectral modeling of K-alpha transitions in Fe XVIII-Fe XXV

A detailed analysis of the iron K-alpha emission spectrum covering the wavelength region from 1.840 to 1.940 A is presented. Measurements are made with a high-resolution Bragg crystal spectrometer on the Princeton Large Torus (PLT) tokamak for plasma conditions which closely resemble those of solar flares. A total of 40 features are identified, consisting of either single or multiple lines from eight charge states in iron, Fe XVIII - Fe XXV, and their wavelengths are determined with an accuracy of 0.1-0.4 mA. Many of these features are identified for the first time. In the interpretation of our observations we rely on model calculations that determine the ionic species abundances from electron density and temperature profiles measured independently with nonspectroscopic techniques and that incorporate theoretical collisional excitation and dielectronic recombination rates resulting in the excitation of the 1s2sr2ps configurations. The model calculations also include the effect of diffusive ion transport. Good overall agreement between the model calculations and the observations is obtained, which gives us confidence in our line identifications and spectral modeling capabilities. The results are compared with earlier analyses of the K-alpha emission from the Sun.

Beiersdorfer, P.↗

NASA NTRS1985

An investigation of environmental influence on the creep behavior of a low pressure plasma sprayed NiCoCrAlY alloy

Low pressure sprayed MCrAlY overlay coatings are currently being used on advanced single crystal superalloy blades for gas turbine engines. Many studies were made on the influence of coatings on the mechanical properties of superalloys in oxidizing or hot-corroding environments, but very few on the properties of the bulk coating alloy itself. The creep behavior of a typical NiCoCrAlY alloyd (PWA 276) was studied in air and vacuum. The as-received low pressure plasma sprayed NiCoCrAlY plates were heat treated for 4 h at 1080 C followed by 32 h at 870 C, the heat treatment applied to coated superalloy parts. Standard creep specimens 12.7 mm long and 3.2 mm in diameter were then machined. Constant load creep-rupture tests were performed in air and vacuum at 650, 850, and 1050 C and various initial stresses. In addition, some specimens were preoxidized at 1050 C for 100 h prior to testing. Results are briefly discussed.

Hebsur, M. G.↗

NASA NTRS2005

Liquid Crystalline Thermosets from Ester, Ester-Imide, and Ester-Amide Oligomers

Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and were end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The resulting reactive end-capped liquid crystal oligomers exhibit a variety of improved and preferred physical properties. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,OOO grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase. These properties make the end-capped liquid crystal oligomers highly processable by a variety of melt process shape forming and blending techniques including film extrusion, fiber spinning, reactive injection molding (RIM), resin transfer molding (RTM), resin film injection (RFI), powder molding, pultrusion, injection molding, blow molding, plasma spraying and thermo-forming. Once processed and shaped, the end- capped liquid crystal oligomers were heated to further polymerize and form liquid crystalline thermosets (LCT). The fully cured products are rubbers above their glass transition temperatures. The resulting thermosets display many properties that are superior to their non-end-capped high molecular weight analogs.

Theodornus J Dingemans↗

NASA NTRS2005

Liquid crystalline thermosets from ester, ester-imide, and ester-amide oligomers

Main chain thermotropic liquid crystal esters, ester-imides, and ester-amides were prepared from AA, BB, and AB type monomeric materials and were end-capped with phenylacetylene, phenylmaleimide, or nadimide reactive end-groups. The resulting reactive end-capped liquid crystal oligomers exhibit a variety of improved and preferred physical properties. The end-capped liquid crystal oligomers are thermotropic and have, preferably, molecular weights in the range of approximately 1000-15,000 grams per mole. The end-capped liquid crystal oligomers have broad liquid crystalline melting ranges and exhibit high melt stability and very low melt viscosities at accessible temperatures. The end-capped liquid crystal oligomers are stable for up to an hour in the melt phase. These properties make the end-capped liquid crystal oligomers highly processable by a variety of melt process shape forming and blending techniques including film extrusion, fiber spinning, reactive injection molding (RIM), resin transfer molding (RTM), resin film injection (RFI), powder molding, pultrusion, injection molding, blow molding, plasma spraying and thermo-forming. Once processed and shaped, the end-capped liquid crystal oligomers were heated to further polymerize and form liquid crystalline thermosets (LCT). The fully cured products are rubbers above their glass transition temperatures. The resulting thermosets display many properties that are superior to their non-end-capped high molecular weight analogs.

Dingemans, Theodorous J.↗

NASA NTRS1980

The soft X-ray polychromator for the Solar Maximum Mission

The paper considers the soft X-ray polychromator (XRP) operating in the 1.4-22.4 A range of the soft X-ray spectrum which includes many emission lines important for the diagnosis of plasmas in the 1.5-50 million deg temperature range. The flat crystal scanning spectrometer provides for a channel polychromatic mapping of flares and active regions in the resonance lines of O VIII, Ne IX, and Mg XI; in its spectral scanning mode it covers essentially the entire 1.4-22.5 A region.

Acton, L. W.↗

NASA NTRS1991

Compact X-Ray And Extreme-Ultraviolet Monochromator

Monochromator for x-ray and extreme-ultraviolet radiation provides higher spectral resolution than achieved with thin-metal-foil broad-band-pass filters. Uses Bragg reflection to band-pass-filter radiation from high-intensity, broad-spectrum source. Operates over much broader x-ray and extreme-ultraviolet spectrum than devices based upon natural crystals. Intended to filter continuum radiation from sources like synchrotrons, laser plasma sources, free-electron lasers, and wigglers to produce monochromatic beams for testing and analysis of x-ray and extreme-ultraviolet telescopes and microscopes, for calibration of photographic films and detectors, for biological and biomedical research, for x-ray lithography, for processing of materials, and for research in properties of materials.

Hoover, Richard B.↗

NASA NTRS1999

Microwave Induced Direct Bonding of Single Crystal Silicon Wafers

We have heated polished doped single-crystal silicon wafers in a single mode microwave cavity to temperatures where surface to surface bonding occurred. The absorption of microwaves and heating of the wafers is attributed to the inclusion of n-type or p-type impurities into these substrates. A cylindrical cavity TM (sub 010) standing wave mode was used to irradiate samples of various geometry's at positions of high magnetic field. This process was conducted in vacuum to exclude plasma effects. This initial study suggests that the inclusion of impurities in single crystal silicon significantly improved its microwave absorption (loss factor) to a point where heating silicon wafers directly can be accomplished in minimal time. Bonding of these substrates, however, occurs only at points of intimate surface to surface contact. The inclusion of a thin metallic layer on the surfaces enhances the bonding process.

Budraa, N. K.↗

NASA NTRS1979

Ray-tracing the convex curved crystal X-ray spectrograph

The convex curved crystal X-ray spectrograph has recently seen increasing use for the spectral analysis of transient plasmas. The present paper describes the calculation of ray paths through the spectrograph for both localized and extended sources. The method traces a ray from any given source point to its point of diffraction by the curved crystal and then to the imaging circle, where the image point is obtained. Application of the ray tracing method is made to some actual experimental configurations to obtain resolution values and source sizes. Wavelength calibrations are obtainable with the ray tracing method in advance of instrument construction.

Kastner, S. O.↗

NASA NTRS2007

Thermal Properties of Oxides With Magnetoplumbite Structure for Advanced Thermal Barrier Coatings

Oxides having magnetoplumbite structure are promising candidate materials for applications as high temperature thermal barrier coatings because of their high thermal stability, high thermal expansion, and low thermal conductivity. In this study, powders of LaMgAl11O19, GdMgAl11O19, SmMgAl11O19, and Gd0.7Yb0.3MgAl11O19 magnetoplumbite oxides were synthesized by citric acid sol-gel method and hot pressed into disk specimens. The thermal expansion coefficients (CTE) of these oxide materials were measured from room temperature to 1500 C. The average CTE value was found to be approx.9.6x10(exp -6)/C. Thermal conductivity of these magnetoplumbite-based oxide materials was also evaluated using steady-state laser heat flux test method. The effects of doping on thermal properties were also examined. Thermal conductivity of the doped Gd0.7Yb0.3MgAl11O19 composition was found to be lower than that of the undoped GdMgAl11O19. In contrast, thermal expansion coefficient was found to be independent of the oxide composition and appears to be controlled by the magnetoplumbite crystal structure. Thermal conductivity testing of LaMgAl11O19 and LaMnAl11O19 magnetoplumbite oxide coatings plasma sprayed on NiCrAlY/Rene N5 superalloy substrates indicated resistance of these coatings to sintering even at temperatures as high as 1600 C.

Bansal, Narottam P.↗

NASA NTRS1988

Fatigue damage modeling for coated single crystal superalloys

A high temperature, low-cycle fatigue life prediction method for coated single crystal nickel-base superalloys is being developed. The method is being developed for use in predicting crack initiation life of coated single crystal turbine airfoils. Although the models are being developed using coated single crystal PWA 1480, they should be readily adaptable to other coated nickel-base single crystal materials. The coatings choosen for this effort were of two generic types: a low pressure plasma sprayed NiCoCrAlY overlay, designated PWA 286, and an aluminide diffusion, designated PWA 273. In order to predict the useful crack initiation life of airfoils, the constitutive and failure behavior of the coating/substrate combination must be taken into account. Coatings alter the airfoil surface microstructure and are a primary source from which cracks originate. The adopted life prediction approach addresses this complexity by separating the coating and single crystal crack initiation regimes. This provides a flexible means for using different life model formulations for the coating and single crystal materials. At the completion of this program, all constitutive and life model formulations will be available in equation form and as software. The software will use the MARC general purpose finite element code to drive the constitutive models and calculate life parameters.

Nissley, David M.↗

NASA NTRS1972

The NRL OSO-4 Bragg crystal spectrometer instrument

Two Bragg crystal spectrometers were placed on the OSO-4 satellite to study solar flare plasmas by their spectral emissions. The solar flare plasma parameters were measured with these spectrometers, which together covered a total wavelength range of 0.6 to 8.4 A. With these instruments, knowledge could be gained into the mechanisms governing the plasma behavior in the high temperature-low density regime of flare production and in solar evolution and elemental abundances in the sun. However, spacecraft limitations forced many restrictions on the design of the instrument, so the final instrument could not measure all the solar flare plasma state parameters.

Meekins, J. F.↗

NASA NTRS1984

Soft X-ray polychromator for the Solar Maximum Mission

The XRP was designed to measure the following temporal and spatial properties of the active and flaring Sun: electron temperature, departures from steady state, ion kinetic temperatures, and electron density. The Bent Crystal Spectrometer (BCS) is capable of measuring the broadening and blue shifts often observed in the impulsive phase of flares. The six simultaneous line fluxes indicative of six different temperatures of formation observable by the Flat Crystal Spectrometer (FCS) allows the derivation of the differential emission measure of the plasma at each raster point. During the operational periods of the XRP hundreds of flares of C-level (GOES classification) were observed and brighter in both the FCS and BCS, including 5 X-flares. Associated theoretical work in atomic physics, stimulated in part by the promise of XRP measurements, has benefitted from the experimental data on solar plasmas which the XRP has provided in abundance.

Haisch, B. M.↗

NASA NTRS1985

Creep-fatigue behavior of NiCoCrAlY coated PWA 1480 superalloy single crystals

Single crystal specimens of a Ni base superalloy, PWA 1480, with a low pressure plasma sprayed NiCoCrAlY coating were tested in various 0.1 Hz fatigue and creep fatigue cycles both at 1015 and 1050 C. Creep fatigue tests of the cp, pc, and cc types were conducted with various constant total strain ranges employing creep dwells at various constant stresses. Considerable cyclic softening occurred as was evidenced particularly by rapidly increasing creep rates in the creep fatigue tests. The cycle time in the creep fatigue tests typically decreased by more than 80 percent at 0.5 N sub f. Though cyclic life did correlate with delta epsilon sub in a better correlation existed with sub f for both the fatigue and creep fatigue tests, and poor correlations were observed with either sigma sub max or the average cycle time. A model containing both delta sigma and delta sigma (sub in), N sub f = alpha delta sigma (sub in) beta delta sigma gamma, with best fit values of sigma for each cycle type, but the same values of beta and gamam, was found to provide good correlations. Life lines were not greatly different among the cycle types, differing only by a factor of about three. The cp cycle life line was lowest for both test temperatures, however among the other three cycle types there was no consistent ranking. For all test types failure occurred predominately by multiple internal cracking originating at pores. The strong correlation of life with delta sigma may reflect a significant crack growth period in the life of the specimens.

Miner, R. V.↗

NASA NTRS1988

Creep-fatigue behavior of NiCoCrAlY coated PWA 1480 superalloy single crystals

Single crystal specimens of a Ni base superalloy, PWA 1480, with a low pressure plasma sprayed NiCoCrAlY coating were tested in various 0.1 Hz fatigue and creep fatigue cycles both at 1015 and 1050 C. Creep fatigue tests of the cp, pc, and cc types were conducted with various constant total strain ranges employing creep dwells at various constant stresses. Considerable cyclic softening occurred as was evidenced particularly by rapidly increasing creep rates in the creep fatigue tests. The cycle time in the creep fatigue tests typically decreased by more than 80 percent at 0.5 N sub f. Though cyclic life did correlate with delta epsilon sub in a better correlation existed with sub f for both the fatigue and creep fatigue tests, and poor correlations were observed with either sigma sub max or the average cycle time. A model containing both delta sigma and delta sigma (sub in), N sub f = alpha delta sigma (sub in) beta delta sigma gamma, with best fit values of sigma for each cycle type, but the same values of beta and gamam, was found to provide good correlations. Life lines were not greatly different among the cycle types, differing only by a factor of about three. The cp cycle life line was lowest for both test temperatures, however among the other three cycle types there was no consistent ranking. For all test types failure occurred predominately by multiple internal cracking originating at pores. The strong correlation of life with delta sigma may reflect a significant crack growth period in the life of the specimens.

Miner, R. V.↗