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At least 55 records · Page 3

Monitoring atmospheric pollutants with a heterodyne radiometer transmitter-receiver

The presence of selected atmospheric pollutants can be determined by transmitting an infrared beam of proper wavelength through the atmosphere, and detecting the reflections of the transmitted beam with a heterodyne radiometer transmitter-receiver using part of the laser beam as a local oscillator. The particular pollutant and its absorption line strength to be measured are selected by the laser beam wave length. When the round-trip path for the light is known or measured, concentration can be determined. Since pressure (altitude) will affect the shape of the molecular absorption line of a pollutant, tuning the laser through a range of frequencies, which includes a part of the absorption line of the pollutant of interest, yields pollutant altitude data from which the altitude and altitude profile is determined.

Menzies, R. T.↗

Gas sampling method for determining pollutant concentrations in the flame zone of two swirl-can combustor modules

A gas sampling probe and traversing mechanism were developed to obtain detailed measurements of gaseous pollutant concentrations in the primary and mixing regions of combustors in order to better understand how pollutants are formed. The gas sampling probe was actuated by a three-degree-of-freedom traversing mechanism and the samples obtained were analyzed by an on-line gas analysis system. The pollutants in the flame zone of two different swirl-can combustor modules were measured at an inlet-air temperature of 590 K, pressure of 6 atmospheres, and reference velocities of 23 and 30 meters per second at a fuel-air ratio of 0.02. Typical results show large spatial gradients in the gaseous pollutant concentration close to the swirl-can module. Average concentrations of unburned hydrocarbons and carbon monoxide decrease rapidly in the downstream wake regions of each module. By careful and detailed probing, the effect of various module design features on pollutant formation can be assessed. The techniques presently developed seem adequate to obtain the desired information.

Duerr, R. A.↗

A model to investigate the influence of suspended sediment on the mass transport of a pollutant in open channel flow

An explicit two-dimensional finite difference model, designed to investigate the influence of suspended sediment on the pollutant transport process, is presented. Specific attention is directed toward examining the role of suspended sediment in: (1) the turbulent vertical transport mechanism in a stratified flow, and (2) pollutant uptake due to sorption. Results presented indicate that suspended sediment plays a major role in the pollutant transport process, and subsequently, any meaningful attempt to model the fate of a pollutant in an alluvial channel must account for the presence of a suspended sediment concentration profile. Similarly, the vertical and longitudinal pollutant concentration distributions provided by the model may be utilized to improve upon the predictive capacities of existing water quality models.

Chapman, R. S.↗

Imaging air pollutants in the near ultraviolet

This paper discusses a program for remote sensing of air pollutants called Multispectral Observation of Pollutants System (MOPS). The broad objective of the program is to photograph 'invisible' gaseous pollutants by combining ultraviolet imaging in several spectral bands with portable data processing equipment. Electronic cameras using solid state imaging arrays of large dynamic range will permit very low contrast images to be electronically ratioed and contrast enhanced, thus bringing out pollutant images which are below the contrast threshold of film. Such photographs will allow synoptic coverage of geographic areas providing source, sink, and flow data on pollutants, and will provide reconnaissance and pointing information for other remote sensors. The principle gases to be mapped by MOPS will be ozone, sulfur dioxide, and nitrogen dioxide.

Norris, D.↗

Theory of spectral radiance of pollutants at sea, volume 1

Remote measurement of pollutants dumped in the sea, not oil slicks, but soluble pollutants that change the color of the water, is addressed. The sensor is a spectral radiometer that flies over the polluted area and compares its spectral radiance (color) to that of surrounding clean seawater. The goal is to infer the concentration of pollutants using the measured radiance of the sea compared to laboratory measurements of reflection and transmission spectra of the pollutants. The subject is treated in three steps: (1) the quantities involved are defined and means for measuring them are described; (2) the equations for remote sensing with a low-flying aircraft are derived, in which wase the absorption and radiance of intervening air is negligible; and (3) high-flying aircraft and satellites are applied, in which case the radiance of intervening air is the major problem.

Source record↗

Joint Conference on Sensing of Environmental Pollutants, 4th, New Orleans, La., November 6-11, 1977, Proceedings

Papers are presented on such topics as environmental chemistry, the effects of sulfur compounds on air quality, the prediction and monitoring of biological effects caused by environmental pollutants, environmental indicators, the satellite remote sensing of air pollution, weather and climate modification by pollution, and the monitoring and assessment of radioactive pollutants. Consideration is also given to empirical and quantitative modeling of air quality, disposal of hazardous and nontoxic materials, sensing and assessment of water quality, pollution source monitoring, and assessment of some environmental impacts of fossil and nuclear fuels.

Source record↗

Stability of the surface layer and its relation to the dispersion of primary pollutants in St. Louis

The effects of atmospheric stability on the dispersion of primary pollutants such as CO, total hydrocarbons (THC), and NO were examined in St. Louis. The pollutant levels were measured at 25 stations, temperature at 12 stations at 5 and 30 m height, and wind speed and direction at the 30 m level at 12 stations. Correlation coefficients were generated for pairs of the vertical temperature differences, the log of the mean wind speed reciprocal, the bulk Richardson number, and specific pollutant concentrations. A high correlation was obtained between the thermal stability and the urban concentration of the primary pollutants in the lowest part of the boundary layer. A restricted nighttime dispersion of the pollutants was observed, indicating near-ground increased concentrations at times when the source emissions actually decrease.

Remsberg, E. E.↗

Tropospheric Ozone Pollution Transport Traced from the TOMS (Total Ozone Mapping Spectrometer) Instrument During the Nashville-1999 Campaign

Over the past several years, we have developed two new tropospheric ozone retrievals from the TOMS (Total Ozone Mapping Spectrometer) satellite instrument that are of sufficient resolution to follow pollution episodes. The modified-residual technique [Hudson and Thompson, 1998; Thompson and Hudson, 1999] uses v. 7 TOMS total ozone and is applicable to tropical regimes in which the wave-one pattern in total ozone is observed. The TOMS-direct method [("TDOT" = TOMS Direct Ozone in the Troposphere; Frolov et al., 2000] represents a new algorithm that uses TOMS radiances directly (i.e., not previously processed for TOMS ozone) to extract tropospheric ozone in regions of constant stratospheric ozone and tropospheric ozone displaying high mixing ratios and variability characteristic of pollution. These events tend to occur in certain meteorological regimes. For example, mid-latitude pollution usually occurs on the backside of subtropical fronts, as low pv, usually moist air intrudes to the extra-tropics. July 1999 was a month characterized by robust pollution in the eastern US, with high ozone, as detected by TOMS, originating over south central states and moving up the Atlantic seaboard. This corresponds to 50-80 DU in tropospheric ozone column depth. In most cases, further transport occurred to the North Atlantic, with ozone plumes traveling to western Europe in 4-5 days. Examples of high ozone and transit across boundaries within the US, as well as US->Europe, give a regional context for model results and field measurements taken in the SE US during the Nashville-1999 campaign period. Validation of the TDOT maps is made with ozonesondes taken during that time. TDOT maps also show ozone pollution from Asia traveling to the western US in July 1999.

Thompson, Anne M.↗

Intercontinental Transport of Air Pollution

The development of the global economy goes beyond raising our standards of living. We are in an ear of increasing environmental as well as economic interdependence. Long-range transport of anthropogenic atmospheric pollutants such as ozone, ozone precursors, airborne particles, heavy metals (such as mercury) and persistent organic pollutants are the four major types of pollution that are transported over intercontinental distances and have global environmental effects. The talk includes: 1) an overview of the international agreements related to intercontinental transport of air pollutants, 2) information needed for decision making, 3) overview of the past research on intercontinental transport of air pollutants - a North American's perspective, and 4) future research needs.

Rogers, David↗

Asian Outflow and Trans-Pacific Transport of Carbon Monoxide and Ozone Pollution: An Integrated Satellite, Aircraft, and Model Perspective

Satellite observations of carbon monoxide (CO) from the Measurements of Pollution in the Troposphere (MOPITT) instrument are combined with measurements from the Transport and Chemical Evolution Over the Pacific (TRACE-P) aircraft mission over the northwest Pacific and with a global three-dimensional chemical transport model (GEOS-CHEM) to quantify Asian pollution outflow and its trans-Pacific transport during spring 2001. Global CO column distributions in MOPITT and GEOS-CHEM are highly correlated (R(exp 2) = 0.87), with no significant model bias. The largest regional bias is over Southeast Asia, where the model is 18% too high. A 60% decrease of regional biomass burning emissions in the model (to 39 Tg/yr) would correct the discrepancy; this result is consistent with TRACE-P observations. MOPITT and TRACE-P also give consistent constraints on the Chinese source of CO from fuel combustion (181 Tg CO/yr). Four major events of trans-Pacific transport of Asian pollution in spring 2001 were seen by MOPITT, in situ platforms, and GEOS-CHEM. One of them was sampled by TRACE-P (26-27 February) as a succession of pollution layers over the northeast Pacific. These layers all originated from one single event of Asian outflow that split into northern and southern plumes over the central Pacific. The northern plume (sampled at 6-8 km off California) had no ozone enhancement. The southern subsiding plume (sampled at 2-4 km west of Hawaii) contained a 8 - 17 ppbv ozone enhancement, driven by decomposition of peroxyacetylnitrate (PAN) to nitrogen oxides (NOx). This result suggests that PAN decomposition in trans-Pacific pollution plumes subsiding over the United States could lead to significant enhancements of surface ozone.

Heald, Colette L.↗

Method for measuring pollutant formation

Diagnostic methods for determining an instantaneous rate of pollutant formation in a combustion system are based on measurement of chemiluminescence intensity generated simultaneously with the formation of the pollutant. The chemiluminescent signal is generated by an analog reaction which occurs in parallel with a key step in the formation of a specific pollutant of interest. The connection between the analog reaction and the pollution reaction is such that the chemiluminescent signal indicates the local, instantaneous formation rate of the pollutant of interest.

Annen, Kurt↗

Possible Influences of Air Pollution, Dust and Sandstorms on the Indian Monsoon

In Asian monsoon countries, such as China and India, human health and safety problems caused by air pollution are becoming increasingly serious, due to the increased loading of atmospheric pollutants from waste gas emissions and from rising energy demand associated with the rapid pace of industrialization and modernization. Meanwhile, uneven distribution of monsoon rain associated with flash floods or prolonged drought, has caused major loss of human life and damage to crops and.property with devastating societal impacts. Historically, air-pollution and monsoons research are treated as separate problems. However recent studies have suggested that the two problems may be intrinsically linked and need to be studied jointly. Fundamentally, aerosols can affect precipitation through radiative effects cif suspended particles in the atmosphere (direct effect) and/or by interfering and changing: the cloud and precipitation formation processes (indirect effect). Based on their optical properties, aerosols can be classified into two types.: those that absorb solar radiation, and those that do not. Both types of aerosols scatter sunlight and reduce the amount of solar radiation from reaching the Earth's surface, causing it to cool. The surface cooling increases atmospheric stability and reduces convection potential, Absorbing aerosols, however, in addition to cooling the surface, can heat the atmosphere. The heating of the atmosphere may reduce the amount of low clouds by increased evaporation in cloud drops. The heating, however, may induce rising motion, enhance low-level moisture, convergence and, hence, increases rainfall, The latent heating from enhanced rainfall may excite feedback processes in the large-scale circulation, further amplify.the initial response to aerosol heating and producing more rain. Additionally, aerosols can increase the concentration of cloud condensation nuclei (CCN), increase cloud amount and decrease coalescence and collision rates, leading to reduced precipitation. However, in the presence of increasing moist and warm air, the reduced coalescence/collision may lead to supercooled drops at higher altitudes where ice precipitation falls and melts. The latent heat release from freezing aloft and melting below implies greater upward heat transport in polluted clouds and invigorate deep convection. In this way, aerosols may lead to increased local convection. Hence, depending on the ambient large-scale conditions and dynamical feedback processes, aerosols' effect on precipitation can be positive, negative or mixed. In the Asian monsoon and adjacent regions, the aerosol forcing and responses of the water cycle are even more complex, Both direct and indirect effects may take place locally and simultaneously, interacting with each other. in addition to local effects, monsoon rainfall may be affected by aerosols transported from other regions and intensified through large-scale circulation and moisture feedback. Thus, dust transported by the large-scale circulation from the adjacent deserts to northern India may affect rainfall over the Bay of Bengal; sulphate and black carbon front industrial pollution in central, southern China and northern India may affect the rainfall regime over the Korean peninsula and Japan; organic and black carbon front biomass burning from Indo-China may modulate the pre-monsoon rainfall regime over southern China and coastal regions, contributing to variability in differential heating and cooling of the atmosphere and to the land-sea thermal contrast. During the pre-monsoon season and monsoon breaks, it has been suggested that radiative forcing by absorbing aerosols have nearly the same order of magnitude as the forcing due to latent heating from convection and surface fluxes. The magnitude of the total aerosol radiative cooling due to sulphates and soot is of the order of 20-40 W/m2 over the Asian monsoon land region in the pre-monsoon season, compared to about 1-2 W/m2 for global warng. However, the combined forcing at the surface and in the atmosphere, including all species. if aerosols, and details of aerosol mixing, and impacts on the energy and water cycles in the monsoon land regions, are not well known.

Lau, William K. M.↗

Tropospheric Emissions: Monitoring of Pollution Overview

TEMPO is now well into its implementation phase, having passed both its Key Decision Point C and the Critical Design Review (CDR) for the instrument. The CDR for the ground systems will occur in March 2016 and the CDR for the Mission component at a later date, after the host spacecraft has been selected. TEMPO is on schedule to measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO measures from Mexico City to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution. TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry. Measurements are from geostationary (GEO) orbit, to capture the inherent high variability in the diurnal cycle of emissions and chemistry. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve O3, NO2, SO2, H2CO, C2H2O2, H2O, aerosols, cloud parameters, and UVB radiation. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions by 50 percent. TEMPO quantifies and tracks the evolution of aerosol loading. It provides near-real-time air quality products that will be made widely, publicly available. TEMPO provides much of the atmospheric measurement capability recommended for GEO-CAPE in the 2007 National Research Council Decadal Survey, Earth Science and Applications from Space: National Imperatives for the Next Decade and Beyond. Instruments from Europe (Sentinel 4) and Asia (GEMS) will form parts of a global GEO constellation for pollution monitoring later this decade, with a major focus on intercontinental pollution transport. TEMPO will launch at a prime time to be a component of this constellation.

Chance, Kelly↗

Determination of Spatial Distribution of Air Pollution by Dye Laser Measurement of Differential Absorption of Elastic Backscatter

This paper presents the results of an analytical study of a lidar system which uses tunable organic dye lasers to accurately determine spatial distribution of molecular air pollutants. Also described will be experimental work to date on simultaneous multiwavelength output dye laser sources for this system. Basically the scheme determines the concentration of air pollutants by measuring the differential absorption of an (at least) two wavelength lidar signal elastically backscattered by the atmosphere. Only relative measurements of the backscattered intensity at each of the two wavelengths, one on and one off the resonance absorption of the pollutant in question, are required. The various parameters of the scheme are examined and the component elements required for a system of this type discussed, with emphasis on the dye laser source. Potential advantages of simultaneous multiwavelength outputs are described. The use of correlation spectroscopy in this context is examined. Comparisons are also made for the use of infrared probing wavelengths and sources instead of dye lasers. Estimates of the sensitivity and accuracy of a practical dye laser system of this type, made for specific pollutants, snow it to have inherent advantages over other schemes for determining pollutant spatial distribution.

Ahmed, S. A.↗

Tropospheric Emissions: Monitoring of Pollution (TEMPO)

TEMPO (Tropospheric Emissions: Monitoring of Pollution) was selected in 2012 by NASA as the first Earth Venture Instrument, for launch between 2018 and 2021. It will measure atmospheric pollution for greater North America from space using ultraviolet and visible spectroscopy. TEMPO observes from Mexico City, Cuba, and the Bahamas to the Canadian oil sands, and from the Atlantic to the Pacific, hourly and at high spatial resolution (approximately 2.1 kilometers N/S by 4.4 kilometers E/W at 36.5 degrees N, 100 degrees W). TEMPO provides a tropospheric measurement suite that includes the key elements of tropospheric air pollution chemistry, as well as contributing to carbon cycle knowledge. Measurements are made hourly from geostationary (GEO) orbit, to capture the high variability present in the diurnal cycle of emissions and chemistry that are unobservable from current low-Earth orbit (LEO) satellites that measure once per day. The small product spatial footprint resolves pollution sources at sub-urban scale. Together, this temporal and spatial resolution improves emission inventories, monitors population exposure, and enables effective emission-control strategies. TEMPO takes advantage of a commercial GEO host spacecraft to provide a modest cost mission that measures the spectra required to retrieve ozone (O3), nitrogen dioxide (NO2), sulfur dioxide (SO2), formaldehyde (H2CO), glyoxal (C2H2O2), bromine monoxide (BrO), IO (iodine monoxide),water vapor, aerosols, cloud parameters, ultraviolet radiation, and foliage properties. TEMPO thus measures the major elements, directly or by proxy, in the tropospheric O3 chemistry cycle. Multi-spectral observations provide sensitivity to O3 in the lowermost troposphere, substantially reducing uncertainty in air quality predictions. TEMPO quantifies and tracks the evolution of aerosol loading. It provides these near-real-time air quality products that will be made publicly available. TEMPO will launch at a prime time to be the North American component of the global geostationary constellation of pollution monitoring together with the European Sentinel-4 (S4) and Korean Geostationary Environment Monitoring Spectrometer (GEMS) instruments.

tropospheric measurement suite↗

Interactions Between Asian Air Pollution and Monsoon System: South Asia (ROSES-2014 ACMAP)

Asia's rapid economic growth over the past several decades has brought a remarkable increase in air pollution levels in that region. High concentrations of aerosols (also known as particulate matter or PM) from pollution sources pose major health hazards to half of the world population in Asia including South Asia. How do pollution and dust aerosols regulate the monsoon circulation and rainfall via scattering and absorbing solar radiation, changing the atmospheric heating rates, and modifying the cloud properties? We conducted a series of regional model experiments with NASA-Unified Weather Research and Forecast (NUWRF) regional model with coupled aerosol-chemistry-radiation-microphysics processes over South Asia for winter, pre-monsoon, and monsoon seasons to address this question. This study investigates the worsening air quality problem in South Asia by focusing on the interactions between pollution and South Asian monsoon, not merely focusing on the increase of pollutant emissions.

regional model experiments with NASA-Unified Weath↗

Atmospheric Trace Gas (NO2 and Ozone) Dynamics over Coastal Waters near Polluted Urban Regions

At the interface between the land, oceans, and atmosphere, coastal regions are highly dynamic environments, characterized by strong variability in both water and air quality. Variability in atmospheric composition is associated with highly variable anthropogenic emissions, as well as complex meteorological processes that influence the circulation and accumulation of atmospheric pollutants at the land-ocean interface. Assessing the spatial and temporal dynamics of atmospheric pollutants, aerosols, and absorbing trace gases in coastal areas is critical for improving modeling of coastal tropospheric air quality, developing accurate satellite retrievals of coastal ocean color and biological processes, determining impacts of atmospheric pollution on human health, and assessing the ecological implications of atmospheric pollutant deposition for coastal terrestrial and aquatic ecosystems.Here, we present new measurements of atmospheric trace gas (NO2, and ozone) dynamics across a range of estuarine and coastal waters near urban regions. Measurements were conducted from research vessels using NASA's shipboard Pandora spectrometers, as part of recent multidisciplinary, multiplatform field campaigns, including the 2016 KORUS OC/AQ field campaign in the Yellow Sea and East Sea/Sea of Japan, the 2017/2018 OLWETS field campaign in the Chesapeake Bay estuary, and the 2018 LISTOS field campaign in the Long Island Sound. Shipboard measurements over these coastal waters were integrated with measurements from a ground-based Pandora network to examine differences in air quality over the land and over the ocean. Measurements were combined with air-parcel back-trajectory simulations to determine the origin of air masses over the coastal ocean. Comparisons with satellite retrievals of atmospheric composition reveal the benefits and limitations of polar-orbit satellite observations in capturing variability in atmospheric pollution gradients over land-water boundaries.

Tzortziou, Maria↗

Satellite-based Estimates of Ambient Air Pollution and Global Variations in Childhood Asthma Prevalence

Background: The effect of ambient air pollution on global variations and trends in asthma prevalence is unclear. Objectives: Our goal was to investigate community-level associations between asthma prevalence data from the International Study of Asthma and Allergies in Childhood (ISAAC) and satellite-based estimates of particulate matter with aerodynamic diameter < 2.5 microm (PM2.5) and nitrogen dioxide (NO2), and modelled estimates of ozone. Methods: We assigned satellite-based estimates of PM2.5 and NO2 at a spatial resolution of 0.1deg × 0.1deg and modeled estimates of ozone at a resolution of 1deg × 1deg to 183 ISAAC centers. We used center-level prevalence of severe asthma as the outcome and multilevel models to adjust for gross national income (GNI) and center- and country-level sex, climate, and population density. We examined associations (adjusting for GNI) between air pollution and asthma prevalence over time in centers with data from ISAAC Phase One (mid-1900s) and Phase Three (2001-2003). Results: For the 13- to 14-year age group (128 centers in 28 countries), the estimated average within-country change in center-level asthma prevalence per 100 children per 10% increase in center-level PM2.5 and NO2 was -0.043 [95% confidence interval (CI): -0.139, 0.053] and 0.017 (95% CI: -0.030, 0.064) respectively. For ozone the estimated change in prevalence per parts per billion by volume was -0.116 (95% CI: -0.234, 0.001). Equivalent results for the 6- to 7-year age group (83 centers in 20 countries), though slightly different, were not significantly positive. For the 13- to 14-year age group, change in center-level asthma prevalence over time per 100 children per 10% increase in PM2.5 from Phase One to Phase Three was -0.139 (95% CI: -0.347, 0.068). The corresponding association with ozone (per ppbV) was -0.171 (95% CI: -0.275, -0.067). Conclusion: In contrast to reports from within-community studies of individuals exposed to traffic pollution, we did not find evidence of a positive association between ambient air pollution and asthma prevalence as measured at the community level.

Air pollution↗