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At least 55 records · Page 3

Advancing Aerosol Chemical Characterization and Vertical Profiling over the Southern Great Plains Using Uncrewed Aerial Sampling and Offline Aerosol Mass Spectrometry

Recent advancements in uncrewed aerial systems (UASs) and particulate matter (PM) analytical techniques have provided opportunities for atmospheric research. In this study, we deployed the Department of Energy’s fixed-wing ArcticShark UAS to examine PM 2.5 composition at varying altitudes─within and above the planetary boundary layer (PBL)─over the Southern Great Plains atmospheric observatory (SGP). A total of 22 flights were conducted across March, June, and August 2023. Composite filter samples were collected during each flight and analyzed with offline aerosol mass spectrometry (AMS), complemented by on-board real-time sensors and ground-based instrumentation, to provide a comprehensive view of regional aerosol characteristics. Results show clear vertical and seasonal differences in the aerosol composition. Relative to ground-level measurements, aloft samples exhibited shifts in the distribution of organic and inorganic PM, with the organic composition varying distinctly across seasons. Particulate organic nitrogen (ON) was elevated, with bulk compositions similar in March and June but strongly altered in August, likely driven by biomass burning and enhanced photochemical activity. Combined AMS and chemical ionization mass spectrometry analyses detected amines, amides, and amino acids. PM above the planetary boundary layer was enriched in oxidized organic aerosols, while ground-level PM contained higher nitrate and sulfate. Seasonal differences in aqueous-phase processing were also observed, which were strongest in March during persistent cloud cover and weaker in the drier August period, suggesting a shift from aqueous- to gas-phase SOA formation. In conclusion, these findings highlight the value of UAS in advancing PM measurements and vertical profiling of aerosol composition.

54 ENVIRONMENTAL SCIENCES

STS-1 operational flight profile. Volume 4: Onorbit profile-cycle 3.1.1

The orbital flight test (OFT) phase of the shuttle program consists of four orbital flights beginning in November 1980and continuing through 1981. The major purpose of the OFT program is to demonstrate and verify shuttle systems and flight capabilities by satisfying the OFT requirements, is presented. The onorbit portion of the operational flight profile (OFP) for the first Space Transportation System-1 (STS-1) flight is presented. This onorbit document (volume 4) is one in a series that, taken together, will define the STS-1 OFP. This OFP onorbit document represents a combination of the STS-1 ground rules and constraints and the initialization data. The STS-1 flight activities described reflect the trajectory, consumable, crew activity, and flight requirement baseline as of May 1, 1980. Flight plans for the ascent, onorbit, and descent phases of the test flight are presented.

Source record

Improvement of OMI Ozone Profile Retrievals in the Troposphere and Lower Troposphere by the Use of the Tropopause-Based Ozone Profile Climatology

An advance algorithm based on the optimal estimation technique has beeen developed to derive ozone profile from GOME UV radiances and have adapted it to OMI UV radiances. OMI vertical resolution : 7-11 km in the troposphere and 10-14 km in the stratosphere. Satellite ultraviolet measurements (GOME, OMI) contain little vertical information for the small scale of ozone, especially in the upper troposphere (UT) and lower stratosphere (LS) where the sharp O3 gradient across the tropopause and large ozone variability are observed. Therefore, retrievals depend greatly on the a-priori knowledge in the UTLS

Bak, Juseon

Marli: Mars Lidar for Global Wind Profiles and Aerosol Profiles from Orbit

The Mars Exploration Analysis Group's Next Orbiter Science Analysis Group (NEXSAG) has recently identified atmospheric wind measurements as one of 5 top compelling science objectives for a future Mars orbiter. To date, only isolated lander observations of martian winds exist. Winds are the key variable to understand atmospheric transport and answer fundamental questions about the three primary cycles of the martian climate: CO2, H2O, and dust. However, the direct lack of observations and imprecise and indirect inferences from temperature observations leave many basic questions about the atmospheric circulation unanswered. In addition to addressing high priority science questions, direct wind observations from orbit would help validate 3D general circulation models (GCMs) while also providing key input to atmospheric reanalyses. The dust and CO2 cycles on Mars are partially coupled and their influences on the atmospheric circulation modify the global wind field. Dust absorbs solar infrared radiation and its variable spatial distribution forces changes in the atmospheric temperature and wind fields. Thus it is important to simultaneously measure the height-resolved wind and dust profiles. MARLI provides a unique capability to observe these variables continuously, day and night, from orbit.

Orbit

Transcript profiling of plastid ferrochelatase two mutants reveals that chloroplast singlet oxygen signals lead to global changes in RNA profiles and are mediated by Plant U-Box 4

Abstract Background In response to environmental stresses, chloroplasts generate reactive oxygen species, including singlet oxygen ( 1 O 2 ), an excited state of oxygen that regulates chloroplast-to-nucleus (retrograde) signaling, chloroplast turnover, and programmed cell death (PCD). Yet, the central signaling mechanisms and downstream responses remain poorly understood. TheArabidopsis thaliana plastid ferrochelatase two(fc2) mutant conditionally accumulates 1 O 2 , and Plant U-Box 4 (PUB4), a cytoplasmic E3 ubiquitin ligase, is involved in propagating 1 O 2 signals for chloroplast turnover and cellular degradation. Thus, thefc2andfc2 pub4mutants are useful genetic tools to elucidate these signaling pathways. Previous studies have focused on the role of 1 O 2 in promoting cellular degradation infc2mutants, but its impact on retrograde signaling from mature chloroplasts (the major site of 1 O 2 production) is poorly understood. Results To gain mechanistic insights into 1 O 2 signaling pathways, we compared transcriptomes of adult wt,fc2, andfc2 pub4plants. The accumulation of 1 O 2 infc2plants broadly repressed genes involved in chloroplast function and photosynthesis, while inducing genes and transcription factors involved in abiotic and biotic stress, the biosynthesis of jasmonic acid (JA) and salicylic acid (SA), microautophagy, and senescence. Elevated JA and SA levels were observed in 1 O 2 -stressedfc2plants.pub4reversed most of this 1 O 2 -induced gene expression and reduced the JA content infc2plants. Thepub4mutation also blocked JA-induced senescence pathways in the dark. However, fc2 pub4 plantsmaintained constitutively elevated levels of SA even in the absence of bulk 1 O 2 accumulation. Conclusions Together, this work demonstrates that infc2plants, 1 O 2 leads to a robust retrograde signal that may protect cells by downregulating photosynthesis and ROS production while simultaneously mounting a stress response involving SA and JA. The induction of microautophagy and senescence pathways indicate that 1 O 2 -induced cellular degradation is a genetic response to this stress, and the bulk of this transcriptional response is modulated by the PUB4 protein. However, the effect ofpub4on hormone synthesis and signaling is complex and indicates that an intricate interplay of SA and JA are involved in promoting stress responses and programmed cell death during photo-oxidative damage.

Plant Sciences

Evaluation of single-footprint AIRS CH4 Profile Retrieval Uncertainties Using Aircraft Profile Measurements

We evaluate the uncertainties of methane optimal estimation retrievals from single footprint thermal infrared observations from the Atmospheric Infrared Sounder (AIRS). These retrievals are primarily sensitive to atmospheric methane in the mid-troposphere through the lower stratosphere (~2 to ~17 km). We compare to in situ observations made from aircraft during the Hiaper Pole to Pole Observations (HIPPO), the NASA Atmospheric Tomography Mission (ATom) campaigns, and from the NOAA ESRL aircraft network, between the surface and 5-13 km, across a range of years, latitudes between 60 S to 80 N, and over land and ocean. After a global, pressure dependent bias correction, we find that the land and ocean have similar biases and that the reported observation error (combined measurement and interference errors) of ~27 ppb is consistent with the standard deviation between aircraft and individual AIRS observations. A single measurement has measurement (noise related) uncertainty of ~17 ppb, a ~20 ppb uncertainty from radiative interferences (e.g. from water, temperature, etc.), and ~ 30 ppb due to “smoothing error”, which is partially removed when making comparisons to in situ measurements or models in a way that account for this regularization. We estimate a 16 ppb validation error because the aircraft typically did not measure methane at altitudes where the AIRS measurements have some sensitivity, e.g. the stratosphere. Daily averaged AIRS measurements of at least 9 observations over spatio-temporal domains of < 1 degree and 1 hour have a standard deviation of ~17 ppb versus aircraft, likely because the observation errors from temperature and water vapor (for example) are only partly reduced through averaging. Seasonal averages can reduce this ~17 ppb uncertainty further to ~10 ppb, as determined through comparison with NOAA aircraft, likely because uncertainties related to radiative effects of temperature and water vapor can be reduced when averaged over a season.

Susan Kulawik