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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Optical and Atomic Force Microscopy Characterization of PbI2 Quantum Dots

Lead iodide (PbI2) clusters were synthesized from the chemical reaction of NaI (or KI) with Pb(NO3)2 in H2O, D2O, CH3OH, and C3H7OH media. The observation of the absorption features above 350 nm with the help of integrating sphere accessory strongly suggests the quantum dot formation of PbI2 in solution. Spectral comparison between the synthesized PbI2 clusters in solution and PbI2 nanophase by impregnation of PbI2 in four different pore-sized porous silica indicates that the PbI2 cluster size in solution is less than 2.5 nm in lateral dimension. Atomic force microscopy (AFM) measurements show that the PbL clusters deposited onto three different molecularly flat surfaces are single-layered. The measured height is 1.0 - 0.1 nm. The swollen layer thickness can be attributed to the intralayer contraction from the strong lateral interaction among PbI2 molecules, which is supported by ab initio calculation. Raman scattering measurement of LO and TO modes of PbI2 in bulk and in the confined state were also conducted in 50-150 cu cm region. The observed three bands at 74, %, 106 1/cm are assigned to TO2, LO2, and LO, mode, respectively. The relatively small red-shift in LO modes may be caused by the surface phonon polaritons of PbI2 nanophase in the porous silica.

Mu, R.↗

Residual thermal stresses in a solid sphere cast from a thermosetting material

Expressions are developed for the residual thermal stresses in a solid sphere cast from a chemically hardening thermosetting material in a rigid spherical mold. The description of the heat generation rate and temperature variation is derived from a first-order chemical reaction. Solidification is described by the continuous transformation of the material from an inviscid liquidlike state into an elastic solid, with intermediate properties determined by the degree of chemical reaction. Residual stress components are obtained as functions of the parameters of the hardening process and the properties of the hardening material. Variation of the residual stresses with a nondimensionalized reaction rate parameter and the relative compressibility of the hardened material is discussed in detail.

Levitsky, M.↗

Space telescope pointing control system

The Space Telescope is a free-flying spacecraft designed for Space Shuttle launch. The Space Telescope's pointing control system slews the optical axis from one target star region of the celestial sphere to the next, and maintains precision pointing for the target star for up to 24 hours. The spacecraft digital computer processes the precision attitude and rate sensor data to generate torque commands for the reaction wheels. The pointing control system has four major elements: the command generator, the control system, the attitude reference processing, and momentum management. The emphasis is on relating design requirements to the hardware and software implementation.

Dougherty, H.↗

Space Telescope pointing control

The Space Telescope Pointing Control System is used to slew the optical axis of the telescope from one target star region of the celestial sphere to the next, and to maintain precision pointing on the target star. A digital computer is employed in the processing of attitude and rate sensor data, in order to generate torque commands for the reaction wheels. The System comprises four major elements: a command generator, the electronic control system, attitude update processing, and momentum management. Emphasis is given to control-related flexibility effects of the Space Telescope's solar cell array and vehicle, and the acquisition methodology and development testing employed, in addition to Pointing Control System design features.

Dougherty, H.↗

Submicron silicon powder production in an aerosol reactor

Powder synthesis by thermally induced vapor phase reactions is described. The powder generated by this technique consists of spherical, nonagglomerated particles of high purity. The particles are uniform in size, in the 0.1-0.2-micron size range. Most of the particles are crystalline spheres. A small fraction of the spheres are amorphous. Chain agglomerates account for less than 1 percent of the spherules.

Wu, J. J.↗

Invasion of the Giant X-Ray Bubbles

More bizarre news from the bizarre world of neutron stars: They got dozens of giant X-ray bubbles taller than the Empire State Building forming and popping every second. Yet finding evidence of this bubble blowing was no childish endeavor. It took a team of Berkeley scientists just about all they could muster: three days' worth of observational data and 1,200 hours of number-crunching on the slickest of supercomputers at the Lawrence Livermore National Laboratory (LLNL). Mind you, these are the same powerful computers used to model nuclear reactions and calculate Bill Gates' salary. Neutron stars are already known as the bad boys of the cosmic neighborhood. They are the core remains of exploded stars, with a mass greater than our sun condensed into a sphere no bigger than Manhattan, A teaspoon of its densely-packed surface matter, the analogy goes, would weigh three billion tons back on earth. Its 10 trillion gauss magnetic field could wipe your credit card clean at a distance half-way to the moon. Its intense gravity lures gas from nearby stars, spinning the neutron star to speeds of up to a thousand times a second. But giant X-ray bubbles dancing on the surface? That even freaked out the discoverers. "Early on, I tended to disbelieve what the calculations were telling me," said Richard Klein, who splits his time between Berkeley and LLNL. "The bubbles 'appeared' and I wasn't convinced they were real."

Wanjek, Christopher↗

Study of Atmospheric Nitric Oxide

We investigated the contribution of energetic nitrogen atoms to the production of nitric oxide in the thermosphere and their influence on the infrared emission spectrum. The nitric oxide molecules are important contributors to the cooling of the atmosphere. We first pointed out that in determining the energy distribution of the nitrogen atoms, it is important to take into account the thermal motion of the atmospheric gases. It had been ignored in all earlier studies. The source spectra are broadened considerably by the center of mass motion of the reactants. We worked out the consequences for the production of nitric oxide at night, using as sources of energetic N atoms, NO(+) + e yield N + O, N(D-2) + O yield N + O. The high energy tail is enhanced by orders of magnitude. We had earlier suggested (Sharma et al. 1993) that the reaction of energetic nitrogen atoms with O2 was responsible for the rotationally enhanced NO identified in the infrared spectrum. Our calculations provided quantitative confirmation of the suggestion. We proceeded to explore the validity of another approximation used in earlier analyses, the hard sphere approximation for the energy loss in elastic collisions. We carried out precise quantum mechanical calculations of the elastic 2 differential scattering of nitrogen atoms in collisions with oxygen atoms and showed that although the hard sphere approximation was nowhere of high precision, reasonable results could be obtained with an effective cross section of 6 x 10(exp 15)sq cm. We also initiated a program to include inelastic energy loss processes in the determination of the energy distribution function. We began a calculation of the rotation and vibrational excitation cross sections of molecular nitrogen and nitrogen atoms and developed a method for including inelastic energy loss as a function of scattering angle in the Boltzmann equation. A procedure for obtaining the solution of the Boltzman equation was worked out.

Dalgarno, A.↗

Mission optimization of the Space Infrared Telescope Facility

The Space Infrared Telescope Facility (SIRTF) mission based on a cryogenically cooled telescope is described. The SIRTF makes it possible to perform background limited measurements with three focal plane instruments in the wavelength range 2-700 microns over the entire celestial sphere for at least five years. A telescope performance limited by the natural astrophysical background between 2 to 300 microns is achieved by using a superfluid helium cryogenic system for maintaining the forebaffle temperature below 8 K. The attitude control system based on Extreme Ultra-Violet Explorer reaction wheels meets the large and small angle slew requirements and provides 0.15 arc sec pointing stability. The present HEO baseline configuration has a mass of 4370 kg. The future Titan IV/Centaur launch capability to 100,000 km for a SIRTF-sized payload is at least 5770 kg.

Brooks, Walter F.↗

The Microwave Anisotropy Probe (MAP) Mission

The Microwave Anisotropy Probe mission is designed to produce a map of the cosmic microwave background radiation over the entire celestial sphere by executing a fast spin and a slow precession of its spin axis about the Sun line to obtain a highly interconnected set of measurements. The spacecraft attitude is sensed and controlled using an inertial reference unit, two star trackers, a digital sun sensor, twelve coarse sun sensors, three reaction wheel assemblies, and a propulsion system. This paper presents an overview of the design of the attitude control system to carry out this mission and presents some early flight experience.

Markley, F. Landis↗

The Attitude Control System for the Wilkinson Microwave Anisotropy Probe

The Wilkinson Microwave Anisotropy Probe mission produces a map of the cosmic microwave background radiation over the entire celestial sphere by executing a fast spin and a slow precession of its spin axis about the Sun line to obtain a highly interconnected set of measurements. The spacecraft attitude is sensed and controlled using an inertial reference unit, two star trackers, a digital sun sensor, twelve coarse sun sensors, three reaction wheel assemblies, and a propulsion system. Sufficient attitude knowledge is provided to yield instrument pointing to a standard deviation (l sigma) of 1.3 arc-minutes per axis. In addition, the spacecraft acquires and holds the sunline at initial acquisition and in the event of a failure, and slews to the proper orbit adjust orientations and to the proper off-sunline attitude to start the compound spin. This paper presents an overview of the design of the attitude control system to carry out this mission and presents some early flight experience.

Markley, F. Landis↗

The Microwave Anisotropy Probe (MAP) Attitude Control System

The Microwave Anisotropy Probe mission is designed to produce a map of the cosmic microwave background radiation over the entire celestial sphere by executing a fast spin and a slow precession of its spin axis about the Sun line to obtain a highly interconnected set of measurements. The spacecraft attitude is sensed and controlled using an Inertial Reference Unit, two Autonomous Star Trackers, a Digital Sun Sensor, twelve Coarse Sun Sensors, three Reaction Wheel Assemblies, and a propulsion system. This paper describes the design of the attitude control system that carries out this mission and presents some early flight experience.

Markley, F. Landis↗

The Microwave Anisotropy Probe (MAP) Mission

The Microwave Anisotropy Probe mission is designed to produce a map of the cosmic microwave background radiation over the entire celestial sphere by executing a fast spin and a slow precession of its spin axis about the Sun line to obtain a highly interconnected set of measurements. The spacecraft attitude is sensed and controlled using an Inertial Reference Unit, two Autonomous Star Trackers, a Digital Sun Sensor, twelve Coarse Sun Sensors, three Reaction Wheel Assemblies, and a propulsion system. This paper describes the design of the attitude control system that carries out this mission and presents some early flight experience.

Markley, F. Landis↗

Comparison of CFD and DSMC Using Calibrated Transport Parameters

Hypersonic re-entry flows span a wide range of length scales where regions of both rarefied and continuum flow exist. Traditional computational fluid dynamics (CFD) techniques do not provide an accurate solution for the rarefied regions of such ‘mixed’ flow fields. Although direct simulation Monte Carlo (DSMC) can be used to accurately capture both the continuum and rarefied features of ‘mixed’ flow fields, they are computationally expensive when employed to simulate the low Knudsen number continuum regimes. Thus, a hybrid framework for seamlessly combining the two methodologies, CFD and DSMC, continues to be a topic of significant research effort. Ensuring consistency in the reaction kinetics and transport models employed within CFD and DSMC is a crucial requirement for obtaining a reliable solution from a hybrid framework for combined continuum/rarefied high speed flows. This paper represents one of the first studies to utilize the calibrated transport parameters developed to ensure consistency between CFD and DSMC solvers. The new variable soft sphere (VSS) parameters are compared to both previous “standard” variable hard sphere (VHS) parameters and also to solutions from the CFD transport properties that the new parameters were developed to reproduce.

Liechty, D. S.↗

Using FLUKA to Calculate Spacecraft: Single Event Environments: A Practical Approach

The FLUKA nuclear transport and reaction code can be developed into a practical tool for calculation of spacecraft and planetary surface asset SEE and TID environments. Nuclear reactions and secondary particle shower effects can be estimated with acceptable accuracy both in-flight and in test. More detailed electronic device and/or spacecraft geometries than are reported here are possible using standard FLUKA geometry utilities. Spacecraft structure and shielding mass. Effects of high Z elements in microelectronic structure as reported previously. Median shielding mass in a generic slab or concentric sphere target geometry are at least approximately applicable to more complex spacecraft shapes. Need the spacecraft shielding mass distribution function applicable to the microelectronic system of interest. SEE environment effects can be calculated for a wide range of spacecraft and microelectronic materials with complete nuclear physics. Evaluate benefits of low Z shielding mass can be evaluated relative to aluminum. Evaluate effects of high Z elements as constituents of microelectronic devices. The principal limitation on the accuracy of the FLUKA based method reported here are found in the limited accuracy and incomplete character of affordable heavy ion test data. To support accurate rate estimates with any calculation method, the aspect ratio of the sensitive volume(s) and the dependence must be better characterized.

Koontz, Steve↗

Observations of Methane and Ethylene Diffusion Flames Stabilized Around a Blowing Porous Sphere Under Microgravity Conditions

This paper presents the experimental and theoretical results for expanding methane and ethylene diffusion flames in microgravity. A small porous sphere made from a low-density and low-heat-capacity insulating material was used to uniformly supply fuel at a constant rate to the expanding diffusion flame. A theoretical model which includes soot and gas radiation is formulated but only the problem pertaining to the transient expansion of the flame is solved by assuming constant pressure infinitely fast one-step ideal gas reaction and unity Lewis number. This is a first step toward quantifying the effect of soot and gas radiation on these flames. The theoretically calculated expansion rate is in good agreement with the experimental results. Both experimental and theoretical results show that as the flame radius increases, the flame expansion process becomes diffusion controlled and the flame radius grows as gamma t. Theoretical calculations also show that for a constant fuel mass injection rate a quasi-steady state is developed in the region surrounded by the flame and the mass flow rate at any location inside this region equals the mass injection rate.

Atreya, Arvind↗

Observations of impact-induced molten metal-silicate partitioning

Observations of molten mid-ocean ridge basalt (MORB)-molybdenum (Mo) interactions produced by shock experiments provide insight into impact and differentiation processes involving metal-silicate partitioning. Analysis of fragments recovered from experiments (achieving MORB liquid shock pressures from 0.8 to 6 GPa) revealed significant changes in the composition of the MORB and Mo due to reaction of the silicate and metal liquids on a short time scale (less than 13 s). The FeO concentration of the shocked liquid decreases systematically with increasing pressure. In fact, the most highly shocked liquid (6 GPa) contains only 0.1 wt% FeO compared to an initial concentration of 9 wt% in the MORB. We infer from the presence of micrometer-sized Fe-, Si- and Mo-rich metallic spheres in the shocked glass that the Fe and Si oxides in the MORB were reduced in an estimated oxygen fugacity of 10(exp -17) bar and subsequently alloyed with the Mo. The in-situ reduction of FeO in the shocked molten basalt implies that shock-induced reduction of impact melt should be considered a viable mechanism for the formation of metallic phases. Similar metallic phases may form during impact accretion of planets and in impacted material found on the lunar surface and near terrestrial impact craters. In particular, the minute, isolated Fe particles found in lunar soils may have formed by such a process. Furthermore, the metallic spheres within the shocked glass have a globular texture similar to the textures of metallic spheroids from lunar samples and the estimated, slow cooling rate of less than or equal to 140 C/s for our spheres is consistent with the interpretation that the lunar spheroids formed by slow cooling within a melted target.

Rowan, Linda R.↗

Down-to-earth studies of carbon clusters

Recent advances in supersonic beam experiments with laser-vaporization sources of clusters have provided some interesting new insights into the nature of the small clusters of carbon, and the processes through which carbon condenses. One cluster in particular, C(sub 60), appears to play a central role. It is argued that this cluster takes the shape of a soccerball: a hollow sphere composed of a shell of 60 carbon atoms connected by a lattice of hexagonal and pentagonal rings, in a pattern of overall icosahedral symmetry. Although C(sub 60) appears to be uniquely stable due to its perfect symmetry, all other even-numbered carbon clusters in the 32 to 100+ atom size range seem to favor similar closed spheroidal forms. These species are interpreted as relatively unreactive side products in condensation reactions of carbon vapor involving spiraling graphitic sheets. The prevalence of C(sub 60) in laser-vaporized carbon vapors and sooting flames suggests that it may be formed readily whenever carbon condenses. Such ready formation and extraordinary stability may have substantial astrophysical implications.

Smalley, R. E.↗

Vertical Spin Tunnel Testing and Stability Analysis of Multi-Mission Earth Entry Vehicles

Multi-Mission Earth Entry Vehicles (MMEEVs) are blunt-body vehicles designed with the purpose of transporting payloads from space to the surface of the Earth. To achieve high reliability and minimum weight, MMEEVs avoid using limited-reliability systems, such as parachutes, retro-rockets, and reaction control systems and rely on the natural aerodynamic stability of the vehicle throughout the Entry, Descent, and Landing phases of flight. Testing in NASA Langley's 20-FT Vertical Spin Tunnel (20-FT VST), dynamically-scaled MMEEV models was conducted to improve subsonic aerodynamic models and validate stability criteria for this class of vehicle. This report documents the resulting data from VST testing for an array of 60-deg sphere-cone MMEEVs. Model configurations included were 1.2 meter, and 1.8 meter designs. The addition of a backshell extender, which provided a 150% increase in backshell diameter for the 1.2 meter design, provided a third test configuration. Center of Gravity limits were established for all MMEEV configurations. An application of System Identification (SID) techniques was performed to determine the aerodynamic coefficients in order to provide databases for subsequent 6-degree-of-freedom simulations.

Glaab, Louis J.↗