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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Design, performance, and field operation of twisting heliostats for 3,000-sun concentration and high temperature

The idea is to combine the solar energy reflected from a field of many heliostats to obtain a single focus of high concentration and high power. We exploit a new type of “twisting” heliostat” in which as the mount is moved to track the sun through the day, the reflector shape is twisted to maintain a focused image of the sun’s disc on the target, through the day over a wide range of angles of incidence. By combining the light reflected by many twisting heliostats into a single focus, we are not only able to accomplish but also maintain very high concentration and temperature through the day, with higher efficiency than has previously been possible with conventional heliostats having a fixed shape. A circular field of twisting heliostats is used to power a single intense focus atop a central tower. The light from all the heliostats is relayed to an upward facing receiver at the focus via a central Cassegrain secondary reflector located above the receiver. In a specific design targeting 1 MW of power, a 100 m diameter field arrays 431 twisting heliostats, each with a 7 m2 reflector. The secondary reflector ,7.2 m in diameter, is located 24 m above the heliostat field, bringing sunlight with annual average power of 1 MW to a circular focus 0.8 m in diameter, at a concentration averaging 3,000 suns.

14 SOLAR ENERGY↗

Potential Non-Linearities in the High Latitude Circulation and Ozone Response to Stratospheric Aerosol Injection

The impacts of Stratospheric Aerosol Injection (SAI) on the atmosphere and surface climate depend on when and where the sulfate aerosol precursors are injected, as well as on how much surface cooling is to be achieved. We use a set of CESM2(WACCM6) SAI simulations achieving three different levels of global mean surface cooling and demonstrate that unlike some direct surface climate impacts driven by the reflection of solar radiation by sulfate aerosols, the SAI-induced changes in the high latitude circulation and ozone are more complex and could be non-linear. This manifests in our simulations by disproportionally larger Antarctic springtime ozone loss, significantly larger intra-ensemble spread of the Arctic stratospheric jet and ozone responses, and non-linear impacts on the extratropical modes of surface climate variability under the strongest-cooling SAI scenario compared to the weakest one. These potential non-linearities may add to uncertainties in projections of regional surface impacts under SAI.

54 ENVIRONMENTAL SCIENCES↗

Diverse sediment microbiota shape methane emission temperature sensitivity in Arctic lakes

Abstract Northern post-glacial lakes are significant, increasing sources of atmospheric carbon through ebullition (bubbling) of microbially-produced methane (CH 4 ) from sediments. Ebullitive CH 4 flux correlates strongly with temperature, reflecting that solar radiation drives emissions. However, here we show that the slope of the temperature-CH 4 flux relationship differs spatially across two post-glacial lakes in Sweden. We compared these CH 4 emission patterns with sediment microbial (metagenomic and amplicon), isotopic, and geochemical data. The temperature-associated increase in CH 4 emissions was greater in lake middles—where methanogens were more abundant—than edges, and sediment communities were distinct between edges and middles. Microbial abundances, including those of CH 4 -cycling microorganisms and syntrophs, were predictive of porewater CH 4 concentrations. Results suggest that deeper lake regions, which currently emit less CH 4 than shallower edges, could add substantially to CH 4 emissions in a warmer Arctic and that CH 4 emission predictions may be improved by accounting for spatial variations in sediment microbiota.

54 ENVIRONMENTAL SCIENCES↗

A Comparison of Emerging and Industry Benchmark Photovoltaic Backsheets Between Different Outdoor Locations

Recent interest within the photovoltaic (PV) module industry is largely directed toward enhanced lifetimes in the field, balanced with improved recyclability. Traditionally, fluoropolymer-based backsheets have been used, however, are difficult to recycle. Emerging polyolefin (PO)-based backsheets are more recyclable and can be formulated to be robust. Properties of different fluoropolymer- and non-fluoropolymer-based backsheet coupons and in encapsulated silicon mini modules that have been fielded in Albuquerque, NM and Cocoa, FL are reported here. Seven backsheets were examined: two novel PO's, TPT, APO, PPE, AAA, and KPf. Methods of examination include module electrical performance (I - V flash test), surface morphology (optical microscope and gloss), polymer chemical structure (FTIR), EL imaging, mechanical tensile testing, DC breakdown voltage, DSC (phase transitions), and optical performance (reflectance spectra).

industries↗

Physical science research needed to evaluate the viability and risks of marine cloud brightening

Marine cloud brightening (MCB) is the deliberate injection of aerosol particles into shallow marine clouds to increase their reflection of solar radiation and reduce the amount of energy absorbed by the climate system. From the physical science perspective, the consensus of a broad international group of scientists is that the viability of MCB will ultimately depend on whether observations and models can robustly assess the scale-up of local-to-global brightening in today’s climate and identify strategies that will ensure an equitable geographical distribution of the benefits and risks associated with projected regional changes in temperature and precipitation. To address the physical science knowledge gaps required to assess the societal implications of MCB, we propose a substantial and targeted program of research—field and laboratory experiments, monitoring, and numerical modeling across a range of scales.

54 ENVIRONMENTAL SCIENCES↗

DOE-NOAA Marine Cloud Brightening (Workshop Report 2022)

Marine Cloud Brightening (MCB) refers to the deliberate injection of aerosol particles into marine clouds to increase their reflection of solar radiation to temporarily cool the planet while decarbonization efforts are pursued. A workshop was conducted to assess the state of knowledge in the field of MCB, and to provide a possible research path toward reducing unknowns in key components of the underlying physical science. This three-day workshop took place in April 2022 and was jointly sponsored by Department of Energy (DOE)’s Atmospheric System Research (ASR) program and the National Oceanic and Atmospheric Administration (NOAA). The workshop focused on identifying key physical science knowledge gaps necessary to answer the following driving questions: 1) Is MCB feasible over sufficiently large regions and is implementation practicable for long-enough durations to avert the worst impacts of global warming? 2) If practicable, what will be the regional impacts of such MCB interventions? 3) Do we have adequate systems in place to detect and quantify the effects of such interventions? 4) What physical and engineering science challenges must be resolved satisfactorily before we can consider embarking on MCB?

54 ENVIRONMENTAL SCIENCES↗

DOE-NOAA Marine Cloud Brightening Workshop

Marine Cloud Brightening (MCB) refers to the deliberate injection of aerosol particles into marine clouds to increase their reflection of solar radiation to temporarily cool the planet while decarbonization efforts are pursued. A workshop was conducted to assess the state of knowledge in the field of MCB, and to provide a possible research path toward reducing unknowns in key components of the underlying physical science. This three-day workshop took place in April 2022 and was jointly sponsored by Department of Energy (DOE)’s Atmospheric System Research (ASR) program and the National Oceanic and Atmospheric Administration (NOAA). The workshop focused on identifying key physical science knowledge gaps necessary to answer the following driving questions: 1. Is MCB feasible over sufficiently large regions and is implementation practicable for long-enough durations to avert the worst impacts of global warming? 2. If practicable, what will be the regional impacts of such MCB interventions? 3. Do we have adequate systems in place to detect and quantify the effects of such interventions? 4. What physical and engineering science challenges must be resolved satisfactorily before we can consider embarking on MCB?

54 ENVIRONMENTAL SCIENCES↗

African smoke particles act as cloud condensation nuclei in the wintertime tropical North Atlantic boundary layer over Barbados

Abstract. The number concentration and properties of aerosol particles serving as cloud condensation nuclei (CCN) are important for understanding cloud properties, including in the tropical Atlantic marine boundary layer (MBL), where marine cumulus clouds reflect incoming solar radiation and obscure the low-albedo ocean surface. Studies linking aerosol source, composition, and water uptake properties in this region have been conducted primarily during the summertime dust transport season, despite the region receiving a variety of aerosol particle types throughout the year. In this study, we compare size-resolved aerosol chemical composition data to the hygroscopicity parameter κ derived from size-resolved CCN measurements made during the Elucidating the Role of Clouds–Circulation Coupling in Climate (EUREC4A) and Atlantic Tradewind Ocean-Atmosphere Mesoscale Interaction Campaign (ATOMIC) campaigns from January to February 2020. We observed unexpected periods of wintertime long-range transport of African smoke and dust to Barbados. During these periods, the accumulation-mode aerosol particle and CCN number concentrations as well as the proportions of dust and smoke particles increased, whereas the average κ slightly decreased (κ=0.46±0.10) from marine background conditions (κ=0.52±0.09) when the submicron particles were mostly composed of marine organics and sulfate. Size-resolved chemical analysis shows that smoke particles were the major contributor to the accumulation mode during long-range transport events, indicating that smoke is mainly responsible for the observed increase in CCN number concentrations. Earlier studies conducted at Barbados have mostly focused on the role of dust on CCN, but our results show that aerosol hygroscopicity and CCN number concentrations during wintertime long-range transport events over the tropical North Atlantic are also affected by African smoke. Our findings highlight the importance of African smoke for atmospheric processes and cloud formation over the Caribbean.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Vegetation Warming Experiment: Environmental Conditions, Utqiagvik (Barrow), Alaska, 2018

Environmental conditions measured in five warming chambers and paired ambient control plots located on the Barrow Environmental Observatory (BEO), Utqiagvik, Alaska from 16 June - 24 September, 2018. These data were recorded in support of the Zero Power Warming (ZPW) vegetation warming experiment, a series of single season vegetation warming treatments conducted over four years from 2017-2021 (no experiment in 2020). Air temperature and humidity, infrared surface (canopy) temperature, soil temperature, soil moisture, NDVI (normalized difference vegetation index), PRI (photochemical reflectance index), solar radiation and chamber venting were recorded in each chamber at 1 minute intervals. Ambient air temperature, humidity, solar radiation and uplooking PRI and NDVI were measured at a centrally located meteorology station. Vapor pressure deficit (VPD) was calculated and included in the final processed data products. Data has undergone full QA/QC and is presented as 1 minute data, and hourly and daily aggregate data products. This data package includes unprocessed raw data (*.dat files), processed data (*.csv) and metadata including a full description of sensors, calculations and processing (*.csv, *.pdf). See related NGEE-Arctic "Vegetation Warming Experiment" data packages for leaf-level gas exchange and other leaf trait data; chamber, plot and landscape phenocamera images; thaw depth, and GPS locations of chambers and ambient plots.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a 15-year research effort (2012-2027) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Vegetation Warming Experiment: Environmental conditions, Utqiagvik (Barrow), Alaska, 2019

Environmental conditions measured in five warming chambers and paired ambient control plots located on the Barrow Environmental Observatory (BEO), Utqiagvik, Alaska from 19 June – 25 September, 2019. These data were recorded in support of the Zero Power Warming (ZPW) vegetation warming experiment, a series of single season vegetation warming treatments conducted over four years from 2017–2021 (no experiment in 2020). Air temperature and humidity, infrared surface (canopy) temperature, soil temperature, soil moisture, NDVI (normalized difference vegetation index), PRI (photochemical reflectance index), solar radiation and chamber venting were recorded in each chamber at 1 minute intervals. Ambient air temperature, humidity, solar radiation and uplooking PRI and NDVI were measured at a centrally located meteorology station. Vapor pressure deficit (VPD) was calculated and included in the final processed data products. Data has undergone full QA/QC and is presented as 1 minute data, and hourly and daily aggregate data products. This data package includes unprocessed raw data (*.dat files), processed data (*.csv) and metadata including a full description of sensors, calculations and processing (*.csv, *.pdf). See related NGEE-Arctic "Vegetation Warming Experiment" data packages for leaf-level gas exchange and other leaf trait data; chamber, plot and landscape phenocamera images; thaw depth, and GPS locations of chambers and ambient plots.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a 15-year research effort (2012-2027) to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Vegetation Warming Experiment: Environmental Conditions, Utqiagvik (Barrow), Alaska, 2017

Environmental conditions measured in five warming chambers and paired ambient control plots located on the Barrow Environmental Observatory (BEO), Utqiagvik, Alaska from 22 June - 17 September, 2017. These data were recorded in support of the Zero Power Warming (ZPW) vegetation warming experiment, a series of single season vegetation warming treatments conducted over four years from 2017-2021 (no experiment in 2020). Air temperature and humidity, infrared surface (canopy) temperature, soil temperature, soil moisture, NDVI (normalized difference vegetation index), PRI (photochemical reflectance index), solar radiation and chamber venting were recorded in each chamber at 1 minute intervals. Ambient air temperature, humidity, solar radiation and uplooking PRI and NDVI were measured at a centrally located meteorology station. Vapor pressure deficit (VPD) was calculated and included in the final processed data products. Data has undergone full QA/QC and is presented as 1 minute data, and hourly and daily aggregate data products. This data package includes unprocessed raw data (*.dat files), processed data (*.csv) and metadata including a full description of sensors, calculations and processing (*.csv, *.pdf). See related NGEE-Arctic Vegetation Warming Experiment data packages for leaf-level gas exchange and other leaf trait data; chamber, plot and landscape phenocamera images; thaw depth, and GPS locations of chambers and ambient plots. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

Vegetation Warming Experiment: Environmental conditions, Utqiagvik (Barrow), Alaska, 2021

Environmental conditions measured in five warming chambers and paired ambient control plots located on the Barrow Environmental Observatory (BEO), Utqiagvik, Alaska from 19 June - 17 September, 2021. These data were recorded in support of the Zero Power Warming (ZPW) vegetation warming experiment, a series of single season vegetation warming treatments conducted over four years from 2017-2021 (no experiment in 2020). Air temperature and humidity, infrared surface (canopy) temperature, soil temperature, soil moisture, NDVI (normalized difference vegetation index), PRI (photochemical reflectance index), solar radiation and chamber venting were recorded in each chamber at 1 minute intervals. Ambient air temperature, humidity, solar radiation and uplooking PRI and NDVI were measured at a centrally located meteorology station. Vapor pressure deficit (VPD) was calculated and included in the final processed data products. Data has undergone full QA/QC and is presented as 1 minute data, and hourly and daily aggregate data products. This data package includes unprocessed raw data (*.dat files), processed data (*.csv) and metadata including a full description of sensors, calculations and processing (*.csv, *.pdf). See related NGEE-Arctic "Vegetation Warming Experiment" data packages for leaf-level gas exchange and other leaf trait data; chamber, plot and landscape phenocamera images; thaw depth, and GPS locations of chambers and ambient plots. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

3D Bacterial flagella as both synthetic biotemplates and ultrathin spacers for enhanced inter-particle coupling and solar energy harvesting

Linear light-absorbing nanomaterials are ideal for film-based solar harvesting applications as they form porous structures that can maximize the absorption and minimize the reflection of the solar light. Conventional 1D nanochains of plasmonic nanoparticle assemblies can achieve significantly broadened optical absorption through surface plasmon coupling, but their optical bands are still not broad enough to absorb through the solar spectrum and thus are not efficient solar absorbers. Here we discovered first by simulation that 3D structured nanochains of plasmonic nanoparticles presented a remarkably increased optical broadening effect and much longer redshift of the optical peaks due to the enhanced inter-particle coupling effect. Then we fabricated 3D nanochains by assembling gold nanoparticles (AuNPs) around 14 nm ultrathin bionanofibers, the bacterial flagella. Additionally, the ultrathin biotemplates enabled the 3D arrangement of 50 nm AuNPs along the nanofiber with a very small inter-particle gap, allowing the strong coupling of surface plasmons in a 3D manner. Consistent with the theoretical prediction, the 3D nanochains, when assembled into films, could effectively convert nearly the full spectrum of solar energy into heat, which was further efficiently converted into electricity through a thermoelectric generation unit. Our work represents a nanobiomaterial approach to highly efficient solar thermal power generation.

36 MATERIALS SCIENCE↗

Snow ALbedo eVOlution (SALVO) Campaign Spectral Albedo and Related Measurements from April - June, 2024 in Utqiagivk, AK

A field-portable spectroradiometer, referred to herein as an ‘ASD’, was used to make spatially-distributed spectral albedo (350 – 2500 nm) measurements on tundra and sea ice surfaces. The ASD detector is carried in a backpack and controlled via a computer mounted on the front of the operator (see Figure 1). The ASD measures the spectral irradiance from a fiber optic cable that is routed from the backpack to a custom, gooseneck cosine collector mounted on the end of a 1-m long boom (Grenfell and Perovich, 2008). The boom was held at hip height (approximately 1 m) and had an integrated bubble level for levelling. To make an albedo measurement, first the operator collect an incident (down-welling) irradiance, followed by a reflected (up-welling) measurement. The time between incident and reflected measurements was typically between 11 and 26 seconds (interquartile range). For each measurement, 10 spectra are averaged together. Albedo is calculated as the ratio of the reflected to incident measurement, which obviates the need for absolute radiometric calibration. Albedo measurements were taken parallel to the 200-m albedo lines at 5-m increments (41 measurements) ~1 m south of the line. While the ASD operator was making measurements, an assistant kept notes on the scan number associated with each measurement, the surface type (see below), and collected photos of each measurement (see companion oblique photos data archive). Measurements were made within 3 hours of solar noon.

ASD Spectroradiometer↗

Satellite solar-induced chlorophyll fluorescence and near-infrared reflectance capture complementary aspects of dryland vegetation productivity dynamics

Mounting evidence indicates dryland ecosystems play an important role in driving the interannual variability and trend of the terrestrial carbon sink. Nevertheless, our understanding of the seasonal dynamics of dryland ecosystem carbon uptake through photosynthesis [gross primary productivity (GPP)] remains relatively limited due in part to the limited availability of long-term data and unique challenges associated with satellite remote sensing across dryland ecosystems. Here, we comprehensively evaluated longstanding and emerging satellite vegetation proxies in their ability to capture seasonal dryland GPP dynamics. Specifically, we evaluated: 1) reflectance-based proxies normalized difference vegetation index (NDVI), soil adjusted vegetation index (SAVI), near infrared reflectance index (NIR v ), and kernel NDVI (kNDVI) from the MODerate resolution Imaging Spectroradiometer (MODIS); and 2) newly available physiologically-based proxy solar-induced chlorophyll fluorescence (SIF) from the TROPOspheric Monitoring Instrument (TROPOMI). As a performance benchmark, we used GPP estimates from a robust network of 21 western United States eddy covariance tower sites that span representative gradients in dryland ecosystem climate and functional composition. We found that NIR v and SIF were the best performing GPP proxies and captured complementary aspects of seasonal GPP dynamics across dryland ecosystem types. NIR v offered better performance than the other proxies across relatively low-productivity, sparsely non-evergreen vegetated sites (R 2 = 0.59 ± 0.13); whereas SIF best captured seasonal dynamics across relatively high-productivity sites, including evergreen-dominated sites (R 2 = 0.74 ± 0.07). Notably, across grass-dominated sites, all reflectance-based proxies (NDVI, SAVI, NIRv and kNDVI) showed significant seasonal bias (hysteresis) that strengthened with the total fraction of woody vegetation cover, likely due to seasonal patterns in woody vegetation reflectance that are unrelated to or decoupled from GPP. In conclusion, future efforts to fully integrate the complementary strengths of NIR v and SIF could significantly improve our understanding and representation of dryland GPP dynamics in satellite-based models.

54 ENVIRONMENTAL SCIENCES↗

Graded Buffer Bragg Reflectors with High Reflectivity and Transparency for Metamorphic Optoelectronics

A graded buffer Bragg reflector (GBBR) is a bifunctional device component that provides the reflection of a distributed Bragg reflector and the adjustable lattice constant of a compositionally graded buffer. Prior work showed that these properties can be combined with low threading dislocation density and high reflectivity. Here, we design and demonstrate complex GBBRs for specific metamorphic solar cell applications. We design buffers that provide (1) high reflectivity over a narrow bandwidth, for quantum well solar cells, (2) reflectivity over a wide bandwidth, for optically thin solar cells, and (3) low sidelobe reflection, for multijunction devices that demand low out-of-band reflection. Apodized and triple GBBRs are demonstrated, and transparency is always considered, requiring designs with carefully engineered material combinations. A GBBR with a reflection of 99% is demonstrated, as well as a triple GBBR that has over 80% reflection for 100?nm of the spectrum around 800?nm. We also analyze potential deviations in a baseline GBBR from that of a perfect DBR using transmission electron microscopy to analyze imperfections in the material and modeling to analyze the impact of imperfect refractive index data for lattice-mismatched AlGaInAs. Minimal crosshatch roughness and unintentional thickness variation occur throughout the buffer, which likely influences reflection slightly. Small deviations between the calculated AlGaInAs and utilized AlGaAs refractive index exist, giving methods for future GBBR improvement. While the GBBR designs are intended for metamorphic solar cells, the broad and high reflection may also be useful for other optoelectronic devices such as light-emitting diodes or lasers.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Cloud water adjustments to aerosol perturbations are buffered by solar heating in non-precipitating marine stratocumuli

Abstract. Marine low-level clouds are key to the Earth's energy budget due to their expansive coverage over global oceans and their high reflectance of incoming solar radiation. Their responses to anthropogenic aerosol perturbations remain the largest source of uncertainty in estimating the anthropogenic radiative forcing of climate. A major challenge is the quantification of the cloud water response to aerosol perturbations. In particular, the presence of feedbacks through microphysical, dynamical, and thermodynamical pathways at various spatial and temporal scales could augment or weaken the response. Central to this problem is the temporal evolution in cloud adjustment, governed by entangled feedback mechanisms. We apply an innovative conditional Monte Carlo subsampling approach to a large ensemble of diurnal large-eddy simulation of non-precipitating marine stratocumulus to study the role of solar heating in governing the evolution in the relationship between droplet number and cloud water. We find a persistent negative trend in this relationship at night, confirming that the role of microphysically enhanced cloud-top entrainment. After sunrise, the evolution in this relationship appears buffered and converges to ∼-0.2 in the late afternoon. This buffering effect is attributed to a strong dependence of cloud-layer shortwave absorption on cloud liquid water path. These diurnal cycle characteristics further demonstrate a tight connection between cloud brightening potential and the relationship between cloud water and droplet number at sunrise, which has implications for the impact of the timing of advertent aerosol perturbations.

Zhang, Jianhao (ORCID:0000000169882935)↗