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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

Direct measurement of the fundamental rotational transitions of the OH radical by laser sideband spectroscopy

The direct (zero-field) spectra of the fundamental rotational transitions of the OH radical in its Omega = 3/2 and 1/2 states at 2509.9 and 1834.7 GHz are obtained using a recently developed far-infrared laser sideband spectrometer. These measurements have verified and refined the predictions of previous laser magnetic resonance work, thereby confirming the far-infrared detection of interstellar OH. The increased accuracy of these direct measurements will be useful to future astronomical and atmospheric studies of these important transitions.

Farhoomand, J.↗

Velocity, Temperature and Density Measurements in Supersonic Jets

Prediction of the flow field properties in supersonic jets using computational fluid dynamics (CFD) codes is challenging when there is a significant temperature difference between the jet core and the ambient air and/or compressibility effects are substantial. A benchmark set of flow field property data were obtained to assess current CFD capabilities and develop better modeling approaches for these turbulent flow fields where accurate calculation of turbulent heat flux is important. Three different convergent-divergent nozzles were investigated with exit Mach numbers of: 1.36, 1.63 and 2.0 at their perfectly expanded conditions. The conditions of the jet were set to obtain a temperature difference of zero between the jet core and the ambient air, and then the temperature difference was progressively increased, at the same jet Mach number. Particle Image Velocimetry (PIV), spontaneous rotational Raman scattering spectroscopy (SRS), Background Oriented Schlieren (BOS) and probe-based measurements were used to acquire high quality, spatially-resolved measurements of the mean and root mean square (rms) velocities as well as the mean and rms gas temperatures and densities in both hot and cold supersonic jet flows. The non-intrusive flow measurements are compared both against probe measurements and against standard Reynolds averaged Navier-Stokes (RANS) predictions of the supersonic jet flow properties.

Rotational Raman Spectroscopy↗

Ultraviolet Spectropolarimetry: on the Origin of Rapidly Rotating B Stars

UV spectroscopy and spectropolarimetry hold the key to understanding certain aspects of massive stars that are largely inaccessible (or exceptionally difficult) with optical or longer wavelength observations. As we demonstrate, this is especially true for the rapidly-rotating Be and Bn stars, owing to their high temperatures, geometric asymmetries, binary properties, evolutionary history, as well as mass ejection and disks (in the case of Be stars). UV spectropolarimetric observations are extremely sensitive to the photospheric consequences of rapid rotation (i.e. oblateness, temperature, and surface gravity gradients), far beyond the reach of optical wavelengths. Our polarized radiative-transfer modelling predicts that with low-resolution UV spectropolarimetry covering 120–300 nm, and with a reasonable SNR, the inclination angle of a rapid rotator can be determined to within 5 degrees, and the rotation rate to within 1%. The origin of rapid rotation in Be/n stars can be explained by either single-star or binary evolution, but their relative importance is largely unknown. Some Be stars have hot sub-luminous (sdO) companions, which at an earlier phase transferred their envelope (and with it mass and angular momentum) to the present-day rapid rotator. Although sdO stars are small and relatively faint, their flux peaks in the UV making this the optimal observational wavelength regime. Through spectral modelling of a wide range of simulated Be/n+sdO configurations, we demonstrate that high-resolution high-signal-to-noise ratio UV spectroscopy can detect an sdO star even when ∼1,000 times fainter in the UV than its Be/n star companion. This degree of sensitivity is needed to more fully explore the parameter space of Be/n+sdO binaries, which so far has been limited to about a dozen systems with relatively luminous sdO stars. We suggest that a UV spectropolarimetric survey of Be/n stars is the next step forward in understanding this population. Such a dataset would, when combined with population synthesis models, allow for the determination of the relative importance of the possible evolutionary pathways traversed by these stars, which is also crucial for understanding their future evolution and fate.

Ultraviolet astronomy↗

MR Persei - A new rotating, spotted flare star

Spectroscopy and photometry are used to show that MR Persei, an object originally classified as a dwarf nova, is in fact a flare star. The automated CCD photometry consists of sequences of exposures within a single night as well as long-term photometry over a five-month interval. One sequence shows a 30-min flare, accompanied by post-flare 'dips'. A 0.2 mag variation with a period of about one-half day is also seen in this sequence. The long-term photometry is used to refine the period to 0.45483 d, which we attribute to the rotation of a spotted star. Evidence for membership of MR Per in the young Alpha Per cluster is considered, and found to be inconclusive.

Honeycutt, R. K.↗

The study of molecular spectroscopy by ab initio methods

This review illustrates the potential of theory for solving spectroscopic problems. The accuracy of approximate techniques for including electron correlation have been calibrated by comparison with full configuration-interaction calculations. Examples of the application of ab initio calculations to vibrational, rotational, and electronic spectroscopy are given. It is shown that the state-averaged, complete active space self-consistent field, multireference configuration-interaction procedure provides a good approach for treating several electronic states accurately in a common molecular orbital basis.

Bauschlicher, Charles W., Jr.↗

Infrared vibration-rotation spectra of the ClO radical using tunable diode laser spectroscopy

Tunable diode laser spectroscopy is used to measure the infrared vibration-rotation spectra of the ClO radical. The radical is generated in a flow system where a Cl2-He mixture passes through a microwave discharge to dissociate the Cl2. An O3-O2 mixture from an ozone generator is injected into the system downstream of the microwave discharge where O3 combines with Cl to form ClO. By adjusting the gas flow rates to yield an excess of Cl atoms, all the ozone is combined. ClO concentration is measured with UV absorption at 2577 and 2772 A and a deuterium lamp as a continuous source. Total cell pressure is 5.5 torr. The diode laser spectrometer is calibrated with ammonia lines as a reference where possible. The frequency of vibration-rotation lines is expressed as a function of rotational quantum number, fundamental vibrational frequency, and the rotational constants of the upper and lower vibrational states.

Rogowski, R. S.↗

Rotational Raman-Based Temperature Measurements in a High-Velocity Turbulent Jet

Spontaneous rotational Raman scattering spectroscopy is used to acquire the first ever high quality, spatially-resolved measurements of the mean and root mean square (rms) temperature fluctuations in turbulent, high-velocity heated jets. Raman spectra in air were obtained across a matrix of radial and axial locations downstream from a 50 mm diameter nozzle operating from subsonic to supersonic conditions over a wide range of temperatures and Mach numbers, in accordance with the Tanna matrix frequently used in jet noise studies. These data were acquired in the hostile, high noise (115 dB) environment of a large scale open air test facility at NASA Glenn Research Center (GRC). Temperature estimates were determined by performing nonlinear least squares fitting of the single shot spectra to the theoretical rotational Stokes spectra of N2 and O2, using a custom in-house code developed specifically for this investigation. The laser employed in this study was a high energy, long-pulsed, frequency doubled Nd:YAG laser. One thousand single-shot spectra were acquired at each spatial coordinate. Mean temperature and rms temperature variations were calculated at each measurement location. Excellent agreement between the averaged and single-shot temperatures was observed with an accuracy better than 2.5 percent for temperature, and rms variations in temperature between +/-2.2 percent at 296 K and +/-4.5 percent at 850 K. The results of this and planned follow-on studies will support NASA GRC's development of physics-based jet noise prediction, turbulence modeling and aeroacoustic source modeling codes.

Randy J Locke↗

Rotational Raman-Based Temperature Measurements in a High-Velocity Turbulent Jet

Spontaneous rotational Raman scattering spectroscopy is used to acquire the first ever high quality, spatially-resolved measurements of the mean and root mean square (rms) temperature fluctuations in turbulent, high-velocity heated jets. Raman spectra in air were obtained across a matrix of radial and axial locations downstream from a 50 mm diameter nozzle operating from subsonic to supersonic conditions over a wide range of temperatures and Mach numbers, in accordance with the Tanna matrix frequently used in jet noise studies. These data were acquired in the hostile, high noise (115 dB) environment of a large scale open air test facility at NASA Glenn Research Center (GRC). Temperature estimates were determined by performing nonlinear least squares fitting of the single shot spectra to the theoretical rotational Stokes spectra of N2 and O2, using a custom in-house code developed specifically for this investigation. The laser employed in this study was a high energy, long-pulsed, frequency doubled Nd:YAG laser. One thousand single-shot spectra were acquired at each spatial coordinate. Mean temperature and rms temperature variations were calculated at each measurement location. Excellent agreement between the averaged and single-shot temperatures was observed with an accuracy better than 2.5 percent for temperature, and rms variations in temperature between +/-2.2 percent at 296 K and +/-4.5 percent at 850 K. The results of this and planned follow-on studies will support NASA GRC's development of physics-based jet noise prediction, turbulence modeling and aeroacoustic source modeling codes.

Randy J Locke↗

A tunable line filter polychromator for gas temperature measurements using laser Raman scattering

A proprietary laser line filter spectrograph (LLFS) was modified to test for improved remote measurement of atmospheric temperature by Raman spectroscopy of the rotational bands of N2 and O2. Both grating scan measurements with fixed PMT and polychromator image plane PMT scans with fixed grating setting were made using HeNe and Ar(+) lasers. The LLFS was found to have a laser line rejection ratio at 6A from the laser line and provides resolved rotational Raman spectral display at the polychromator exit plane. Spectral resolution is adequate to measure and correct for background in the Stokes spectrum. It is anticipated that this system should allow measurement of gas or atmospheric temperature to + or - 1 C.

Grossman, J. J.↗

New observations of a large concentration of ClO in the springtime lower stratosphere over Antarctica and its implications for ozone-depleting chemistry

New measurements of stratospheric chlorine monoxide (ClO) were made at McMurdo Station, Antarctica, during the austral spring of 1987. Rotational emission line spectroscopy, employing a ground-based detector, was used to determine mixing ratio profiles over the range about 17-45 km. A spectral band pass double that was used for similar measurements in 1986 allowed an improvement to be made in the definition of the anomalous low-altitude stratospheric ClO layer associated with springtime ozone depletion. A peak mixing ratio of 1.6 + or - 0.4 parts per billion by volume (ppbv) (95 percent confidence level) was found at 19.5 + or - 1 km at midday during the period September 20-24, 1987. The observed peak mixing ratio and diurnal behavior are discussed in relation to chemical depletion theories. Calculations indicate that the large observed ClO concentration provides an efficient closure for a catalytic Cl cycle through the ClO dimer mechanism, yielding good agreement with various observed features of O3 depletion.

De Zafra, R. L.↗

Velocity, Temperature and Density Measurements in Supersonic Jets

Prediction of the flow field properties in supersonic jets using computational fluid dynamics (CFD) codes is challenging when there is a significant temperature difference between the jet core and the ambient air and/or compressibility effects are substantial. A benchmark set of flow field property data were obtained to assess current CFD capabilities and develop better modeling approaches for these turbulent flow fields where accurate calculation of turbulent heat flux is important. Three different convergent-divergent nozzles were investigated with exit Mach numbers of: 1.36, 1.63 and 2.0 at their perfectly expanded conditions. The conditions of the jet were set to obtain a temperature difference of zero between the jet core and the ambient air, and then the temperature difference was progressively increased, at the same jet Mach number. Particle Image Velocimetry (PIV), spontaneous rotational Raman scattering spectroscopy (SRS), Background Oriented Schlieren (BOS) and probe-based measurements were used to acquire high quality, spatially-resolved measurements of the mean and root mean square (rms) velocities as well as the mean and rms gas temperatures and densities in both hot and cold supersonic jet flows. The non-intrusive flow measurements are compared both against probe measurements and against standard Reynolds averaged Navier-Stokes (RANS) predictions of the supersonic jet flow properties.

Raman Spectroscopy↗

Enhanced Raman spectroscopic study of rotational isomers on metal surfaces

Surfaced-enhanced Raman spectroscopy has been used to study rotational isomers of succinonitrile and N-methyl-thioacetamide on Cu and Ag surfaces. Both the gauche and trans conformers of succinonitrile are found to chemisorb on the metal surface. The doubly degenerate nu(C-triple bond-N) in the free molecules is removed when succinonitrile adsorbs on copper, which indicates that the two (C-triple bond-N) groups are no longer chemically equivalent. Both conformers are found to coordinate to the copper surface through the pi system of one of the two (C-triple bond-N) groups. In the case of N-methyl-thioacetamide, the population of the cis isomer is greatly increased on Cu and Ag surfaces. This is probably due to surface-induced cis-trans isomerization, in which the predominant trans isomer is converted to the cis isomer.

Loo, B. H.↗

PIV and Rotational Raman-Based Temperature Measurements for CFD Validation in a Single Injector Cooling Flow

Film cooling is used in a wide variety of engineering applications for protection of surfaces from hot or combusting gases. The design of more efficient thin film cooling geometries/configurations could be facilitated by an ability to accurately model and predict the effectiveness of current designs using computational fluid dynamics (CFD) code predictions. Hence, a benchmark set of flow field property data were obtained for use in assessing current CFD capabilities and for development of better turbulence models. Both Particle Image Velocimetry (PIV) and spontaneous rotational Raman scattering (SRS) spectroscopy were used to acquire high quality, spatially-resolved measurements of the mean velocity, turbulence intensity and also the mean temperature and normalized root mean square (rms) temperatures in a single injector cooling flow arrangement. In addition to flowfield measurements, thermocouple measurements on the plate surface enabled estimates of the film effectiveness. Raman spectra in air were obtained across a matrix of radial and axial locations downstream from a 68.07 mm square nozzle blowing heated air over a range of temperatures and Mach numbers, across a 30.48cm long plate equipped with a single injector cooling hole. In addition, both centerline streamwise 2-component PIV and cross-stream 3-component Stereo PIV data at 15 axial stations were collected in the same flows. The velocity and temperature data were then compared against Wind-US CFD code predictions for the same flow conditions. The results of this and planned follow-on studies will support NASA's development and assessment of turbulence models for heated flows.

Turbulence Modeling↗

The millimeter and submillimeter rotational spectrum of the MgCN radical (X (sup 2) Sigma(+))

The pure rotational spectrum of the MgCN radical has been recorded in the laboratory using millimeter/submillimeter direct absorption spectroscopy. Twenty-seven rotational transitions of the species were observed in the range 101-376 GHz and indicate that the molecule is linear with a (sup 2)Sigma(+) ground electronic state, as predicted by theory. Spin rotation interactions were resolved in the spectra, but no hyperfine splittings were observed, which would originate with the nitrogen nuclear spin. The rotational and fine-structure constants were determined for this radical from a nonlinear least-squares fit to the data using a (sup 2)Sigma Hamiltonian. MgCN is of astrophysical interest because it is the metastable isomer of MgNC, which recently has been detected toward IRC +10216

Anderson, M. A.↗

Voyager measurement of the rotation period of Saturn's magnetic field

Saturn's radio rotation period was determined using measurements made by the planetary radio astronomy experiment onboard the Voyager spacecraft. The sidereal period deduced, 10 hr 39 min 24 sec ? 7 sec, is within the 10 hr to 11 hr range of optical periods derived from a century of atmospheric spot and Doppler spectroscopy observations. The radio rotation period is presumably that of the planet's magnetic field. A provisional Saturn longitude convention is proposed and equations are provided to compute a longitude ephemeris and to transform between the proposed system and the (10 hr 14 min) system used for the Pioneer 11/Saturn encounter. The degree of longitude smearing which could result over the long term from the merging of data sets organized in this system is evaluated. No evidence of control of the radio emission by any of Saturn's satellites was found.

Desch, M. D.↗

Rotationally resolved collisional transfer rates in OH

Fluorescence lidar measurements of the hydroxyl radical require detailed information concerning collision induced processes in order to deduce the radical number density from a lidar return. The Goddard SFC OH lidar currently utilizes a broadband detector which precludes the necessity of fully understanding collisional redistribution of rotational energy within the excited state. Numerous advantages result however from the inclusion of a detector with a bandpass only slightly larger that the Doppler width of a rotational line. This however places more stringent requirements on the spectroscopy. Measurements were accordingly made of rotationally resolved quenching rates for collisions with O2, N2, and H2O. Rotational transfer rates were also measured for the same colliders. Quenching rates were measured using a Nd-YAG pumped Rh6G dye laser doubled into the UV. The OH lifetimes were measured as a function of pressure of quenching gas at total pressures of between 50 and 250 microns. Rotational transfer rates were measured by recording the emission spectrum on an intensified diode array and integrating over 10.000 laser shots.

Mcgee, T. J.↗

Rotational modulation and flares on RS CVn and BY Draconis stars. XIII - IUE spectroscopy and photometry of II Pegasi during September 1986

UV spectroscopy obtained for the RS CVn star II Pegasi in September, 1986, indicates the presence of a rotational modulation effect for the Mg II h and k and O I 1305 A lines; the largest flux is observed when the primary spot concentration is nearly on the opposite hemisphere, and the rotational modulation is noted to be of opposite sense to that observed in 1981. Optical photometry shows the largest concentration of spots on one hemisphere ever observed on II Peg, implying a spot group covering over 50 percent of the projected area of one hemisphere.

Doyle, J. G.↗