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The flux ratio of the [N II] λ λ 6548, 6583 Å lines in sample of Active Galactic Nuclei Type 2

In spectra of the Active Galactic Nuclei (AGNs), the [N II]λλ 6548, 6583 Å lines are commonly fitted using the fixed intensity ratio of these two lines (R [NII] = I 6583 /I 6548 ). However, the used values for fixed intensity ratio are slightly different through literature. There are several theoretical calculations of the transition probabilities which can be used for the line ratio estimation, but there are no experimental measurements of this ratio, since the [N II] lines are extremely weak in laboratory plasma. Therefore, the intensity ratio of [N II] lines can be measured only in the spectra of astrophysical objects. However, precise and systematic measurements have not be done so far, because of difficulties in measurement of the [N II] ratio in various spectra (overlapping with Hα, weak intensity of [N II], influence of the continuum noise and outflow contribution, etc.). Here we present the measurements of the flux ratio of the [N II] λλ 6548, 6583 Å emission lines for a sample of 250 Type 2 AGNs spectra taken form Sloan Digital Sky Survey (SDSS) data base. Further, the spectra are chosen to have high signal-to-noise ratio and to [N II] and Hα lines do not overlap. The obtained mean flux ratio from measurements is 3.049 ± 0.021. Our result is in agreement with theoretical result obtained by taking into account the relativistic corrections to the magnetic dipole operator.

79 ASTRONOMY AND ASTROPHYSICS↗

EUV emission from a sample of Active Galactic Nuclei

Active Galactic Nuclei (AGN) emit a substantial fraction of their total radiated power in the EUV passband, because spectroscopically this band is situated at or near the peak of the 'big blue bump,' which is bounded on either side by the UV and soft X-ray excesses. Owing to the lack of observational data, the shape of AGN spectra in the EUV is not well known. This paper presents broad band (65-190 eV) count rates of 11 AGN detected by the Extreme Ultraviolet Explorer (EUVE). Assuming a power law spectral shape for the EUV and soft X-ray energies, we demonstrate that the photon indices of the sources are considerably steeper than typical AGN indices. For 6 sources where ROSAT data are available to provide a more precise determination of their spectral parameters in the 0.1-2.5 keV range, we have used these parameters to compute predicted EUVE count rates and compared them with the observed values. The two sets of quantities agree to within experimental error. We conclude that there is no evidence of spectral steepening or turn-over of the soft X-ray excess at EUV wavelengths for a sample of AGN which covers a wide range of brightness.

Lieu, R.↗

Independent Verification Survey of Section 3, Survey Units 1, 4 and 5 Excavated Surfaces, Whittaker Corporation, Reynolds Industrial Park, Transfer, Pennsylvania (Interim Report)

At Pennsylvania Department of Environmental Protection's request, ORAU's IEAV program conducted verification surveys on the excavated surfaces of Section 3, SUs 1, 4, and 5 at the Whittaker site on March 13 and 14, 2013. The survey activities included visual inspections, gamma radiation surface scans, gamma activity measurements, and soil sampling activities. Verification activities also included the review and assessment of the licensee's project documentation and methodologies. Surface scans identified four areas of elevated direct gamma radiation distinguishable from background; one area within SUs 1 and 4 and two areas within SU5. One area within SU5 was remediated by removing a golf ball size piece of slag while ORAU staff was onsite. With the exception of the golf ball size piece of slag within SU5, a review of the ESL Section 3 EXS data packages for SUs 1, 4, and 5 indicated that these locations of elevated gamma radiation were also identified by the ESL gamma scans and that ESL personnel performed additional investigations and soil sampling within these areas. The investigative results indicated that the areas met the release criteria.

54 ENVIRONMENTAL SCIENCES↗

The BRAVE Program. I. Improved Bulge Stellar Velocity Dispersion Estimates for a Sample of Active Galaxies

We present new bulge stellar velocity dispersion measurements for 10 active galaxies with secure M {sub BH} determinations from reverberation mapping. These new velocity dispersion measurements are based on spatially resolved kinematics from integral-field (IFU) spectroscopy. In all but one case, the field of view of the IFU extends beyond the effective radius of the galaxy, and in the case of Mrk 79 it extends to almost one half the effective radius. This combination of spatial resolution and field of view allows for secure determinations of stellar velocity dispersion within the effective radius for all 10 target galaxies. Spatially resolved maps of the first ( V ) and second ( σ {sub ⋆}) moments of the line of sight velocity distribution indicate the presence of kinematic substructure in most cases. In future projects we plan to explore methods of correcting for the effects of kinematic substructure in the derived bulge stellar velocity dispersion measurements.

79 ASTRONOMY AND ASTROPHYSICS↗

Collecting Samples from the Máaz Formation of Jezero Crater with the Mars 2020 Perseverance Rover

Collection of samples that could be returned to Earth from the floor of Jezero,a Noachian crater characterized by a delta–lake system with high potential for habitability, is a major goal of the Mars 2020 mission. The Mars 2020 Perseverancerover iscurrently exploringthe Máaz and Séítahformationsto the southeastof the delta. Here wefocus on thecrater-retainingMáaz formation, a widespread, rough and fractured terrain with lobatemarginsmapped in orbital images, e.g.[1]. Outcrop morphology and texture, as well as the appearance, composition and mineralogy of abraded rock surfaces observed by Perseverance suggest that theMáazformation consists of asequence of maficigneous units, likely lavas flows. These rocks have experienced variable interaction with aqueous fluids. Type localities of the lower Roubion and the more resistant Rochette members of the Máazformation have been targeted and their abraded surfaces characterized prior to sample collection. In thispresentation we will summarize these sampling activities and potential future sampling of theheavily crateredupperCh’ałmember that is indicative of the Máazformationfrom orbit.

Justin Ibrahim Simon↗

High efficiency active environmental sampling of chemical traces

A method of sample collection includes collecting an analyte from a sampling surface using a rapidly curable liquid gel comprising one or more metal particles; co-aggregating the one or more metal particles from the rapidly curable liquid gel and the analyte from the sampling surface; and rapidly curing the rapidly curable liquid gel. The composition and sample preparation conditions may facilitate improved collection efficiency of analytes during environmental and forensic evidence sampling. In addition, the composition and sample preparation conditions may facilitate enhanced detection and identification of the analyte using e.g., Surface Enhanced Raman Spectrometry (SERS).

Junghans, Ann↗

Temperature dependent DC electrical conductivity studies of ZnO nanoparticle thick films prepared by simple solution combustion method

ZnO nanoparticles of different size were prepared by varying the molar ratio of glycine and zinc nitrate hexahydrate as fuel and oxidizer (F/O = 0.8, 1.11, 1.7) by simple solution combustion method. Powder samples were characterized by UV-Visible spectrophotometer, X-ray diffractometer, Scanning electron microscope (SEM). DC electrical conductivity measurements at room temperature and in the temperature range of 313-673K were carried out for the prepared thick films and it was found to increase with increase of temperature which confirms the semiconducting nature of the samples. Activation energies were calculated and it was found that, F/O molar ratio 1.7 has low E{sub AL} (Low temperature activation energy) and high E{sub AH} (High temperature activation energy) compared to other samples.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Gamma Detector Response/Soil Concentration Correlation Study at the AAR Manufacturing, Inc. Site, Livonia, Michigan

At the NRC's request, ORAU conducted surveys of the AAR Manufacturing site during the period of September 25 through September 27, 2012. The survey activities included walkover surveys and sampling activities. Once the survey team was onsite, the NRC personnel decided to forgo survey activities in the New Addition and the pickling area. Areas of the planned study boundary were inaccessible due to overgrowth/large pieces of concrete covering the soil surface; therefore, the study boundary was redefined. Gamma walkover scans of the site boundary and front yard identified multiple areas of elevated gamma radiation. As a result, two judgmental samples were collected. Sample results were above thorium background levels The answer to the PSQ relating to the relationship between thorium concentration in soil and NaI instrument response is Yes. NaI instrument response can be used as a predictor of Th-232 concentration in the 0 to 1 m layer. An R2 value of 0.79 was determined for the surface soil relationship, thus satisfying the DQOs. Moreover, the regression was cross-checked by comparing the predicted Th-232 soil core concentration to the average Th-232 concentration (Section 5.3.2). Based on the cross-check, the regression equation provides a reasonable estimate for the Th-232 concentration at the judgmental locations. Consideration must be given when applying this equation to other soil areas of the site. If the contamination was heterogeneously distributed, and not distributed in a discrete layer as it was in the study area, then using the regression equation to predict Th-232 concentration would not be applicable.

54 ENVIRONMENTAL SCIENCES↗

Sampling of Jezero Crater Máaz Formation By Mars 2020 Perseverance Rover

Collection of samples that could be returned to Earth from the floor of Jezero crater is a major goal of the Mars 2020 mission. Laboratory analyses of these will expand exploration of Jezero, a Noachian crater on Mars characterized by a delta–lake system with high potential for habitability. The samples will also be used to test current ideas about the early planetary evolution of Mars. The Perseverance rover has collected samples from two members of the Máaz formation, mapped in orbital images as the Crater floor fractured rough unit by [1]. Type localities of the Roubion and Rochette members have been targeted and abraded prior to sample collection. Here we summarize these sampling activities and the potential of sampling the Chal member of Máaz. A similar summary for samples collected from the Séítah formation is described in Hickman-Lewis et al. (this meeting).

Mars 2020↗

Predictions of LDEF radioactivity and comparison with measurements

As part of the program to utilize LDEF data for evaluation and improvement of current ionizing radiation environmental models and related predictive methods for future LEO missions, calculations have been carried out to compare with the induced radioactivity measured in metal samples placed on LDEF. The predicted activation is about a factor of two lower than observed, which is attributed to deficiencies in the AP8 trapped proton model. It is shown that this finding based on activation sample data is consistent with comparisons made with other LDEF activation and dose data. Plans for confirming these results utilizing additional LDEF data sets, and plans for model modifications to improve the agreement with LDEF data, are discussed.

Armstrong, T. W.↗

Chloride diffusivity, chloride threshold, and corrosion initiation in reinforced alkali-activated mortars: Role of calcium, alkali, and silicate content

The aim of this study is to investigate systematically the chloride diffusivity and chloride threshold of a wide range of calcium-rich and fly ash-dominated alkali-activated samples in light of their compositional differences. To this end, the effects of various fly ash (FA)-to-slag ratios, of alkali concentrations and of silicate content in the activator were investigated. The electrochemical aspects of the passive samples were also assessed. Results show the prominent role of calcium in the matrix to reduce the chloride diffusivity. While higher alkali concentration increased the porosity and chloride diffusivities in general, lower modulus ratios provided considerably better performance in the FA-dominated samples. Chloride threshold values range between 0.19 (wt% binder mass) for calcium-rich mortars fabricated at low levels of alkalinities and 0.69 for FA-dominated mortars fabricated with highly alkaline activators. Half-cell potential and polarization resistance of alkali-activated samples were in general lower than their Portland cement counterparts.

36 MATERIALS SCIENCE↗

Robotic Arm Manipulator Using Active Control for Sample Acquisition and Transfer, and Passive Mode for Surface Compliance

A robotic arm that consists of three joints with four degrees of freedom (DOF) has been developed. It can carry an end-effector to acquire and transfer samples by using active control and comply with surface topology in a passive mode during a brief surface contact. The three joints are arranged in such a way that one joint of two DOFs is located at the shoulder, one joint of one DOF is located at the elbow, and one joint of one DOF is located at the wrist. Operationally, three DOFs are moved in the same plane, and the remaining one on the shoulder is moved perpendicular to the other three for better compliance with ground surface and more flexibility of sample handling. Three out of four joints are backdriveable, making the mechanism less complex and more cost effective

Liu, Jun↗

Wilson Corners Solid Waste Management Unit (SWMU) 001: 2021 Annual Long-Term Monitoring Report, Kennedy Space Center, Florida

This report presents a summary of the long-term monitoring (LTM) activities that occurred in 2021 at Wilson Corners, Solid Waste Management Unit (SWMU) 001, at Kennedy Space Center (KSC), Florida. The site is monitored under KSC’s Resource Conservation and Recovery Act (RCRA) Corrective Action Program. Adaptive site management is being utilized through ongoing assessment, design, and interim measures (IM). Annual LTM of the groundwater is also being conducted at the site. This approach also meets the requirements of Chapter 62-780, Florida Administrative Code (F.A.C.). The goal of LTM at this site is threefold: to determine groundwater flow characteristics, monitor the downgradient concentration trends, and monitor select locations internal to the groundwater plume. Every 5 years, upgradient and side-gradient monitoring wells are sampled to verify delineation. The last time this was performed was in 2015. The sampling of these wells in 2020 was replaced with the direct push technology (DPT) investigations completed in October 2020 and April 2021. This DPT groundwater data was presented in an Advance Data Package (ADP) in September 2021 and discussed in the Implementation Work Plan (IWP) dated November 2021 for installation of an air sparge (AS) system. Based on results from groundwater sampling activities performed during the previous reporting period, including the 2020 and 2021 DPT groundwater sampling, it was determined that the LTM sampling plan was no longer meeting the goal of LTM because delineation was not verified. The 2021 LTM sampling plan was modified to include the sampling of monitoring wells located around the perimeter of the low concentration plume (LCP); the area with concentrations of contaminants of concern [COCs] greater than Groundwater Cleanup Target Levels [GCTLs]), and sampling of 10 monitoring wells proposed for installation (April 2021 KSC Remediation Team (KSCRT) Meeting, Decision 2104-D32). The modified LTM plan received team consensus at the September 2021 KSCRT Meeting (Decision Number 2109-D03), and sampling of the existing monitoring wells was completed in December 2021. The proposed monitoring wells are planned for installation in late 2022, concurrent with ongoing IM construction activities. December 2021 LTM data was presented at the May 2022 KSCRT Meeting, and activities are summarized in this report. The activities presented in this report include the December 2021 groundwater gauging of 42 monitoring wells and sampling of 44 monitoring wells. During the December 2021 event, the low flow sampling method was used, and samples were analyzed for a select list of volatile organic compounds (VOCs), including 1,1,2-trichloro-1,2,2-trifluoroethane (Freon 113). The following conclusions can be made based on the 2021 LTM results: - In December 2021, groundwater flow for the site was generally to the west at all intervals. This is generally consistent with historical observations at the site, with the exception of a southwest and southeast flow component observed at 34 to 48 feet below land surface (bls). - The vertical extent of VOCs was historically delineated by monitoring wells screened greater than 48 feet bls. The results from the two vertical extent monitoring wells, WILC-MW0078 (screened 65 to 70 feet bls) and WILC-MW0130 (screened 56 to 66 feet bls) that were sampled during the 2021 LTM indicate that groundwater vinyl chloride (VC) concentrations in both wells were greater than the GCTL. The Remediation Team has previously agreed to delay deeper DPT investigations in this area to prevent the creation of additional pathways for vertical migration. - The LCP continues to extend both horizontally, predominantly to the west, and vertically beyond the current monitoring well network, with some retraction observed to the southeast. Evaluation of this data combined with data from the 2020 and 2021 DPT sampling event indicate that the LCP encompasses an estimated 20.7 acres based on an expanded sampling area, as compared to the 2020 LCP footprint of 17.0 acres. - Freon 113 was not detected above GCTLs during the 2021 LTM event. Based on groundwater sampling activities performed in 2021, including April 2021 DPT groundwater sampling, the following recommendations are provided: - Perform the next LTM sampling event, targeted to occur in 2023, concurrently with the IM baseline sampling prior to AS system installation; - Include sampling from nine monitoring wells that are planned to be installed in late 2022, concurrent with upcoming IM construction activities. Installation of one deep vertical well, screened 70 to 80 feet bls, will be delayed to prevent the creation of an additional pathway for vertical migration; - Continue to sample under the modified annual LTM plan as presented in Table 4-1 concurrently with IM baseline sampling; and - Once the AS system install and start-up is complete, select monitoring wells from the LTM program will transition into the performance monitoring plan, and LTM will be temporarily discontinued. Performance monitoring will be performed quarterly, and the monitoring well network will be evaluated following the first performance monitoring sampling event.

long-term monitoring (LTM)↗

Lunar and Meteorite Sample Disk for Educators

NASA Johnson Space Center (JSC) has the unique responsibility to curate NASA's extraterrestrial samples from past and future missions. Curation includes documentation, preservation, preparation and distribution of samples for research, education and public outreach. Between 1969 and 1972 six Apollo missions brought back 382 kilograms of lunar rocks, core and regolith samples, from the lunar surface. JSC also curates meteorites collected from a US cooperative effort among NASA, the National Science Foundation (NSF) and the Smithsonian Institution that funds expeditions to Antarctica. The meteorites that are collected include rocks from Moon, Mars, and many asteroids including Vesta. The sample disks for educational use include these different samples. Active relevant learning has always been important to teachers and the Lunar and Meteorite Sample Disk Program provides this active style of learning for students and the general public. The Lunar and Meteorite Sample Disks permit students to conduct investigations comparable to actual scientists. The Lunar Sample Disk contains 6 samples; Basalt, Breccia, Highland Regolith, Anorthosite, Mare Regolith and Orange Soil. The Meteorite Sample Disk contains 6 samples; Chondrite L3, Chondrite H5, Carbonaceous Chondrite, Basaltic Achondrite, Iron and Stony-Iron. Teachers are given different activities that adhere to their standards with the disks. During a Sample Disk Certification Workshop, teachers participate in the activities as students gain insight into the history, formation and geologic processes of the moon, asteroids and meteorites.

Foxworth, Suzanne↗

Independent Confirmatory Survey Summary and Results for the Ford Nuclear Reactor, Ann Arbor, Michigan

At the NRC's request, ORAU conducted confirmatory surveys of the FNR during the period of December 4 through 6, 2012. The survey activities included visual inspections and measurement and sampling activities. Confirmatory activities also included the review and assessment of UM's project documentation and methodologies. Surface scans identified elevated activity in two areas. The first area was on a wall outside of Room 3103 and the second area was in the southwest section on the first floor. The first area was remediated to background levels. However, the second area was due to gamma shine from a neighboring source storage area. A retrospective analysis of UM's FSS data shows that for the SUs investigated by the ORAU survey team, UM met the survey requirements set forth in the FSSP. The total mean surface activity values were directly compared with the mean total surface activity reported by UM. Mean surface activity values determined by UM were within two standard deviations of the mean determined by ORAU. Additionally, all surface activity values were less than the corresponding gross beta DCGLW. Laboratory analysis of the soil showed that COC concentrations were less than the respective DCGLW values. For the inter-lab comparison, the DER was above 3 for only one sample. However, since the sum of fractions for each of the soil samples was below 1, thus none of the samples would fail to meet release guidelines. Based on the findings of the side-by-side direct measurements, and after discussion with the NRC and ORAU, UM decided to use a more appropriate source efficiency in their direct measurement calculations and changed their source efficiency from 0.37 to 0.25.

54 ENVIRONMENTAL SCIENCES↗