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A Comparison of Aircraft and Ground-Based Measurements at Mauna Loa Observatory, Hawaii, During GTE PEM-West and MLOPEX 2

During October 19-20, 1991, one flight of the NASA Global Tropospheric Experiment (GTE) Pacific Exploratory Mission (PEM-West A) mission was conducted near Hawaii as an intercomparison with ground-based measurements of the Mauna Loa Observatory Photochemistry Experiment (MLOPEX 2) and the NOAA Climate Modeling and Diagnostics Laboratory (CMDL). Ozone, reactive nitrogen species, peroxides, hydrocarbons, and halogenated hydrocarbons were measured by investigators aboard the DC-8 aircraft and at the ground site. Lidar cross sections of ozone revealed a complex air mass structure near the island of Hawaii which was evidenced by large variation in some trace gas mixing ratios. This variation limited the time and spatial scales for direct measurement intercomparisons. Where differences occurred between measurements in the same air masses, the intercomparison suggested that biases for some trace gases was due to different calibration scales or, in some cases, instrumental or sampling biases. Relatively large uncertainties were associated with those trace gases present in the low parts per trillion by volume range. Trace gas correlations were used to expand the scope of the intercomparison to identify consistent trends between the different data sets.

Atlas, E.↗

Fusion of Surface Ceilometer Data and Satellite Cloud Retrievals in 2D Mesh Interpolating Model with Clustering

For accurate cloud ceiling information, a data fusion approach is proposed that utilizes satellite data to extend surface station information to much wider areas. Cloud base height (CBH) retrieved from satellite observations provides for much larger spatial coverage and higher resolution. The direct comparison of GOES-16 CBH with surface station ceiling yields a local bias that has to be corrected for in the initial GOES-16 cloud base information. This sparsely sampled bias correction presents an irregular 2D mesh of control points, which is then interpolated by constructing a continuous smooth field using polyharmonic splines. The influence of remote stations is restricted by grouping the control points into clusters depending on an effective distance. This cluster-based approach allows for constructing separate spline surfaces corresponding to physically different clouds. The obtained continuous bias correction function is then applied to the entire GOES-16 pixel level CBH except for areas far away from surface stations in data sparse regions such as offshore. The described method is currently being tested using daytime-only observations over the central and eastern United States. Overall, this approach has potential to provide more accurate, high spatial resolution cloud ceiling information for the aviation community.

Khlopenkov, Konstantin↗

Does Collection Time Bias the Ecology of Cleanroom Air Samples?

Microbial monitoring of astromaterials collections has taken on increased importance with the return of biologically sensitive samples from the asteroids Ryugu and Bennu and the initiation of the Mars Sample Return Program. Terrestrial bacteria and fungi can alter the mineralogy and organic composition of our collections causing irreversible contamination of pristine samples and increasing the risk of false positives for life detection measurements. NASA has conducted routine microbial monitoring of its existing collections since 20181. Initial monitoring focused on surface samples collected with foam swabs. Although, airborne microbiology is often decoupled from surface microbiology in the built environment2 culture-based air sampling techniques like impactors were not compliant with existing contamination control requirements. Bringing organic rich media, gelatin or liquids into curation cleanrooms presents an unacceptable risk to pristine samples. In 2022 NASA purchased a materials complaint air sampler and began collecting air samples from the cleanrooms in addition to surface samples3. The new instrument uses an electret filter to collect samples that are suitable for cultivating organisms or for direct DNA sequencing. Preliminary DNA sequencing results appeared to indicate that longer sampling times biased the microbial community in favor of hearty, spore-forming bacteria3. We present the results of a study comparing overnight sampling (17 hours) to short (1 hour) sampling of unoccupied curation cleanrooms. The results will help us optimize our monitoring protocols and develop a more detailed inventory of the ecology of astromaterials curation cleanrooms. Methods: We analyzed 72 paired air samples from six different cleanrooms including the meteorite processing lab (ISO 7 equivalent, 16 samples), the lunar lab (ISO 6 equivalent, 10 samples), the stardust lab (ISO 5 equivalent 14 samples), the OSIRIS-REx lab (ISO 5 equivalent, 12 samples), the Hayabusa2 lab (ISO 5 equivalent, 14 samples), and the Genesis lab (ISO 4 equivalent, 6 samples). All the samples were collected with an InnovaPrep Bobcat air sampler operating at a sampling rate of 200 L/min. The sampler operates for 5 minutes out of every 20 minute period. Half of the samples were collected by filtering 3,000L (15 min. of active sampling) of air across an electret filter for one hour. The rest of the samples were collected by filtering approximately 51,000 L air across the filter overnight (~17 hours, 255 min. of active sampling). Cells were eluted from the filter using 6-7 ml of pressurized 0.15% tween 20 in PBS (phosphate buffered saline). This liquid was used to cultivate bacteria according to previously published methods1,4,5 and for DNA extraction and next generation sequencing. DNA was extracted with a Qiagen MagAttract PowerMicrobiome kit6. To identify bacteria and archaea, the 16S rRNA gene was amplified using Earth Microbiome primers for the V4 region 7. The amplified DNA was sequenced on an Illumina MiSeq using a V3 reagent kit. The resulting sequences were processed using DADA2 and QIIME2 as implemented on the EDGE bioinformatics platform8–10. Results: Only two of the 72 samples had no amplifiable DNA. Amplified DNA concentrations ranged from 2.67 – 0.272 ng/µl. The median concentration of amplified DNA for the 1 hour samples was 0.770 ± 0.368 ng/µl. The median concentration of amplified DNA for the overnight samples was 0.877 ± 0.434 ng/µl. On average the overnight samples had slightly more sequences (58,960 vs. 59,456) and ASV’s (amplicon sequence variants) (60 vs 64.5) than the one hour samples, but these differences are not statistically significant. The most abundant ASV in every sample mapped to the genus Cupravidus. ASV’s mapping to the genuses Bacillus, Schlegelella, Thermus, and Staphylococcus were also common. Discussion and Future Work: Alpha diversity statistics like Shannon Entropy and Faith Phylogenetic Diversity are used to describe the diversity of organisms in a single sample. If a longer sampling time was biasing the data, we would expect to see a change in these diversity statistics vs. sample time. However, we did not observe this in our data. The median Shannon entropy was slightly higher for the overnight samples (3.773 vs 3.611) as was the Faith Phylogenetic Diversity (4.042 vs 3.596), but both values were within a standard deviation of each other for the two sampling times (Fig. 1). It is unlikely, that the longer sampling time is introducing bias into our data. We do observe a significant decrease in diversity when comparing the air samples by lab. The Genesis lab (ISO 4 equivalent) has a lower median number of ASV’s (45.5) than the other labs (62). Median values for Shannon Entropy (3.717 vs. 3.430) and Faith Phylogenetic Diversity (3.796 vs. 3.548) are also lower for Genesis, but those values are with one standard deviation of each other for the different sampling times. This is consistent with previous culture-based results suggesting that the environment in cleanrooms tends to select for a core group of organisms capable of surviving under dry, low nutrient, conditions. The presence of the ASV’s mapping to Cupravidus and Thermus in our sequencing blanks and controls suggests that several of the most common organisms in our samples represent contaminants from the reagents used to perform the DNA extractions and sequencing. Further work is needed to identify these contaminants, remove them from our data and recalculate the diversity statistics. This is a systematic error. Therefore, we do not expect removing the sequencing contaminants to change our conclusions. Longer air sample collection times appear to result in slightly higher diversity and do not bias the results towards “hardy” bacteria like spore-formers. Based on these preliminary results we conclude that sampling at least 3,000 liters of air is sufficient to capture the microbial diversity of cleanrooms, and that air samples can also be collected overnight without negatively impacting diversity. These results allow us to be flexible when designing microbial monitoring plans so that they do not interfere with routine lab activity. References: 1. Regberg, A. B. et al. 49th Lunar and Planetary Science Conference (2018). 2. The United States Pharmacopeial Convention. USP General Chapter <1116> (2013). 3. Regberg, A. B., et al. 54th Lunar and Planetary Science Conference (2023). 4. Regberg, A. B. et al. 53rd Lunar and Planetary Science Conference ( 2022). 5. Davis, R. E.,et al. 50th Lunar and Planetary Science Conference (2019). 6. Qiagen. MagAttract® PowerMicrobiome® DNA/RNA EP Kit Handbook. (2018). 7. Walters, W. et al. mSystems 1, (2015). 8. Callahan, B. J. et al. Nat. Methods 13, 581–583 (2016). 9. Hall, M. & Beiko, R. G. Microbiome Analysis: Methods and Protocols113–129 (Springer, 2018). 10. Philipson, C. et al. Bio-Protoc. 7, e2622 (2017).

A. B. Regberg↗

Crustal radiogenic heat production and the selective survival of ancient continental crust

It is pointed out that the oldest terrestrial rocks have so far revealed no evidence of the impact phase of Earth evolution. This observation suggests that processes other than impact were dominant at the time of stabilization of these units. However, a use of the oldest terrestrial rocks as a sample of the early terrestrial crust makes it necessary to consider the possibility that these rocks may represent a biased sample. In the present study, the global continental heat flow data set is used to provide further evidence that potassium, uranium, and thorium abundances are, on the average, low in surviving Archean crust relative to younger continental crust. An investigation is conducted of the implications of relatively low crustal radiogenic heat production to the stabilization of early continental crust, and possible Archean crustal stabilization models are discussed.

Morgan, P.↗

Crustal radiogenic heat production and the selective survival of ancient continental crust

It is pointed out that the oldest terrestrial rocks have so far revealed no evidence of the impact phase of earth evolution. This observation suggests that processes other than impact were dominant at the time of stabilization of these units. However, a use of the oldest terrestrial rocks as a sample of the early terrestrial crust makes it necessary to consider the possibility that these rocks may represent a biased sample. In the present study, the global continental heat flow data set is used to provide further evidence that potassium, uranium, and thorium abundances are, on the average, low in surviving Archean crust relative to younger continental crust. An investigation is conducted of the implications of relatively low crustal radiogenic heat production to the stabilization of early continental crust, and possible Archean crustal stabilization models are discussed.

Morgan, P.↗

Solute chemistry for streams draining geomorphic features and varying land cover gradients in the East River watershed, Colorado

This dataset contains solute chemistry data and GPS coordinates for surface water samples collected in the East River watershed in the Elk and West Elk Ranges of Colorado from August 3rd through August 11th, 2022. Samples were collected from streams and groundwater seeps as part of a comprehensive analysis within the watershed of how different geomorphic features (such as landslides and rock glaciers) along with variations in land cover (such as the presence of vegetation) affect stream water quality in this Rocky Mountain headwater environment. This dataset includes concentrations of the following in a single csv file: fluoride, chloride, sulfate, nitrate, calcium, potassium, magnesium, sodium, silicon, and total organic carbon (TOC). All concentrations are reported in mg/L. The sulfate data in this version have been updated to account for an earlier ion chromatograph instrument method error whereby sulfate and bromide peaks overlapped in calibration solution samples, biasing calculated sulfate concentrations low by 30-50%. Sulfate data reported herein are from a re-run of the samples performed in December 2024 using a corrected instrument method. All samples were stored under refrigerated conditions and filtered on initial collection.

54 ENVIRONMENTAL SCIENCES↗

Flying the TRMM Satellite in a GCM

By incorporating the Tropical Rainfall Measurement Mission (TRMM) satellite orbital information into the Colorado State University General Circulation Model (CSU GCM), we are able to 'fly' a satellite in the GCM, and sample the simulated atmosphere in the same way as the TRMM sensors sample the real atmosphere. The TRMM-sampled statistics for precipitation and radiative fluxes at annual, intraseasonal, monthly-mean and seasonal-mean diurnal time scales are evaluated by comparing the satellite-sampled against fully-sampled simulated atmospheres. The sampling rates of the TRMM sensors are significantly affected by the sensors' swath widths. The TRMM Microwave Imager (TMI) and the Visible Infrared Scanner (VIRS) sample each 2.25 x 2.25 degree grid box in the Tropics and subtropics about once per day, but at a different local time every day, while the Precipitation Radar (PR) and the Clouds and the Earth's Radiant Energy System (CERES) sensor visit each grid box about once every three days and twice per day, respectively. Besides inadequate samplings resulting from sensors' swath widths, there is a large, systematic diurnal undersampling associated with TRMM's orbital geometry for grid boxes away from the Equator. When only one month of TRMM data are used, this diurnal undersampling can lead to more daytime samples relative to nighttime samples in one hemisphere, and more nighttime samples relative to daytime samples in the other hemisphere. The resulting sampling biases (3-6 W m(exp-2)) are very pronounced in outgoing longwave radiation (OLR) over the subtropical land masses. The sampling errors in OLR monthly- and seasonal-means are less than 8 W m(exp-2) (5%) for each 2.25 x 2.25 degree grid box. The OLR monthly- and seasonal-means are not sensitive to diurnal undersamplings associated with the TRMM orbits and sensors' swath widths. However, this is not the case for total precipitation. Diurnal undersampling could produce errors as large as 20% in the Tropics and 40% in the subtropics, for the zonally averaged monthly-mean rain rates. The TRMM orbits sample each 2.25 x 2.25 degree grid box in the Tropics and subtropics 1-6 times for each hour of the day within a single season. The seasonal-mean diurnal cycles of precipitation and OLR are not well sampled for any one grid box. By either accumulating the satellite data for a long enough period, or averaging the data over a large area with a relatively uniform diurnal signal, the diurnal cycles of precipitation and OLR can be satisfactorily sampled. The effects TRMM sampling errors on the inferred tropical-mean hydrologic cycle and radiative fluxes are also evaluated. There are strong spurious oscillations associated with TRMM's orbital geometry, with periods of 23 days and 3-4 months, in tropical-mean daily and monthly precipitation. While the relative fluctuations of the sampled-OLR are negligible, the relative fluctuations of the sampled precipitation have magnitudes similar to those of the observed climate variability. Caution must therefore be used when applying TRMM observations of tropical-mean precipitation to interpret climate variations at intraseasonal and interannual scales.

Lin, Xin↗

Radar error statistics for the space shuttle

Radar error statistics of C-band and S-band that are recommended for use with the groundtracking programs to process space shuttle tracking data are presented. The statistics are divided into two parts: bias error statistics, using the subscript B, and high frequency error statistics, using the subscript q. Bias errors may be slowly varying to constant. High frequency random errors (noise) are rapidly varying and may or may not be correlated from sample to sample. Bias errors were mainly due to hardware defects and to errors in correction for atmospheric refraction effects. High frequency noise was mainly due to hardware and due to atmospheric scintillation. Three types of atmospheric scintillation were identified: horizontal, vertical, and line of sight. This was the first time that horizontal and line of sight scintillations were identified.

Lear, W. M.↗

A dictionary learning algorithm for compression and reconstruction of streaming data in preset order

There has been an emerging interest in developing and applying dictionary learning (DL) to process massive datasets in the last decade. Many of these efforts, however, focus on employing DL to compress and extract a set of important features from data, while considering restoring the original data from this set a secondary goal. On the other hand, although several methods are able to process streaming data by updating the dictionary incrementally as new snapshots pass by, most of those algorithms are designed for the setting where the snapshots are randomly drawn from a probability distribution. In this paper, we present a new DL approach to compress and denoise massive dataset in real time, in which the data are streamed through in a preset order (instances are videos and temporal experimental data), so at any time, we can only observe a biased sample set of the whole data. Here, our approach incrementally builds up the dictionary in a relatively simple manner: if the new snapshot is adequately explained by the current dictionary, we perform a sparse coding to find its sparse representation; otherwise, we add the new snapshot to the dictionary, with a Gram-Schmidt process to maintain the orthogonality. To compress and denoise noisy datasets, we apply the denoising to the snapshot directly before sparse coding, which deviates from traditional dictionary learning approach that achieves denoising via sparse coding. Compared to full-batch matrix decomposition methods, where the whole data is kept in memory, and other mini-batch approaches, where unbiased sampling is often assumed, our approach has minimal requirement in data sampling and storage: i) each snapshot is only seen once then discarded, and ii) the snapshots are drawn in a preset order, so can be highly biased. Through experiments on climate simulations and scanning transmission electron microscopy (STEM) data, we demonstrate that the proposed approach performs competitively to those methods in data reconstruction and denoising.

97 MATHEMATICS AND COMPUTING↗

A Coupled Evaluation of Operational MODIS and Model Aerosol Products for Maritime Environments Using Sun Photometry: Evaluation of the Fine and Coarse Mode

Although satellite retrievals and data assimilation have progressed to where there is a good skill for monitoring maritime Aerosol Optical Depth (AOD), there remains uncertainty in achieving further degrees of freedom, such as distinguishing fine and coarse mode dominated species in maritime environments (e.g., coarse mode sea salt and dust versus fine mode terrestrial anthropogenic emissions, biomass burning, and maritime secondary production). For the years 2016 through 2019, we performed an analysis of 550 nm total AOD550, fine mode AOD (FAOD550; also known as FM AOD in the literature), coarse mode AOD (CAOD550), and fine mode fraction (η550) between Moderate Resolution Spectral Imaging Radiometer (MODIS) V6.1 MOD/MYD04 dark target aerosol retrievals and the International Cooperative for Aerosol Prediction (ICAP) core four multi-model consensus (C4C) of analyses/short term forecasts that assimilate total MODIS AOD550. Differences were adjudicated by the global shipboard Maritime Aerosol Network (MAN) and selected island AERONET sun photometer observations with the application of the spectral deconvolution algorithm (SDA). Through a series of conditional and regional analyses, we found divergence included regions of terrestrial influence and latitudinal dependencies in the remote oceans. Notably, MODIS and the C4C and its members, while having good correlations overall, have a persistent +0.04 to +0.02 biases relative to MAN and AERONET for typical AOD550 values (84th% < 0.28), with the C4C underestimating significant events thereafter. Second, high biases in AOD550 are largely associated with the attribution of the fine mode in satellites and models alike. Thus, both MODIS and C4C members are systematically overestimating AOD550 and FAOD550 but perform better in characterizing the CAOD550. Third, for MODIS, findings are consistent with previous reports of a high bias in the retrieved Ångström Exponent, and we diagnosed both the optical model and cloud masking as likely causal factors for the AOD550 and FAOD550 high bias, whereas for the C4C, it is likely from secondary overproduction and perhaps numerical diffusion. Fourth, while there is no wind-speed-dependent bias for surface winds <12 m s−1, the C4C and MODIS AOD550s also overestimate CAOD550 and FAOD550, respectively, for wind speeds above 12 m/s. Finally, sampling bias inherent in MAN, as well as other circumstantial evidence, suggests biases in MODIS are likely MODIS and the C4C products have their own strengths and challenges for a given climate application and discuss needed research. even larger than what was diagnosed here. We conclude with a discussion on how

Aerosols↗

Diagnosing AIRS Sampling with CloudSat Cloud Classes

AIRS yield and sampling vary with cloud state. Careful utilization of collocated multiple satellite sensors is necessary. Profile differences between AIRS and ECMWF model analyses indicate that AIRS has high sampling and excellent accuracy for certain meteorological conditions. Cloud-dependent sampling biases may have large impact on AIRS L2 and L3 data in climate research. MBL clouds / lower tropospheric stability relationship is one example. AIRS and CloudSat reveal a reasonable climatology in the MBL cloud regime despite limited sampling in stratocumulus. Thermodynamic parameters such as EIS derived from AIRS data map these cloud conditions successfully. We are working on characterizing AIRS scenes with mixed cloud types.

model analyses↗

Cat Mountain: A meteoritic sample of an impact-melted chondritic asteroid

Although impact cratering and collisional disruption are the dominant geologic processes affecting asteroids, samples of impact melt breccias comprise less than 1 percent of ordinary chondritic material and none exist among enstatite and carbonaceous chondrite groups. Because the average collisional velocity among asteroids is sufficiently large to produce impact melts, this paucity of impact-melted material is generally believed to be a sampling bias, making it difficult to determine the evolutionary history of chondritic bodies and how impact processes may have affected the physical properties of asteroids (e.g., their structural integrity and reflectance spectra). To help address these and related issues, the first petrographic description of a new chondritic impact melt breccia sample, tentatively named Cat Mountain, is presented.

Kring, David A.↗

Experimental study on particle formation in a pressurized oxy-fuel combustor using a novel in-situ optical instrument

Particle formation in pressurized oxy-fuel combustion can be fundamentally different from oxy-fuel combustion at atmospheric pressure. Under high pressures, the rate of char gasification with CO2 and H2O increases significantly and dominates the char reactions particularly at high temperatures. Also, the extent of fragmentation varies. This could result in a very different particle size distribution from that of air-fired combustion. To accurately obtain the particle size distribution in a pressurized oxy-fuel combustor without sampling bias, the particle measurement should be made at the system pressure. Very few published studies have accomplished this, and never under the conditions reported herein. In this work, we fire PRB coal in a 100 kWth staged pressurized oxy-fuel combustor (SPOC) under two pressures, 15 and 2 bara. A sampling probe (oil-cooled) is installed at the combustor outlet and the aerosol flow are sampled isokinetically. We utilize a state-of-the-art optical analyzer (Malvern Insitec) with a novel high-pressure and high-temperature flow cell to measure the particle size distribution and concentration in-situ in a sampled flow, which contains moist/corrosive flue gas under the process pressure and a controlled temperature that is kept above the dew point. The results show that the pressure can significantly influence the particle size distribution and concentration from the oxy-fuel combustor.

Cheng, Mao↗

Longitudinal variations of very-low-frequency chorus activity in the magnetosphere - Evidence of excitation by electrical power transmission lines

The distribution of VLF chorus in the high-altitude magnetosphere as detected by the Ogo 3 satellite was investigated. Chorus occurrence frequency over 4,668 samples of 5 min of broadband data was computed for Northern Hemisphere bins of 10 deg by 10 deg in dipole invariant latitude and longitude. Peaks in activity were noted over Alaska, the eastern U.S. and Canada, western Europe, and western Siberia, and were shown not to be the result of biased sampling. It is suggested that power line radiation of only about 1 W or less at a given harmonic frequency may be sufficient to stimulate the observed chorus activity and that such power levels can be expected in industrial areas or from large distribution networks. Preliminary results show that chorus starting frequencies are highly correlated with 60 Hz harmonics in the American sector and with 50 Hz harmonics in the European sector.

Luette, J. P.↗

Nonparametric Multiparticle Set Methods for Interpreting Environmental Samples

Collection and analysis of environmental samples is commonly used by a range of stakeholders in nuclear safeguards and security contexts. While the ubiquity of samples and their transport in the environment allow regular collection, developing and demonstrating methods for analyzing these samples is difficult. In this work, an environmental sample consists of a set of one or more individual particles. Recent advances in reactor simulation have allowed us to generate data that are more representative of real-world environmental samples, enabling statistically defensible method development and testing. The most notable of these advances is a drastic increase in the number of material depletion regions, which allows our simulations to capture the variation in isotopic composition seen at length scales consistent with environmental samples. Traditional approaches for handling multiparticle samples treat each particle in the sample individually, estimating the quantity of interest (e.g., core-average burnup) resulting from measurement and analysis of signatures (e.g., nuclide assays) from each individual particle. Individual estimates are then averaged to generate a single estimate of the quantity of interest over the entire sample. In this presentation, we introduce two novel approaches for interpreting environmental samples that comprise of multiple particles: (1) the Quantile-Quantile Comparator, which uses a multivariate generalization of quantile-quantile plots for comparing unknown statistical distributions, and (2) the Set Transformer, an attention-based neural network module designed to model interactions among elements (particles) in the input set (sample). Statistically representative sampling cannot be guaranteed as samples are passively collected and are beholden to what particles are available in the environment. These new analysis methods for set-input problems are expected to be more robust than traditional approaches to issues of sampling bias where particles are not uniformly distributed throughout regions of interest, as well as generally outperform traditional approaches by jointly considering all elements in the set. We will present results comparing the performance of traditional single particle approaches and the novel Quantile-Quantile Comparator and Set Transformer for interpretation of simulated environmental samples.

Phathanapirom, Birdy↗

Disentangling jet modification in jet simulations and in Z+jet data

The selection of jets in heavy-ion collisions based on their p T after jet quenching is known to bias towards jets that lost little energy in the quark-gluon plasma. In this work, we study and quantify the impact of this selection bias on jet substructure observables so as to isolate effects caused by the modification of the substructure of jets by quenching. We do so at first in a simplified Monte Carlo study in which it is possible to identify the same jet before and after quenching. We show explicitly that jets selected based on their quenched (i.e. observable) p T have substantially smaller fractional energy loss than those selected based on the p T that they would have had in the absence of any quenching. This selection bias has a large impact on jet structure and substructure observables. As an example, we consider the angular separation ΔR of the hardest splitting in each jet, and find that the ΔR distribution of the (biased) sample of jets selected based upon their quenched p T is almost unmodified by quenching. In contrast, quenching causes dramatic modifications to the ΔR distribution of a sample of jets selected based upon their unquenched p T , with a significant enhancement at larger ΔR coming from the soft particles originating from the wake of the jet in the quark-gluon plasma. The jets which contribute to this enhancement are those which have lost the most energy and which were, therefore, left out of the sample selected after quenching. In a more realistic study, we then show that the same qualitative effects can all be observed in Z+jet events. Selecting jets in such events based on either the jet p T or the Z-boson p T provides an experimentally accessible way to quantify the effects of selection biases in jet observables and separate them from the modification of jet substructure caused by quenching. Selecting Z+jet events based upon the jet p T yields a ΔR distribution that appears almost unmodified whereas selecting Z+jet events based upon the Z-boson p T reveals a significant modification to the ΔR-distribution caused by quenching, once again arising from the wakes of those jets that lose more energy.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

The Imprint of Southern Ocean Storms on Modeled Surface Chlorophyll, Their Drivers and Satellite Biases

Southern Ocean (SO) phytoplankton chlorophyll is highly variable on sub-seasonal time scales. Although the SO is the windiest ocean basin globally, it is not conclusively understood how storms impact SO phytoplankton dynamics. Much of our existing knowledge stems from satellites, but biases due to data gaps from cloud cover and low solar angles remain unquantified. Here, we use ocean–sea-ice simulations with the Community Earth System Model to quantify the climatological 1997–2018 imprint of storms on chlorophyll and phytoplankton dynamics in the ice-free SO. Additionally, by comparing the full-field model output to synthetic satellite observations, we quantify sampling biases in satellite-derived estimates. We find that both the sign and the magnitude of the average surface chlorophyll imprint vary substantially across storms but last for at least 4 days after the storm passing. Based on our analysis, more than one third of the storms explain the majority of local non-seasonal chlorophyll variability, but satellite-derived storm imprints are often too large in magnitude. On the day of the storm passing, changes in vertical mixing predominantly cause surface chlorophyll anomalies, and reduced light availability due to enhanced cloud cover outweighs the enhanced nutrient availability due to entrainment. Interestingly, storms imprint differently on total net primary production than on surface chlorophyll, demonstrating the difficulty to derive carbon-cycle impacts from a surface-chlorophyll assessment. With SO future storm activity projected to increase, complementing satellite observations with other observing technologies, for example, profiling floats, is necessary to better constrain how storms impact biological carbon cycling in the SO.

Nissen, Cara [University of Colorado, Boulder, CO ↗

Comparisons of Instantaneous TRMM Ground Validation and Satellite Rain Rate Estimates at Different Spatial Scales

This study provides a comprehensive inter-comparison of instantaneous rain estimates from the two rain sensors aboard the TRMM satellite with ground data from thee designated Ground Validation Sites: Kwajalein Atoll, Melbourne, Florida and Houston, Texas. The satellite rain retrievals utilize rain observations collected by the TRMM microwave imager (TMI) and the Precipitation Radar (PR) aboard the TRMM satellite. Three standard instantaneous rain products are the generated from the rain information retrieved from the satellite using the TMI, PR and Combined (COM) rain algorithms. The validation data set used in this study was obtained from instantaneous rain rates inferred from ground radars at each GV site. The first comparison used 0.5(sup 0) x 0.5(sup 0) gridded data obtained from the TRMM 3668 product, and similarly gridded GV data obtained from ground-based radars. The comparisons were made at the same spatial and temporal scales in order to eliminate sampling biases in our comparisons. An additional comparison was made by averaging rain rates for the PR, COM and GV estimates within each TMI footprint (approx. 150 square kilometers). For this analysis, unconditional mean rain rates from PR, COM and GV estimates were calculated within each TMI footprint that was observed within 100 km from the respective GV site (and also observed by the PR). This analysis used all the available matching data from the period 1999-2004, representing a sample size of over 50,000 footprints for each site. In the first analysis our results showed that all of the respective rain rate estimates agree well, with some exceptions. The more salient differences were associated with heavy rain events in which one or more of the algorithms failed to properly retrieve these extreme events. Also, it appears that there is a preferred mode of precipitation for TMI rain rates at or near 2 mm per hour over the ocean. This mode was noted over ocean areas of Melbourne, Florida and Kwajalein, Republic of the Marshall Islands, and is shown to exist in TRMM tropical-global ocean areas as well. Further research by algorithm developers is needed to explain or justify the seemingly errant observed probability distributions.

Wolff, David B.↗