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Landslide Likelihood Prediction using Machine Learning Algorithms

The supply of electricity via power plants is criticalto the operation of many critical infrastructure systems in mod-ern society. Natural hazards can disrupt the power supply, causepower outages that can halt economic growth, and impede emer-gency response until power is restored. The proposed work aimsto predict the landslides likelihood in these critical infrastructurelocations in the Northeastern USA using integrated databases ofexplanatory variables and machine learning algorithms. First,data related to landslides are obtained and merged, includingtopographic, soil moisture, and precipitation-related data. Fiveregression algorithms, namely: Random Forest, Extreme Gradi-ent Boosting (XGBoost), K-Nearest Neighbor regression (KNN),Linear Support Vector Regressor (SVR), and Linear regression,are utilized to predict the landslide probability and evaluatedon the dataset. The accuracy of the models is assessed by usingstatistical metrics such as mean absolute error (MAE), meansquared error (MSE), and root mean squared error (RMSE).The study results show that Random Forest outperformed othermodels with the mutual information feature selection method.It achieved an MSE of 0.0011 with mutual information-basedfeature selection and an MSE of 0.00157 without feature selection.KNN regressor outperformed the other models with an MSEof 0.00139 with correlation-based information selection. Theproposed landslide identification model with Random Forestalgorithm shows outstanding robustness and great potential intackling the landslide likelihood prediction by employing MLalgorithms.

Vasundhara Acharya↗

The Sensitivity of US Wildfire Occurrence to Pre-Season Soil Moisture Conditions Across Ecosystems

It is well accepted that drought and low moisture conditions are linked with increased wildfire occurrence. However, quantifying the sensitivity of wildfire to surface moisture state has been challenging due to a lack of soil moisture observations at an appropriate spatial scale. Here we apply model simulations of surface soil moisture that numerically assimilate observations from NASA’s Gravity Recovery and Climate Experiment (GRACE) mission, combined in a predictive algorithm with the US Forest Service’s Fire-Occurrence Database. We estimate a relationship between historic surface moisture and wildfire occurrence to produce annual probable wildfire occurrence and burned area at 0.25-degree resolution for the contiguous United States by land-cover classification. Cross-validation indicates increased frequency of smaller fires when the months preceding fire season are wet, while larger fires are more frequent when soils are dry. This demonstrates that assimilated GRACE data holds information that could aid national-scale fire potential assessments for early decision-support.

Fire-Occurrence database↗

Geodata Modeling and Query in Geographic Information Systems

Geographic information systems (GIS) deal with collecting, modeling, man- aging, analyzing, and integrating spatial (locational) and non-spatial (attribute) data required for geographic applications. Examples of spatial data are digital maps, administrative boundaries, road networks, and those of non-spatial data are census counts, land elevations and soil characteristics. GIS shares common areas with a number of other disciplines such as computer- aided design, computer cartography, database management, and remote sensing. None of these disciplines however, can by themselves fully meet the requirements of a GIS application. Examples of such requirements include: the ability to use locational data to produce high quality plots, perform complex operations such as network analysis, enable spatial searching and overlay operations, support spatial analysis and modeling, and provide data management functions such as efficient storage, retrieval, and modification of large datasets; independence, integrity, and security of data; and concurrent access to multiple users. It is on the data management issues that we devote our discussions in this monograph. Traditionally, database management technology have been developed for business applications. Such applications require, among other things, capturing the data requirements of high-level business functions and developing machine- level implementations; supporting multiple views of data and yet providing integration that would minimize redundancy and maintain data integrity and security; providing a high-level language for data definition and manipulation; allowing concurrent access to multiple users; and processing user transactions in an efficient manner. The demands on database management systems have been for speed, reliability, efficiency, cost effectiveness, and user-friendliness. Significant progress have been made in all of these areas over the last two decades to the point that many generalized database platforms are now available for developing data intensive applications that run in real-time. While continuous improvement is still being made at a very fast-paced and competitive rate, new application areas such as computer aided design, image processing, VLSI design, and GIS have been identified by many as the next generation of database applications. These new application areas pose serious challenges to the currently available database technology. At the core of these challenges is the nature of data that is manipulated. In traditional database applications, the database objects do not have any spatial dimension, and as such, can be thought of as point data in a multi-dimensional space. For example, each instance of an entity EMPLOYEE will have a unique value corresponding to every attribute such as employee id, employee name, employee address and so on. Thus, every Employee instance can be thought of as a point in a multi-dimensional space where each dimension is represented by an attribute. Furthermore, all operations on such data are one-dimensional. Thus, users may retrieve all entities satisfying one or more constraints. Examples of such constraints include employees with addresses in a certain area code, or salaries within a certain range. Even though constraints can be specified on multiple attributes (dimensions), the search for such data is essentially orthogonal across these dimensions.

Adam, Nabil↗

Oregon Wildfires: Integrating ECOSTRESS to Map & Analyze Vegetation Moisture for Wildfire Modeling

Wildfire season in the western USA is starting earlier and gaining in intensity. The Bootleg Fire in Southern Oregon began on July 6th, 2021, and burned over 1675 km2 before it was fully contained on August 15th, 2021. Evapotranspiration (ET) is one indicator of vegetation moisture and there is interest in using high-resolution ET products from ECOsystem and Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) in future wildfire modeling. In partnership with the Pacific Northwest National Laboratory and US Forest Service, the team examined ECOSTRESS ET for the two years before the Bootleg Fire and assessed the relationship between ET, topography, and vegetation. Remotely sensed data from Shuttle Radar Topography Mission (SRTM) and Global Ecosystem Dynamics Investigation (GEDI) along with ancillary data from the National Land Cover Database (NLCD) and Landscape Fire Resource Management Planning Tools (LANDFIRE) were incorporated. The team examined data in relation to soil burn severity from the Burned Area Emergency Response (BAER) program. From ET median composites for April 1st – July 5th, 2021 and 2019, the Bootleg Fire area showed a 7 mm/day decrease in ET and a relative 75% decrease in ET between 2019 and 2021. Approximately 6% of the Bootleg Fire area was identified as having a high soil burn severity and these areas were found predominantly in the evergreen forest land cover class and northward facing slopes with a mean ET decrease of 3 mm/day between 2019 and 2021. The team also analyzed ECOSTRESS Water Use Efficiency products as an additional vegetation moisture indicator of pre-fire conditions in the study area. The end products will allow the partners to assess if higher resolution vegetation moisture datasets from ECOSTRESS will improve wildfire modeling for other susceptible areas.

Brenna Hatch↗

Role of the Tenax® Adsorbent in the Interpretation of the EGA and GC‐MS Analyses Performed With the Sample Analysis at Mars in Gale Crater

The Sample Analysis at Mars (SAM) experiment on the National Aeronautics and Space Administration Curiosity rover seeks evidence of organic compounds on the surface of Mars. Since the beginning of the mission, various organic molecules have been detected and identified. While several have been demonstrated to be indigenous to the Martian soil and rocks analyzed, others appear to have been produced from sources internal to the experiment. The objective of this study is to build an exhaustive molecular database to support the interpretation of SAM results by identifying all the chemical species produced from Tenax® adsorbents, by determining (1) the thermal degradation by‐products of Tenax®, (2) the effect of Tenax® conditioning on the formation of Tenax® by‐products, (3) the impact of MTBSTFA or a mixture of MTBSTFA and DMF on Tenax® decomposition, and (4) the reaction between Tenax® and calcium perchlorate. Our results indicate that the by‐products of the SAM trap are due to the impact of trap heating, the impact of the derivatization reagent (MTBSTFA) and the presence of perchlorate in Martian soil. Some of these by‐products are observed in the SAM gas chromatograph mass spectrometer data from Mars.

Buch, A.↗

A Quasi-Global Approach to Improve Day-Time Satellite Surface Soil Moisture Anomalies through the Land Surface Temperature Input

Passive microwave observations from various spaceborne sensors have been linked to the soil moisture of the Earth's surface layer. A new generation of passive microwave sensors are dedicated to retrieving this variable and make observations in the single theoretically optimal L-band frequency (1-2 GHz). Previous generations of passive microwave sensors made observations in a range of higher frequencies, allowing for simultaneous estimation of additional variables required for solving the radiative transfer equation. One of these additional variables is land surface temperature, which plays a unique role in the radiative transfer equation and has an influence on the final quality of retrieved soil moisture anomalies. This study presents an optimization procedure for soil moisture retrievals through a quasi-global precipitation-based verification technique, the so-called Rvalue metric. Various land surface temperature scenarios were evaluated in which biases were added to an existing linear regression, specifically focusing on improving the skills to capture the temporal variability of soil moisture. We focus on the relative quality of the day-time (01:30 pm) observations from the Advanced Microwave Scanning Radiometer for Earth Observing System (AMSR-E), as these are theoretically most challenging due to the thermal equilibrium theory, and existing studies indicate that larger improvements are possible for these observations compared to their night-time (01:30 am) equivalent. Soil moisture data used in this study were retrieved through the Land Parameter Retrieval Model (LPRM), and in line with theory, both satellite paths show a unique and distinct degradation as a function of vegetation density. Both the ascending (01:30 pm) and descending (01:30 am) paths of the publicly available and widely used AMSR-E LPRM soil moisture products were used for benchmarking purposes. Several scenarios were employed in which the land surface temperature input for the radiative transfer was varied by imposing a bias on an existing regression. These scenarios were evaluated through the Rvalue technique, resulting in optimal bias values on top of this regression. In a next step, these optimal bias values were incorporated in order to re-calibrate the existing linear regression, resulting in a quasi-global uniform LST relation for day-time observations. In a final step, day-time soil moisture retrievals using the re-calibrated land surface temperature relation were again validated through the Rvalue technique. Results indicate an average increasing Rvalue of 16.5%, which indicates a better performance obtained through the re-calibration. This number was confirmed through an independent Triple Collocation verification over the same domain, demonstrating an average root mean square error reduction of 15.3%. Furthermore, a comparison against an extensive in situ database (679 stations) also indicates a generally higher quality for the re-calibrated dataset. Besides the improved day-time dataset, this study furthermore provides insights on the relative quality of soil moisture retrieved from AMSR-E's day- and night-time observations.

soil moisture↗

Classifying Agnostic Biosignatures using Raman, VNIR, and Elemental Data

How can we use our current wealth of terrestrial data, encompassing biogenic and abiogenic systems, to determine the distinguishing properties of life? SCOBI (Statistical Classification of Biosignature Information) uses machine learning techniques to algorithmically identify combinations of measurements that are “indicative of life”. A set of ~1000 observations, comprising elemental abundance, isotopic fractionation, VNIR reflectance, and (in progress) Raman spectra, have been assembled from existing literature and databases. The observations cover systems classified as “indicative alive” (e.g., cells, vegetation), “indicative non-alive” (e.g., fossils, teeth), “mixed indicative” (e.g., soil, pond water), or “non-indicative” (e.g., rocks, meteorites). VNIR data was preprocessed by linear interpolation from 400-2100 nm and smoothed with a Savitzky-Golay filter. To limit the amount of Earth-biochemistry-specific (non-agnostic) information included, the first five spectral features extracted were number of peaks, number of troughs, mean reflectance, mean peak width, and broadest peak width. To help further emphasize agnostic biosignatures, Earth-specific features such as chlorophylls have been manually flagged so that feature importance with and without them can be compared. Classifiers including k-nearest neighbors (KNN), Gaussian Naïve Bayes (GNB), logistic regression (LR), random forest (RF), and support vector machine (SVM) were implemented, as was a combination voting classifier. Performance metrics included false positive rates, false negative rates, and AUC with 50-50 test/train splits (Monte Carlo simulations). Key takeaways from this stage, prior to the inclusion of Raman spectra, are (1) the overall success rate of 0.933 AUC was most heavily influenced by the elemental abundance data; and (2) VNIR reflectance had the lowest classification performance with 0.52 AUC (58% of objects correctly classified). The next steps are to complete integration of Raman spectral data and to improve the approach to pre-processing and feature extraction for both types of spectral data, such as automated baseline removal, whole spectrum matching, and dimensionality reduction.

Biosignatures↗

Drinking Water Database

This summer I had the opportunity to work in the Environmental Management Office (EMO) under the Chemical Sampling and Analysis Team or CS&AT. This team s mission is to support Glenn Research Center (GRC) and EM0 by providing chemical sampling and analysis services and expert consulting. Services include sampling and chemical analysis of water, soil, fbels, oils, paint, insulation materials, etc. One of this team s major projects is the Drinking Water Project. This is a project that is done on Glenn s water coolers and ten percent of its sink every two years. For the past two summers an intern had been putting together a database for this team to record the test they had perform. She had successfully created a database but hadn't worked out all the quirks. So this summer William Wilder (an intern from Cleveland State University) and I worked together to perfect her database. We began be finding out exactly what every member of the team thought about the database and what they would change if any. After collecting this data we both had to take some courses in Microsoft Access in order to fix the problems. Next we began looking at what exactly how the database worked from the outside inward. Then we began trying to change the database but we quickly found out that this would be virtually impossible.

Murray, ShaTerea R.↗

Mars Phoenix Scout Thermal Evolved Gas Analyzer (TEGA) Database: Thermal Database Development and Analysis

The Mars Phoenix Scout Lander mission in 2008 examined the history of water, searched for organics, and evaluated the potential for past/present microbial habitability in a martian arctic ice-rich soil [1]. The Thermal Evolved Gas Analyzer (TEGA) instrument measured the isotopic composition of atmospheric CO2 and detected volatile bearing mineralogy (perchlorate, carbonate, hydrated mineral phases) in the martian soil [2-7]. The TEGA data are archived at the Planetary Data System (PDS) Geosciences Node but are reported in forms that require further processing to be of use to the non-TEGA expert. The soil and blank TEGA thermal data are reported as duty cycle and must be converted to differential power (mW) to allow for enthalpy calculations of exothermic/endothermic transitions. The exothermic/endothermic temperatures are also used to determine what phases (inorganic/organic) are present in the sample. The objectives of this work are to: 1) Describe how interpretable thermal data can be created from TEGA data sets on the PDS and 2) Provide additional thermal data interpretation of two Phoenix soils (Baby Bear, Wicked Witch) and include interpretations from three unreported soils (Rosy Red 1, 2, and Burning Coals).

Sutter, B.↗

Role of Antecedent Soil Moisture and Vegetation Stress in Lightning-Initiated Wildfires

Lightning-caused wildfires are a small percentage of all wildfire events within the Conterminous U.S. (CONUS), but they account for over 56% of the acreage burned. The atmospheric conditions favoring wildfire and rapid growth are well understood: large dewpoint depressions, unstable planetary boundary layer, strong winds, etc. However, antecedent land surface conditions affecting dead and live fuel moisture is more difficult to quantify. This study examines over 20 years of antecedent land surface, vegetation stress, and wildfire characteristic data associated with nearly 77,000 lightning-initiated wildfires from the U.S. Forest Service Wildfire Database. We will invoke two in-house databases generated by the NASA Short-term Prediction Research and Transition (SPoRT) Center: an observations-driven, climatological run of the Noah land surface model within the NASA Land Information System (i.e., SPoRT-LIS) to depict soil moisture deficits / anomalies, and a satellite-constrained Evaporative Stress Index (ESI) product to denote areas of stressed vegetation. We will mine these datasets associated with lightning-caused (and null) events to determine important relationships, distributions, and delineators that correspond to elevated threat areas for lightning-initiated wildfires.

Wildfire↗

Land Surface Microwave Emissivities Derived from AMSR-E and MODIS Measurements with Advanced Quality Control

A microwave emissivity database has been developed with data from the Advanced Microwave Scanning Radiometer-EOS (AMSR-E) and with ancillary land surface temperature (LST) data from the Moderate Resolution Imaging Spectroradiometer (MODIS) on the same Aqua spacecraft. The primary intended application of the database is to provide surface emissivity constraints in atmospheric and surface property retrieval or assimilation. An additional application is to serve as a dynamic indicator of land surface properties relevant to climate change monitoring. The precision of the emissivity data is estimated to be significantly better than in prior databases from other sensors due to the precise collocation with high-quality MODIS LST data and due to the quality control features of our data analysis system. The accuracy of the emissivities in deserts and semi-arid regions is enhanced by applying, in those regions, a version of the emissivity retrieval algorithm that accounts for the penetration of microwave radiation through dry soil with diurnally varying vertical temperature gradients. These results suggest that this penetration effect is more widespread and more significant to interpretation of passive microwave measurements than had been previously established. Emissivity coverage in areas where persistent cloudiness interferes with the availability of MODIS LST data is achieved using a classification-based method to spread emissivity data from less-cloudy areas that have similar microwave surface properties. Evaluations and analyses of the emissivity products over homogeneous snow-free areas are presented, including application to retrieval of soil temperature profiles. Spatial inhomogeneities are the largest in the vicinity of large water bodies due to the large water/land emissivity contrast and give rise to large apparent temporal variability in the retrieved emissivities when satellite footprint locations vary over time. This issue will be dealt with in the future by including a water fraction correction. Also note that current reliance on the MODIS day-night algorithm as a source of LST limits the coverage of the database in the Polar Regions. We will consider relaxing the current restriction as part of future development.

Moncet, Jean-Luc↗

Critical Load Exceedances for North America and Europe using an Ensemble of Models and an Investigation of Causes for Environmental Impact Estimate Variability: An AQMEII4 Study

Exceedances of critical loads for deposition of sulphur (S) and nitrogen (N) to different ecosystems were estimated using European and North American ensembles of air quality models, under Phase 4 of the Air Quality Model Evaluation International Initiative (AQMEII4), to identify where risk of ecosystem harm is expected to occur based on model deposition estimates. The ensembles were driven by common emissions and lateral boundary condition inputs. Model output was regridded to common North American and Europe 0.125° resolution domains, which were then used to calculate critical load exceedances. New, targeted deposition diagnostics implemented in AQMEII4 allowed an unprecedented level of post-simulation analysis to be carried out and facilitated the identification of specific causes of model-to-model variability in critical load exceedance estimates. New datasets for North American critical loads for acidity for forest soil water and aquatic ecosystems were combined with the ensemble deposition predictions to show a substantial decrease in the area and number of locations in exceedance between 2010 and 2016 (forest soils: 13.2 % to 6.1 %; aquatic ecosystems: 21.2 % to 11.4 %). All models agreed in the direction of the ensemble exceedance change between 2010 and 2016. The North American ensemble also predicted a decrease in both severity and total area in exceedance between the years 2010 and 2016 for eutrophication-impacted ecosystems in the USA (sensitive epiphytic lichen: 81.5 % to 75.8 %). The exceedances for herbaceous community richness also decreased between 2010 and 2016, from 13.9 % to 3.9 %. The uncertainty associated with the North American eutrophication results is high; there were sharp differences between the models in both predictions of total N deposition and the change in N deposition, and hence in the predicted eutrophication exceedances between the two years. The European ensemble was used to predict relatively static exceedances of critical loads with respect to acidification (4.48 % to 4.32 % from 2009 to 2010) while eutrophication exceedance increased slightly (60.2 % to 62.2 %). While most models showed the same changes in critical load exceedances as the ensemble between the two years, the spatial extent and magnitude of exceedances varied significantly between the models. The reasons for this variation were examined in detail by first ranking the relative contribution of different sources of sulphur and nitrogen deposition in terms of deposited mass and model-to-model variability in that deposited mass, followed by their analysis using AQMEII4 diagnostics, along with evaluation of the most recent literature. All models in both the North American and European ensembles had net annual negative biases with respect to observed wet deposition of sulphate, nitrate and ammonium. Diagnostics and recent literature suggest that this bias may stem from insufficient cloud scavenging of aerosols and gases, and may be improved through the incorporation of multiphase hydrometeor scavenging within the modelling frameworks. The inability of North American models to predict the timing of the seasonal peak in wet ammonium ion deposition (observed maximum was in April, while all models predicted a June maximum) may also relate to the need for multiphase hydrometeor scavenging (absence of snow scavenging in all models employed here). High variability in the relative importance of particulate sulphate, nitrate and ammonium deposition fluxes between models was linked to the use of updated particle dry deposition parameterizations in some models. However, recent literature and further development of some of the models within the ensemble suggests these particulate biases may also be ameliorated via the incorporation of multiphase hydrometeor scavenging. Annual sulphur and nitrogen deposition prediction variability was linked to SO 2 and HNO 3 dry deposition parameterizations, and diagnostic analysis showed that the cuticle and soil deposition pathways dominate the deposition mass flux of these species. Further work improving parameterizations for these deposition pathways should reduce variability in model acidifying gas deposition estimates. The absence of base cation chemistry in some models was shown to be a major factor in positive biases in fine mode particulate ammonium and particle nitrate concentrations. Models employing ammonia bidirectional fluxes had both the largest and the smallest magnitude biases, depending on the model and bidirectional flux algorithm employed. A careful analysis of bidirectional flux models suggests that those with poor NH 3 performance may underestimate the extent of NH 3 emissions fluxes from forested areas. Based on these results, an increased process-research focus is therefore recommended for the following model processes and on observations which may assist in model evaluation and improvement: multiphase hydrometeor scavenging combined with updated particle dry deposition, cuticle and soil deposition pathway algorithms for acidifying gases, base cation chemistry and emissions, and NH 3 bidirectional fluxes. Comparisons with satellite observations suggest that oceanic NH 3 emissions sources should be included in regional chemical transport models. The choice of land use database employed within any given model was shown to significantly influence deposition totals in several instances, and employing a common land use database across chemical transport models and critical load calculations is recommended for future work.

critical loads↗

A Prototype Physical Database for Passive Microwave Retrievals of Precipitation over the US Southern Great Plains

An accurate understanding of the instantaneous, dynamic land surface emissivity is necessary for a physically based, multi-channel passive microwave precipitation retrieval scheme over land. In an effort to assess the feasibility of the physical approach for land surfaces, a semi-empirical emissivity model is applied for calculation of the surface component in a test area of the US Southern Great Plains. A physical emissivity model, using land surface model data as input, is used to calculate emissivity at the 10GHz frequency, combining contributions from the underlying soil and vegetation layers, including the dielectric and roughness effects of each medium. An empirical technique is then applied, based upon a robust set of observed channel covariances, extending the emissivity calculations to all channels. For calculation of the hydrometeor contribution, reflectivity profiles from the Tropical Rainfall Measurement Mission Precipitation Radar (TRMM PR) are utilized along with coincident brightness temperatures (Tbs) from the TRMM Microwave Imager (TMI), and cloud-resolving model profiles. Ice profiles are modified to be consistent with the higher frequency microwave Tbs. Resulting modeled top of the atmosphere Tbs show correlations to observations of 0.9, biases of 1K or less, root-mean-square errors on the order of 5K, and improved agreement over the use of climatological emissivity values. The synthesis of these models and data sets leads to the creation of a simple prototype Tb database that includes both dynamic surface and atmospheric information physically consistent with the land surface model, emissivity model, and atmospheric information.

microwave↗

Algorithmic Classification of Raman Spectra Biosignatures: Improving Life Detection Confidence

“Agnostic” biosignatures – indicators of life (or the absence of life), independent of a particular biochemistry – are increasingly considered a high standard for life detection. The Ladder of Life Detection (2018) called for investigating how combinations of independent and different potential biosignatures affect confidence. To address this gap, statistical classification of elemental abundances, isotopic fractionation, and reflectance spectroscopy (VNIR) has been implemented. Raman spectroscopy, highly desirable due to its wide availability, has the potential to improve this predictive power. This work implemented biosignature classification algorithms on Raman data alone, in preparation for combination with the other data types. Raman spectroscopy data was collected from published databases and papers as part of a manually curated dataset of “indicative” and “non-indicative of life” samples. These currently include 61 non-indicative samples (meteorites, magnetite); 3 indicative living samples (bacteria); 20 indicative non-living samples (chalk, bone); and 12 indicative mixed (with non-indicative material) samples (soil, microbial mats). Laboratory work is ongoing to characterize additional samples, particularly a greater breadth of mixed systems. Spectra were interpolated, filtered with the Savitzsky-Golay filter, and de-noised. For a preliminary examination, agnostic features were manually extracted including mean intensity, number of peaks, and mean peak width. Different peak prominences and filtering polynomials were used to refine features. Classification algorithms were implemented: k-nearest neighbors (KNN), logistic regression (LR), linear support vector machines (SVM), random forest (RF), Gaussian naïve bayes (GNB). Lastly, Monte Carlo simulations on 1,000 50%-train-test-splits were used to validate classification performance and feature significance. The preliminary feature set achieved its highest AUC of 0.52 with LR, with no strongly discriminatory features. Work to improve feature extraction, such as through deep learning with back propagation, is planned. In future work, the Raman data will be combined with the other data types, and potentially new data types such as enantiomeric excess. This project was partially supported through the NASA Ames Project EXcellence (APEX) incubator program.

Astrobiology↗

Atlas of reflectance spectra of terrestrial, lunar, and meteoritic powders and frosts from 92 to 1800 nm

The spectra of samples of several powder and frost materials are presented to serve in a reference database for future far-UV scans of solar system bodies. The spectra cover in the 92-1800 nm wavelengths, i.e., wavenumbers 110,000-5600/cm and photon energies from 13.5-1.5 eV. Preparation procedures for the particulates are delineated. The survey includes feldspars, orthopyroxenes, clinopyroxenes, olivines, assorted minerals, achondrites, carbonaceous chondrites and ordinary chondrites, lunar soils and rocks. Frosts of H2O, CO2, NH3 and SO2 gases were also examined. The data are expected to aid in obtaining spectral matches for asteroids and meteoroids when far-UV telescopy of solar system bodies is performed.

Wagner, Jeffrey K.↗

The Impact of Soil Reflectance on the Quantification of the Green Vegetation Fraction from NDVI

The green vegetation fraction (Fg) is an important climate and hydrologic model parameter. A common method to calculate Fg is to create a simple linear mixing rnodeP between two NDVI endmembers: bare soil NDVI (NDVI(sub o)) and full vegetation NDVI (NDVI(sub infinity)). Usually it is assumed that NDVI(sub o), is close to zero (NDVI(sub o) approx.-0.05) and is generally chosen from the lowest observed NDVI values. However, the mean soil NDVI computed from 2906 samples is much larger (NDVI=0.2) and is highly variable (standard deviation=O. 1). We show that the underestimation of NDVI(sub o) yields overestimations of Fg. The largest errors occur in grassland and shrubland areas. Using parameters for NDVI(sub o) and NDVI(sub infinity) derived from global scenes yields overestimations of Fg ((Delta) Fg*) that are larger than 0.2 for the majority of U.S. land cover types when pixel NDVI values are 0.2<NDVI(sub pixel)<0.4. Figure 1 shows how the Fg overestimation varies for the most common land cover types in the conterminous U.S. for typical seasonal NDVI values. When using conterminous U.S. scenes to derive NDV(sub o) and NDVI(sub infinity), the overestimation is less (0.10-0.17 for 0.2<NDVI(sub pixel)<0.4). As a result, parts of the conterminous U.S. are affected at different times of the year depending on the local seasonal NDVI cycle. We propose using global databases of NDVI(sub o) along with information on historical NDVI(sub pixel) values to compute a statistically most-likely estimate of Fg (Fg*). Using in situ measurements made at the Sevilleta LTER, we show that this approach yields better estimates of Fg than using global invariant NDVI(sub o) values estimated from whole scenes (Figure 2). At the two studied sites, the Fg estimate was adjusted by 52% at the grassland and 86% at the shrubland. More significant advances will require information on spatial distribution of soil reflectance.

Montandon, L. M.↗

From Oxygen Generation to Metals Production: In Situ Resource Utilization by Molten Oxide Electrolysis

For the exploration of other bodies in the solar system, electrochemical processing is arguably the most versatile technology for conversion of local resources into usable commodities: by electrolysis one can, in principle, produce (1) breathable oxygen, (2) silicon for the fabrication of solar cells, (3) various reactive metals for use as electrodes in advanced storage batteries, and (4) structural metals such as steel and aluminum. Even so, to date there has been no sustained effort to develop such processes, in part due to the inadequacy of the database. The objective here is to identify chemistries capable of sustaining molten oxide electrolysis in the cited applications and to examine the behavior of laboratory-scale cells designed to generate oxygen and to produce metal. The basic research includes the study of the underlying high-temperature physical chemistry of oxide melts representative of lunar regolith and of Martian soil. To move beyond empirical approaches to process development, the thermodynamic and transport properties of oxide melts are being studied to help set the limits of composition and temperature for the processing trials conducted in laboratory-scale electrolysis cells. The goal of this investigation is to deliver a working prototype cell that can use lunar regolith and Martian soil to produce breathable oxygen along with metal by-product. Additionally, the process can be generalized to permit adaptation to accommodate different feedstock chemistries, such as those that will be encountered on other bodies in the solar system. The expected results of this research include: (1) the identification of appropriate electrolyte chemistries; (2) the selection of candidate anode and cathode materials compatible with electrolytes named above; and (3) performance data from a laboratory-scale cell producing oxygen and metal. On the strength of these results it should be possible to assess the technical viability of molten oxide electrolysis for in situ resource utilization on the Moon and Mars. In parallel, there may be commercial applications here on earth, such as new green technologies for metals extraction and for treatment of hazardous waste, e.g., fixing heavy metals.

Khetpal, Deepak↗

Lunar and Planetary Science XXXV: Moon and Mercury

The session" Moon and Mercury" included the following reports:Helium Production of Prompt Neutrinos on the Moon; Vapor Deposition and Solar Wind Implantation on Lunar Soil-Grain Surfaces as Comparable Processes; A New Lunar Geologic Mapping Program; Physical Backgrounds to Measure Instantaneous Spin Components of Terrestrial Planets from Earth with Arcsecond Accuracy; Preliminary Findings of a Study of the Lunar Global Megaregolith; Maps Characterizing the Lunar Regolith Maturity; Probable Model of Anomalies in the Polar Regions of Mercury; Parameters of the Maximum of Positive Polarization of the Moon; Database Structure Development for Space Surveying Results by Moon -Zond Program; CM2-type Micrometeoritic Lunar Winds During the Late Heavy Bombardment; A Comparison of Textural and Chemical Features of Spinel Within Lunar Mare Basalts; The Reiner Gamma Formation as Characterized by Earth-based Photometry at Large Phase Angles; The Significance of the Geometries of Linear Graben for the Widths of Shallow Dike Intrusions on the Moon; Lunar Prospector Data, Surface Roughness and IR Thermal Emission of the Moon; The Influence of a Magma Ocean on the Lunar Global Stress Field Due to Tidal Interaction Between the Earth and Moon; Variations of the Mercurian Photometric Relief; A Model of Positive Polarization of Regolith; Ground Truth and Lunar Global Thorium Map Calibration: Are We There Yet?;and Space Weathering of Apollo 16 Sample 62255: Lunar Rocks as Witness Plates for Deciphering Regolith Formation Processes.

Source record↗