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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
All sourcesNASA NTRSDOE OSTI
NASA NTRS1979

InP and GaAs characterization with variable stoichiometry obtained by molecular spray

Both InP and GaAs surfaces were studied in parallel. A molecular spray technique was used to obtain two semiconductor surfaces with different superficial compositions. The structures of these surfaces were examined by electron diffraction. Electron energy loss was measured spectroscopically in order to determine surface electrical characteristics. The results are used to support conclusions relative to the role of surface composition in establishing a Schottky barrier effect in semiconductor devices.

Massies, J.↗
NASA NTRS1983

A variable-geometry combustor used to study primary and secondary zone stoichiometry

A combustion program is underway to evaluate fuel quality effects on gas turbine combustors. A rich-lean variable geometry combustor design was chosen to evaluate fuel quality effects over a wide range of primary and secondary zone equivalence ratios at simulated engine operating conditions. The first task of this effort, was to evaluate the performance of the variable geometry combustor. The combustor incorporates three stations of variable geometry to control primary and secondary zone equivalence ratio and overall pressure loss. Geometry changes could be made while a test was in progress through the use of remote control actuators. The primary zone liner was water cooled to eliminate the concern of liner durability. Emissions and performance data were obtained at simulated engine conditions of 80 percent and full power. Inlet air temperature varied from 611 to 665K, inlet total pressure varied from 1.02 to 1.24 MPa, reference velocity was a constant 1400 K.

Briehl, D.↗
NASA NTRS1988

Electron Diffraction Evidence for the Ordering of Excess Nickel Atoms by Relation to Stoichiometry in Nickel-Rich Beta'-Nial Formation of a Nickel-Aluminum (Ni2al) Superlattices

In electron diffraction patterns of nickel-rich beta-NiAl alloys, many anomalies are observed. One of these is the appearance of diffuse intensity maxima between the reflexions of the B2 structure. This is explained by the short-range ordering of the excess nickel atoms on the simple cubic sublattice occupied only by aluminum atoms in the stoichiometric, perfectly ordered NiAl alloy. After annealing Ni 37.5 atomic percent Al and Ni 37.75 atomic percent Al for 1 week at 300 and 400 C, the diffuse intensity maxima transformed into sharp superstructure reflexions. These reflexions are explained by the formation of the four possible variants of an ordered hexagonal superstructure corresponding to the Ni2Al composition. This structure is closely related to the Ni2Al3 structure (same space group) formed by the ordering of vacancies on the nickel sublattice in aluminum-rich beta-NiAl alloys.

Reynaud, F.↗
NASA NTRS1987

Rapidly solidified nickel aluminide of improved stoichiometry and ductilization

It has been found that tri-nickel aluminide compositions are quite sensitive to the ratio of nickel to aluminum in their ability to receive boron as a dopant and that compositions which are relatively poor in the aluminum component can be doped more effectively with boron. Further, it has been found for the nickel aluminides which have lower concentrations of aluminum that the percentage of boron which can be added to the composition to effectively increase the strength of the alloys is . favored by the lower aluminum ratio so that higher concentrations of boron are addable. The compositions which result have significant strength properties based on tensile tests of the compositions.

Alan I Taub↗
NASA NTRS1995

The control of purity and stoichiometry of compound semiconductors by high vapor pressure transport

In this report we summarize the results of a three year research program on high pressure vapor transport (HPVT) of compound semiconductors. Most of our work focused onto pnictides, in particular ZnGeP2, as a model system. Access to single crystals of well controlled composition of this material is desired for advancing the understanding and control of its point defect chemistry in the contest of remote, real-time sensing of trace impurities, e.g., greenhouse gases, in the atmosphere by ZnGeP2 optical parametric oscillators (OPO's).

Bachmann, Klaus J.↗
NASA NTRS1993

Electron Mobility Studies of Device Quality InAs/GaAs Short Period Supprlattices Grown by Dynamic Stoichiometry Control and Floating In Flash-off Methods

The Strained Layer InGaAs/GaAs system has been the subject of substantial work emphasizing both growth studies and device applications. Relatively few studies have successfully explored the binary InAs on GaAs system because of the difficulties of maintaining a specular growth front and the apparently small value of the critical thickness.

Electron Mobility↗
NASA NTRS2022

Atomic-Scale Structure and Non-Stoichiometry of Meteoritic Hibonite: A Transmission Electron Microscope Study

Hibonite (CaAl_12O_19) is a common refractory mineral in Ca-Al-rich inclusions (CAIs) in primitive meteorites. Transmission electron microscope (TEM) studies have identified enigmatic planar defects in different occurrences of hibonite in the Allende meteorite that give rise to strong streaking along c* in electron diffraction patterns. Atomic resolution high-angle annular dark-field (HAADF) imaging and energy-dispersive X-ray (EDX) analyses were used to determine the nature and origin of these planar features. HAADF images of hibonite grains reveal lamellar intergrowths of common 1.6 nm spacing, and less commonly 2.0 and 2.5 nm spacings, interspersed in stoichiometric hibonite showing 1.1 nm (002) spacing. Stoichiometric hibonite consists of alternating Ca-containing (“R”) and spinel-structured (“S”) blocks stacked in a sequence RS. In contrast, the 1.6 nm layers result from a doubled S block such that the stacking sequence is RSS, while in the widest defect observed, the stacking sequence is RSSSS. These intergrowths are epitaxial and have coherent, low-strain boundaries with the host hibonite Meteoritic hibonite shows common Ti and Mg substitution for Al in its structure. Atomic-resolution EDX maps of hibonite grains in the Allende CAI confirm the preferred site occupancy of Mg on tetragonal M3 sites in S blocks and of Ti on trigonal bipyramidal M2 and octahedral M4 sites in R blocks. Mg is highly concentrated, but Ti is absent in the planar defects where wider S blocks show Al-rich compositions compared to stoichiometric MgAl_2O_4 spinel. Therefore, Mg likely played the major role in the formation and metastability of planar defects in hibonite. Electron energy loss spectroscopy data from the Ti L_2,3 edge show the presence of mixed Ti oxidation states with ~ 15–20% of Ti as Ti^(3+) in hibonite, suggesting a direct substitution of Ti^(3+) ↔ Al^(3+) in hibonite. The remaining ~ 80–85% of Ti is present as Ti^(4+) and corresponding EDX analyses are consistent with the well-known coupled substitution 2Al^(3+) ↔ Ti^(4+) + Mg^(2+) being the major mechanism for Ti and Mg substitution in hibonite. The formation of planar defects in hibonite occurred during high-temperature nebular condensation or melting/crystallization processes. The occurrence of non-stoichiometric hibonite in the Allende CAI deviates from the mineral formation sequence predicted from equilibrium condensation models. Overall, our atomic resolution TEM observations signify non-equilibrium, kinetic-controlled crystal growth during the high-temperature formation of refractory solids in the early solar nebula.

hibonite↗
NASA NTRSDate not supplied

Cryogenic Extension of NASA Species Polynomials Using Hydrogen and Oxygen at Stoichiometry

NASA has been conducting research in Rotating Detonation Rocket Engines (RDREs) for several years. A recent test at the Marshall Spaceflight Center has successfully shown operation of a RDRE that ran for 251 seconds which had combustion chamber cryogenic inlet conditions [1]. However, an overall pressure gain was not observed in the performance of the engine. Such an indication could mean an optimal chamber design is yet to be discovered. Such a design could significantly reduce parasitic pressure loses and improve overall engine efficiency beyond that of conventional rockets. To investigate different chamber configurations, new CFD capability is needed to accurately capture cryogenic thermophysical and transport property data. Such an effort is currently part of NASA’s Early Career Initiative (ECI) program. This paper focuses on the thermophysical property mixture model approach that makes use of NASA’s polynomial fits of species and another cryogenic model chosen from NIST’s Refprop program. Presented in this paper are results of a 1D denotation CFD simulation of stoichiometric Hydrogen and Oxygen mixture at a cryogenic upstream condition.

Combustion↗
DOE OSTI2024

Low Purge and Mercury Recovery Testing with Sludge Batch 10 Tank 40 Simulant

Researchers at the Savannah River National Laboratory (SRNL) have completed testing as requested by Savannah River Mission Completion (SRMC) to perform experiments to determine the impact of using a lower or inert purge in Sludge Batch (SB) 10 processing under the Nitric-Glycolic Acid (NGA) flowsheet. A key objective of this testing was also to determine the mercury speciation and recovery during each experiment. The testing was performed as part of the SB10 Technical Task Request (TTR) and Task Technical and Quality Assurance Plan (TTQAP). Two sets of tests were performed, and a Run Plan was approved prior to each set of experiments to document the planned testing. Three initial experiments were completed to determine whether a low air purge would be beneficial to CPC processing at higher acid stoichiometry (110%) based on the Koopman minimum acid (KMA) equation (116% Hsu). One of the tests, an inert nitrogen purge experiment, was also completed to demonstrate that excluding oxygen did not introduce any new hazards. The experiments were designed to be identical except for the change in purge gas and purge flowrate from run to run. After reviewing the results from the initial three experiments, six additional tests were proposed by SRNL to support the lower purge study and to look for processing alternatives for improving mercury recovery. These additional six tests were all completed at a very low acid stoichiometry to mimic the pH experienced during processing in DWPF (~7). DWPF is processing SB10 sludge at an acid stoichiometry of 90% based on the Hsu equation. The additional SRNL experiments were performed at an acid stoichiometry of 62.5% KMA stoichiometry (66.3% Hsu) to produce a Sludge Receipt and Adjustment Tank (SRAT) product with a pH of about 7. All experiments used simulants of both SWPF streams, although no entrained solvent was added during any of the experiments

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗