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New and highly sensitive method of detecting infrared irradiation makes possible solid state infrared detector which is more sensitive near room temperature than usual photoconductive low band gap semiconductor devices. Reconfiguration of high field domains in cadmium sulphide crystals provides basis for discovery.
Recent results from the Apollo seismic network suggest that primitive differentiation occurred in the outer shell of the moon to a depth of approximately 300 km; and the central region of the moon is presently molten to a radius of between 200 and 300 km. If early melting to a depth of 300 to 400 km was a consequence of accretional energy, very short accretion times are required. The best model for the zone of original differentiation appears to be a crust 40 to 80 km thick, ranging in composition from anorthositic gabbro to gabbro; overlying an ultramafic cumulate (olivine-pyroxene) about 250 km thick. The best candidate for the molten core appears to be iron or iron sulphide. A new class of seismic signals has recently been identified that may correspond to shallow moonquakes. These are rare, but much more energetic than the more numerous, deep moonquakes.
One of the detectors is an illumination detector consisting of two spaced apart elongated strips with a strip of cadmium sulphide (Cds) deposited therebetween. Whenever the line image impinges the CdS strip, the resistance between the two other strips is relatively low, while being high when the line image is outside the field of view of the illumination detector. Also included is a sun angle detector which consists of a vapor deposited resistor strip connected at one end to plus 10v and at the other end to minus 10v. Spaced apart from the resistor strip is an elongated strip of low resistance material acting as an output strip, with a CdS strip between the two strips. When the line image is within the field of view of the sun angle detector, the output voltage at the output strip depends on the position of the line image across the sun angle detector.
Recent results from the Apollo Seismic Network suggest that primitive differentiation occurred in the outer shell of the moon to a depth of approximately 300 km and the central region of the moon is presently molten to a radius of between 200 and 300 km. If early melting to a depth of 300 to 400 km was a consequence of accretional energy, very short accretion times are required. It was shown that the best model for the zone of original differentiation is a crust 40 to 80 km thick, ranging in composition from anorthositic gabbro to gabbro, and overlying an ultramafic cumulate about 250 km thick. The best candidate for the molten core appears to be iron or iron sulphide. A new class of seismic signals recently were identified that may correspond to shallow moonquakes. These are rare, but much more energetic than the more numerous, deep moonquakes.
Enstatite chondrites have oxygen isotope ratios closer to those of the earth and moon than other meteorites. Their minerals are chemically reduced; metal contains Si, and some Ca, Ti, Mg and Mn are incorporated in sulphides rather than silicates. Clinoenstatite and olivine are virtually Fe-free. Two types of clinoenstatite in the Indarch enstatite chondrite have been reported, one luminescing blue and one red. Similar clinoenstatites in the Kota-Kota enstatite chondrite are associated with two distinct types of forsteritic olivine, one luminescing orange and the other blue. The textural relations and differences in chemical composition cannot be explained by progressive condensation from the solar nebula and require the mechanical mixing of material from at least two sources. It is suggested here that enstatite chondrites result from mechanical and chemical processes during aerodynamic sorting and gravitational settling of debris from a hot cloud of dust, liquid and gas produced during collision of planetesimals.
A directional solidification technique was developed and applied to the problem of fractional crystallization of an iron meteorite parent body. Samples of Fe-Ni alloys close to meteorite compositions and containing S, P, and C were made. The solidified structures contain secondary phases such as sulphides within the proeutectic single crystal austenite (taenite). As a result of these experiments, we propose that the secondary phases observed in iron meteorites were formed during primary solidification of austenite (taenite). The measured composition profiles of Ni, P and C in the alloys were used to explain the elemental distribution within a chemical group of iron meteorites. An analytical procedure was applied to determine the equilibrium distribution coefficients as a function of fraction solidified for Ni and P from the composition profiles. The distribution coefficients of Ni and P agree with previous values. These distribution coefficients are of particular interest in the determination of the elemental distributions in iron meteorites.
Twenty-six chondrules, chondrule fragments or clasts were analyzed. An automated wavelength dispersive instrument with a 90 micrometer beam integrated a series of analyses in traverses across each object. Depending on the size of the cross-sectional area, from 1 to 21 analyses were performed for each bulk analysis. Si, Ti, Al, Cr, Fe, Ni, Mn, Mg, Ca, Na, K and S were determined, and an analyzed augite was used as a secondary standard before and after each set of analyses. The work is part of a study of chondrule rims, interchondrule matrix, chondrules and clasts in unequilibrated ordinary chondrites. Only two of the twenty-six objects analyzed have Ca/Al atomic ratios greater than the ordinary chondritic average of 0.74. The bulk meteorite has a normal Ca/Al ratio, so presumably a Ca-rich, Al-poor component must be present to compensate for chondrules and chlasts. This component is unlikely to be rim or matrix, but may be phosphate associated with metal or sulphide. Na/Al ratios range from 1 to almost zero, but there is no hiatus as in a suite of Manych chondrules and glasses.
The present conference on state-of-the-art IR systems and components technologies and their applications encompasses developments in IR systems design, production technologies, IR component testing, IR systems evaluations, laboratory and industrial applications, and aerospace ranging sensor and surveillance sensor applications. Attention is given to IR zoom lens telescopes, large zinc sulphide windows for airborne applications, thermal imaging system evaluation, minimum resolvable temperature difference measurement methods, industrial use of IR spectroscopy, platinum silicide sensor imagery, and recent developments in laser rangefinders.
Experimental studies indicate that opaque assemblages rich in refractory siderophile elements were formed within host calcium- and aluminum-rich inclusions (CAIs) by exsolution, oxidation and sulphidization of homogeneous alloys, rather than by aggregation of materials in the solar nebula before the formation of CAIs. These opaque assemblages are thus not the oldest known solid materials, as was once thought, and they do not constrain processes in the early solar nebula before CAI formation. Instead, the assemblages record the changing oxygen fugacity experienced by CAIs during slow cooling in nebular and/or planetary environments.
Hydrothermal precipitates, black smoker particulate, and massive sulphide dredge samples from the Explorer Ridge on the Juan de Fuca Plate and the TAG hydrothermal area on the Mid-Atlantic Ridge were analyzed for selected noble metals including Au, Ir and Pd by radiochemical neutron activation analysis. The preliminary results indicate that gold contents may reach the ppm range although values in the neighborhood of 100 to 200 ppb are more typical. The platinum group elements (PGE) represented by Ir and Pd are typically less than 0.02 ppb and less than 2 ppb respectively. These abundances represent a significant enrichment of gold relative to the PGE in comparison with average noble metal abundances in mid-ocean ridge basalts (MORB). A partial explanation of this distinctive fractionation can be found in the concepts of sulfur-saturation of basic magma in mid-ocean ridge (MOR) settings, and the origin of MOR hydrothermal fluids. Experimental and petrological data suggest that MORBs are sulfur-saturated at the time of magma generation and that an immiscible sulfide component remains in the mantle residue. Hence, MORBs are noble metal-poor, particularly with respect to PGE. Consequently, black smoker fluids can be expected to reflect the low Ir and Pd contents of the rock column. The average Au content of MORB is 1.3 ppb, and so the rock column is not significantly enriched in Au. The generation of fluids which precipitate solids with 200 ppb Au is apparently dependent on highly efficient fluid chemistry to mobilize Au from the rock column, high Au solubility in seawater hydrothermal fluids and efficient precipitation mechanisms to coprecipitate Au on Fe, Zn and Cu sulfides. Significant differences in these parameters appear to be the ultimate cause of the strong Au-PGE fractionation in the MOR setting. It does not appear from the current data base that MOR hydrothermal fluids are significant contributors to the Ir enrichment seen in Cretaceous-Tertiary boundary sediments.
This talk outlines a simple process for the fabrication of n(+)-p solar cells in indium phosphide. Large area cells (greater than 0.25 sq cm) have been made by this process, with a photovoltaic conversion efficiency of 15.21 percent under AM0 conditions of illumination. An ideality factor of 1.1 and a saturation current density of 8 x 10 to the minus 15th power A/sq cm have been observed for these cells. The technique for cell fabrication involves the diffusion of sulfur into InP by an open tube process, and gives highly reproducible results from run to run. A vacuum-deposited layer of gallium sulphide (Ga2S3) was used as the source for sulfur diffusion, with a chemically vapor deposited SiO2 cap layer to prevent decomposition of the InP surface during heat treatment. Diffusions were carried out in a flowing nitrogen ambient at 585 to 708 C, and characterized by their surface carrier concentration and the diffusion constant. The diffusion profile for sulfur in InP is estimated to be of the complementary error function type. The activation energy of the diffusion was estimated to be 1.94 eV. The technique described here is ideally suited for the fabrication of shallow n(+)-p junctions in InP, and has been used for space-borne solar cells.
A 10 g sample of the Bholghati howardite was disaggregated in order to separate two eucrite clasts, several small carbonaceous clasts, fragments of diogenitic pyroxene, and bulk matrix. The eucrite clasts show evidence of moderately rapid cooling from a melt, followed by prolonged subsolidus annealing. The carbonaceous clasts mostly resemble CM2 carbonaceous chondrites with low-iron silicates and Fe-Ni sulphides in a fine grained dark matrix. One clast, however, is mineralogically, petrographically, and compositionally similar to a CI1 chondrite. Both carbonaceous and eucritic clasts have a complex history prior to incorporation into the howardite matrix with no evidence of significant metamorphism since assembly. Most clasts in the howardite breccia are monomineralic, with pyroxene and plagioclase predominant. Pyroxenes range from 'diogenitic' to 'eucritic' with diogenitic compositions most abundant; a significant number of intermediate compositions are present, consistent with derivation from a series of rocks related by fractionation.
Source gases are defined as those gases that influence levels of stratospheric ozone (O3) by transporting species containing halogen, hydrogen, and nitrogen to the stratosphere. Examples are the CFC's, methane (CH4), and nitrous oxide (N2O). Other source gases that also come under consideration in an atmospheric O3 context are those that are involved in the O3 or hydroxyl (OH) radical chemistry of the troposphere. Examples are CH4, carbon monoxide (CO), and nonmethane hydrocarbons (NMHC's). Most of the source gases, along with carbon dioxide (CO2) and water vapor (H2O), are climatically significant and thus affect stratospheric O3 levels by their influence on stratospheric temperatures. Carbonyl sulphide (COS) could affect stratospheric O3 through maintenance of the stratospheric sulphate aerosol layer, which may be involved in heterogeneous chlorine-catalyzed O3 destruction. The previous reviews of trends and emissions of source gases, either from the context of their influence on atmospheric O3 or global climate change, are updated. The current global abundances and concentration trends of the trace gases are given in tabular format.
Determinations of oxidation states and the crystal chemistry of iron-bearing minerals in CM meteorites by Moessbauer spectroscopy are complicated by thermally-induced electron hopping in cronstedtite and by ill-defined contributions from the hydrous iron sulphide phase believed to be tochilinite. Moessbauer spectral measurements at 30 K of several cronstedtite and tochilinite specimens have enabled modal proportions of these minerals, as well as Fe(3+)/Fe(2+) ratios, to be determined quantitatively for a suite of CM-type carbonaceous chondrites that included Murchison, Murray, Cold Bokkeveld, ALH 83100, and LEW 90500.
A new development on the measurement of the Os isotopic composition by mass spectrometry using negative ions opened a new field of applications. The Re-Os systematic provides time information on the differentiation of the nobel metals. The nobel metals are strongly partitioned into metal and sulphide phases, but also the generation of silicate melts might fractionate the Re-Os system. Compared to the other isotopic systems which are mainly dating the fractionation of the alkalis and alkali-earth elements, the Re-Os system is expected to disclose entirely new information about the geochemistry. Especially the differentiation and early evolution of the planets such as the formation of the core will be elucidated with this method.
Chemical effects arising from the exchange of molecules between dust and gas in dense clumps are described. Selective desorption of CO and N2 from grains in cool cores can account for the presence of ammonia in several cores in the NGC 2024 cloud. Evaporation of ices containing methanol and ethanol can lead to detectable abundances of (C2H5)(sub 2)O and CH3OC2H5. Results are presented for the hot core chemistries of sulphur and phosphorus which are initiated by evaporated hydrogen sulphide and phosphine. The implications of these studies for understanding the nature of molecular mantles, the evolution of molecular complexity in the gas phase, and the presence of small-scale abundance gradients in star-forming regions, are briefly discussed.
In a similar approach to that used for the previously issued correlation report for Coflon (CAPP/M.10), this report aims to identify any correlations between mechanical property changes and chemical/morphological changes for Tefzel, using information supplied in other MERL and TRI project reports (plus latest data which will be included in final reports for Phase 1). Differences identified with Coflon behaviour will be of scientific interest as well as appropriate to project applications, as Tefzel and Coflon are chemical isomers. Owing to the considerable chemical resistance of Tefzel, much of its testing so far has been based on mechanical properties. Where changes have occurred, chemical analysis can now be targeted more effectively. Relevant test data collated here include: tensile modulus and related properties, permeation coefficients, % crystallinity, and other observations where significant. Fluids based on methanol and amine (Fluid G), a mixture of methane, carbon dioxide and hydrogen sulphide gases plus an aqueous amine solution (Fluid F), and an aromatic oil mix of heptane, cyclohexane, toluene and I-propanol (Fluid 1) have affected Tefzel to varying degrees, and are discussed in some detail herein.
This report aims to identify correlations between mechanical property changes and chemical/morphological structure changes for Coflon. It is intended both to illustrate the overall methodology and to indicate the testing that needs to be undertaken in order to obtain correlations. Many fluid exposures have now been carried out on Coflon during the project and many data generated as a result. The report summarises the changes observed in mechanical and physical properties and relates these as well as possible to the chemistry thought to be occurring during ageing. For this purpose, data have been collated from already-issued MERL and TRI technical and progress reports. Most of the mechanical testing of aged testpieces has been performed soon after the completion of the exposure; however, there is of necessity a delay in obtaining chemical analysis of the same testpieces, so that more physical than chemical data are shown. Three fluids have so far caused measurable deterioration of Coflon, these being: methanol (Fluid A), a methanol and amine mixture (Fluid G), and a mixture of methane, carbon dioxide gas and hydrogen sulphide gas plus aqueous amine (Fluid F). Only the effects of these fluids will be dealt with in any detail in this report, although other fluids are assessed to give relevant background information. Relevant test data collated here include: tensile modulus and related properties, mode of sample failure at break, fracture toughness, fatigue crack growth rate and resistance, stress relaxation rate, permeation coefficients, % crystallinity and molecular weight distributions together with changes in fluorine levels, and other observations where appropriate. However, not all of these were obtained for every ageing condition. Because of the wide range of tests employed, and the different ways in which their results are obtained, the following section has been included to serve as a background for making comparisons.