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At least 55 records · Page 3

Reactions and diffusion between an Al film and a Ti substrate

The reaction between a 0.5 to 1.0 micron Al film and a thick Ti substrate to form TiAl3 occurs very rapidly on heating to 635 C and causes the Al to be confined to the surface region. After heating to 900 C, Ti3Al is formed with little release of Al into alpha-Ti. Further annealing at 900 C eventually causes the Ti3Al phase to decompose and a substantial amount of Al is released into alpha-Ti. The interdiffusion coefficient for Al in alpha-Ti at 900 C was found to increase by less than one order of magnitude as Al is varied from 0 to 20 at. pct. These data were obtained from the (101) X-ray diffraction intensity band using polycrystalline samples. Improvements in the analysis of X-ray diffraction data for the determination of composition profiles are discussed.

Rao, V. B.↗

Photochemical stability of UV-screening transparent acrylic copolymers of 2-(2-hydroxy-5-vinylphenyl)-2H-benzotriazole

The mechanism of photodegradation of certain hydroxyphenyl benzotriazole based ultraviolet absorbers has been investigated and a new polymerizable ultraviolet absorber in this group has been synthesized. The photoreactivity is entirely confined at the surface of polymethylmethacrylate films containing the ultraviolet absorbers as pendant groups. A mechanism involving sensitized photooxidation has been proposed to interpret the data.

Gupta, A.↗

Search for dark companions of K and M giants - Preliminary results for Alpha Boo

Preliminary results are presented for Alpha Boo, encompassing selected measurements during the period from January 1979 to June 1984. Four groups of data are chosen, each group taken within an interval of up to 1.5 months, and examined the internal consistency of each set to look for short term trends. The radial velocity was found to be very consistent with a standard deviation of about + or - 50 m/s within time scales of hours, days, and weeks. No significant radial velocity changes over these periods were detected. This suggests that the stellar surface activity is confined to the level of uncertainty. Because of this consistency it was possible to take the means of the radial velocity measurements within each group and compare them to look for possible long term changes. Variations of the radial velocity of about 200 m/s were found over the span of a few years, significant at the 6 to 8 sigma level.

Heyer, I.↗

Apparatus for producing diamond-like carbon flakes

A vacuum arc from a spot at the face of a graphite cathode to a graphite anode produces a beam of carbon ions and atoms. A carbon coating from this beam is deposited on an ion beam sputtered target to produce diamond-like carbon flakes. A graphite tube encloses the cathode, and electrical isolation is provided by an insulating sleeve. The tube forces the vacuum arc spot to be confined to the surface on the outermost end of the cathode. Without the tube the arc spot will wander to the side of the cathode. This spot movement results in low rates of carbon deposition, and the properties of the deposited flakes are more graphite-like than diamond-like.

Banks, Bruce A.↗

Two-Pole Caustic Model for High-Energy Lightcurves of Pulsars

We present a new model of high-energy lightcurves from rotation powered pulsars. The key ingredient of the model is the gap region (i.e. the region where particle acceleration is taking place and high-energy photons originate) which satisfies the following assumptions: i) the gap region extends from each polar cap to the light cylinder; ii) the gap is thin and confined to the surface of last open magnetic-field lines; iii) photon emissivity is uniform within the gap region. The model lightcurves are dominated by strong peaks (either double or single) of caustic origin. Unlike in other pulsar models with caustic effects, the double peaks arise due to crossing two caustics, each of which is associated with a different magnetic pole. The generic features of the lightcurves are consistent with the observed characteristics of pulsar lightcurves: 1) the most natural (in terms of probability) shape consists of two peaks (separated by 0.4 to 0.5 in phase for large viewing angles); 2) the peaks possess well developed wings; 3) there is a bridge (inter-peak) emission component; 4) there is a non-vanishing off-pulse emission level; 5) the radio pulse occurs before the leading high-energy peak. The model is well suited for four gamma-ray pulsars - Crab, Vela, Geminga and B1951+32 - with double-peak lightcurves exhibiting the peak separation of 0.4 to 0.5 in phase. Hereby, we apply the model to the Vela pulsar. Moreover, we indicate the limitation of the model in accurate reproducing of the lightcurves with single pulses and narrowly separated (about 0.2 in phase) pulse peaks. We also discuss the optical polarization properties for the Crab pulsar in the context of the two-pole caustic model.

Dyks, J.↗

Mineral induction by immobilized phosphoproteins

Dentin phosphoproteins are thought to have a primary role in the deposition of mineral on the collagen of dentin. In this study we determined the type of binding between collagen and phosphoproteins necessary for mineral formation onto collagen fibrils and whether the phosphate esters are required. Bovine dentin phosphophoryn or phosvitin from egg yolk were immobilized on reconstituted skin type I collagen fibrils by adsorption or by covalent cross-linking. In some samples the ester phosphate was removed from the covalently cross-linked phosphoproteins by treatment with acid phosphatase. All samples were incubated at 37 degrees C in metastable solutions that do not spontaneously precipitate. Reconstituted collagen fibrils alone did not induce mineral formation. The phosphoproteins adsorbed to the collagen fibrils desorbed when the mineralization medium was added, and mineral was not induced. The mineral induced by the cross-linked phosphoproteins was apatite, and the crystals were confined to the surface of the collagen fibrils. With decreasing medium saturation the time required for mineral induction increased. The interfacial tensions calculated for apatite formation by either phosphoprotein cross-linked to collagen were about the same as that for phosphatidic acid liposomes and hydroxyapatite. This similarity in values indicates that the nucleation potential of these highly phosphorylated surfaces is about the same. It is concluded that phosphoproteins must be irreversibly bound to collagen fibrils for the mineralization of the collagen network in solutions that do not spontaneously precipitate. The phosphate esters of phosphoproteins are required for mineral induction, and the carboxylate groups are not sufficient.

Non-NASA Center↗

Variable Altitude Cognizant Slepian Functions

We present an approach to calculate potential fields on a planet’s surface from regionally confined gradient data at spacecraft altitude, such as measurements of magnetic fields or gravitational acceleration. Our method uses altitude cognizant Slepian functions with a reference radial position that varies as a function of longitude and latitude. This is an evolution from previous altitude cognizant Slepian functions which use a fixed reference radial position. We demonstrate the advantage of these variable altitude cognizant Slepian functions over the fixed altitude cognizant Slepian functions and the classical Slepian functions using numerical tests.

planetary science↗

GaAs/AlGaAs heterostructure point-contact concentrator cells

Point-contact cells fabricated in silicon have recently achieved very high efficiencies. Applying this structure to GaAs is difficult as it requires both surface passivation of the GaAs and a film of GaAs with thickness less than 10 microns. The authors propose to overcome these difficulties by (1) using AlGaAs layers grown by OMCVD to act as front- and back-surface fields in order to confine the photogenerated minority carriers away from the surfaces, and (2) using the CLEFT technology to produce thin, separated films of this structure. It has been found that much of the necessary technologies have been developed and that the primary problem remaining to be solved is localized junction formation.

Gale, R. P.↗

Growth of GaAs from a free surface melt under controlled arsenic pressure in a partially confined configuration

A partially confined configuration for the growth of GaAs from melt in space was developed, consisting of a triangular prism containing the seed crystal and source material in the form of a rod. It is suggested that the configuration overcomes two obstacles in the growth of GaAs in space: total confinement in a quartz crucible and lack of arsenic pressure control. Ground tests of the configuration show that it is capable of crystal growth in space and is useful for studying the growth of GaAs from a free-surface melt on earth. The resulting chemical composition, electrical property variations, and phenomenological models to account for the results are presented.

Gatos, H. C.↗

Growth of delta-doped layers on silicon CCD/S for enhanced ultraviolet response

The backside surface potential well of a backside-illuminated CCD is confined to within about half a nanometer of the surface by using molecular beam epitaxy (MBE) to grow a delta-doped silicon layer on the back surface. Delta-doping in an MBE process is achieved by temporarily interrupting the evaporated silicon source during MBE growth without interrupting the evaporated p+ dopant source (e.g., boron). This produces an extremely sharp dopant profile in which the dopant is confined to only a few atomic layers, creating an electric field high enough to confine the backside surface potential well to within half a nanometer of the surface. Because the probability of UV-generated electrons being trapped by such a narrow potential well is low, the internal quantum efficiency of the CCD is nearly 100% throughout the UV wavelength range. Furthermore, the quantum efficiency is quite stable.

Hoenk, Michael E.↗

Incompressible magnetohydrodynamic surface waves - Nonlinear aspects

The nonlinear properties of MHD surface waves in the solar atmosphere are investigated analytically, assuming that the fluid is incompressible and that the waves are confined to a single surface, with semiinfinite regions on both sides. The governing equations are derived in detail, and qualitative results are presented in a graph. For propagating waves, second-order terms in the wave amplitude are found to lead to wave steepening at leading or trailing edges, the steepening rate becoming very large as the threshold for the linear Kelvin-Helmholtz instability is approached. Second-order effects on standing waves include crest and trough sharpening (increasing with time), a current independent of distance on the surface but decreasing exponentially with distance from the surface, and pressure-field fluctuations of infinite extent. It is suggested that these effects could account for a large fraction of solar-atmosphere heating.

Hollweg, Joseph V.↗

Steady state growth and segregation under zero gravity: InSb

It was established that ideal diffusion controlled steady state conditions, never accomplished on earth, were achieved during the growth of Te-doped InSb crystals in Skylab. Surface tension effects were found to establish non-wetting conditions under which free surface solidification took place in confined geometry. It was further found that, under forced contact conditions, surface tension effects led to the formation of surface ridges (not previously observed on earth) which isolated the growth system from its container. In addition, it was possible for the first time to identify unambiguously: the origin of segregation discontinuities associated with facet growth, the mode of nucleation and propagation or rotational twin boundaries, and the specific effect of mechanical-shock perturbations on segregation. The results obtained prove the advantageous conditions provided by outer space. Thus, fundamental data on solidification thought to be unattainable because of gravity induced interference on earth are now within reach.

Witt, A. F.↗

Indium antimonide crystal growth experiment M562

It was established that ideal diffusion controlled steady state conditions, never accomplished on earth, were achieved during the growth of Te-doped InSb crystals in Skylab. Surface tension effects led to nonwetting conditions under which free surface solidification took place in confined geometry. It was further found that, under forced contact conditions, surface tension effects led to the formation of surface ridges (not previously observed on earth) which isolated the growth system from its container. In addition, it was possible, for the first time, to identify unambiguously: the origin of segregation discontinuities associated with facet growth, the mode of nucleation and propagation of rotational twin boundaries, and the specific effect of mechanical-shock perturbations on segregation. The results obtained prove the advantageous conditions provided by outer space. Thus, fundamental data on solidification thought to be unattainable because of gravity-induced interference on earth are now within reach.

Gatos, H. C.↗

Chapter 6: Fundamental Satellite Precipitation Data Records

The observation and measurement of precipitation across a range of temporal and spatial scales is of great importance for many user requirements and applications. Precipitation is a key component of the global energy and water cycle moving water, and its’ associated energy, through the Earth system at relatively fine spatial and temporal scales. At the societal level, precipitation provides fresh water and moderates our climate, but can also be destructive through storms, droughts and spreading diseases. Monitoring and measuring the distribution and quantities of precipitation, across the Earth’s surface is therefore crucial to physical and social applications, together with changes in precipitation over time. While conventional surface instruments provide a reasonably long record, these tend to be confined to well populated land surface areas: most ocean regions and sparsely populated regions have few measurements. Satellite-based precipitation products can provide global measurements, although the timespan of such products is limited and the data record is comprised of different instruments that operate over different periods of record. The challenge of any climate record is to provide a consistent product over the full period of record. Many satellite precipitation products incorporate ancillary data, such as surface gauge data or model data, which may limit their utility in the validation or verification of other climate data records. This chapter provides a review of the importance of precipitation to the climate system, the basis of satellite precipitation retrievals, climate data records of satellite data for precipitation retrievals and the development of fundamental precipitation data records for climate applications.

Climate data record↗

A Review on the Coalescence of Confined Drops with a Focus on Scaling Laws for the Growth of the Liquid Bridge

The surface–tension-driven coalescence of drops has been extensively studied because of the omnipresence of the phenomenon and its significance in various natural and engineering systems. When two drops come into contact, a liquid bridge is formed between them and then grows in its lateral dimensions. As a result, the two drops merge to become a bigger drop. The growth dynamics of the bridge are governed by a balance between the driving force and the viscous and inertial resistances of involved liquids, and it is usually represented by power–law scaling relations on the temporal evolution of the bridge dimension. Such scaling laws have been well-characterized for the coalescence of unconfined or freely suspended drops. However, drops are often confined by solid or liquid surfaces and thus are a different shape from spheres, which affects their coalescence dynamics. As such, the coalescence of confined drops poses more complicated interfacial fluid dynamics challenges compared to that of unconfined drops. Although there have been several studies on the coalescence of confined drops, they have not been systematically reviewed in terms of the properties and geometry of the confining surface. Thus, we aim to review the current literature on the coalescence of confined drops in three categories: drop coalescence on a solid surface, drop coalescence on a deformable surface, and drop coalescence between two parallel surfaces with a small gap (i.e., Hele-Shaw cell), with a focus on power–law scaling relations, and to suggest challenges and outlooks for future research on the phenomena.

Sangjin Ryu↗

LDEF fiber-composite materials characterization

Degradation of a number of fiber/polymer composites located on the leading and trailing surfaces of LDEF where the atomic oxygen (AO) fluences ranged from 10(exp 22) to 10(exp 4) atoms/cm(sup 2), respectively, was observed and compared. While matrices of the composites on the leading edge generally exhibited considerable degradation and erosion-induced fragmentation, this 'asking' process was confined to the near surface regions because these degraded structures acted as a 'protective blanket' for deeper-lying regions. This finding leads to the conclusion that simple surface coatings can significantly retard AO and other combinations of degrading phenomena in low-Earth orbit. Micrometeoroid and debris particle impacts were not a prominent feature on the fiber composites studied and apparently do not contribute in a significant way to their degradation or alteration in low-Earth orbit.

Miglionico, C. J.↗

Origin of low-frequency (intraseasonal) oscillations in the tropical atmosphere. II - Structure and propagation of mobile wave-CISK modes and their modification by lower boundary forcings

An improved treatment of diabatic heating due to moist convection is introduced into the dynamical model of Lau and Peng (1987) to study the origin of intraseasonal oscillations in the tropics. It is found that the periods of slow-moving wave-CISK disturbances in the tropical troposphere with fixed sea surface temperature vary from 20 to 50 days. The results suggest that heating in the lower troposphere may be important in slowing down the wave-CISK modes. Also, it is shown that the intraseasonal oscillation can propagate around the globe even when the associated deep convection is only confined over warm sea surface temperatures.

Sui, Chung-Hsiung↗