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At least 55 records · Page 3

Using Mineralogy to Interpret Martian Geologic History

The surface mineralogy of Mars is key to interpreting the planet’s geologic history and constraining when and where Mars may have been habitable to microbial life. Orbital mineralogical data from infrared spectrometers collected over the last two decades have demonstrated that Mars is more than a basaltic planet. Thermal infrared (TIR) emission spectrometers have identified regional variations in igneous minerals, iron oxides, and chloride salts, showing evidence for magmatic evolution and aqueous alteration. Orbital visible/shortwave infrared reflectance spectra provide detailed information about the aqueous history of Mars through the identification of clay minerals, sulfates, carbonates, zeolites, and amorphous materials in ancient ~3-4-billion-year-old terrains. Mineralogical data from rovers allow us to better characterize mineral formation mechanisms by identifying mineral assemblages and placing them in geologic context using outcrop- to grain-scale images. TIR and Mössbauer data from the Mars Exploration Rovers helped identify an ancient dune-interdune playa environment with multiple episodes of groundwater at Meridiani Planum and volcanism-induced hydrothermalism at Gusev crater. The CheMin X-ray diffractometer on the Mars Science Laboratory Curiosity rover in Gale crater is the first fully quantitative mineralogical instrument sent to another planetary surface. CheMin data allow the quantification of minerals and X-ray amorphous materials with a mineral detection limit of <1 wt.% and provide crystal chemistry of major phases from refined unit-cell parameters. CheMin has revealed local mineralogical changes in ancient sedimentary rocks not seen from orbit and helped identify habitable environments. Throughout the 600+ m of vertical stratigraphy studied so far, changes in clay mineralogy, Fe-oxides/oxyhydroxides, sulfates, and carbonates demonstrate a long history of surface and groundwater at Gale crater with variable salinity, pH, Eh, and temperature. Recent CheMin data document a decrease in clay minerals and an increase in sulfate minerals in younger strata that corresponds with a change from fluvio-lacustrine to eolian depositional environments, potentially documenting a change to a drier climate across the planet.

E. B. Rampe↗

Surface chemistry and mineralogy

The accumulated knowledge on the chemistry and mineralogy of Martian surface materials is reviewed. Pertinent information obtained by direct analyses of the soil on Mars by the Viking Landers, by remote sensing of Mars from flyby and orbiting spacecraft, by telescopic observations from earth, and through detailed analyses of the SNC meteorites presumed to be Martian rocks are summarized and analyzed. A compositional model for Mars soil, giving selected average elemental concentrations of major and trace elements, is suggested. It is proposed that the fine surface materials on Mars are a multicomponent mixture of weathered and nonweathered minerals. Smectite clays, silicate mineraloids similar to palagonite, and scapolite are suggested as possible major candidate components among the weathered minerals.

Banin, A.↗

Exploring Mars for Evidence of Past or Present Life: Roles of Robotic and Human Missions

During the coming decade, robotic field science will play a fundamental role in exploring Mars for evidence of past life and/or prebiotic chemistry. To create a context for such exploration, we especially need to understand the mineralogy and chemistry of the Martian surface. We have learned that the preservation of biological signatures in rocks on Earth is favored by rapid mineralization processes that are restricted to a comparatively small number of geological settings. Thus, a detailed knowledge of surface mineralogy will provide valuable clues about past Martian environments as a necessary context for future exobiological exploration.

Farmer, Jack D.↗

Computer modeling of the mineralogy of the Martian surface, as modified by aqueous alteration

Mineralogical constraints can be placed on the Martian surface by assuming chemical equilibria among the surface rocks, atmosphere and hypothesized percolating groundwater. A study was made of possible Martian surface mineralogy, as modified by the action of aqueous alteration, using the EQ3/6 computer codes. These codes calculate gas fugacities, aqueous speciation, ionic strength, pH, Eh and concentration and degree of mineral saturation for complex aqueous systems. Thus, these codes are also able to consider mineralogical solid solutions. These codes are able to predict the likely alteration phases which will occur as the result of weathering on the Martian surface. Knowledge of the stability conditions of these phases will then assist in the definition of the specifications for the sample canister of the proposed Martian sample return mission. The model and its results are discussed.

Zolensky, M. E.↗

The Hyperspectral Infrared Imager (HyspIRI) Public Health and Air Quality Applications

The neglected tropical diseases (NTDs), a group of chronic, debilitating, and poverty-promoting parasitic, bacterial, and some viral and fungal infections, are among the most common causes of illness of the poorest people living in developing countries. Abiotic environmental factors are important in determining the distribution of disease-causing vectors and their life-cycles. HyspIRI observations can be merged through a Land Data Assimilation System (LDAS) be used to drive spatially-explicit ecological models of NTD vectors distribution & life cycles. Assimilations will be driven by observational data LDAS and satellite-derived meteorological forcing data, parameter datasets, and assimilation observations. HyspIRI hyperspectral measurements would provide global measurements of surface mineralogy and biotic crusts important in accessing the impact of dust in human health. HyspIRI surface thermal measurements would also help identify the variability of dust sources due to surface moisture conditions and map mineralogy.

Luvall, Jeffrey C.↗

The Hyperspectral Infrared Imager (HyspIRI) Public Health and Air Quality Applications

The neglected tropical diseases (NTDs), a group of chronic, debilitating, and poverty-promoting parasitic, bacterial, and some viral and fungal infections, are among the most common causes of illness of the poorest people living in developing countries. Abiotic environmental factors are important in determining the distribution of disease-causing vectors and their life-cycles. HyspIRI observations can be merged through a Land Data Assimilation System (LDAS) be used to drive spatially-explicit ecological models of NTD vectors distribution & life cycles. Assimilations will be driven by observational data LDAS and satellite-derived meteorological forcing data, parameter datasets, and assimilation observations. HyspIRI hyperspectral measurements would provide global measurements of surface mineralogy and biotic crusts important in accessing the impact of dust in human health. HyspIRI surface thermal measurements would also help identify the variability of dust sources due to surface moisture conditions and map mineralogy.

Luvall, Jeffrey C.↗

The Hyperspectral Infrared Imager (HyspIRI) Public Health & Air Quality Applications

The neglected tropical diseases (NTDs), a group of chronic, debilitating, and poverty-promoting parasitic, bacterial, and some viral and fungal infections, are among the most common causes of illness of the poorest people living in developing countries. Abiotic environmental factors are important in determining the distribution of disease-causing vectors and their life-cycles. HyspIRI observations can be merged through a Land Data Assimilation System (LDAS) be used to drive spatially-explicit ecological models of NTD vectors distribution & life cycles. Assimilations will be driven by observational data LDAS and satellite-derived meteorological forcing data, parameter datasets, and assimilation observations. HyspIRI hyperspectral measurements would provide global measurements of surface mineralogy and biotic crusts important in accessing the impact of dust in human health. HyspIRI surface thermal measurements would also help identify the variability of dust sources due to surface moisture conditions and map mineralogy.

Luvall, Jeffrey C.↗

The Hyperspectral Infrared Imager (HyspIRI) Public Health and Air Quality Applications

The neglected tropical diseases (NTDs), a group of chronic, debilitating, and poverty-promoting parasitic, bacterial, and some viral and fungal infections, are among the most common causes of illness of the poorest people living in developing countries. Abiotic environmental factors are important in determining the distribution of disease-causing vectors and their life-cycles. HyspIRI observations can be merged through a Land Data Assimilation System (LDAS) be used to drive spatially-explicit ecological models of NTD vectors distribution and life cycles. Assimilations will be driven by observational data LDAS and satellite-derived meteorological forcing data, parameter datasets, and assimilation observations. HyspIRI hyperspectral measurements would provide global measurements of surface mineralogy and biotic crusts important in accessing the impact of dust in human health. HyspIRI surface thermal measurements would also help identify the variability of dust sources due to surface moisture conditions and map mineralogy.

Luvall, Jeffrey C.↗

The Complex Refractive Indices of Mineral Aerosols and Why They Matter

Aerosol refractive indices are fundamental parameters that are generally measured by spec-troscopists with specialized knowledge. We in the Earth science community frequently utilizethese refractive indices because they are essential for computing aerosol radiative effects andretrieving aerosol composition. Unfortunately, there are a wide variety of refractive indiceswith significant differences for some aerosol species (e.g., hematite) and a lack of refractiveindex choices for other aerosols (e.g., clay minerals, goethite), and this hinders our ability toaccurately compute the radiative effect of mineral dust. Additionally, the mineral refractiveindices used in atmospheric science are not necessarily linked to the mineral reflectancesused to identify surface mineralogy; this creates a disconnect between the atmosphere andthe surface that frustrates closure analyses.In this talk, we will present an overview of some refractive indices of radiative importancein aeolian dust (illite, kaolinite, montmorillonite, hematite, goethite). We will discuss howmineral refractive indices are used in aerosol retrievals, and how we can use remote sensingretrievals to narrow the range of viable choices. We will also discuss how we can use pub-lished spectroscopic measurements to extrapolate the refractive indices that are inferred ata handful of visible and near-infrared wavelengths to the longwave regime. Finally, we willdiscuss how working groups like MIRA (Models, In situ, and Remote sensing of Aerosols;https://science.larc.nasa.gov/mira-wg/) and community repositories like TAO (Tables ofAerosol Optics) can improve radiative closure by enhancing interactions between the threedisciplines.1

aerosols↗

Bulk Composition of Vesta as Constrained by the Dawn Mission and the HED Meteorites

Of the objects in the main asteroid belt, Vesta is of particular interest as it is large enough to have experienced internal differentiation (520 km diameter), and it is known to have a basaltic surface dominated by FeO-bearing pyroxenes. Furthermore, visible-IR spectra of Vesta and associated Vestoids are remarkably similar to laboratory spectra of Howardite-Eucrite-Diogenite (HED) meteorites, leading to the paradigm that the HEDs ultimately came from Vesta. Geochemical and petrological studies of the HEDs confirm the differentiated nature of the near-surface region of their parent body, and imply that crust extraction occurred well within the first 10 Ma of solar system history Vesta is therefore a prime target for studies that aim to constrain the earliest stages of planet building, and it is within this context that the NASA Dawn spacecraft orbited Vesta from July 2011 to September 2012. The results of the Dawn mission so far have significantly reinforced the HED-Vesta connection, confirming a significant degree of internal differentiation, a surface mineralogy compatible with that of the HEDs, and near-surface ratios of Fe/O and Fe/Si consistent with HED lithologies. The combination of data from the HED meteorites and the Dawn mission thus presents an unprecedented opportunity to use Vesta as a natural laboratory of early differentiation processes in the early solar system. However, the bulk composition of Vesta remains a significant unknown parameter, but one that plays a key role on the physical and chemical properties of the internal and surface reservoirs (core, mantle, crust). Several attempts have been made to constrain the bulk composition of the eucrite parent body, early endeavours relying on petrological or cosmochemical constraints. More recently, individual chondrite class compositions, or mixtures thereof, have been considered, constrained by considerations such as O-isotopes, trace-element ratios and siderophile element concentrations of the eucrites. The work presented here builds upon these latter studies, with the primary aims of: i) illustrating the potential diversity of the geochemical and geophysical properties of a fully differentiated Vesta-sized parent body, and ii) assessing which, if any, of the known chondritic bulk compositions are plausible analogues for proto-Vesta.

Toplis, M. J.↗

Detectability of crystalline ferric and ferrous minerals on Mars

Telescopic and spacecraft spectroscopic and geochemical data have been used to constrain the surface mineralogy of Mars and to yield clues about past and present Mars surface weathering/alteration scenarios. Based primarily on their visible to near-IR reflectance properties, several terrestrial iron-bearing minerals have been either identified on Mars or proposed as Mars spectral analogs. Among these are crystalline hematite, pyroxenes, as well as poorly crystalline materials like nonophase hematite and palagonite. Other iron-bearing minerals include nontronite, magnetite, jarosite, and goethite and the have been proposed as Mars surface constituents based on Viking Lander measurements or geochemical modeling. If present on Mars, these materials likely appear as spectral mixtures at the coarse spatial resolution of remotely sensed data. The detectability of any of these components must be evaluated relative to the other components with which they occur. The primary goal of this study is to determine how much of any given mineral would have to be present for it to be detectable in remotely-sensed data. Here, the detectability of iron-bearing minerals was evaluated using detection threshold analysis (DTA), an analytical technique based on spectral mixture analysis.

Sabol, Donald E., Jr.↗

Remote spectroscopic identification of carbonaceous chondrite mineralogies Applications to Ceres and Pallas

High-resolution spectroscopic observations of asteroids Ceres and Pallas have been obtained in the 1.0- to 2.6-micron region. Combined with previous spectral measurements at other wavelengths, this work presents the broadband spectral reflectances of these asteroids over the 0.4- to 3.6-micron region. This extended coverage permits new analyses of the surface mineralogies of these objects. Using laboratory comparison spectra of meteorites and mixtures of terrestrial minerals, the surfaces of Ceres and Pallas are consistent with mixtures of opaques and hydrated silicates, such as are found in types C1 and C2 meteorites. This research emphasizes the importance of the 3-micron spectral region for studying by remote methods the relationship of carbonaceous chondrite mineralogies to asteroid surfaces.

Larson, H. P.↗

Regolith Evolved Gas Analyzer (REGA): An Instrument to Characterize the Martian Soil Mineralogy and Atmosphere Composition

This abstract describes an instrument and experiment to be proposed for a future Mars surface mission to conduct basic research on environmental characterization. The Regolith Evolved Gas Analyzer (REGA) experiment is designed to provide information on Mars surface material properties in preparation for human missions of exploration. The goals of the investigation are: 1) Define and determine surface mineralogy of soil and dust and their effects on humans and machines; and 2) Conduct in-situ investigations aimed at identifying possible evidence of past or present life on Mars.

Hoffman, John H.↗

Integrated Spectroscopic Studies of Anhydrous Sulfate Minerals

Sulfates have been identified in Martian soils and bedrock and are emerging as an important indicator for aqueous activity on Mars. Sulfate minerals can form in a variety of low-temperature (evaporitic; chemical-weathering) and high-temperature (volcanic/fumarolic; hydrothermal) environments and their formational environments can range from alkaline to acidic. Although sulfates generally form in the presence of water, not all sulfates are hydrous or contain water in their structures. Many of these anhydrous sulfates (Dana group 28; Strunz class 67A) are minerals that form as accompanying phases to the main minerals in ore deposits or as replacement deposits in sedimentary rocks. However, some form from thermal decomposition of OH or H2O-bearing sulfates, such as from the reaction [1]: jarosite = yavapaiite + Fe2O3 + H2O. Where known, the stability fields of these minerals all suggest that they would be stable under martian surface conditions [2]. Thus, anhydrous sulfate minerals may contribute to martian surface mineralogy, so they must be well-represented in spectral libraries used for interpretation of the Martian surface. We present here the preliminary results of an integrated study of emittance, reflectance, and Mossbauer spectroscopy of a suite of wel-lcharacterized anhydrous sulfates.

Lane, M. D.↗

Analysis of MGS TES Data over Acidalia Planitia and Cydonia Mensae: Compositional Evidence for Hydrovolcanic Activity?

For this study, Mars Global Surveyor (MGS) Thermal Emission Spectrometer (TES) emissivity data for Acidalia Planitia and Cydonia Mensae (Figure 1) were assembled and used to examine the surface mineralogy of these areas. Analyzing TES data for high latitude locales such as Acidalia presents a challenge since the surface temperatures over these regions is inherently lower than for equatorial locales. In this report, analyses of TES data are described and results are evaluated for potential compositional evidence for hydrovolcanic activity in Acidalia and Cydonia.

Farrand, W. H.↗

Abundance and distribution of ultramafic microbreccia in Moses Rock dike - Quantitative application of mapping spectroscopy

Data from the Airborne Imaging Spectrometer were used to map the distribution and abundance of the serpentized ultramafic microbreccia (SUM) component in the Moses Rock dike, which is a Tertiary diatreme located on the Colorado Plateau in Utah. The geologic setting and composition of Moses Rock dike are discussed together with its texture and the relationship to the bedrock of surface materials. These observations along with laboratory spectroscopic data are used to interpret surface mineralogy of the dike and the surrounding regions from the imaging spectometer data. The spatial distribution and the abundance of the primary surface components were calculated using a nonlinear model for the mixing of spectra from multicomponent surfaces. The derived SUM distribution and abundance data support McGetchin's (1968) model for the emplacement of Moses Rock dike as a fluidized system.

Mustard, John F.↗

Near-infrared observations of primitive asteroids and a possible extinct comet

Photometry was obtained simultaneously in the near-infrared and in the visible, of several D-type asteroids, thought to be composed of the most primordial material in the asteroid belt. These objects have been previously classified as D-type based on their low albedo and broadband colors in the visible region of the spectrum. One of the objects observed is 944 Hidalgo, which is possibly an extinct comet, based on its orbital elements. The photometry further constrains the surface mineralogy and is a test of whether differences exist between these objects in different regions of the asteroid belt. Refining the knowledge of the surface composition of these objects will allow a better measure of the amount of thermal processing which has taken place in these so-called primitive asteroids. Spectral slope is assumed to be sensitive to surface composition. There is some variability in spectral slope among those objects classified as D-type, with indications of increasing slope into the near-infrared with heliocentric distance. The spectral features are quite subtle as expected for these low albedo objects, but there is possible evidence of subtle features in some of the D-type asteroids and possibly some active comets. Further analysis of these spectra and the implications for the outer region of the asteroid belt is presented.

Howell, E. S.↗

GRO 95577 (CR1) as a mineralogical analogue for asteroid (101955) Bennu

Orbital spectra of asteroid (101955) Bennu collected by NASA's Origins, Spectral Interpretation, Resource Identification, Security–Regolith Explorer (OSIRIS–REx) spacecraft have identified ungrouped C, CI, and CM meteorites having petrologic types 1, 1/2, and 2 as the best mineralogical analogues to Bennu to date. Here we present spectral evidence that Grosvenor Mountains (GRO) 95577, a CR1, is a better analogue for Bennu's bulk surface mineralogy. CR-like parent bodies are targets of interest because they contain some of the most pristine materials from the solar nebula and can contain substantial amounts of H2O and OH− in addition to exotic organics. Unfortunately, terrestrial weathering makes constraining their indigenous mineralogy and organics challenging. Analysis of samples retrieved directly from an asteroid would help us disentangle the effects of terrestrial weathering and asteroidal aqueous alteration and hence whether some of the exotic organics and large populations of presolar grains were affected by terrestrial processes in meteorites. If Bennu is comprised of CR1(−like) material, in whole or in part, the OSIRIS–REx returned sample represents a tremendous opportunity to explore in depth what is currently a unique material among carbonaceous chondrites.

Asteroids↗