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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

TPSAS-NF1676L-27509-DND

The information about composition of aerosols has a great importance for monitoring and understanding of climate and environment dynamics. Such information can be obtained using situ measurements or chemical transport models. However, in situ sampling has limited spatial and temporal coverage, while estimations have large uncertainties. The present work enables the monitoring of aerosol chemical species from space-borne observations, providing observationally-based results with spatial and temporal coverage. Following the ideas of Schuster et al.(2005, 2009, 2016), we retrieve chemical composition directly from satellite observations without intermediate retrieval of the refractive index (in contrast with Schuster's approach). This approach is expected to reduce the influence of modeling uncertainties, and to provide additional constraints in situations where remote sensing observations do not have enough spectral sensitivity to refractive index. One of principal difficulties is the identification of an adequate model for linking refractive index to chemical composition. Therefore, the initial effort of this work has focused on identifying an optimal physico-chemistry to refractive index conversion model. With that purpose, we first tested the retrieval approach using a simplified volume-weighting model and updated by the Maxwell Garnett mixing model. This concept was incorporated into the GRASP algorithm designed to retrieve an extended set of atmospheric parameters from remote sensing observations. Then a series of sensitivity tests using synthetic data of POLDER/PARASOL were conducted, and followed by inversion of real PARASOL observations over Africa. The sensitivity tests showed that these two models allow the retrieval to distinguish amongst the assumed chemical species. Results obtained from real PARASOL data demonstrated good agreement with the optical characteristics provided by AERONET. In addition, the obtained patterns of chemical component distribution agreed with known physical expectations. We also compared the chemical composition retrievals to GOCART model simulations and obtained good consistencies.

Lei Li↗

Enhanced crop discrimination using the mid-IR (1.55-1.75 microns)

Improvements in crop discrimination can be realized by using mid-IR bands (1.55 -1.75 and 2.08 -2.35 microns) which are sensitive to canopy moisture content. Analyses of data from two growing seasons in Webster County, Iowa clearly indicate that corn and soybeans are highly separable in the mid-IR from early season through harvest. This contrasts sharply with visible and near-IR bands where corn and soybeans are confused throughout much of the growing season. The mid-IR temporal reflectance behavior appears to result from differences between C4 monocot and C3 dicot internal leaf structure. If this hypothesis holds, mid-IR observations should improve discrimination in other instances where similar differences in internal leaf structure are present.

Ungar, S. G.↗

Normalization of multidirectional red and NIR reflectances with the SAVI

Directional reflectance measurements were made over a semi-desert gramma grassland at various times of the growing season. View angle measurements from +40 to -40 degrees were made at various solar zenith angles and soil moisture conditions. The sensitivity of the Normalized Difference Vegetation Index (NDVI) and the Soil Adjusted Vegetation Index (SAVI) to bidirectional measurements was assessed for purposes of improving remote temporal monitoring of vegetation dynamics. The SAVI view angle response was found to be symmetric about nadir while the NDVI response was strongly anisotropic. This enabled the view angle behavior of the SAVI to be normalized with a cosine function. In contrast to the NDVI, the SAVI was able to minimize soil moisture and shadow influences for all measurement conditions.

Huete, A. R.↗

On sound generation by turbulent convection: A new look at old results

We have revisited the problem of acoustic wave generation by turbulent convection in stellar atmospheres. The theory of aerodynamically generated sound, originally developed by Lighthill and later modified by Stein to include the effects of stratification, has been used to estimate the acoustic wave energy flux generated in solar and stellar convection zones. We correct the earlier computations by incorporating an improved description of the spatial and temporal spectrum of the turbulent convection. We show the dependence of the resulting wave fluxes on the nature of the turbulence, and compute the wave energy spectra and wave energy fluxes generated in the Sun on the basis of a mixing-length model of the solar convection zone. In contrast to the previous results, we show that the acoustic energy generation does not depend very sensitively on the turbulent energy spectrum. However, typical total acoustic fluxes of order F(sub A) = 5 x 10(exp 7) ergs/sq cm/s with a peak of the acoustic frequency spectrum near omega = 100 mHz are found to be comparable to those previously calculated. The acoustic flux turns out to be strongly dependent on the solar model, scaling with the mixing-length parameter alpha as alpha(exp 3.8). The computed fluxes most likely constitute a lower limit on the acoustic energy produced in the solar convection zone if recent convection simulations suggesting the presence of shocks near the upper layers of the convection zone apply to the Sun.

Musielak, Z. E.↗

Exoplanet Yield Sensitivity for the Hybrid Lyot Coronagraph from end-to-end modeling for LUVOIR-A

NASA's future direct imaging flagship mission will require telescope mirror segmentation to survey a statistically significant population of nearby stellar systems by increasing aperture size beyond that achieved by traditional space-borne monolithic apertures thus far. Segmentation is a path for the size expansion, but it entails a challenge due to the introduction of temporal pupil discontinuities in terms of both phase and amplitude. Modeling of the integrated performance of the coronagraph with the expected dynamical profile of the telescope is an important step toward realistic estimates of the mission's science yields. We present results of a study using the hybrid Lyot coronagraph with a 15-m on-axis, segmented optical telescope assembly (OTA), akin to that of the Large UV / Optical /Infrared (LUVOIR) mission. We have developed a high-fidelity, end-to-end model as part of the Segmented Coronagraph Design and Analysis (SCDA) study that includes diffractive optical propagations at the 1e-10 contrast level across the optical train including the OTA and intermediate re-imaging optics inside the coronagraph instrument. We perform a sensitivity analysis to assess the contrast sensitivity to wavefront perturbations for a set of key telescope terms including segment-level low-order and mid-spatial frequency aberrations and evaluate expected exoplanet yields obtained in the presence of these sets of aberrations. Industry-provided segment-level wavefront aberration datasets involving the following mechanisms are input to the end-to-end model: (1) thermal gradients and accelerations, and (2) telescope dynamics including line-of-sight and segment jitter. Dynamically averaged PSFs in the presence of aberrations are fed into AYO (Altruistic Yield Optimization), a mission design reference simulator, that then assesses the scientific yield sensitivities.

high-contrast imaging↗

Recent Amplified Global Gross Primary Productivity Due to Temperature Increase is Offset by Reduced Productivity Due to Water Constraints

Satellite remote sensing observationsshow an increased greenness trend over land in recent decades. Whilegreennessobservationscanindicateincreased productivity, estimation of total annual productivity is highly dependent on vegetation response to climate and environmental conditions. Models have been struggling to determinehow much carbon is taken up by plants as a result of increased atmospheric CO2fertilization. Current remote sensing light use efficiency (LUE) models contain considerable uncertainty due to the lack of spatial and temporal variability in maximum LUE parameter and climate sensitivity defined for global plantfunctional types (PFTs). We usedthe optimum LUE (LUEopt) previously derived fromtheglobal FLUXNET network to improve estimation of global gross primary productivity (GPP)for the period 1982–2016. Our results indicateincreasing GPP in northern latitudesowing to reduced cold temperature constraintson plant growth, thereby suggesting increasing negative carbon-climate feedbackin high latitudes. In the tropics, by contrast, our results indicate an emerging positive climate feedback,mainly due to increasing atmospheric vapor pressure deficit(VPD).Further pervasive VPD increase is likely to continue to reduce global GPPand amplify carbon emissions.

Climate change↗

Contrasting Carbon–Water–Energy Dynamics in Perennial and Annual Bioenergy Agroecosystems Using Eddy Covariance and Interpretable Machine Learning

Understanding how agroecosystems respond to environmental variability is fundamental to predicting productivity and sustainability under a changing climate. We analyzed 55 site-years of high-frequency eddy covariance observations from five agroecosystems—two perennial grasses (miscanthus and switchgrass), two annual rotation systems (maize–soybean and sorghum–soybean), and a restored native prairie—to examine ecosystem-scale carbon, water, and energy fluxes. Using an interpretable machine-learning framework with regression tree ensembles, Shapley Additive Explanations, and Accumulated Local Effects, we quantified how environmental and temporal factors regulate gross primary productivity (GPP), evapotranspiration (ET), water-use efficiency, and the Bowen ratio. Perennials exhibited stronger physiological buffering and maintained fluxes across a broader range of temperature and moisture conditions, reflecting deeper rooting and persistent canopy cover. Annuals, in contrast, showed greater short-term variability and stronger coupling to atmospheric demand, with GPP and ET declining rapidly under low humidity or soil moisture. Differences in temperature sensitivity of Bowen ratio further revealed that perennials sustained proportionally greater sensible heat flux under cool conditions, whereas annuals exhibited constrained energy exchange when evaporative demand was low. Together, these results demonstrate that crop life cycle and canopy structure are fundamental determinants of ecosystem-scale carbon–water–energy coupling. By integrating long-term flux observations with interpretable machine learning, this study identifies the environmental drivers that shape agroecosystem function and highlights how conversion from annual to perennial feedstocks can enhance climatic resilience and alter land–atmosphere energy feedbacks. These findings provide a data-driven basis for improving crop and Earth-system models and for guiding bioenergy landscape design under future climate scenarios.

Accumulated Local Effects↗

Noise Analysis of Spatial Phase coding in analog Acoustooptic Processors

Optical beams can carry information in their amplitude and phase; however, optical analog numerical calculators such as an optical matrix processor use incoherent light to achieve linear operation. Thus, the phase information is lost and only the magnitude can be used. This limits such processors to the representation of positive real numbers. Many systems have been devised to overcome this deficit through the use of digital number representations, but they all operate at a greatly reduced efficiency in contrast to analog systems. The most widely accepted method to achieve sign coding in analog optical systems has been the use of an offset for the zero level. Unfortunately, this results in increased noise sensitivity for small numbers. In this paper, we examine the use of spatially coherent sign coding in acoustooptical processors, a method first developed for digital calculations by D. V. Tigin. This coding technique uses spatial coherence for the representation of signed numbers, while temporal incoherence allows for linear analog processing of the optical information. We show how spatial phase coding reduces noise sensitivity for signed analog calculations.

Gary, Charles K.↗

Broadband Photoconductive Sampling in Gallium Phosphide

Abstract Direct measurements of the electric field of light enable new observations of light–matter interactions. In the near‐infrared and visible spectral ranges, this typically relies on techniques that exploit nonlinearities in gases or solids, which limits their sensitivity. Here, a method for the detection of broadband near‐infrared fields spanning more than one octave from 110 to 220 THz based on linear absorption in a semiconductor is demonstrated. This technique, which avoids complex vacuum setups and works under ambient conditions, employs linear photoconductive sampling (LPS) in gallium phosphide. Simulations reveal that the response function of LPS is concerned with the intensity envelope of the gate field, in contrast to electro‐optic sampling, relaxing the stringent temporal requirements on the gate pulse.

36 MATERIALS SCIENCE↗

Excitonic density wave and spin-valley superfluid in bilayer transition metal dichalcogenide

Artificial moiré superlattices in 2 d van der Waals heterostructures are a new venue for realizing and controlling correlated electronic phenomena. Recently, twisted bilayer WSe 2 emerged as a new robust moiré system hosting a correlated insulator at moiré half-filling over a range of twist angle. In this work, we present a theory of this insulating state as an excitonic density wave due to intervalley electron–hole pairing. We show that exciton condensation is strongly enhanced by a van Hove singularity near the Fermi level. Our theory explains the remarkable sensitivity of the insulating gap to the vertical electric field. In contrast, the gap is weakly reduced by a perpendicular magnetic field, with quadratic dependence at low field. The different responses to electric and magnetic field can be understood in terms of pair-breaking versus non-pair-breaking effects in a BCS analog of the system. We further predict superfluid spin transport in this electrical insulator, which can be detected by optical spin injection and spatial-temporal imaging.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Portable Unit for Metabolic Analysis

The Portable Unit for Metabolic Analysis (PUMA) is an instrument that measures several quantities indicative of human metabolic function. Specifically, this instrument makes time-resolved measurements of temperature, pressure, flow, and the partial pressures of oxygen and carbon dioxide in breath during both inhalation and exhalation. Portable instruments for measuring these quantities have been commercially available, but the response times of those instruments are too long to enable temporal resolution of phenomena on the time scales of human respiration cycles. In contrast, the response time of the PUMA is significantly shorter than characteristic times of human respiration phenomena, making it possible to analyze varying metabolic parameters, not only on sequential breath cycles but also at successive phases of inhalation and exhalation within the same breath cycle. In operation, the PUMA is positioned to sample breath near the subject s mouth. Commercial off-the-shelf sensors are used for three of the measurements: a miniature pressure transducer for pressure, a thermistor for temperature, and an ultrasonic sensor for flow. Sensors developed at Glenn Research Center are used for measuring the partial pressures of oxygen and carbon dioxide: The carbon dioxide sensor exploits the relatively strong absorption of infrared light by carbon dioxide. Light from an infrared source passes through the stream of inhaled or exhaled gas and is focused on an infrared- sensitive photodetector. The oxygen sensor exploits the effect of oxygen in quenching the fluorescence of ruthenium-doped organic molecules in a dye on the tip of an optical fiber. A blue laser diode is used to excite the fluorescence, and the optical fiber carries the fluorescent light to a photodiode, the temporal variation of the output of which bears a known relationship with the rate of quenching of fluorescence and, hence, with the partial pressure of oxygen. The outputs of the sensors are digitized, preprocessed by a small onboard computer, and then sent wirelessly to a desktop computer, where the collected data are analyzed and displayed. In addition to the raw data on temperature, pressure, flow, and mole fractions of oxygen and carbon dioxide, the display can include volumetric oxygen consumption, volumetric carbon dioxide production, respiratory equivalent ratio, and volumetric flow rate of exhaled gas.

Dietrich, Daniel L.↗

Performance Comparison of Machine Learning Models for Ultrasonic Nondestructive Evaluation of Alkali-Silica Reaction in Concrete

Alkali-silica reaction (ASR) causes concrete degradation, leading to cracking, rebar corrosion, and reduced structural integrity, which raises safety concerns. Ultrasonic nondestructive evaluation (NDE) effectively assesses concrete properties and monitors ASR progression. However, its deployment and analysis require specialized expertise and subjective interpretation. As computational power increases, artificial intelligence (AI) and machine learning (ML) algorithms are increasingly being used to automate NDE data analysis across various industries for AI-assisted automation. Regulatory agencies are adapting to this technological shift, prompting a need to evaluate current ML technologies’ capabilities and limitations in assessing concrete material properties and damage. This report presents a comparative analysis of four ML regression models for predicting concrete material damage induced by ASR expansion using long-term ultrasonic data monitoring. The models investigated include linear regression (LR), support vector regression (SVR), shallow neural networks (NN), and deep neural networks (DNN). LR, SVR, and shallow NN models use features extracted from ultrasonic signals, whereas the DNN model processes time-domain ultrasonic signals and frequency spectra directly. The study systematically compared the models’ performance from various perspectives, including model input, prediction performance, and generalization ability. The findings indicate significant variability in model performance, with some ML algorithms achieving very high or very low prediction accuracy depending on the preprocessing and feature engineering (extraction and selection) applied. Key insights include the observation that shallow ML models (LR, SVR, and shallow NNs) require meticulous preprocessing and feature extraction to achieve high accuracy. In contrast, the DNN model, although it bypasses the need for feature engineering, necessitates extensive preprocessing to mitigate noise and computational demands. The SVR model emerged as the top performer among the shallow models, and the DNN model exhibited superior performance on specific datasets but struggled with generalization across specimens from different batches. Additionally, the SVR model is sensitive to temperature variations, whereas the DNN model is robust in this regard. Using recurrent neural networks is recommended for future ASR expansion prediction studies. Recurrent neural networks’ inherent ability to capture temporal dependencies and long-term patterns makes them well suited for analyzing sequential ultrasonic monitoring data. Overall, the results and conclusions of this study could provide insights into the capabilities and effectiveness of ML when applied to ultrasonic NDE data and help identify best practices for using ML for ultrasonic NDE of concrete material properties.

36 MATERIALS SCIENCE↗

Distinct microbiomes underlie divergent responses of methane emissions from diverse wetland soils to oxygen shifts

Abstract Hydrological shifts in wetlands, a globally important methane (CH4) source, are critical constraints on CH4 emissions and carbon-climate feedbacks. A limited understanding of how hydrologically driven oxygen (O2) variability affects microbial CH4 cycling in diverse wetlands makes wetland CH4 emissions uncertain. Transient O2 exposure significantly stimulated anoxic CH4 production in incubations of Sphagnum peat from a temperate bog by enriching for polyphenol oxidizers and polysaccharide degraders, enhancing substrate flow toward methanogenesis under subsequent anoxic conditions. To assess whether shifts in soil microbiome structure and function operate similarly across wetland types, here we examined the sensitivity of different wetland soils to transient oxygenation. In slurry incubations of Sphagnum peat from a minerotrophic fen, and sediments from a freshwater marsh and saltmarsh, we examined temporal shifts in microbiomes coupled with geochemical characterization of slurries and incubation headspaces. Oxygenation did not affect microbiome structure and anoxic CH4 production in mineral-rich fen-origin peat and freshwater marsh soils. Key taxa linked to O2-stimulated CH4 production in the bog-origin peat were notably rare in the fen-origin peat, supporting microbiome structure as a primary determinant of wetland response to O2 shifts. In contrast to freshwater wetland experiments, saltmarsh geochemistry—particularly pH—and microbiome structure were persistently and significantly altered postoxygenation, albeit with no significant impact on greenhouse gas emissions. These divergent responses suggest wetlands may be differentially resistant to O2 fluctuations. With climate change driving greater O2 variability in wetlands, our results inform mechanisms of wetland resistance and highlight microbiome structure as a potential resiliency biomarker.

Reji, Linta (ORCID:0000000213376782)↗

Real-Time Monitoring of Strain Accumulation and Relief during Epitaxy of Ultrathin Co Ferrite Films with Varied Co Content

Ultrathin Co x Fe 3-x O 4 films of high structural quality and with different Co content (x = 0.6–1.2) were prepared by reactive molecular beam epitaxy on MgO(001) substrates. Epitaxy of these ferrite films is extensively monitored by means of time-resolved (operando) X-ray diffraction recorded in out-of-plane geometry to characterize the temporal evolution of the film structure. The Co ferrite films show high crystalline ordering and smooth film interfaces independent of their Co content. All Co x Fe 3-x O 4 films exhibit enhanced compressive out-of-plane strain during the early stages of growth, which partly releases with increasing film thickness. When the Co content of the ferrite films increases, the vertical-layer distances increase, accompanied by slightly increasing film roughnesses. The latter result is supported by surface-sensitive low-energy electron diffraction as well as X-ray reflectivity measurements on the final films. In contrast, the substrate–film interface roughness decreases with increasing Co content, which is confirmed with X-ray reflectivity measurements. In addition, the composition and electronic structure of the ferrite films is characterized by means of hard X-ray photoelectron spectroscopy performed after film growth. The experiments reveal the expected increasing Fe 3+ /Fe 2+ cation ratios for a higher Co content.

36 MATERIALS SCIENCE↗

Invited article: X-ray phase contrast imaging in inertial confinement fusion and high energy density research

X-ray phase contrast imaging (XPCI) provides enhanced image contrast beyond absorption-based x-ray imaging alone due to refraction and diffraction from gradients in the object material density. It is sensitive to small variations in density, such as internal voids, cracks, grains, defects, and material flow, as well as to stronger density variations such as from a shock wave. Beyond its initial use in biology and materials science, XPCI is now routinely used in inertial confinement fusion (ICF) and high energy density (HED) research, first to characterize ICF capsules and targets, and later applied in dynamic experiments, where coherent x-ray sources, ultrafast x-ray pulses, and high temporal and spatial resolution are required. In this Review article, XPCI image formation theory is presented, its diverse use in ICF and HED research is discussed, the unique requirements for ultrafast XPCI imaging are given, as well as current challenges and issues in its use.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Strainmeters and tiltmeters in geophysics

Several types of sensitive strainmeters and tiltmeters have been developed, and it is now becoming clear which geophysical applications are most suitable for these instruments. In general, strainmeters and tiltmeters are used for observing ground deformation at periods of minutes to days. Small-scale lateral inhomogeneities at the instrument sites distort signals by a few percent, although the effects of large structures can be calculated. In earth tide work these lateral inhomogeneities and unknown ocean loading signals prevent accurate values of the regional tide from being obtained. This limits tidal investigations to looking for temporal variations, possibly associated with pre-earthquake dilatancy, and spatial variations caused by gross elasticity contrasts in the local geological structure. Strainmeters and tiltmeters are well suited for observing long-period seismic waves, seismic slip events on faults and volcano tumescence, where small site-induced distortions in the measured signals are seldom important.

Goulty, N. R.↗

Optimizing Sub-Sampled STEM Imaging for Beam Sensitive Materials and Dynamic Processes

The goal of this research is to quantify how sub-sampling and inpainting (broadly classified as methods in Artificial Intelligence) can be used to obtain the highest resolution images under any experimental conditions, and to use this to reproducibly control dynamic in-situ processes in gases and liquids on the nanoscale. As atomic diffusion under non-extreme conditions is typically in the sub-ms time domain, the ability to use this sub-sampling approach to reduce the effect of the electron beam and to speed-up the imaging process represents the optimum combination of spatial and temporal resolution achievable in a conventional microscope. This LDRD funding demonstrated the feasibility of imaging dynamics in complex energy systems using this methodology by establishing the optimum experimental sampling conditions (optimizing the number of pixels, speed, contrast and resolution) for each experiment. For in-situ liquid cell experiments this analysis shows that simply by distributing the same dose and dose rate maximally in space and time, the kinetics for radiolysis products can be modified significantly. The final stage of this work, i.e. the experimental demonstration of its use for nucleation and growth, was severely curtailed by issues with COVID19. However, all the experiments are designed and currently underway, with the goal to complete the final demonstration and publication as soon as safety concerns for laboratory access are met.

36 MATERIALS SCIENCE↗

A measurement of stratospheric HO2 by ground-based millimeter-wave spectroscopy

Stratospheric perhydroxyl (HO2) was measured by using a sensitive mm-wave receiver to obtain spectroscopic line profiles of three rotational emission lines in the vicinity of 265.8 GHz. The observations were carried out over four days in September-October 1982 at Mauna Kea, Hawaii and yield good agreement with the column density and vertical distribution predicted above 35 km by three representative two-dimensional photochemical models employing JPL 82-57 reaction rates and chemistry. Contrasts between current theoretical predictions and previous observations by Anderson et al. (1981) are pointed out for HO2 in the 28 to 37-km range, along with the difficulty of joining the latter with the present measurements through a monotonically varying vertical profile for HO2. A possible explanation involving strong temporal and spatial variation in stratospheric water vapor content is suggested.

De Zafra, R. L.↗