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Thermal efficiency of gas turbine engine increases as the temperature and pressure at the combustor increases. Consequently, the materials used inside a combustor must survive an increasingly challenging environment. For this reason, accurate assessment of heat transfer is crucial for combustor design. While all three modes of heat transfer are present inside a combustor, the focus of this paper is the thermal radiation. Radiative heat transfer in a gas turbine combustors are particularly interesting from three reasons. Firstly, the radiative heat loss from the combustion region may affect the emission performance. Secondly, the cooling air will protect the liner from convection but not necessary from radiation. Finally, it is less frequently incorporated in CFD analysis than other forms of heat transfer. In this work, radiative heat transfer using discrete ordinate method has been incorporated in OpenNCC (a publicly releasable version of the National Combustion Code) developed at NASA Glenn Research Center. Aside from massively parallel computation capability using MPI and the ability to utilize unstructured mesh, the current implementation includes two types of spectral models, namely, the weighted some of gray gas model and the full spectrum correlated k-distribution model. After presenting the theory and the strategy of implementation, results of validation cases for gray gas and spectral models will be presented. While the implementation of the radiation solver is intended for gas turbine application, the radiation solver can run independently from the convection/combustion solver and the same theory can be applied to other application.