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Results for “thermodynamic equilibrium”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3
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NASA NTRS1989

Line blanketing without local thermodynamic equilibrium. II - A solar-type model in radiative equilibrium

A statistical solution for the problem of non-LTE radiative transfer in the millions of atomic transitions responsible for line blanketing is proposed which takes into account the influence of scattering on the atomic populations. A multifrequency/multigray algorithm is used to analyze the thermal equilibrium. Although CO is shown to cool the upper atmosphere to a boundary temperature of 2640 K, the molecule has little influence in the region of the solar temperature minimum.

Anderson, Lawrence S.↗
NASA NTRS1990

CH4 nonlocal thermodynamic equilibrium in the atmospheres of the giant planets

The present consideration of methane's vibrational relaxation in the Giant Planets' upper stratospheres employs a model for the thermalization of solar energy absorbed under non-LTE conditions, at the 1.7, 2.3. and 3.3 micron-centered CH4 band groups. On this basis, a range of model atmospheres was produced, reflecting current uncertainties concerning CH4 collisional excitation rates. At 0.1 mbar, all of the non-LTE models are within 2 K of the LTE reference models; the extreme non-LTE models steadily depart from reference LTE ones, however, and reach about + or - 20 K at 0,1 mbar.

Appleby, John F.↗
NASA NTRS1991

Nonlocal thermodynamic equilibrium processes in ozone - Implications for the energy budget of the mesosphere and lower thermosphere

The conversion of chemical potential energy and infrared radiative energy to kinetic energy by non-LTE processes involving ozone is a potentially significant source of heat in the terrestrial upper mesosphere and lower thermosphere. Heating rates are calculated and compared using two different statistical equilibrium models previously applied in the analysis of measurements of limb emission from ozone. The calculated heating depends strongly on the assumed distribution and relaxation of energy in the quasi-nascent ozone molecule. Finally, in the absence of a detailed data base of rate coefficients it may be possible to estimate the heating rate due to non-LTE processes in ozone from appropriate satellite measurements of the ozone concentration and of the infrared emission from ozone in the 9-12 micron spectral interval.

Milynczak, Martin G.↗
NASA NTRS1991

A non-local thermodynamic equilibrium, line-blanketed synthetic spectrum of Iota Herculis - C, Al, and Si lines

A non-LTE line-blanketed model stellar atmosphere is used to compute a model of I Herculis (B3 IV) with a Teff of 17,500 K and a log g of 3.75, following the conclusions of Peters and Polidan (1985). Detailed profiles of a number of lines of C, Al, and Si in the 1200-2000-A region are computed, including the resonance lines of C II, Al II, and Al III. These profiles are compared to observations obtained from the coaddition of eight IUE SWP images, using a technique developed by Leckrone and Adelman (1989). Comparison of carbon lines with a model that is underabundant in carbon by a factor of 2 relative to the sun indicates that the C abundance of Iota Her is at most one-half solar. Non-LTE effects are examined by comparing an LTE model possessing identical atmospheric parameters with the non-LTE model. Substantial differences in the populations of the model atomic states are found, but differences in the temperature structure of the two models often mask the non-LTE effects in the synthetic spectra.

Grigsby, James A.↗
NASA NTRS1993

Nonlocal thermodynamic equilibrium effects of vibrationally excited NO

Results are presented of a laboratory investigation of the vibrational distribution of NO produced in the reaction between O(3P) and NO2(X 2A1). To minimize vibrational quenching, the experiments were performed in a fast-flow system. The production of NO(X) radicals was monitored with laser-induced fluorescence. It was found that the NO vibrational population ratio measured correlates well with the earlier observation of high vibrational excitation in O2.

Moralejo, C.↗
NASA NTRS1985

Equilibrium thermodynamics and stochastic nonlinear acoustic fields

A crystalline solid is considered to consist of a large number of incoherent nonlinear acoustic radiation sources identified with the vibrating particles of the crystalline lattice. Randomization of the field, together with the assumption of a stochastically independent, fluctuating, radiation field at the absolue zero of temperature, leads to an expression of the temperature-dependent radiation field in terms of the zero-point field. The equation is identified with the Planck distribution formula of quantum mechanics in the linear field limit. The thermodynamic state functions are also obtained in terms of the nonlinear acoustic modal energies per unit mass and reduce to the results of the Debye-Einstein stochastic quantum oscillator model in the linear field limit.

Cantrell, J. H.↗
NASA NTRS1995

The stability of amino acids at submarine hydrothermal vent temperatures

It has been postulated that amino acid stability at hydrothermal vent temperatures is controlled by a metastable thermodynamic equilibrium rather than by kinetics. Experiments reported here demonstrate that the amino acids are irreversibly destroyed by heating at 240 C and that quasi-equilibrium calculations give misleading descriptions of the experimental observations. Equilibrium thermodynamic calculations are not applicable to organic compounds under high-temperature submarine vent conditions.

Bada, Jeffrey L.↗
NASA NTRS1981

Thermodynamic equilibrium-air correlations for flowfield applications

Equilibrium-air thermodynamic correlations have been developed for flowfield calculation procedures. A comparison between the postshock results computed by the correlation equations and detailed chemistry calculations is very good. The thermodynamic correlations are incorporated in an approximate inviscid flowfield code with a convective heating capability for the purpose of defining the thermodynamic environment through the shock layer. Comparisons of heating rates computed by the approximate code and a viscous-shock-layer method are good. In addition to presenting the thermodynamic correlations, the impact of several viscosity models on the convective heat transfer is demonstrated.

Zoby, E. V.↗
NASA NTRS1990

Equilibrium Statistical Thermodynamics of a Many-Particle System Coupled to an External Scalar Field

The equilibrium thermodynamics of a many-particle assembly in the presence of an external scalar field is examined. Two types of scalar coupling are considered: an external field coupled to the particle density and an external scalar field coupled to the energy density. It is shown that the broken translational and rotational invariance of the system due to the external field is reflected in the macroscopic physics by loss of the usual extensivity property of the system and by means of anisotropy in the response of the system to changes in the system lengths or to the system shape. In addition, the assumptions used in local equilibrium analyses are shown to be incorrect in principle. Nonlocal effects due to the external field must be included in the determination of the equation of state. Simple model calculations for a system in an external gravitational field and an externally imposed temperature field are presented as illustrations.

Salvino, R. E.↗
NASA NTRS1982

Model atmospheres, predicted spectra, and colors

Theoretical models of stellar atmospheres and the process of forming a spectrum are reviewed with particular reference to the spectra of B stars. In the case of classical models the stellar atmosphere is though to consist of plane parallel layers of gas in which radiative and hydrostatic equilibrium exists. No radiative energy is lost or gained in the model atmosphere, but the detailed shape of the spectrum is changed as a result of the interactions with the ionized gas. Predicted line spectra using statistical equilibrium local thermodynamic equilibrium (LTE), and non-LTE physics are compared and the determination of abundances is discussed. The limitations of classical modeling are examined. Models developed to demonstrate what motions in the upper atmosphere will do to the spectrum and to explore the effects of using geometries different from plane parallel layer are reviewed. In particular the problem of radiative transfer is addressed.

Source record↗
NASA NTRS1992

The role of sea ice dynamics in global climate change

The topics covered include the following: general characteristics of sea ice drift; sea ice rheology; ice thickness distribution; sea ice thermodynamic models; equilibrium thermodynamic models; effect of internal brine pockets and snow cover; model simulations of Arctic Sea ice; and sensitivity of sea ice models to climate change.

Hibler, William D., III↗
NASA NTRS1992

Evolution of a terrestrial magma ocean: Thermodynamics, kinetics, rheology, convection, differentiation

The evolution of an initially totally molten magma ocean is constrained on the basis of analysis of various physical problems in the magma ocean. First of all an equilibrium thermodynamics of the magma ocean is developed in the melting temperature range. The equilibrium thermodynamical parameters are found as functions only of temperature and pressure and are used in the subsequent models of kinetics and convection. Kinematic processes determine the crystal size and also determine a non-equilibrium thermodynamics of the system. Rheology controls all dynamical regimes of the magma ocean. The thermal convection models for different rheological laws are developed for both the laminar convection and for turbulent convection in the case of equilibrium thermodynamics of the multiphase system. The evolution is estimated on the basis of all the above analysis.

Solomatov, V. S.↗
NASA NTRS1983

Speculative-theoretical Modeling of the Atmosphere Enveloping a Hypothetical (closed, Thermal) Star

The predictions of theoretical stellar atmospheric structural modeling and the theoretical picture of the local stellar environment as derived from the speculation that stars are (closed, thermal) thermodynamic systems, are summarized. The definition and representation of space- and state-fluxes is discussed and both classical (local thermodynamic equilibrium) and neoclassical (non-local thermodynamic equilibrium) thermal models are addressed.

Source record↗
NASA NTRS1988

Lightning production of hydrocarbons and HCN on Titan - Laboratory measurements

Experimental measurements have been obtained for the chemical yields of hydrogen cyanide, acetylene, ethylene, ethane, and propane from simulated lightning discharges, in order to ascertain whether lightning in the troposphere of Titan may be contributing to the hydrocarbon inventory. A comparison of these results with those obtained on the basis of thermodynamic equilibrium considerations shows substantial discrepancies and implies that thermodynamic equilibrium theories are inadequate. The production of ethylene by lightning and its subsequent stratospheric diffusion nevertheless appears to be one reasonable mechanism.

Borucki, W. J.↗
NASA NTRS1976

Solar astrophysics - Ghettosis from, or symbiosis with, stellar and galactic astrophysics

The purpose of the paper is to show how the solar-stellar symbiotic approach has led to the modeling of a star as a concentration of matter and energy. By 'solar-stellar symbiosis' is meant the philosophy of investigation according to which one asks what change in our general understanding of stellar structure and of stellar spectroscopic diagnostics is required to satisfy both the sun and an unusual star when, for example, some feature of an unusual star is discovered. The evolution of stellar models is traced, from walled, thermodynamic-equilibrium models to de-isolated models featuring transition zones and nonlocal thermodynamic equilibrium.

Pecker, J.-C.↗
NASA NTRS1993

The solar spectral irradiances from x ray to radio wavelengths

Sources of new measurements of the solar EUV, UV, and visible spectrum are presented together with discussion of formation of the solar spectrum as a problem in stellar atmospheres. Agreement between the data and a modern synthetic spectrum shows that observed radiative variability is a minor perturbation on a photosphere in radiative equilibrium and local thermodynamic equilibrium (LTE). Newly observed solar variability in 1992 defines a magnetic episode on the Sun closely associated with changes in both spectral irradiances and the total irradiance. This episode offers the opportunity to track the relationship between radiation and magnetic flux evolution.

White, O. R.↗