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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 55 records · Page 3

The stability analysis of magnetohydrodynamic equilibria - Comparing the thermodynamic approach with the energy principle

This paper is a contribution to the stability analysis of current-carrying plasmas, i.e., plasma systems that are forced by external mchanisms to carry a nonrelaxing electrical current. Under restriction to translationally invariant configurations, the thermodynamic stability criterion for a multicomponent plasma is rederived within the framework of nonideal MHD. The chosen dynamics neglects scalar resistivity, but allows for other types of dissipation effects both in Ohm's law and in the equation of motion. In the second section of the paper, the thermodynamic stability criterion is compared with the ideal MHD based energy principle of Bernstein et al. With the help of Schwarz's inequality, it is shown that the former criterion is always more 'pessimistic' than the latter, i.e., that thermodynamic stability implies stability according to the MHD principle, but not vice versa. This reuslt confirms the physical plausible idea that dissipational effects tend to weaken the stability properties of current-carrying plasma equilibria by breaking the constraints of ideal MHD and allowing for possibly destabilizing effects such as magnetic field line reconfiguration.

Brinkmann, R. P.↗

Thermodynamic analysis of chemical stability of ceramic materials in hydrogen-containing atmospheres at high temperatures

The chemical stability of several ceramic materials in hydrogen-containing environments was analyzed with thermodynamic considerations in mind. Equilibrium calculations were made as a function of temperature, moisture content, and total system pressure. The following ceramic materials were considered in this study: SiC, Si3N4, SiO2, Al2O3, mullite, ZrO2, Y2O3, CaO, MgO, BeO, TiB2, TiC, HfC, and ZrC. On the basis of purely thermodynamic arguments, upper temperature limits are suggested for each material for long-term use in H2-containing atmospheres.

Misra, Ajay K.↗

Aldehydes in hydrothermal solution - Standard partial molal thermodynamic properties and relative stabilities at high temperatures and pressures

Aldehydes are common in a variety of geologic environments and are derived from a number of sources, both natural and anthropogenic. Experimental data for aqueous aldehydes were taken from the literature and used, along with parameters for the revised Helgeson-Kirkham-Flowers (HKF) equations of state, to estimate standard partial molal thermodynamic data for aqueous straight-chain alkyl aldehydes at high temperatures and pressures. Examples of calculations involving aldehydes in geological environments are given, and the stability of aldehydes relative to carboxylic acids is evaluated. These calculations indicate that aldehydes may be intermediates in the formation of carboxylic acids from hydrocarbons in sedimentary basin brines and hydrothermal systems like they are in the atmosphere. The data and parameters summarized here allow evaluation of the role of aldehydes in the formation of prebiotic precursors, such as amino acids and hydroxy acids on the early Earth and in carbonaceous chondrite parent bodies.

Schulte, Mitchell D.↗

CS2 - Candidate for the 3150-A Venus band

The 3150-A absorption on Venus, found by Barker et al. (1975), may be due to carbon disulfide. The stability and thermodynamics of the carbon chalcogenides are briefly discussed.

Young, A. T.↗

Propellant Tanks for Tethered Orbital Refueling Facility

Thermodynamics, mechanical stability, and mass penalties affect design. Pair of reports presents design study for propellant tanks used in low gravity. Each tank, which most likely contains liquid H2 or O2, part of fuel depot tethered to station in orbit around Earth. Some engineering concepts in study applied to design of tanks for use on Earth in transport and storage of cryogenic liquids and other fluids requiring special handling.

Rudolph, L. Kevin↗

The X-43A Flight Research Program: Lessons Learned on the Road to Mach 10

During an aerospace engineer's undergraduate studies, he or she will attend classes in aerodynamics, thermodynamics, structures, stability and control, dynamics, design, propulsion, and computer science, along with the related courses in mathematics, physics, statistics, and chemistry required to understand the material. Upon graduation, the new engineer will have acquired a basic knowledge of how to build an aerospace vehicle. What only comes through experience, however, is the understanding of the inevitable imperfect process through which an aerospace vehicle is built. This is the adventure of turning a basic concept into functional hardware. Engineers working on a project must often deal with ambiguous situations. They are routinely asked by management to provide risk assessments of a project, yet even after careful analysis uncertainties remain. The project must be accomplished within finite limits of time and money. The question an engineer answers is whether the solution to potential problem is worth the cost and schedule delay, or if the solution might actually be worse than the problem it is meant to solve. Review protocols are established to ensure that an unknown has not been overlooked. But these cannot protect against an unknown unknown. Examples of these situations can be found in the history of the X-43A Hyper-X (Hypersonic Experiment) program. In this NASA project, a supersonic combustion ramjet (scramjet) engine was flight tested on a subscale vehicle. The X-43A Hyper-X Research Vehicle (HXRV) was launched from a B-52B mothership, then boosted to the test speed by a modified Pegasus rocket first stage, called the Hyper-X Launch Vehicle (HXLV). Once at the proper speed and altitude, the X-43A separated from the booster, stabilized itself, and then the engine test began. Although wind-tunnel scramjet engine tests had begun in the late 1950s, before the Hyper-X program there had never been an actual in-flight test of such an engine integrated with an appropriate airframe. Thus, while the scramjet had successfully operated in the artificial airflow of wind tunnels, the concept had yet to be proven in real air. These conditions meant changes in density and temperature, as well as changes in angle of attack and sideslip of a free-flying vehicle. A wind tunnel is limited in its ability to simulate these subtle factures, which have a major impact on almost any vehicle, but especially that of a scramjet's performance. The Hyper-X project was to provide a real-world benchmark of the ground test data. The full scale X-43A engine would be operated in the wind tunnel, and then flown, and the data from its operation would then be compared with projections. If these matched, the wind tunnel data would be considered a reliable design tool for future scramjet. If there were significant differences, the reasons for these would have to be identified. Until such information was available, scramjets would lack the technological maturity to be considered for future space launch or high-speed atmospheric flight vehicles.

Peebles, Curtis↗

Oxidation of ZrB2 SiC TaSi2 Materials at Ultra High Temperatures

ZrB2 - 20v% SiC - 20v% TaSi2 was oxidized in stagnant air for ten minute cycles for times up to 100 minutes at 1627 C and 1927 C. The sample oxidized at 1627 C showed oxidation resistance better than that of the standard ZrB2 - 20v% SiC. The sample oxidized at 1927 C, however, showed evidence of liquid phase formation and complex oxidation products. The sample exposed at 1927 C was analyzed in detail by scanning electron microprobe and wavelength dispersive spectroscopy to understand the complex oxidation and melting reactions occurring during exposure. The as hot-pressed material shows the formation of a Zr(Ta)B2 phase in addition to the three phases in the nominal composition already noted. After oxidation, the TaSi2 in the matrix was completely reacted to form Ta(Zr)C. The layered oxidation products included SiO2, ZrO2, Ta2O5, and a complex oxide containing both Zr and Ta. Likely reactions are proposed based on thermodynamic phase stability and phase morphology.

Opila, E.↗

Inviscid spatial stability of a compressible mixing layer. III - Effect of thermodynamics

The results of a comprehensive comparative study of the inviscid spatial stability of a parallel compressible mixing layer using various models for the mean flow are reported. The models are: (1) the hyperbolic tangent profile for the mean speed and the Crocco relation for the mean temperature, with the Chapman viscosity-temperature relation and a Prandtl number of one; (2) the Lock profile for the mean speed and the Crocco relation for the mean temperature, with the Chapman viscosity-temperature relation and a Prandtl number of one; and (3) the similarity solution for the coupled velocity and temperature equations using the Sutherland viscosity temperature relation and arbitrary but constant Prandtl number. The purpose was to determine the sensitivity of the stability characteristics of the compressible mixing layer to the assumed thermodynamic properties of the fluid. It is shown that the quantitative features of the stability characteristics are quite similar for all models but that there are quantitative differences resulting from the difference in the thermodynamic models. In particular, it is shown that the stability characteristics are sensitive to the value of the Prandtl number.

Jackson, T. L.↗

Inviscid spatial stability of a compressible mixing layer. Part 3: Effect of thermodynamics

The results of a comprehensive comparative study of the inviscid spatial stability of a parallel compressible mixing layer using various models for the mean flow are reported. The models are: (1) the hyperbolic tangent profile for the mean speed and the Crocco relation for the mean temperature, with the Chapman viscosity-temperature relation and a Prandtl number of one; (2) the Lock profile for the mean speed and the Crocco relation for the mean temperature, with the Chapman viscosity-temperature relation and a Prandtl number of one; and (3) the similarity solution for the coupled velocity and temperature equations using the Sutherland viscosity temperature relation and arbitrary but constant Prandtl number. The purpose was to determine the sensitivity of the stability characteristics of the compressible mixing layer to the assumed thermodynamic properties of the fluid. It is shown that the quantative features of the stability characteristics are quite similiar for all models but that there are quantitative differences resulting from the difference in the thermodynamic models. In particular, it is shown that the stability characteristics are sensitive to the value of the Prandtl number.

Jackson, T. L.↗

Salt modulates the stability and lipid binding affinity of the adipocyte lipid-binding proteins

Adipocyte lipid-binding protein (ALBP or aP2) is an intracellular fatty acid-binding protein that is found in adipocytes and macrophages and binds a large variety of intracellular lipids with high affinity. Although intracellular lipids are frequently charged, biochemical studies of lipid-binding proteins and their interactions often focus most heavily on the hydrophobic aspects of these proteins and their interactions. In this study, we have characterized the effects of KCl on the stability and lipid binding properties of ALBP. We find that added salt dramatically stabilizes ALBP, increasing its Delta G of unfolding by 3-5 kcal/mol. At 37 degrees C salt can more than double the stability of the protein. At the same time, salt inhibits the binding of the fluorescent lipid 1-anilinonaphthalene-8-sulfonate (ANS) to the protein and induces direct displacement of the lipid from the protein. Thermodynamic linkage analysis of the salt inhibition of ANS binding shows a nearly 1:1 reciprocal linkage: i.e. one ion is released from ALBP when ANS binds, and vice versa. Kinetic experiments show that salt reduces the rate of association between ANS and ALBP while simultaneously increasing the dissociation rate of ANS from the protein. We depict and discuss the thermodynamic linkages among stability, lipid binding, and salt effects for ALBP, including the use of these linkages to calculate the affinity of ANS for the denatured state of ALBP and its dependence on salt concentration. We also discuss the potential molecular origins and potential intracellular consequences of the demonstrated salt linkages to stability and lipid binding in ALBP.

NASA Discipline Cell Biology↗

Thermodynamic Cycle Analysis of Superadiabatic Matrix-Stabilized Combustion for Gas Turbine Engines

In aircraft propulsion as well as stationary power generation, gas turbine engines remain a key energy conversion technology due to their high thermal efficiencies and low emissions. However, as emission requirements become increasingly stringent, engine manufacturers have sought to design combustion systems that operate near the fuel-lean limit of flammability. In this study, superadiabatic matrix-stabilized combustion, also known as porous media combustion, is evaluated as an advanced combustion concept for extending the lean flammability limit to achieve improved efficiency and emissions. To this end, a Brayton cycle analysis is developed and key parameters of the porous matrix are identified for maximizing the extension of the lean flammability limit. It is shown that stabilization of combustion below the nominal lean flammability limit allows for the design of engines with significantly higher pressure ratios and lower dilution ratios without increasing turbine inlet temperatures, thus improving cycle thermal efficiency. Combustor flammability limits were shown to be extendable by up to 32% when employing matrix-stabilized combustion, resulting in thermal efficiency gains of up to 11% compared to a nominal design.

Superadiabatic combustion↗

Formation Mechanism of Iron-Rich Olivine: Experimental Constrains into Early Fluid-Assisted Hydration and Dehydration Processes on Asteroids

Iron-rich olivine is one of the major minerals in the matrices of unequilibrated ordinary (UOCs) and carbonaceous (CV, CK, CO) chondrites whose petrologic type is >3.1. There has been an extensive discussion in the literature as to the formation mechanism of these olivines; however, their origin is poorly understood. The formation of ferroan olivine during hydrothermal alteration has been demonstrated to be thermodynamically viable. The stability of ferroan olivine is highly dependent on several variables, including temperature, water/ rock (W/R) ratio, pressure, oxygen fugacity, and bulk rock composition. So far, hydrothermal alteration experiments have not been successful at forming FeO-rich olivines with the compositions and textures observed in the matrices of chondrites. Therefore, understanding the formation conditions of FeO-rich olivines remains a key problem to explain the effects of hydrothermal alteration on chondrite matrices.

Iron-rich olivine↗

A Thermodynamic Theory of Solid Viscoelasticity. Part 3: Nonlinear Glassy Viscoelasticity, Stability Constraints, Specifications

This paper, the last in the series, continues developing the nonlinear constitutive relations for non-isothermal, compressible, solid viscoelasticity. We initially discuss a single integral approach, more suitable for the glassy state of rubber-like materials, with basic functionals involved in the thermodynamic description for this type of viscoelasticity. Then we switch our attention to analyzing stability constraints, imposed on the general formulation of the nonlinear theory of solid viscoelasticity. Finally, we discuss specific (known from the literature or new) expressions for material functions that are involved in the constitutive formulations of both the rubber-like and glassy-like, complementary parts of the theory.

Freed, Alan↗

Can enstatite meteorites form from a nebula of solar composition

Doubts have been expressed as to whether solar matter is sufficiently reducing to explain the minerals occurring in the enstatite chondrites and in the enstatite achondrites. Thermodynamic calculations on the stabilities of TiN, Si2N2O, CaS and silicon-bearing iron metal show that these substances can form under equilibrium conditions from a nebula of solar composition provided that the total pressure exceeds about 1 atm and that thermodynamic equilibria are frozen in at near-formation temperatures.

Herndon, J. M.↗

Morphological instability in rapid directional solidification

Mullins and Sekerka (1964) showed for fixed temperature gradient that the planar interface is linearly stable for all pulling speeds V above some critical value, the absolute stability limit. Near this limit, where solidification rates are rapid, the assumption of local equilibrium at the interface may be violated. Here, nonequilibrium effects are incorporated into a linear stability analysis of the planar front by allowing the segregation coefficient and interface temperature to depend on V in a thermodynamically consistent way. The absolute stability limit of the cellular mode is modified. A new oscillatory state is formed which, in the absence of latent heat, has a critical wavenumber of zero; by itself this instability would lead to the formation of solute bands in the solid. This mode has its own absolute-stability limit determined by solute trapping and kinetics. Under certain conditions, there exists a window of stability above the steady absolute-stability boundary and below the oscillatory-stability boundary; here the planar segregation-free state is restabilized.

Merchant, G. J.↗