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Special analytical column having in series two separate absorption sections charged with beads of porous polymer and a sample of gas detects traces of hydrocarbons. New method requires only 15 minutes for execution.
Composition and daily fluctuations of trace contaminants during 90-day space station simulator test
The technology and methods developed at the Plum Brook Reactor to analyze 1000 samples per year and report data on as many as 56 elements are described. The manpower for the complete analysis of 20 to 24 samples per week required only 3 to 3.5 hours per sample. The solutions to problems encountered in sample preparation, irradiation, and counting are discussed. The automation of data reduction is described. Typical data on various sample matrices are presented.
Method has been developed in which measurements are made only over viscous flow range, eliminating fractionation before the molecular leak and problems due to surface elution.
Trace gases evolved from a polyimide film during its thermal curing stages have been studied using ion-induced nucleation mass spectrometry. The technique involved exposing the test gas sample to a low energy beta source and recording the masses of the ion-induced molecular clusters formed in the reaction chamber. On the basis of the experimentally observed molecular cluster spectra, it has been concluded that the dominant trace component had a molecular weight of 87 atomic mass units. This component has been identified as a molecule of dimethylacetamide (DMAC) which had been used as a solvent in the preparation of the test polyimide specimen. This identification has been further confirmed by comparing the spectra of the test gas sample and the DMAC calibration sample obtained with a conventional mass spectrometer. The advantages of the ion-induced nucleation mass spectrometer versus the conventional mass spectrometer are discussed.
A derivative spectrometer is sensitive to changes in spectral intensity over narrow wavelength internal. Specifically, a second derivative spectrometer senses the curvature of the incident spectral intensity, providing an output voltage signal proportional to the second derivative of intensity with respect to wavelength. When such an instrument is combined with multi-pass White cell, a unique trace gas analyzer results. The analyzer, operating within the middle ultraviolet spectral region, provides a highly amplified derivative spectrum of any molecular narrow band absorption which is used for trace gas identification. The intensity of any peak within a spectrum is proportional to the trace gas concentration. Such an analyzer, utilizing a 20 meter pathlength White cell, is presently being used to automatically monitor ambient air for SO2, NO, NO2, and O3 with minimum detectable concentration limits in the part per billion range.
Polycyclic Aromatic Hydrocarbons (PAHs) are of considerable interest today because they are ubiquitous on Earth and in the interstellar medium (ISM). In fact, about 20% of cosmic carbon in the galaxy is estimated to be in the form of PAHs. Investigation of these species has obvious uses for determining the cosmochemistry of the solar system. Work in this laboratory has focused on four main areas: 1) Mapping the spatial distribution of PAHs in a variety of meteoritic samples and comparing this distribution with mineralogical features of the meteorite to determine whether a correlation exists between the two. 2) Developing a method for detection of fullerenes in extraterrestrial samples using microprobe Laser Desorption Ionization Mass Spectroscopy and utilizing this technique to investigate fullerene presence, while exploring the possibility of spatially mapping the fullerene distribution in these samples through in situ detection. 3) Investigating a possible formation pathway for meteoritic and ancient terrestrial kerogen involving the photochemical reactions of PAHs with alkanes under prebiotic and astrophysically relevant conditions. 4) Studying reaction pathways and identifying the photoproducts generated during the photochemical evolution of PAH-containing interstellar ice analogs as part of an ongoing collaboration with researchers at the Astrochemistry Lab at NASA Ames. All areas involve elucidation of the solar system formation and chemistry using microprobe Laser Desorption Laser Ionization Mass Spectrometry. A brief description of microprobe Laser Desorption Ionization Mass Spectroscopy, which allows selective investigation of subattomole levels of organic species on the surface of a sample at 10-40 micrometer spatial resolution, is given.
The air quality of any manned spacecraft needs to be continuously monitored in order to safeguard the health of the crew. Air quality monitoring grows in importance as mission duration increases. Due to the small size, low power draw, and performance reliability, semiconductor laser-based instruments are viable candidates for this purpose. Achieving a minimum instrument size requires lasers with emission wavelength coinciding with the absorption of the fundamental absorption lines of the target gases, which are mostly in the 3.0-5.0 mu m wavelength range. In this paper we report on our progress developing high wall plug efficiency type-I quantum-well GaSb-based diode lasers operating at room temperatures in the spectral region near 3.0-3.5 mu m and quantum cascade (QC) lasers in the 4.0-5.0 mu m range. These lasers will enable the development of miniature, low-power laser spectrometers for environmental monitoring of the spacecraft
No abstract available
The air quality of any manned spacecraft needs to be continuously monitored in order to safeguard the health of the crew. Air quality monitoring grows in importance as mission duration increases. Due to the small size, low power draw, and performance reliability, semiconductor laser-based instruments are viable candidates for this purpose. Achieving a minimum instrument size requires lasers with emission wavelength coinciding with the absorption of the fundamental absorption lines of the target gases, which are mostly in the 3.0-5.0 micron wavelength range. In this paper we report on our progress developing high wall plug efficiency type-I quantum-well GaSb-based diode lasers operating at room temperatures in the spectral region near 3.0-3.5 micron and quantum cascade (QC) lasers in the 4.0-5.0 micron range. These lasers will enable the development of miniature, low-power laser spectrometers for environmental monitoring of the spacecraft.
No abstract available
The air quality of any manned spacecraft needs to be continuously monitored in order to safeguard the health of the crew. Air quality monitoring grows in importance as mission duration increases. Due to the small size, low power draw, and performance reliability, semiconductor laser-based instruments are viable candidates for this purpose. The minimum instrument size requires lasers with emission wavelength coinciding with the absorption of the fundamental frequency of the target gases which are mostly in the 3.0-5.0 micrometers wavelength range. In this paper we report on our progress developing high wall plug efficiency type-I quantum-well GaSb-based diode lasers operating at room temperatures in the spectral region near 3.0-3.5 micrometers and quantum cascade (QC) lasers in the 4.0-5.0 micrometers range. These lasers will enable the development of miniature, low-power laser spectrometers for environmental monitoring of the spacecraft.
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An example is presented of using a combined ray trace and diffraction modeling code to simulate effects of objective-lens tilt in an optical data storage device. In some cases, neither ray-trace analysis nor diffraction analysis can give an adequate description of an optical system. The designer that is faced with the problem of analyzing such a system is forced to use a ray-trace program to determine aberrations in the exit pupil and then introduce aberration coefficients into a diffraction model that simulate the propagation. This approach was found rather awkward, especially if complicated aberrations are present. Our approach is to integrate a diffraction analysis and a ray-trace description of an optical path into one program. Our design is taken from a data storage application, where we must analyze the effects of objective-lens tilt.
A ray tracing analysis has been performed for the spectral slicing zoom X-ray telescope for configurations in which a convex layered synthetic microstructure (LSM) optic is placed in front of the prime focus or a concave LSM optic is placed behind the prime focus. The analysis has considered the geometrical shape of the LSM optic to be either a hyperboloid, sphere, ellipsoid or constant optical path aspheric element for two configurations of the glancing incidence X-ray telescope: the ATM Experimental S-056 Wolter I system and the Stanford/MSFC Wolter-Schwarzchild nested system. For the different systems the RMS blur circle radii, the point spread function (PSF), the full width half maximum (FWHM) of the PSF have been evaluated as a function of field angle and magnification of the secondary to determine resolution of the system. The effects of decentration and tilt of the selected LSM element on the performance of the system have been studied to determine mounting and alignment tolerances.
This paper presents a coordinate-free ray-trace analysis of optical beam trains consisting of mirrors, lenses and reference surfaces. The analysis leads to optical models that can be directly integrated with standard structure and control models for integrated instrument design, analysis and simulation. This capability is required for a coming generation of spaceborn optical instruments which use controlled optical elements supported by flexible structures. New results include analytic formulas for optical sensitivities as functions of structural and control geometric parameters. An example problem calculates a linear (small-motion) optical model, derives optical gains for small- and large-angle controlled mirrors, and shows the propagation of a wavefront.