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Results for “unconventional oil resource”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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39 records · Page 3

Fundamental Understanding of Methane-Carbon Dioxide-Water (CH 4 -CO 2 - H 2 O) Interactions in Shale Nanopores under Reservoir Conditions (Quarterly Report)

Shale is characterized by the predominant presence of nanometer-scale (1-100 nm) pores. The behavior of fluids in those pores directly controls shale gas storage and release in shale matrix and ultimately the wellbore production in unconventional reservoirs. Recently, it has been recognized that a fluid confined in nanopores can behave dramatically differently from the corresponding bulk phase due to nanopore confinement. CO 2 and H 2 O, either preexisting or introduced, are two major components that coexist with shale gas (predominately CH 4 ) during hydrofracturing and gas extraction. Note that liquid or supercritical CO 2 has been suggested as an alternative fluid for subsurface fracturing such that CO 2 enhanced gas recovery can also serve as a CO 2 sequestration process. Limited data indicate that CO 2 may preferentially adsorb in nanopores (particularly those in kerogen) and therefore displace CH 4 in shale. Similarly, the presence of water moisture seems able to displace or trap CH 4 in shale matrix. Therefore, fundamental understanding of CH 4 -CO 2 -H 2 O behavior and their interactions in shale nanopores is of great importance for gas production and the related CO 2 sequestration. This project focuses on the systematic study of CH 4 -CO 2 -H 2 O interactions in shale nanopores under high-pressure and high temperature reservoir conditions. The proposed work will help develop new stimulation strategies to enable efficient resource recovery from fewer and less environmentally impactful wells.

04 OIL SHALES AND TAR SANDS↗

Aromatic amino acid metabolism and active transport regulation are implicated in microbial persistence in fractured shale reservoirs

Abstract Hydraulic fracturing has unlocked vast amounts of hydrocarbons trapped within unconventional shale formations. This large-scale engineering approach inadvertently introduces microorganisms into the hydrocarbon reservoir, allowing them to inhabit a new physical space and thrive in the unique biogeochemical resources present in the environment. Advancing our fundamental understanding of microbial growth and physiology in this extreme subsurface environment is critical to improving biofouling control efficacy and maximizing opportunities for beneficial natural resource exploitation. Here, we used metaproteomics and exometabolomics to investigate the biochemical mechanisms underpinning the adaptation of model bacterium Halanaerobium congolense WG10 and mixed microbial consortia enriched from shale-produced fluids to hypersalinity and very low reservoir flow rates (metabolic stress). We also queried the metabolic foundation for biofilm formation in this system, a major impediment to subsurface energy exploration. For the first time, we report that H. congolense WG10 accumulates tyrosine for osmoprotection, an indication of the flexible robustness of stress tolerance that enables its long-term persistence in fractured shale environments. We also identified aromatic amino acid synthesis and cell wall maintenance as critical to biofilm formation. Finally, regulation of transmembrane transport is key to metabolic stress adaptation in shale bacteria under very low well flow rates. These results provide unique insights that enable better management of hydraulically fractured shale systems, for more efficient and sustainable energy extraction.

04 OIL SHALES AND TAR SANDS↗

Laboratory and pilot-scale studies of membrane distillation for desalination of produced water from Permian Basin

Substantial quantities of produced water generated during the extraction of oil and gas from unconventional reservoirs present significant environmental concern and increase the operating cost for this industry. Membrane Distillation (MD) can serve as a potential solution for beneficial reuse of produced water by generating high-quality permeate and reducing the volume of produced water requiring disposal. This study investigated treatment of produced water from Permian Basin in both laboratory and pilot-scale studies. Laboratory tests revealed the potential to successfully recover 50% of produced water although some increase in permeate conductivity was observed due to the passage of ammonia from the feed side. Initial pilot-scale test with filtration of raw produced water as the only pre-treatment step led to precipitation of SrSO 4 , NaCl, and Fe in the system once the solubility limits for these salts were exceeded. However, chemical pretreatment that included pH adjustment, aeration, and barite precipitation, allowed successful steady-state operation of the AGMD pilot system for 5 days where the produced water was concentrated from 127 g/L to 255 g/L (~50% water recovery) while recovering high quality permeate. Overall, greater than 99.7 % salt rejection was achieved with the average permeate flux of 1.86 LMH. Finally, mass balance analysis suggested potential Ba and Ca precipitation in the system but there was no impact on AGMD performance and permeate quality during 5 days of continuous operation in the field.

42 ENGINEERING↗