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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1980

The effect of growth rate, diameter and impurity concentration on structure in Czochralski silicon crystal growth

It is demonstrated that maximum growth rates of up to 80% of the theoretical limit can be attained in Czochralski-grown silicon crystals while maintaining single crystal structure. Attaining the other 20% increase is dependent on design changes in the grower, to reduce the temperature gradient in the liquid while increasing the gradient in the solid. The conclusions of Hopkins et al. (1977) on the effect of diameter on the breakdown of structure at fast growth rates are substantiated. Copper was utilized as the test impurity. At large diameters (greater than 7.5 cm), concentrations of greater than 1 ppm copper were attained in the solid (45,000 ppm in the liquid) without breakdown at maximum growth speeds. For smaller diameter crystals, the sensitivity of impurities is much more apparent. For solar cell applications, impurities will limit cell performance before they cause crystal breakdown for fast growth rates of large diameter crystals.

Digges, T. G., Jr.↗

NASA NTRS1980

Photovoltaics as a terrestrial energy source. Volume 2: System value

Assumptions and techniques employed by the electric utility industry and other electricity planners to make estimates of the future value of photovoltaic (PV) systems interconnected with U.S. electric utilities were examined. Existing estimates of PV value and their interpretation and limitations are discussed. PV value is defined as the marginal private savings accruing to potential PV owners. For utility-owned PV systems, these values are shown to be the after-tax savings in conventional fuel and capacity displaced by the PV output. For non-utility-owned (distributed) systems, the utility's savings in fuel and capacity must first be translated through the electric rate structure (prices) to the potential PV system owner. Base-case estimates of the average value of PV systems to U.S. utilities are presented. The relationship of these results to the PV Program price goals and current energy policy is discussed; the usefulness of PV output quantity goals is also reviewed.

Smith, J. L.↗

DOE OSTI2023

Calcium Cosalt Addition to Alter the Cation Solvation Structure and Enhance the Ca Metal Anode Performance

Accessing the energy density and sustainability of calcium metal batteries requires mastering reversible calcium electrodeposition through electrolyte design. Several electrolytes support reversible, ambient temperature deposition but at utilization and rate too low for practical applications. These challenges stem from solvation structures characterized by either high barriers for cation desolvation or thermodynamic instability, leading to parasitic decomposition of the salt and solvent. The optimal solvation structure for the effective delivery of calcium to the electrode interface is not known. In this work, we show that adding a relatively small amount of a weakly associating calcium salt (calcium carba-closo-dodecaborate) to an otherwise strongly associated solution (calcium borohydride in tetrahydrofuran) produces a surprising population of fully solvent-coordinated Ca2+ cations in the form of solvent-separated ion pairs (SSIPs). We further demonstrate that the formation of these SSIPs beneficially impacts the kinetics and thermodynamics of calcium electrodeposition, revealing the unexpected finding that direct coordination of Ca2+ by the BH4– anion limits the electrodeposition process. These findings reveal how the competition between solvent and anion coordination to Ca2+ affects calcium deposition kinetics and cycling stability, setting the stage for a new calcium electrolyte design based on mixed anion electrolytes.

Landers, Alan T.↗

NASA NTRS2021

Atoms to Aircraft to Spacecraft

The next generation of aerospace systems requires materials and structures that combine high performance at high utilization in short missions with the possibility of high rate production, without excessive non-recurring cost, to allow for rate flexibility and shorter structural life cycles. The development of materials and structures that offer this flexibility in rate without negatively influencing performance and economic viability will require a matching and overlapping experimental and computational design approach. The objective is to go from Atom to Airframe to Spaceframe for thermoplastic unidirectional tape based fastener-free assemblies. Thermoplastic composites are chosen as the focus because these materials allow for reversible fusion bonding in every stage of their life cycle after synthesis. Our strategy is to combine multi-scale computational approaches with multi-scale experimental activities to develop an understanding of and capabilities to manufacture custom unidirectional thermoplastic tape. This tape will be the basis for our high-rate multiple-technology manufacturing approach validated by the production of two representative demonstrators for urban air mobility vehicle structures. The multi-disciplinary team will work in an integrated manner to effectively combine computational approaches with experimental approaches at each stage of characteristic manufacturing flows. The team aims for tools and technology to quantify the thermo-rheological aspects of unidirectional tape-based production and assembly of aerospace quality thermoplastic components as well as for validated tools for unidirectional tape-based thermoplastic preform and part design and manufacture. The work will be used to design and build two demonstration structural parts characteristic for urban air mobility vehicles.

Paul Ziehl↗

NASA NTRS2009

A Summary of the Development of a Nominal Land Landing Airbag Impact Attenuation System for the Orion Crew Module

Airborne Systems North America (formally Irvin Aerospace Inc) has developed an Airbag Landing System for the Orion Crew Module of the Crew Exploration Vehicle. This work is in support of the NASA Langley Research Center Landing System Advanced Development Project. Orion is part of the Constellation Program to send human explorers back to the moon, and then onwards to Mars and other destinations in the Solar System. A component of the Vision for Space Exploration, Orion is being developed to also enable access to space following the retirement of the Space Shuttle in the next decade. This paper documents the development of a conceptual design, fabrication of prototype assemblies, component level testing and two generations of airbag landing system testing. The airbag system has been designed and analyzed using the transient dynamic finite element code LS-DYNA(RegisteredTradeMark). The landing system consists of six airbag assemblies; each assembly comprising a primary impact venting airbag and a non-venting anti-bottoming airbag. The anti-bottoming airbag provides ground clearance following the initial impact attenuation sequence. Incorporated into each primary impact airbag is an active vent that allows the entrapped gas to exit the control volume. The size of the vent is tailored to control the flow-rate of the exiting gas. An internal shaping structure is utilized to control the shape of the primary or main airbags prior to ground impact; this significantly improves stroke efficiency and performance.

Tutt, Ben↗

DOE OSTI2022

Growth mechanism of glucose-based hydrochar under the effects of acid and temperature regulation

Improving the tailorability of hydrochar synthesis is an effective way to enhance its performance and utilization efficiency. In this study, the growth rate, morphology, and molecular structure of hydrochar were controlled by regulating the pH and temperature of the hydrothermal carbonization process. Growth process analysis indicates that hydrochar has three growth periods: induction, rapid, and stable growth periods. It is mainly controlled by 5-hydroxymethylfurfural (HMF), which is formed by converting glucose and its transformation products. Further, the regulation of acid can significantly shorten the induction period of hydrochar, even under low-temperature conditions (<180 °C), and increase the growth rate of hydrochar. However, the degree of hydrochar adhesion varies: the lower the temperature, the greater the degree of its adhesion. Molecular structural analysis demonstrates that hydrochar mainly consists of furan structural domains and aromatic clusters, and its surface is rich in oxygen-containing functional groups. The degree at which hydrochar was aromatized was improved by increasing the reaction temperature (160–220 °C); whereas the regulation of acid reduced it and increased the content of oxygen-containing functional groups on the hydrochar surface. Based on these results, it is proposed that hydrochar formation has five stages and three growth periods with or without acid regulation.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2020

MN Solar Pathways: Solar Deployment Strategies-Modeling and Case Studies

As part of the Minnesota Solar Pathways project, funded in part by the Department of Energy’s Solar Energy Technologies Office, Clean Power Research (CPR) developed a Solar Deployment Strategies modeling tool to calculate the economic impacts and market incentives created by different solar portfolios and rate structures. CPR developed the tool using Minnesota-specific data and assumptions. The case studies described in this report provide insight into possible pathways toward the state goal of 10% solar, but the emphasis of the report is the demonstration of the tool in use cases that can be expanded and modified in future years as needs change.

14 SOLAR ENERGY↗

NASA NTRS2024

Effective structural impact detection and localization using convolutional neural network and Bayesian information fusion with limited sensors

Due to their unpredictable nature, many impact events (e.g., overheight vehicles striking on bridges) go unnoticed or get reported many hours later. However, they can induce structural failures or hidden damage that accelerates the structure’s long-term degradation. Therefore, prompt impact detection and localization strategies are essential for early warning of impact events and rapid maintenance of structures. Most existing impact detection strategies are developed for aircraft composite panels utilizing high-rate synchronized measurement from densely deployed sensors. Limited efforts have been made for infrastructure or human habitats which generally require large-scale but low-rate measurement. In particular, due to harsh environments (e.g., deep space habitats under meteoroids), structural impact localization must be robust to limited sensors (e.g., sensor damage during impacts) and multi-source errors (e.g., measurement errors). In this study, an effective impact detection and localization strategy is proposed using a limited number of vibration measurements, especially in harsh environments (e.g. in deep space). Convolutional neural networks are trained for each sensor node and are fused using Bayesian theory to improve the accuracy of impact localization. Special considerations are paid to evaluate the effect of both measurement error and modeling error in the analysis. The proposed strategy is illustrated using 1D structure, and further validated in 3D geodesic dome structure numerically. The results demonstrate that it can detect and localize impact events accurately and robustly on structures.

Yuguang Fu↗

DOE OSTI2022

Nucleation Rate Theory for Coordination Number: Elucidating Water-Mediated Formation of a Zigzag Na 2 SO 4 Morphology

Predicting and controlling nanostructure formation during nucleation can pave the way to synthesizing novel energy materials via crystallization. However, such control over nucleation and crystallization remains challenging due to an inadequate understanding of critical factors that govern evolving atomistic structures and dynamics. Here, in this paper, we utilize coordination number as a reaction coordinate and rate theory to investigate how sodium sulfate, commonly known as a phase-change energy material, nucleates in a supersaturated aqueous solution. In conjunction with ab initio and force field-based molecular dynamics simulation, the rate theoretical analysis reveals that sodium sulfate from an initially dissolved metastable state transits to a heterogeneous mixture of prenucleated clusters and finally to a large cylindrical zigzag morphology. Measurements of Raman spectra and their ab initio modeling confirm that this nucleated morphology contains a few waters for every sulfate. Rate processes such as solvent exchange and desolvation exhibit high sensitivity to the evolving prenucleation/nucleation structures, providing a means to distinguish between critical nucleation precursors. Desolvation and forming the first-shell interionic coordination structure via monomer-by-monomer addition around sulfates are found to explain the formation of large nuclei. Thus, a detailed understanding of the step-by-step structure formation across scales has been achieved. This can be leveraged to predict nucleation-related structures and dynamics and potentially control the synthesis of novel phase-change materials for energy applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1985

Effects of stratospheric lapse rate on numerically simulated thunderstorm cloud top structure

The three-dimensional anelastic model of Schlesinger (1975, 1978, 1984) is utilized to study the effects of stratospheric stability on thunderstorm cloud top structure. Three experiments were conducted; in the first the stratosphere is assumed isothermal, in the second test there is a temperature lapse of 3 K/km, and in the third case there is a 3 K/km inversion. Time variations of vertical velocity, mature storm structure, and cloud top are examined. It is observed that the cloud summit height is lowered as stratospheric stability increases, a cloud-top thermal couplet occurs in all cases, the cold region has a U or V shape, and there is a height minimum in the warm regions.

Schlesinger, Robert E.↗

NASA NTRS2005

Ionizing Radiation Environment on the International Space Station: Performance vs. Expectations for Avionics and Material

The role of structural shielding mass in the design, verification, and in-flight performance of International Space Station (ISS), in both the natural and induced orbital ionizing radiation (IR) environments, is reported. Detailed consideration of the effects of both the natural and induced ionizing radiation environment during ISS design, development, and flight operations has produced a safe, efficient manned space platform that is largely immune to deleterious effects of the LEO ionizing radiation environment. The assumption of a small shielding mass for purposes of design and verification has been shown to be a valid worst-case approximation approach to design for reliability, though predicted dependences of single event effect (SEE) effects on latitude, longitude, SEP events, and spacecraft structural shielding mass are not observed. The Figure of Merit (FOM) method over predicts the rate for median shielding masses of about 10g/cm(exp 2) by only a factor of 3, while the Scott Effective Flux Approach (SEFA) method overestimated by about one order of magnitude as expected. The Integral Rectangular Parallelepiped (IRPP), SEFA, and FOM methods for estimating on-orbit (Single Event Upsets) SEU rates all utilize some version of the CREME-96 treatment of energetic particle interaction with structural shielding, which has been shown to underestimate the production of secondary particles in heavily shielded manned spacecraft. The need for more work directed to development of a practical understanding of secondary particle production in massive structural shielding for SEE design and verification is indicated. In contrast, total dose estimates using CAD based shielding mass distributions functions and the Shieldose Code provided a reasonable accurate estimate of accumulated dose in Grays internal to the ISS pressurized elements, albeit as a result of using worst-on-worst case assumptions (500 km altitude x 2) that compensate for ignoring both GCR and secondary particle production in massive structural shielding.

Koontz, Steven L.↗

NASA NTRS1989

A comparison of radar measurements of atmospheric turbulence intensities by both C sub n sup 2 and spectral width methods

There are two main techniques by which turbulence intensities in the atmosphere can be measured by radars. One is to utilize the absolute backscattered power received by the radar, and use this to deduce C sub n sup 2 (refractivity turbulence structure constant). With appropriate assumptions, this parameter can then be converted to an energy dissipation rate. The second method utilizes the width of the spectrum of the signal received by the radar. Neither of these techniques have been used a great deal, and they have never been properly compared. Thus it was not possible to determine the validity of the assumptions made in applying each technique, nor was it possible to determine the limitations of each method. The first comparisons of the two techniques are presented. Measurements were made with the Adelaide VHF ST radar, and the results of the comparison are discussed.

Hocking, W. K.↗

DOE OSTI2022

Industrial battery operation and utilization in the presence of electrical load uncertainty using Bayesian decision theory

Behind the meter battery storage is becoming increasing popular in all sectors, though enthusiasm has recently lagged in the industrial sector. Even though there may be many factors contributing to this including lack of innovation, prohibitive costs, and undesirable rate structures, a difficulty arises in accounting for uncertainty of electrical load in industrial facilities while still attempting to utilize battery storage as much as possible all while trying to achieve fiscal profitability. Here this study utilizes Gaussian process regression and Bayesian decision theory to organize load data and quantify electrical load uncertainty to properly and effectively discharge industrial battery storage. The study employs a simulation model to set battery load setpoints for the span of the utility billing period according to the degree of risk aversion. This combination of economic analysis according to utility billing period and utilization of degree of risk aversion to make decisions on the uncertainty of the data has not before been applied to battery storage. The method resulted in an annual average reduction of peak demand by 3.8 % at the lowest amount of savings and lowest risk aversion. The highest risk aversion resulted in an annual average reduction of peak demand of 7.5 %. The maximum reduction of peak load in any month was 13.8 % in the month of December with a relatively high risk aversion. With a the highest amount risk aversion tested, the model reduced demand ten of the twelve months of the year.

25 ENERGY STORAGE↗

DOE OSTI2023

Solar–Driven CO 2 Conversion via Optimized Photothermal Catalysis in a Lotus Pod Structure

Photothermal CO 2 reduction is one of the most promising routes to efficiently utilize solar energy for fuel production at high rates. However, this reaction is currently limited by underdeveloped catalysts with low photothermal conversion efficiency, insufficient exposure of active sites, low active material loading, and high material cost. Herein, we report a potassium-modified carbon-supported cobalt (K + –Co–C) catalyst mimicking the structure of a lotus pod that addresses these challenges. As a result of the designed lotus-pod structure which features an efficient photothermal C substrate with hierarchical pores, an intimate Co/C interface with covalent bonding, and exposed Co catalytic sites with optimized CO binding strength, the K + –Co–C catalyst shows a record-high photothermal CO 2 hydrogenation rate of 758 mmol gcat –1 h –1 (2871 mmol gCo –1 h –1 ) with a 99.8 % selectivity for CO, three orders of magnitude higher than typical photochemical CO 2 reduction reactions. Here, we further demonstrate with this catalyst effective CO 2 conversion under natural sunlight one hour before sunset during the winter season, putting forward an important step towards practical solar fuel production.

36 MATERIALS SCIENCE↗

DOE OSTI2021

Microhole drilling technology utilizing a golden section search algorithm

A fundamental issue in microhole drilling is that delivering high weight-on-bit (WOB), high torque rotational horsepower to a conventional drill bit does not scale down to the hole sizes necessary to realize the envisioned cost savings An optimization algorithm called a golden section search (GSS) was used to systematically identify the preferred WOB for a given set of conditions. This research focused on implementing and evaluating two low WOB drilling technologies for microhole drilling: - Laser-assisted mechanical drill, which was tested in the laboratory - Lightly modified commercial off-the-shelf (COTS) percussive hammer, which was tested in a limited field test. Data were collected for microhole GSS using WOB optimization via simulation as well as at the Blue Canyon Dome Site in Socorro, NM. Information on the attached files and folders are as follows: - the .tdms files are LabView data files, which can be opened within Excel using a .tdms add-in or using a Matlab .tdms converter - the .tdms_index files are part of the .tdms file structure - sampling rate, column headers, and length data within the .tdms files follow SOP when utilizing Excel and/or Matlab as described above

15 GEOTHERMAL ENERGY↗

DOE OSTI2025

Rooftop Solar Deployment, Potential Electricity Rate Impacts, and the Timing of Revisions to State Net Metering Policy

Most U.S. states require utilities to credit residential solar photovoltaic (PV) output at the retail electricity rate, a structure known as net metering. However, 12 states have replaced net metering with alternative rate structures that reduce PV adopter bill savings. The share of households living in states that require net metering fell from around 84% in 2014 to around 57% by the end of 2023. Proponents of net metering revisions have argued that net metering can affect the electricity rates of customers without PV. This report analyzes the relationships between state PV deployment levels, potential electricity rate impacts on PV nonadopters, and the timing of revisions to net metering policy.

14 SOLAR ENERGY↗

NASA NTRS1982

NASA/FAA Helicopter ATC simulation investigation of RNAV/MLS instrument approaches

The NASA/FAA Helicopter Air Traffic Control (ATC) simulation investigations to determine the feasibility of simultaneous, independent instrument approach procedures for helicopters at major terminal areas, using Area Navigation/Microwave Landing System (RNAV/MLS) guidance, was conducted at several levels of helicopter display sophistication, up to that of a Cockpit Display of Traffic Information (CDTI) system. Test objectives included the determination of pilot acceptability and the tracking performance of the RNAV/MLS's noninterfering rotorcraft approach path structure, along with the evaluation of the effect on controller workload of multiroute structures combining conventional and rotorcraft approaches at various arrival rates and traffic separations. The utility of electronic area maps and CDTI displays was also investigated. Participating pilots flew 127 simulated instrument approaches in an ATC simulation laboratory.

Peach, L. L., Jr.↗

NASA NTRS1990

Analyzing the flared landing task with pitch-rate flight control systems

A closed-loop handling qualities methodology is applied to an analysis of the flared landing task with pitch-rate flight control systems. A model of pilot behavior throughout approach and flare is developed which postulates the manner in which the pilot may move from pitch attitude to flight path angle control. Twenty-five configurations flight tested on the NC-131H Total In-flight Simulator aircraft are analyzed using a structural pilot model ad a handling qualities methodology previously reported in the literature. Closed-loop simulation of the simplified landing task is undertaken using the structural model. The pilot ratings from flight test extended the data base supporting the utility of a model-based handling qualities metric. A handling qualities sensitivity function is introduced which may have potential as a design tool.

Hess, Ronald A.↗