The entanglement region and non-Newtonian polymer flow
Shear dependence of viscosity for concentrated polymer systems related to polymer molecular weight distribution
MOLECULAR WEIGHT↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Low-thrust vehicle concept studies
Part of NASA's orbit transfer vehicle propulsion program is devoted to the development of analytical tools to define propulsion system performance, weight, size, and other parameters, and to develop packing concepts for LSS mission propulsion and payload systems. Packing studies discussed relate to shuttle cargo bay constraints; low thrust engine profile and performance; large space frame concept and weight; low thrust vehicles stowed in shuttle, LSS payload capability, and weight distribution. Further study is needed to determine interactions among propulsion system, payload structures, and shuttle. Low thrust-to-weight ratios are desirable to maximize payload weights and deployed areas.
Smolak, G. R.↗
Lunar soils grain size catalog
This catalog compiles every available grain size distribution for Apollo surface soils, trench samples, cores, and Luna 24 soils. Original laboratory data are tabled, and cumulative weight distribution curves and histograms are plotted. Standard statistical parameters are calculated using the method of moments. Photos and location comments describe the sample environment and geological setting. This catalog can help researchers describe the geotechnical conditions and site variability of the lunar surface essential to the design of a lunar base.
Graf, John C.↗
Integrating multi-modal remote sensing, deep learning, and attention mechanisms for yield prediction in plant breeding experiments
In both plant breeding and crop management, interpretability plays a crucial role in instilling trust in AI-driven approaches and enabling the provision of actionable insights. The primary objective of this research is to explore and evaluate the potential contributions of deep learning network architectures that employ stacked LSTM for end-of-season maize grain yield prediction. A secondary aim is to expand the capabilities of these networks by adapting them to better accommodate and leverage the multi-modality properties of remote sensing data. In this study, a multi-modal deep learning architecture that assimilates inputs from heterogeneous data streams, including high-resolution hyperspectral imagery, LiDAR point clouds, and environmental data, is proposed to forecast maize crop yields. The architecture includes attention mechanisms that assign varying levels of importance to different modalities and temporal features that, reflect the dynamics of plant growth and environmental interactions. The interpretability of the attention weights is investigated in multi-modal networks that seek to both improve predictions and attribute crop yield outcomes to genetic and environmental variables. This approach also contributes to increased interpretability of the model's predictions. The temporal attention weight distributions highlighted relevant factors and critical growth stages that contribute to the predictions. The results of this study affirm that the attention weights are consistent with recognized biological growth stages, thereby substantiating the network's capability to learn biologically interpretable features. Accuracies of the model's predictions of yield ranged from 0.82-0.93 R 2 ref in this genetics-focused study, further highlighting the potential of attention-based models. Further, this research facilitates understanding of how multi-modality remote sensing aligns with the physiological stages of maize. The proposed architecture shows promise in improving predictions and offering interpretable insights into the factors affecting maize crop yields, while demonstrating the impact of data collection by different modalities through the growing season. By identifying relevant factors and critical growth stages, the model's attention weights provide valuable information that can be used in both plant breeding and crop management. The consistency of attention weights with biological growth stages reinforces the potential of deep learning networks in agricultural applications, particularly in leveraging remote sensing data for yield prediction. To the best of our knowledge, this is the first study that investigates the use of hyperspectral and LiDAR UAV time series data for explaining/interpreting plant growth stages within deep learning networks and forecasting plot-level maize grain yield using late fusion modalities with attention mechanisms.
59 BASIC BIOLOGICAL SCIENCES↗
Comparison of the properties of some synthetic crudes with petroleum crudes
Physical properties and chemical compositions of six synthetic crudes were determined. The results were compared to those of typical petroleum crudes, with the interest being the feasibility of making jet fuels from oil shale and coal syncrudes. The specific gravity, viscosity, and pour point were measured, showing that these crudes would be described as heavier rather than lighter crudes. The boiling range distribution of the crudes was determined by distillation and by gas chromatography. In addition, gel permeation chromatograms were obtained, giving a unique molecular weight distribution profile for each crude. Analyses for carbon, hydrogen, nitrogen and sulfur concentrations were performed, as well as for hydrocarbon group type and trace element concentrations. It was found that the range in concentration of vanadium, an element whose presence in turbine fuels is of major concern, was lower than that of petroleum crudes. Sodium and potassium, other elements of concern, were present in comparatively high concentrations.
Antoine, A. C.↗
Cradles for Support in Transit
C-shaped cradles distribute weight of large objects. Originally developed for holding satellite in bay of Space Shuttle orbiter, concept also adaptable to such terrestrial uses as carrying odd-shaped equipment by truck. Cradle set consists of single prime cradle and several basic cradles. Composed of bar bent into a half circle, each cradle has own keel and longeron trunnions that brace structure by mating with receptacles in vehicle and its own foam pads, on which load rests. One 548-lb (249-kg) cradle supports up to 3,000 lb (1,361 kg); thus, 15,000-lb (6,800-kg) object requires five cradles distributed along its length. Through their trunnions, cradles spread weight of load along vehicle.
Crane, W. H.↗
Optimization of step rockets by the discrete maximum principle.
Optimum stage weight distribution in multistage rocket obtained by discrete maximum principle
WEIGHT FACTOR↗
Suspension of SiC Powders in Allyhydridopolycarbosilane (AHPCS): Control of Rheology
Inert particulate fillers can be blended with preceramic polymers prior to infiltration of composite preforms to increase pyrolysis yield and decrease shrinkage, thus reducing the number of infiltration/ pyrolysis cycles required for densification. However, particulate filler loadings and concentration of added dispersants necessary to maintain low viscosity (< 0.50 N.s/sq m) slurries vary with the characteristics of the particular AHPCS polymer batch. These batch to batch variations occur with alterations in the synthesis process and method of allyl substitution, which in turn alter polymer structure and molecular weight distribution. A number of different polymer batches were characterized by NMR, GPC and thermal analysis, and the influence of polymer structure on rheology of filled systems determined. When the high molecular weight fraction increased to too great a level, suitably fluid slurries could no longer be attained.
Hurwitz, Frances I.↗
Erectile antenna study Final report, 2 Mar. - 15 Sep. 1967
Optimum antenna weight distribution curves for six techniques to erect large aperture antennas
SPACE ERECTABLE STRUCTURE↗
Gel Permeation Chromatography of Fluoroether Polymers
A Method is described for determining the molecular weight distribution of fluorinated polymers by gel permeation chromatography. Porous silica-packed columns are used with Freon 113 as the chromatographic solvent. Fluoroether oligomers are used for column calibration in the molecular weight range of 1400 to 12000.
Korus, Roger A.↗
Optimization of step rockets by the discrete maximum principle.
Optimum stage weight distribution in multistage rocket obtained by discrete maximum principle
MULTISTAGE ROCKET↗
On the decoder error probability of linear codes
By using coding and combinatorial techniques, an approximate formula for the weight distribution of decodable words of most linear block codes is evaluated. This formula is then used to give an approximate expression for the decoder error probability P(sub E)(u) of linear block codes, given that an error pattern of weight u has occurred. It is shown that P(sub E)(u) approaches the constant Q as u gets large, where Q is the probability that a completely random error pattern will cause decoder error.
Cheung, K.-M.↗
Insight into the Competitive Adsorption Behavior of Polymer Chains in Silica Nanopores by Small-Angle Neutron Scattering
Processive hydrogenolysis catalysts, in which a metal nanoparticle (e.g., Pt) embedded at the bottom of a cylindrical silica nanopore can repeatedly cleave polymer chains and produce value-added hydrocarbon products, offer a potential solution for billions of tons of waste plastics. As the chain stays longer near the Pt catalysts, it would have a higher chance of getting cut, and therefore the molecular weight distribution of the product could be affected by the adsorption behavior of virgin chains (long polymers) versus cleaved chains (short polymers) into the nanopores. Further, this work reports a model study to understand the competitive adsorption behavior of the two different molecular weight polymers that are mixed, mimicking the reaction medium in the intermediate stage of the catalytic reaction. This study employs small-angle neutron scattering (SANS), which takes advantage of contrast differences between hydrogenous and deuterated polystyrenes to experimentally observe the relative composition of the two polymers in the silica nanopores. Our results reveal preferential adsorption of longer chains in the silica nanopores, which is consistent with the theoretical prediction in the literature for the case of the enthalpic attraction between polymers and pore walls.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
The Southern Argentina Agile Meteor Radar Orbital System (SAAMER-OS): An Initial Sporadic Meteoroid Orbital Survey in the Southern Sky
We present an initial survey in the southern sky of the sporadic meteoroid orbital environment obtained with the Southern Argentina Agile MEteor Radar (SAAMER) Orbital System (OS), in which over three-quarters of a million orbits of dust particles were determined from 2012 January through 2015 April. SAAMER-OS is located at the southernmost tip of Argentina and is currently the only operational radar with orbit determination capability providing continuous observations of the southern hemisphere. Distributions of the observed meteoroid speed, radiant, and heliocentric orbital parameters are presented, as well as those corrected by the observational biases associated with the SAAMER-OS operating parameters. The results are compared with those reported by three previous surveys performed with the Harvard Radio Meteor Project, the Advanced Meteor Orbit Radar, and the Canadian Meteor Orbit Radar, and they are in agreement with these previous studies. Weighted distributions for meteoroids above the thresholds for meteor trail electron line density, meteoroid mass, and meteoroid kinetic energy are also considered. Finally, the minimum line density and kinetic energy weighting factors are found to be very suitable for meteoroid applications. The outcomes of this work show that, given SAAMERs location, the system is ideal for providing crucial data to continuously study the South Toroidal and South Apex sporadic meteoroid apparent sources.
meteorites↗
An analytical study of electric vehicle handling dynamics
Hypothetical electric vehicle configurations were studied by applying available analytical methods. Elementary linearized models were used in addition to a highly sophisticated vehicle dynamics computer simulation technique. Physical properties of specific EV's were defined for various battery and powertrain packaging approaches applied to a range of weight distribution and inertial properties which characterize a generic class of EV's. Computer simulations of structured maneuvers were performed for predicting handling qualities in the normal driving range and during various extreme conditions related to accident avoidance. Results indicate that an EV with forward weight bias will possess handling qualities superior to a comparable EV that is rear-heavy or equally balanced. The importance of properly matching tires, suspension systems, and brake system front/rear torque proportioning to a given EV configuration during the design stage is demonstrated.
Greene, J. E.↗
A solution-adaptive mesh algorithm for dynamic/static refinement of two and three dimensional grids
An adaptive grid algorithm has been developed in two and three dimensions that can be used dynamically with a solver or as part of a grid refinement process. The algorithm employs a transformation from the Cartesian coordinate system to a general coordinate space, which is defined as a parallelepiped in three dimensions. A weighting function, independent for each coordinate direction, is developed that will provide the desired refinement criteria in regions of high solution gradient. The adaptation is performed in the general coordinate space and the new grid locations are returned to the Cartesian space via a simple, one-step inverse mapping. The algorithm for relocation of the mesh points in the parametric space is based on the center of mass for distributed weights. Dynamic solution-adaptive results are presented for laminar flows in two and three dimensions.
Benson, Rusty A.↗
A three-dimensional dynamic solution-adaptive mesh algorithm
A solution-adaptive grid algorithm has been developed for use in two and three dimensions. The algorithm uses a transformation from the cartesian coordinate system to a general coordinate space, which will be defined as a parallelepiped. A weighting function for adaption of the grid is developed that will allow adaption to the gradients of any combination of dependent variables in the flow. The adaption is carried out in the parametric space and a simple inverse mapping to return the new parametric space to the physical space is derived. The concept used to relocate the grid-points in the parametric space is based on the center of mass of distributed weights. Solution-adaptive results are presented for various laminar flows in two dimensions and for mathematical weighting functions in three dimensions.
Benson, Rusty A.↗
Ethylene Polymerizations Catalyzed by Fluorinated “Sandwich” Diimine-Nickel and Palladium Complexes
Nickel and palladium complexes bearing “sandwich” diimine ligands with perfluorinated aryl caps have been synthesized, characterized, and explored in ethylene polymerization reactions. The X-ray crystallographic analysis of the precatalysts 16 and 6b show differences from their non-fluorinated analogues 17 and 19, with the perfluorinated aryl caps centered precisely over the nickel and palladium centers which results in higher buried volumes of the metal centers relative to the non-fluorinated analogs. The sandwich diimine palladium complexes 5a and 5b containing perfluorinated aryl caps polymerize ethylene in a controlled fashion with activities that are substantially increased compared with their non-fluorinated analogues. Migratory insertion rates in relevant methyl ethylene complexes agree with activities exhibited in bulk polymerization experiments. DFT studies suggest that facility of ethylene rotation from its preferred orientation perpendicular to the Pd-alkyl bond into a parallel in-plane conformation contributes to the higher polymerization activity for 5b relative to 18a. For these palladium systems polymer molecular weights can be controlled via hydrogen addition (hydrogenolysis) which is unusual for late transition metal-catalyzed olefin polymerizations with no catalyst deactivation occurring. Sandwich diimine nickel complexes 6a and 6b with perfluorinated aryl caps show ethylene polymerization activities that are about half that of classical tetraisopropyl-substituted catalyst 2 but again are more active than the analogous nonfluorinated sandwich complexes. Ethylene polymerizations exhibit living behavior and branched ultra-high molecular weight polyethylenes (UHMWPEs) with very low molecular weight distributions (less than 1.1) are obtained. The activated nickel catalysts are stable in the absence of monomer and show good long-term stability at 25 °C.
36 MATERIALS SCIENCE↗