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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30

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NASA NTRS1999

Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

Single crystal oxides such as yttria-stabilized zirconia (Y2O3-ZrO2), yttrium aluminum garnet (Y3Al5O12, or YAG), magnesium oxide (MgO) and sapphire (Al2O3) are candidate refractive secondary concentrator materials for high temperature solar propulsion applications. However, thermo-mechanical reliability of these components in severe thermal environments during the space mission sun/shade transition is of great concern. Simulated mission tests are important for evaluating these candidate oxide materials under a variety of transient and steady-state heat flux conditions, and thus provide vital information for the component design. In this paper, a controlled heat flux thermal shock test approach is established for the single crystal oxide materials using a 3.0 kW continuous wave CO2 laser, with a wavelength 10.6 micron. Thermal fracture behavior and failure mechanisms of these oxide materials are investigated and critical temperature gradients are determined under various temperature and heating conditions. The test results show that single crystal sapphire is able to sustain the highest temperature gradient and heating-cooling rate, and thus exhibit the best thermal shock resistance, as compared to the yttria-stabilized zirconia, yttrium aluminum garnet, and magnesium oxide.

Zhu, Dongming↗

NASA NTRS1999

Thermal-Mechanical Stability of Single Crystal Oxide Refractive Concentrators for High-Temperature Solar Thermal Propulsion

Zhu, Dongming↗

NASA NTRS2019

Validation of Regional CO2 Concentrations in the ECMWF Real-Time Analysis and Carbon-Tracker Reanalysis with Airborne Observations from ACT-A Field Campaign

Through verifying against hundreds of hours of airborne in-situ measurements from the NASA-sponsored Atmospheric Carbon and Transport – America (ACT-A) field campaign, this study systematically examines the regional uncertainties and biases of the carbon dioxide (CO2) concentrations from two of the state-of-the-art global analysis products, namely the real-time analysis from the European Center (EC) for Medium Range Forecasting and NOAA’s near real-time Carbon Tracker (CT) reanalysis. It is found that both the EC and CT-NRT analyses agree reasonably well with the independent ACT-A flight-level CO2 measurements in the free troposphere but the uncertainties are considerably larger in the boundary layer during both the summer months of 2016 and the winter months of 2017. There are also strong variabilities in accuracy and bias between seasons, and across three different subregions in the United States (Mid-Atlantic, Midwest and South). Overall, the analysis uncertainties of the EC and CT-NRT analyses in terms of root-mean square deviations against airborne data are comparable to each other, both of which are between 1-2 ppm in the free troposphere but can be as large as 10 ppm near the surface, which are grossly consistent with the difference between the two analyses. The current study not only provides systematic uncertainty estimates for both analysis products over North America but also demonstrated that these two independent estimates can be used to approximate the overall regional CO2 analysis uncertainties. Both statistics are important in future studies in quantifying the uncertainties of regional carbon concentration and flux estimates, as well as in assessing the impact of regional transport through more refined regional modeling and analysis systems.

Chen, Hans W.↗

NASA NTRSDate not supplied

Radiative Heating Under Particulate-Laden Conditions During Hypersonic Planetary Entry

An important consideration while designing for hyper-sonic planetary entry is the interaction between the multitude of physical phenomena that manfist them-selves at these extreme conditions. This fact is also true for a Martian landing where in addition to thermo-chemical non-equilibriurm, vehicular predictions are impacted by radiative heating and potentially atmos-pheric dust. Previous studes have indicated that infra-red (IR) radiation emanating from CO2 and CO mole-cules constitute a significant fraction, especially in the backshell, of the total surface heat flux. In similar vein, dust particles, which can be present even under quiescent conditions, have been shown to increase the erosion rate of the heatshield. However, what remains relatively unquantified is the possible modification of the radiative environment due to the presence of dust. The present study is expected to provide the most de-tailed assessment to date of particles introducing changes to the radiative energy transfer both through the attenuation of existing shocked gas-induced radia-tion and additional emission.

Radiation↗

DOE OSTI2023

Carbon and Water Fluxes of the Boreal Evergreen Needleleaf Forest Biome Constrained by Assimilating Ecosystem Carbonyl Sulfide Flux Observations

Gross primary production (GPP) by boreal forests is highly sensitive to environmental changes. However, GPP simulated by land surface models (LSMs) remains highly uncertain due to the lack of direct photosynthesis observations at large scales. Carbonyl sulfide (COS) has emerged as a promising proxy to improve the representation of GPP in LSMs. Because COS is absorbed by vegetation following the same diffusion pathway as CO2 during photosynthesis and not emitted back to the atmosphere, incorporating a mechanistic representation of vegetation COS uptake in LSMs allows using COS observations to refine GPP representation. Here, we perform ecosystem COS flux and GPP data assimilations to constrain the COS- and GPP-related parameters in the ORCHIDEE LSM for boreal evergreen needleleaf forests (BorENF). Assimilating ecosystem COS fluxes at Hyytiälä forest increases the simulated net ecosystem COS uptake by 14%. This increase largely results from changes in the internal conductance to COS, highlighting the need to improve the representation of COS internal diffusion and consumption. Moreover, joint assimilation of ecosystem COS flux and GPP at Hyytiälä improves the simulated latent heat flux, contrary to the GPP-only data assimilation, which fails to do so. Finally, we scaled this assimilation framework up to the boreal region and find that the joint assimilation of COS at Hyytiälä and GPP fluxes at 10 BorENF sites increases the modeled vegetation COS uptake up to 18%, but not GPP. Therefore, this study encourages the use of COS flux observations to inform GPP and latent heat flux representations in LSMs.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1993

Impact of the CO2 and H2O clouds of the Martian polar hood on the polar energy balance

Clouds covering extensive areas above the martian polar caps have regularly been observed during the fall and winter seasons of each hemisphere. These 'polar hoods' are thought to be made of H2O and CO2. In particular, the very cold temperatures observed during the polar night by Viking and Mariner 9 around both poles have been identified as CO2 clouds and several models, including GCM, have indicated that the CO2 can condense in the atmosphere at all polar latitudes. Estimating the impact of the polar hood clouds on the energy balance of the polar regions is necessary to model the CO2 cycle and address puzzling problems like the polar caps assymetry. For example, by altering the thermal radiation emitted to space, CO2 clouds alter the amount of CO2 that condenses during the fall and winter season. The complete set of Viking IRTM data was analyzed to define the spatial and temporal properties of the polar hoods, and how their presence affects the energy radiated by the atmosphere/caps system to space was estimated. The IRTM observations provide good spatial and temporal converage of both polar regions during fall, winter, and spring, when a combination of the first and the second Viking year is used. Only the IRTM brightness temperatures at 11, 15, and 20 microns are reliable at martian polar temperatures. To recover the integrated thermal fluxes from the IRTM data, a simple model of the polar hood, thought to consist of 'warm' H2O clouds lying above colder and opaque CO2 clouds was developed. Such a model is based on the analysis of the IRIS spectra, and is consistent with the IRTM data used.

Forget, Francois↗

NASA NTRS2016

Discussion of Yellow Starthistle Response to Irradiance, Photoperiod, and CO2

Yellow Starthistle (Centaurea solstitialis) is a native annual weed of Eurasia and since introduction into the US has become an invasive and noxious weed. It grows in a rosette habit during the vegetative state and usually bolts in summer to produce a large and branched flowering stem. Time to flowering in Yellow Starthistle has been attributed to photoperiod, nitrogen nutrition, temperature, and water stress. We executed a series of studies to investigate the role of light, both photoperiod and photosynthetic photon flux, on flowering and development in Yellow Starthistle. Treatments were presented in 4 ways: (1) Varying day length with constant photosynthetic photon flus (PPF) - providing increasing daily integrated Photosynthetic Photon (PP) exposure with longer day lengths, (2) Varying day length while adjusting PPF to maintain daily PP exposure for all treatments, (3) Extending photoperiod treatments beyond common 12-h photosynthetic period with low light levels to maintain both PPF and daily PP across all treatments; and (4) Reciprocal exchange of plant among photoperiod treatments. Yellow Starthistle appears to be a long-day plant with a critical day length requirement between 14-h and 16-h to induce transition from vegetative to floral stages in development. PPF and daily absorbed photons did not affect time to vegetative / floral stage transition, but did affect factors such as biomass accumulation and canopy parameters such as specific leaf mass. Reciprocal exchange of plants between floral inducing and inhibiting photoperiod treatments, starting at 2-weeks post germination, had no effect on to flower. Flowering was determined by photoperiod experienced during the first 2-weeks (or less) post germination. Yellow Starthistle net photosynthetic response to elevated atmospheric CO2 concentrations over a range of photosynthetically active radiation flux rates and temperatures will also be presented and discussed.

Photons↗

NASA NTRS1983

The thermal structure of the atmospheric surface boundary layer on Mars as modified by the radiative effect of aeolian dust

A computational simulation, based on Mariner 9 data, was performed for the thermal characteristics of the Martian atmospheric surface boundary layer in clear and dust-filled conditions. A radiative transfer model consisting of the atmospheric enthalpy rate equation, the radiative flux integrated over the 0.2-50 microns, the solid angle interval, and 0.50 km altitudes, broken into 52 levels. Mariner 9 IR data for CO2 absorption lines were included in the form of a temperture-dependent equation, while the line-widths were interpreted in terms of the pressure dependene as well as temperature. The lines covered the regions from 1-50 microns and varying conditions of dust content in the atmosphere. Attention was given to the thermal coupling between the ground and the atmosphere. It was found that convective heat exchange develops quickly due to radiative heating of the Martian desert surface, but does not cool the surface because of the attenuated atmosphere. The model predictd the 100 K temperature variations in the dusty atmosphere, as observed by the Viking thermal mapper. It is suggested that radiative flux convergence is as important as convection at equivalent efficiencies.

Pallmann, A. J.↗

NASA NTRS1979

An investigation and analysis of the density and thermal balance of the Martian ionosphere

The major photochemistry consisted of solar EUV and photoelectrons comprising 70 percent and 30 percent respectively, of the initial source of CO2(+) and O(+). The energetic O2(+) provided a substantial source of energy to the ambient ions, distributing of the order of 1.6 x 10 to the -7 power W/sq m at an average of 160 km. This input can be compared to that from the ambient electrons of 1.3 x 10 to the -7 power W/sq m with average deposition at 145 km and from the calculated thermal conduction of 1 x 10 to the -9 power W/sq m at 270 km and 1 x 10 to the -8 power at 230 km for assumed dip angles of 2 deg and 12 deg respectively, for a 10nT magnetic field. At altitudes above 250 km upward, vertical fluxes of the order 6 x 10 to the 10th power/sq m/sec for the thermal ions were calculated. The net ionization of O(+) and CO2(+) by charge exchange with incoming solar wind protons varied from 5 x 10 to the 8th power to 5 x 10 to the 12th power /sq m/sec for assumed field strengths of 50nT to 2nT on the dayside of the planet.

Rohrbaugh, R. P.↗

NASA NTRS2017

Discussion of Yellow Starthistle Response to Photosynthetic Irradiance, Photoperiod, and CO2

Yellow Starthistle (Centaurea solstitialis) is a native annual weed of Eurasia and since introduction into the United STates has become an invasive and noxious weed. It grows in a rosette habit during the vegetative state and usually bolts in summer to produce a large and branched flowering stem. Time to flowering in Yellow Starthistle has been attributed to photoperiod, nitrogen nutrition, temperature, and water stress. We executed a series of studies to investigate the role of light, both photoperiod and photosynthetic photon flux, on flowering and development in Yellow Starthistle. Treatments were presented in 4 ways: 1) varying day length with constant photosynthetic photon flus (PPF) providing increasing daily integrated Photosynthetic Photon (PP) exposure with longer day lengths 2) varying day length while adjusting PPF to maintain daily PP exposure for all treatments 3) extending photoperiod treatments beyond common 12-h photosynthetic period with low light levels to maintain both PPF and daily PP across all treatments4)reciprocal exchange of plant among photoperiod treatments Yellow Starthistle appears to be a long-day plant with a critical day length requirement between 14-h and 16-h to induce transition from vegetative to floral stages in development. PPF and daily absorbed photons did not affect time to vegetative floral stage transition, but did affect factors such as biomass accumulation and canopy parameters such as specific leaf mass. Reciprocal exchange of plants between floral inducing and inhibiting photoperiod treatments, starting at 2-weeks post germination, had no effect on to flower. Flowering was determined by photoperiod experienced during the first 2-weeks (or less) post germination.Yellow Starthistle net photosynthetic response to elevated atmospheric CO2 concentrations over a range of photosynthetically active radiation flux rates and temperatures will also be presented and discussed.

Photosynthetic↗

NASA NTRS1971

CO2 laser experiments using nuclear reactions as the ionization source.

Experimental studies show that the output of a CO2 laser is significantly increased by products of the nuclear reaction He-3 (n,p)T. Helium-3 was used in lieu of the natural helium normally present in the 1:1:8 CO2:N2:He laser gas mixture (pressure = 6 torr). The laser assembly was then exposed to a reactor thermal neutron flux of about 100 million neutrons/sq cm/sec. Power output of the laser doubled while the electrical power input decreased; electrical efficiency was thus more than doubled. Results indicate that additional ionization by the energetic charged particles may be responsible for the improved laser performance.

Rhoads, H. S.↗

NASA NTRS1986

An approach for verifying clear-sky radiation models with ERBS scanner measurements

A technique is proposed for validating radiation models using Earth Radiation Budget Satellite (ERBS) top of the atmosphere longwave radiance exitance data. ERBS measures clear-sky fluxes in terms of reflected solar and emitted longwave radiation. The radiation model considered accounts for the effects of H2O, CO2, O3, CH4, and N2O. ERBS nighttime radiance data for the region 60 deg N to 60 deg S latitude for most of November 1984 are compared with radiances over 5/cm intervals predicted by the model by means of the Malkmus theory for transmittances for line absorption.

Ramanathan, V.↗

NASA NTRS1990

Laser supported detonation wave source of atomic oxygen for aerospace material testing

A pulsed high-flux source of nearly monoenergetic atomic oxygen was developed to perform accelerated erosion testing of spacecraft materials in a simulated low-earth orbit (LEO) environment. Molecular oxygen is introduced into an evacuated conical expansion nozzle at several atmospheres pressure through a pulsed molecular beam valve. A laser-induced breakdown is generated in the nozzle throat by a pulsed CO2 TEA laser. The resulting plasma is heated by the ensuing laser-supported detonation wave, and then it rapidly expands and cools. An atomic oxygen beam is generated with fluxes above 10 to the 18th atoms per pulse at 8 + or - 1.6 km/s with an ion content below 1 percent for LEO testing. Materials testing yielded the same surface oxygen enrichment in polyethylene samples as observed on the STS mission, and scanning electron micrographs of the irradiated polymer surfaces showed an erosion morphology similar to that obtained on low earth orbit.

Krech, Robert H.↗

NASA NTRS1996

Quick-Mixing Studies Under Reacting Conditions

The low-NO(x) emitting potential of rich-burn/quick-mix/lean-burn )RQL) combustion makes it an attractive option for engines of future stratospheric aircraft. Because NO(x) formation is exponentially dependent on temperature, the success of the RQL combustor depends on minimizing high temperature stoichiometric pocket formation in the quick-mixing section. An experiment was designed and built, and tests were performed to characterize reaction and mixing properties of jets issuing from round orifices into a hot, fuel-rich crossflow confined in a cylindrical duct. The reactor operates on propane and presents a uniform, non-swirling mixture to the mixing modules. Modules consisting of round orifice configurations of 8, 9, 10, 12, 14, and 18 holes were evaluated at a momentum-flux ratio of 57 and jet-to-mainstream mass-flaw ratio of 2.5. Temperatures and concentrations of O2, CO2, CO, HC, and NO(x) were obtained upstream, down-stream, and within the orifice plane to determine jet penetration as well as reaction processes. Jet penetration was a function of the number of orifices and affected the mixing in the reacting system. Of the six configurations tested, the 14-hole module produced jet penetration close to the module half-radius and yielded the best mixing and most complete combustion at a plane one duct diameter from the orifice leading edge. The results reveal that substantial reaction and heat release occur in the jet mixing zone when the entering effluent is hot and rich, and that the experiment as designed will serve to explore satisfactorily jet mixing behavior under realistic reacting conditions in future studies.

Leong, May Y.↗

NASA NTRS2003

Effects of Atmospheric and Surface Dust on the Sublimation Rates of CO2 on Mars

We present an overview of our modeling work dedicated to study the effects of atmospheric dust on the sublimation of CO2 on Mars. The purpose of this study is to better understand the extent to which dust storm activity can be a root cause for interannual variability in the planetary CO2 seasonal cycle, through modifying the springtime regression rates of the south polar cap. We obtain calculations of the sublimation fluxes for various types of polar surfaces and different amounts of atmospheric dust. These calculations have been compared qualitatively with the regression patterns observed by Mars Global Surveyor (MGS) in both visible and infrared wavelengths, for two years of very different dust histories (1999, and 2001).

Bonev, B. P.↗

NASA NTRS2016

Electron Energetics in the Martian Dayside Ionosphere: Model Comparisons with MAVEN Data

This paper presents a study of the energetics of the dayside ionosphere of Mars using models and data from several instruments on board the Mars Atmosphere and Volatile EvolutioN spacecraft. In particular, calculated photoelectron fluxes are compared with suprathermal electron fluxes measured by the Solar Wind Electron Analyzer, and calculated electron temperatures are compared with temperatures measured by the Langmuir Probe and Waves experiment. The major heat source for the thermal electrons is Coulomb heating from the suprathermal electron population, and cooling due to collisional rotational and vibrational CO2 dominates the energy loss. The models used in this study were largely able to reproduce the observed high topside ionosphere electron temperatures (e.g., 3000 K at 300 km altitude) without using a topside heat flux when magnetic field topologies consistent with the measured magnetic field were adopted. Magnetic topology affects both suprathermal electron transport and thermal electron heat conduction. The effects of using two different solar irradiance models were also investigated. In particular, photoelectron fluxes and electron temperatures found using the Heliospheric Environment Solar Spectrum Radiation irradiance were higher than those with the Flare Irradiance Spectrum Model-Mars. The electron temperature is shown to affect the O2(+) dissociative recombination rate coefficient, which in turn affects photochemical escape of oxygen from Mars.

magnetic topology↗

NASA NTRSDate not supplied

Characterization of OCO-2 and ACOS-GOSAT biases and errors for flux estimates

We characterize the magnitude of seasonally and spatially varying biases in the National Aeronautics and Space Administration (NASA) Orbiting Carbon Observatory-2 (OCO-2) Version 8 (v8) and the Atmospheric CO2 Observations from Space (ACOS) Greenhouse Gas Observing SATellite (GOSAT) version 7.3 (v7.3) satellite CO2 retrievals by comparisons to measurements collected by the Total Carbon Column Observing Network (TCCON), Atmospheric Tomography (ATom) experiment, and National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory (ESRL) and U. S. Department of Energy (DOE) aircraft, and surface stations. Although the ACOS-GOSAT estimates of the column averaged carbon dioxide (CO2) dry air mole fraction (XCO2) have larger random errors than the OCO-2 XCO2 estimates, and the space-based estimates over land have larger random errors than those over ocean, the systematic errors are similar across both satellites and surface types, 0.6 ± 0.1 ppm. We find similar estimates of systematic error whether dynamic versus geometric coincidences or ESRL/DOE aircraft versus TCCON are used for validation (over land), once validation and co-location errors are accounted for. We also find that areas with sparse throughput of good quality data (due to quality flags and preprocessor selection) over land have ~double the error of regions of high-throughput of good quality data. We characterize both raw and bias-corrected results, finding that bias correction improves systematic errors by a factor of 2 for land observations and improves errors by ~0.2 ppm for ocean. We validate the lowermost tropospheric (LMT) product for OCO-2 and ACOS-GOSAT by comparison to aircraft and surface sites, finding systematic errors of ~1.1 ppm, while having 2-3 times the variability of XCO2. We characterize the time and distance scales of correlations for OCO-2 XCO2 errors, and find error correlations on scales of 0.3 degrees, 5-10 degrees, and 60 days. We find comparable scale lengths for the bias correction term. Assimilation of the OCO-2 bias correction term is used to estimate flux errors resulting from OCO-2 seasonal biases, finding annual flux errors on the order of 0.3 and 0.4 PgC/yr for Transcom-3 ocean and land regions, respectively.

Susan S Kulawik↗

NASA NTRS2004

Exploring the limits of crop productivity: beyond the limits of tipburn in lettuce

The productivity of lettuce in a combination of high light, high temperature, and elevated CO2 has not been commonly studied because rapid growth usually causes a calcium deficiency in meristems called tipburn, which greatly reduces quality and marketability. We eliminated tipburn by blowing air directly onto the meristem, which allowed us to increase the photosynthetic photon flux (PPF) to 1000 micromoles m-2 s-1 (57.6 mol m-2 d-1); two to three times higher than normally used for lettuce. Eliminating tipburn doubled edible yield at the highest PPF level. In addition to high PPF, CO2 was elevated to 1200 micromoles m-2 mol-1, which increased the temperature optimum from 25 to 30 degrees C. The higher temperature increased leaf expansion rate, which improved radiation capture and more than doubled yield. Photosynthetic efficiency, measured as canopy quantum yield in a whole-plant gas exchange system, steadily increased up to the highest temperature of 32 degrees C in high CO2. The highest productivity was 19 g m-2 d-1 of dry biomass (380 g d-1 fresh mass) averaged over the 23 days the plants received light. Without the limitation of tipburn, the combination of high PPF, high temperature, and elevated CO2 resulted in a 4-fold increase in growth rate over productivity in conventional environments.

NASA Discipline Life Support Systems↗