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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 541 records · Page 30

Reaction propagation test. Evaluation of the behavior of nonmetallic materials in hydrogen

Results of tests conducted to evaluate the behavior of nonmetallic materials in hydrogen are described. The reaction propagation test simulates the conditions resulting from the interaction of an electrical wire in an overload condition in contract with a material in the test medium. The test is designed to evaluate the behavior of a material subjected to an energy input (usually heat) sufficient to cause a reaction which propagates to consume larger quantities of the material. Ten nonmetallic materials were evaluated to establish baseline data on the behavior of nonmetallic materials in hydrogen and to characterize, on an initial basis, one mode of material failure considered to be a factor pertinent to the safe use of a material in hydrogen.

Smith, I. D.↗

Pulse energy dependence of subcellular dissection by femtosecond laser pulses

Precise dissection of cells with ultrashort laser pulses requires a clear understanding of how the onset and extent of ablation (i.e., the removal of material) depends on pulse energy. We carried out a systematic study of the energy dependence of the plasma-mediated ablation of fluorescently-labeled subcellular structures in the cytoskeleton and nuclei of fixed endothelial cells using femtosecond, near-infrared laser pulses focused through a high-numerical aperture objective lens (1.4 NA). We find that the energy threshold for photobleaching lies between 0.9 and 1.7 nJ. By comparing the changes in fluorescence with the actual material loss determined by electron microscopy, we find that the threshold for true material ablation is about 20% higher than the photobleaching threshold. This information makes it possible to use the fluorescence to determine the onset of true material ablation without resorting to electron microscopy. We confirm the precision of this technique by severing a single microtubule without disrupting the neighboring microtubules, less than 1 micrometer away. c2005 Optical Society of America.

Non-NASA Center↗

Luminescence induced by dehydration of kaolin - Association with electron-spin-active centers and with surface activity for dehydration-polymerization of glycine

Experimental data concerning emission of light upon dehydration as a function of preheating and pre-gamma-irradiation are correlated with reported studies of electron-spin resonance (ESR) activity after similar pretreatments. The effect of these pretreatments on the kaolin-promoted incorporation of glycine into peptide oligomers in a wet/cold, hot/dry fluctuating environment is compared to their effect on the ESR and luminescent signals. The existence of spectroscopically active centers appears to be loosely anticorrelated with reaction yield; these yields are increased by increasing the overall energy content of the material. It is concluded that some part of the chemical yield is produced by a mechanism involving intrinsic, excited electronic states of the clay crystal lattice. These states may be derived from thermally, interfacially, and/or mechanically induced charge reorganization within interspersed energy levels in the band structure of the material.

Coyne, L.↗

A Monte Carlo-finite element model for strain energy controlled microstructural evolution - 'Rafting' in superalloys

This paper presents a specialized microstructural lattice model, MCFET (Monte Carlo finite element technique), which simulates microstructural evolution in materials in which strain energy has an important role in determining morphology. The model is capable of accounting for externally applied stress, surface tension, misfit, elastic inhomogeneity, elastic anisotropy, and arbitrary temperatures. The MCFET analysis was found to compare well with the results of analytical calculations of the equilibrium morphologies of isolated particles in an infinite matrix.

Gayda, J.↗

High-Energy Space Propulsion Based on Magnetized Target Fusion

Magnetized target fusion is an approach in which a magnetized target plasma is compressed inertially by an imploding material wall. A high energy plasma liner may be used to produce the required implosion. The plasma liner is formed by the merging of a number of high momentum plasma jets converging towards the center of a sphere where two compact toroids have been introduced. Preliminary 3-D hydrodynamics modeling results using the SPHINX code of Los Alamos National Laboratory have been very encouraging and confirm earlier theoretical expectations. The concept appears ready for experimental exploration and plans for doing so are being pursued. In this talk, we explore conceptually how this innovative fusion approach could be packaged for space propulsion for interplanetary travel. We discuss the generally generic components of a baseline propulsion concept including the fusion engine, high velocity plasma accelerators, generators of compact toroids using conical theta pinches, magnetic nozzle, neutron absorption blanket, tritium reprocessing system, shock absorber, magnetohydrodynamic generator, capacitor pulsed power system, thermal management system, and micrometeorite shields.

Thio, Y. C. F.↗

Pulsed radiolysis of model aromatic polymers and epoxy based matrix materials

Models of primary processes leading to deactivation of energy deposited by a pulse of high energy electrons were derived for epoxy matrix materials and polyl-vinyl naphthalene. The basic conclusion is that recombination of initially formed charged states is complete within 1 nanosecond, and subsequent degradation chemistry is controlled by the reactivity of these excited states. Excited states in both systems form complexes with ground state molecules. These excimers or exciplexes have their characteristics emissive and absorptive properties and may decay to form separated pairs of ground state molecules, cross over to the triplet manifold or emit fluorescence. ESR studies and chemical analyses subsequent to pulse radiolysis were performed in order to estimate bond cleavage probabilities and net reaction rates. The energy deactivation models which were proposed to interpret these data have led to the development of radiation stabilization criteria for these systems.

Gupta, A.↗

Origins of life: a comparison of theories and application to Mars

The field of study that deals with the origins of life does not have a consensus for a theory of life's origin. An analysis of the range of theories offered shows that they share some common features that may be reliable predictors when considering the possible origins of life on another planet. The fundamental datum dealing with the origins of life is that life appeared early in the history of the Earth, probably before 3.5 Ga and possibly before 3.8 Ga. What might be called the standard theory (the Oparin-Haldane theory) posits the production of organic molecules on the early Earth followed by chemical reactions that produced increased organic complexity leading eventually to organic life capable of reproduction, mutation, and selection using organic material as nutrients. A distinct class of other theories (panspermia theories) suggests that life was carried to Earth from elsewhere--these theories receive some support from recent work on planetary impact processes. Other alternatives to the standard model suggest that life arose as an inorganic (clay) form and/or that the initial energy source was not organic material but chemical energy or sunlight. We find that the entire range of current theories suggests that liquid water is the quintessential environmental criterion for both the origin and sustenance of life. It is therefore of interest that during the time that life appeared on Earth we have evidence for liquid water present on the surface of Mars.

Review, Academic↗

Theory of extrinsic and intrinsic heterojunctions in thermal equilibrium

A careful analysis of an abrupt heterojunction consisting of two distinct semiconductors either intrinsic or extrinsic is presented. The calculations apply to a one-dimensional, nondegenerate structure. Taking into account all appropriate boundary conditions, it is shown that the intrinsic Fermi level shows a discontinuity at the interface between the two materials which leads to a discontinuity of the valence band edge equal to the difference in the band gap energies of the two materials. The conduction band edge stays continuous however. This result is independent of possible charged interface states and in sharp contrast to the Anderson model. The reasons for this discrepancy are discussed.

Von Ross, O.↗

Solar system sputtering

The sites and materials involved in solar system sputtering of planetary surfaces are reviewed, together with existing models for the processes of sputtering. Attention is given to the interaction of the solar wind with planetary atmospheres in terms of the role played by the solar wind in affecting the He-4 budget in the Venus atmosphere, and the erosion and differentiation of the Mars atmosphere by solar wind sputtering. The study is extended to the production of isotopic fractionation and anomalies in interplanetary grains by irradiation, and to erosion effects on planetary satellites with frozen volatile surfaces, such as with Io, Europa, and Ganymede. Further measurements are recommended of the molecular form of the ejected material, the yields and energy spectra of the sputtered products, the iosotopic fractionation sputtering causes, and the possibility of electronic sputtering enhancement with materials such as silicates.

Tombrello, T. A.↗

Monte Carlo calculations of high energy nucleon meson cascades and applications to galactic cosmic ray transport

Results obtained using a recently developed calculational method for determining the nucleon-meson cascade induced in thick materials by high-energy nucleons and charged pions are presented. The calculational method uses the intranuclear-cascade-evaporation model to treat nonelastic collisions by particles with energies approximately or smaller than GeV and an extrapolation model at higher energies. The following configurations are considered: (1) 19.2-GeV/c protons incident on iron; (2) 30.3-GeV/c protons incident on iron; (3) solar and galactic protons incident on the moon, and (4) galactic protons incident on tissue. For the first three configurations, experimental results are available and comparisons between the experimental and calculated results are given.

Armstrong, T. W.↗

Solid Micro Horn Array (SMIHA) for Acoustic Matching

Transduction of electrical signals to mechanical signals and vice-versa in piezoelectric materials is controlled by the material coupling coefficient. In general in a loss-less material the ratio of energy conversion per cycle is proportional to the square of the coupling coefficient. In practical transduction however the impedance mismatch between the piezoelectric material and the electrical drive circuitry or the mechanical structure can have a significant impact on the power transfer. This paper looks at novel methods of matching the acoustic impedance of structures to the piezoelectric material in an effort to increase power transmission and efficiency. In typical methods the density and acoustic velocity of the matching layer is adjusted to give good matching between the transducer and the load. The approach discussed in this paper utilizes solid micro horn arrays in the matching layer which channel the stress and increase the strain in the layer. This approach is found to have potential applications in energy harvesting, medical ultrasound and in liquid and gas coupled transducers.

power transmission↗

Acoustic behavior of a fibrous bulk material

A semiempirical model is presented describing the acoustic behavior of Kevlar 29, a bulk absorbing material. The model is based on an approximate solution to the one-dimensional equations representing conservation of fluctuating mass, momentum and energy. By treating the material as a momentum sink, theoretical expressions of the material complex propagation constants and characteristic impedance were derived in terms of a single constant. Evaluating the constant at a single frequency for a particular specimen, excellent agreement between prediction and measurement was achieved for a large range of sound frequencies and material porosities and thicknesses. Results show that Kevlar 29 absorbs sound efficiently even at low frequencies. This is explained in terms of a frequency dependent material phase speed.

Hersh, A. S.↗

Magma ocean: Mechanisms of formation

The thermal state of the Earth at the time relevant to formation of a magma ocean was dominated by the great impact that created the Moon. As shown in computer experiments, the iron in the impacting bodies quickly sank to the core of the proto-Earth, while a significant fraction of silicates was pushed far enough out beyond the geosynchronous limit to constitute the main material of the Moon. Most of any atmosphere would have been pushed aside, rather than being expelled in the impact. However, the energy remaining in the material not going to the core or expelled was still sufficient to raise its temperature some 1000's of degrees, enough to vaporize silicates and to generate a strong 'planetary wind': a hydrodynamic expansion carrying with it virtually all volatiles plus appreciable silicates. This expansion was violent and uneven in its most energetic stage, but probably the resulting magma ocean was global. The duration, until cooling, was sufficient for silicates to condense to melt and the duration was probably short. Comparison of the Earth and Venus indicates that the great impact was extraordinarily effective in removing volatiles from the proto-Earth; in particular, the enormous differences in primordial inert gases between the planets demand a catastrophic difference in origin circumstances. On the other hand, the comparison limits the amount of silicates lost by the Earth to a rather minor fraction; most of that expelled in the wind must have condensed soon enough for the silicate to fall back to Earth or be swept up by the proto-Moon. So the Earth was left with a magma ocean. The question is whether sufficient water was retained to constitute a steam atmosphere. Probably not, but unknowns affecting this question are the efficiencies of outgassing in great impacts and in subsequent convective churnings deep in the mantle. During the stage when mantle convection is turbulent, an appreciable fraction of volatiles were also retained at depth, perhaps in some mineral phases not yet well-defined. We still have primordial helium being outgassed.

Kaula, W. M.↗

Aircraft Radiation Shield Experiments--Preflight Laboratory Testing

In the past, measurements onboard a research Boeing 57F (RB57-F) aircraft have demonstrated that the neutron environment within the aircraft structure is greater than that in the local external environment. Recent studies onboard Boeing 737 commercial flights have demonstrated cabin variations in radiation exposure up to 30 percent. These prior results were the basis of the present study to quantify the potential effects of aircraft construction materials on the internal exposures of the crew and passengers. The present study constitutes preflight measurements using an unmoderated Cf-252 fission neutron source to quantify the effects of three current and potential aircraft materials (aluminum, titanium, and graphite-epoxy composite) on the fast neutron flux. Conclusions about the effectiveness of the three selected materials for radiation shielding must wait until testing in the atmosphere is complete; however, it is clear that for shielding low-energy neutrons, the composite material is an improved shielding material over aluminum or titanium.

Singleterry, Robert C., Jr.↗

Assessment of Technologies for Noncryogenic Hybrid Electric Propulsion

The Subsonic Fixed Wing Project of NASA's Fundamental Aeronautics Program is researching aircraft propulsion technologies that will lower noise, emissions, and fuel burn. One promising technology is noncryogenic electric propulsion, which could be either hybrid electric propulsion or turboelectric propulsion. Reducing dependence on the turbine engine would certainly reduce emissions. However, the weight of the electricmotor- related components that would have to be added would adversely impact the benefits of the smaller turbine engine. Therefore, research needs to be done to improve component efficiencies and reduce component weights. This study projects technology improvements expected in the next 15 and 30 years, including motor-related technologies, power electronics, and energy-storage-related technologies. Motor efficiency and power density could be increased through the use of better conductors, insulators, magnets, bearings, structural materials, and thermal management. Energy storage could be accomplished through batteries, flywheels, or supercapacitors, all of which expect significant energy density growth over the next few decades. A first-order approximation of the cumulative effect of each technology improvement shows that motor power density could be improved from 3 hp/lb, the state of the art, to 8 hp/lb in 15 years and 16 hp/lb in 30 years.

Electric Propulsion↗

Evaluation of catalyst for closed cycle operation of high energy pulsed CO2 lasers

Several catalyst materials have been tested for efficiency of converting CO and O2 to CO2 for use in a high energy CO2 laser. The composition of the gas mixtures was monitored by mass spectrometry and gas chromatography. A copper/copper oxide catalyst and a platinum/tin oxide catalyst were used for closed cycle operation of a CO2 laser (0.7 joules/pulse), operating at 10 pulses/sec.

Rogowski, R. S.↗

The Effect of Penetration Depth on Thermal Contrast of NDT by Thermography

Nondestructive evaluation by Thermography (TNDE) is generally classified into two categories, the passive approach and the active approach. The passive approach is usually performed by measuring the natural temperature difference between the ambient and the material or structure to be tested. The active approach, on the other hand, requires the application of an external energy source to stimulate the material for inspection. A laser, a heater, a hot air blower, a high power thermal pulse, mechanical, or electromagnetic energy may provide the energy sources. For the external heating method to inspect materials for defects and imperfection at ambient temperature, a very short burst of heat can be introduced to one of the surfaces or slow heating of the side opposite to the side being observed. Due to the interruption of the heat flow through the defects, the thermal images will reveal the defective area by contrasting against the surrounding good materials. This technique is called transient Thermography, pulse video Thermography, or thermal wave imaging. As an empirical rule, the radius of the smallest defect should be at least one to two times larger than its depth under the surface. Thermography is being used to inspect void, debond, impact damage, and porosity in composite materials. It has been shown that most of the defects and imperfection can be detected. However, the current method of inspection using thermographic technique is more of an art than a practical scientific and engineering approach. The success rate of determining the defect location and defect type is largely depend on the experience of the person who operates thermography system and performs the inspection. The operator has to try different type of heat source, different duration of its application time, as well as experimenting with the thermal image acquisition time and interval during the inspection process. Further-more, the complexity of the lay-up and structure of composites makes it more difficult to determine the optimal operating condition for revealing the defects. In order to develop an optimal thermography inspection procedure, we must understand the thermal behavior inside the material subjected to transient heat in order to interpret the thermal images correctly. Fabrication of finite element models of characteristic defects in composite materials subjected to transient heat will enable the development of appropriate procedure for thermography inspection. Design of phantom defects could be modeled and behavior characterized prior to physically building these test parts. Since production of phantom test parts can be very time consuming and laborious, it is important to design good representative defects.

Chu, Tsuchin Philip↗