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At least 541 records · Page 30

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NASA NTRS1980

Ground cloud hydrogen chloride measurements from three Titan launches at the Kennedy Space Center during 1978 and 1979

Total hydrogen chloride and gaseous hydrogen chloride concentrations were measured in the exhaust cloud produced at three Titan 3 launches at the Kennedy Space Center in March 1978, December 1978, and November 1979 to determine the degree of hydrogen chloride partitioning in a solid rocket exhaust cloud between gaseous hydrogen chloride and hydrochloric acid aerosol as a function of ambient relative humidity. Moderately low relative humidity conditions were present during a daytime launch on Mar 25, 1978, and high relative humidity conditions were present during a nighttime launch on December 13, 1978. Gaseous hydrogen chloride concentrations and meteorological data, as a function of time after launch, are presented. Hydrogen chloride is present in both the gaseous and aerosol phase in the exhaust cloud. Total HCl concentrations ranged from 18 parts per million by volume (ppm) several minutes after launch down to 1 ppm after the cloud stabilization period, depending on the meteorological conditions. Gaseous HCl concentrations ranged from 2 to 3 ppm several minutes after launch to less than 1 ppm after cloud stabilization. These measured concentrations indicated significant HCl aerosol formation.

Seabacher, D. I.↗

NASA NTRS1981

Ultra-high modulus organic fiber hybrid composites

An experimental organic fiber, designated Fiber D, was characterized, and its performance as a reinforcement for composites was investigated. The fiber has a modulus of 172 GPa, tensile strength of 3.14 GPa, and density of 1.46 gm/cu cm. Unidirectional Fiber D/epoxy laminates containing 60 percent fiber by volume were evaluated in flexure, shear, and compression, at room temperature and 121 C in both the as fabricated condition and after humidity aging for 14 days at 95 percent RH and 82 C. A modulus of 94.1 GPa, flexure strength of 700 MPa, shear strength of 54 MPa, and compressive strength of 232 MPa were observed at room temperature. The as-fabricated composites at elevated temperature and humidity aged material at room temperature had properties 1 to 20 percent below these values. Combined humidity aging plus evaluated temperature testing resulted in even lower mechanical properties. Hybrid composite laminates of Fiber D with Fiber FP alumina or Thornel 300 graphite fiber were also evaluated and significant increases in modulus, flexure, and compressive strengths were observed.

Champion, A. R.↗

NASA NTRS1981

Effect of water vapor on sound absorption in nitrogen at low frequency/pressure ratios

Sound absorption measurements were made in N2-H2O binary mixtures at 297 K over the frequency/pressure range f/P of 0.1-2500 Hz/atm to investigate the vibrational relaxation peak of N2 and its location on f/P axis as a function of humidity. At low humidities the best fit to a linear relationship between the f/P(max) and humidity yields an intercept of 0.013 Hz/atm and a slope of 20,000 Hz/atm-mole fraction. The reaction rate constants derived from this model are lower than those obtained from the extrapolation of previous high-temperature data.

Zuckerwar, A. J.↗

NASA NTRS1981

Dependence of tropospheric temperature on the parameterization of cumulus convection in the GLAS model of the general circulation

Analysis of the simulation of seasonal change by the GLAS model of the general circulation reveals deficiencies in the simulation of tropospheric temperature and of convective cloud cover. These interrelated deficiencies are due to a spurious doubling from January to July in the convective cloud cover of the Northern Hemisphere. The spurious doubling, in turn, is due to the oversensitivity of cumulus convection, in the GLAS model, to the specific humidity of the lower atmosphere. The oversensitivity is enhanced by a feedback mechanism which perpetuates the existence of deep, penetrative convective clouds at certain preferred locations. The cumulus parameterization scheme has been modified to more realistically relate the onset of cumulus convection to the relative humidity of the lower atmosphere. The modified parameterization has improved the simulation of tropospheric temperature, planetary albedo and convective cloud cover as well as their seasonal variations. Comparison of this experiment with its control has shown a high degree of interrelation among these fields in the GLAS model and has demonstrated the sensitivity of the atmospheric heat budget to the design of the cumulus parameterization scheme. Also, the modification to the cumulus scheme has demonstrated a plausible mechanism to explain the correlation between convective cloud cover and relative humidity in the real atmosphere.

Helfand, H. M.↗

NASA NTRS1981

Comparison of observed and computed brightness temperatures for the HIRS2 and MSU sounders on TIROS-N

Given the radiosonde temperature and humidity profile, brightness temperatures for the temperature sounding IR channels on HIRS 2 were calculated. The temperature profile was interpolated to 53 levels between 1000 and 30 mb assuming temperature to be linear in the logarithm of the pressure between the mandatory levels. The 11 levels above 30 mb were extrapolated according to climatology. The surface was taken to be the climatological sea surface temperature. The specific humidity was interpolated between mandatory levels assuming a p(n) dependence. A specific humidity corresponding to a climatological water vapor mixing ratio of 2 ppmv was assumed at and above 100 mb. Zonally averaged climatological ozone profiles were used to compute the ozone component of the transmittance.

Susskind, J.↗

NASA NTRS1982

Calculation of composition distribution of ultrafine ion-H2O-H2SO4 clusters using a modified binary ion nucleation theory

Thomson's ion nucleation theory was modified to include the effects of curvature dependence of the microscopic surface tension of field dependent, nonlinear, dielectric properties of the liquid; and of sulfuric acid hydrate formation in binary mixtures of water and sulfuric acid vapors. The modified theory leads to a broadening of the ion cluster spectrum, and shifts it towards larger numbers of H2O and H2SO4 molecules. Whether there is more shifting towards larger numbers of H2O or H2SO4 molecules depends on the relative humidity and relative acidity of the mixture. Usually, a broadening of the spectrum is accompanied by a lowering of the mean cluster intensity. For fixed values of relative humidity and relative acidity, a similar broadening pattern is observed when the temperature is lowered. These features of the modified theory illustrate that a trace of sulfuric acid can facilitate the formation of ultrafine, stable, prenucleation ion clusters as well as the growth of the prenucleation ion clusters towards the critical saddle point conditions, even with low values of relative humidity and relative acidity.

Singh, J. J.↗

NASA NTRS1981

A moisture analysis procedure utilizing surface and satellite data

Four analyses have been produced by a moisture analysis procedure which uses satellite, precipitation and surface specific humidity data to augment the standard radiosonde observations (RAOB) of moisture: (1) using RAOB data only, (2) using RAOB data supplemented by data obtained from the surface observations of specific humidity, (3) using RAOB data supplemented only by satellite and precipitation data, and (4) employing all sources of data. Penn State University Mesoscale Model forecasts were performed to determine the effect of the high-resolution moisture analyses. For the data set used, supplementary satellite and rainfall data was found to improve the precipitation forecast more than surface humidity data and permitted the model to produce rain rates during the first four hours of the forecast that were 100% larger and more realistic than those produced without these data.

Wolcott, S. W.↗

NASA NTRS1983

Propagation of sound through the Earth's atmosphere

The data collected at a pressure of one atmosphere for the different temperatures and relative humidities of the air-water vapor mixtures is summarized. The dew point hygrometer used in these measurements did not give reliable results for dew points much above the ambient room temperature. For this reason measurements were not attempted at the higher temperatures and humidities. Viscous wall losses in the resonant tube at 0 C so dominate the molecular relaxation of nitrogen, in the air-water vapor mixture, that reliable data could not be obtained using the free decay method in a resonant tube at one atmosphere. In an effort to obtain viable data at these temperatures, measurements were performed at a pressure of 10 atmospheres. Since the molecular relaxation peak is proportional to the pressure and the viscous losses are proportional to the inverse square root of the pressure the peak height should be measurable at the higher pressure. The tradeoff here is that at 10 atmospheres; the highest relative humidity attainable is 10 percent. The data collected at 10 atmospheres is also summarized.

Meredith, R. W.↗

NASA NTRS1983

Tribological measurements on a Charnley-type artificial hip joint

A total hip simulator was used to determine the friction and wear properties of Charnley-type (316L stainless steel balls and sterile ultrahigh molecular weight polyethylene cups) hip prostheses. Three different sets of specimens were tested to 395,000, 101,500 and 233,000 walking cycles, respectively. All tests were run unlubricated, at ambient conditions (22 to 26 C, 30 to 50 percent relative humidity), at 30 walking cycles per minute, under a dynamic load simulating walking. Polyethylene cup wear rates ranged from 1.4 to 39 ten billions cu m which corresponds to dimensional losses of 4.0 to 11 microns per year. Although these wear rates are lower than those obtained from other hip simulators and from in vivo X-ray measurements, they are comparable when taking run-in and plastic deformation into account. Maximum tangential friction forces ranged from 93 to 129 N under variable load (267 to 3090 N range) and from 93 to 143 N under a static load of 3090 N. A portion of one test 250,000 walking cycles) run under dry air ( 1 percent relative humidity) yielded a wear rate almost 6 times greater than that obtained under wet air ( 70 percent relative humidity) conditions.

Jones, W. R., Jr.↗

NASA NTRS1982

Rare earth elements in the sedimentary cycle - A pilot study of the first leg

The effects of source rock composition and climate on the natural abundances of rare elements (REE) in the first leg of the sedimentary cycle are evaluated using a study with Holocene fluvia sands. The medium grained sand fraction of samples collected from first order streams exclusively draining granitic plutons in Montana (semi-arid), Georgia (humid), and South Carolina (humid) are analyzed. It is found that the REE distribution patterns (but not the total absolute abundances) of the daughter sands are very similar, despite compositional differences between parent plutons. Averages of the three areas are determined to have a La/Lu ratio of about 103, showing a depletion of heavy REE with respect to an average granite (La/Lu = 79) or the composition of North American Shales (La/Lu = 55). However, the Eu/Sm ratio in sands from these areas is about 0.22, which is very close to this ratio in North American Shales (0.21), although the overall REE distribution of these sands is not similar to that of the North American Shales in any way. It is concluded that the major rock type, but neither its minor subdivisions nor the climate, controls the REE distribution patterns in first cycle daughter sands, although the total and the parent rock-normalized abundances of REE in sands from humid areas are much lower than those in sands from arid areas.

Basu, A.↗

NASA NTRS1984

Preprototype SAWD subsystem

A regenerable, three man preprototype solid amine, water desorbed (SAWD) CO2 removal and concentation subsystem was designed, fabricated, and successfully acceptance tested by Hamilton Standard. The preprototype SAWD incorporates a single solid amine canister to perform the CO2 removal function, an accumulator to provide the CO2 storage and delivery function, and a microprocessor which automatically controls the subsystem sequential operation and performance. The SAWD subsystem was configured to have a CO2 removal and CO2 delivery capability at the rate of 0.12 kg/hr (0.264 lb/hr) over the relative humidity range of 35 to 70%. The controller was developed to provide fully automatic control over the relative humidity range via custom software that was generated specifically for the SAWD subsystem. The preprototype SAWD subsystem demonstrated a total of 281 hours (208) cycles of operation during ten acceptance tests that were conducted over the 3 to 70% relative humidity range. This operation was comprised of 178 hours (128 cycles) in the CO2 overboard mode and 103 hours (80 cycles) in the CO2 reduction mode. The average CO2 removal/delivery rate met or exceeded the design specification rate of 0.12 kg/hr (0.254 lb/hr) for all ten of the acceptance tests.

Nalette, T. A.↗

NASA NTRS1984

Low-frequency sound absorption measurements in air

Thirty sets of sound absorption measurements in air at a pressure of 1 atmosphere are presented at temperatures from 10 C to 50 C, relative humidities from 0 to 100 percent, and frequencies from 10 to 2500 Hz. The measurements were conducted by the method of free decay in a resonant tube having a length of 18.261 m and bore diameter of 0.152 m. Background measurements in a gas consisting of 89.5 percent N2 and 10.5 percent Ar, a mixture which has the same sound velocity as air, permitted the wall and structural losses of the tube to be separated from the constituent absorption, consisting of classical rotational and vibrational absorption, in the air samples. The data were used to evaluate the vibrational relaxation frequencies of N2 and/or O2 for each of the 30 sets of meteorological parameters. Over the full range of humidity, the measured relaxation frequencies of N2 in air lie between those specified by ANSI Standard S1.26-1978 and those measured earlier in binary N2H2O mixtures. The measured relaxation frequencies could be determined only at very low values of humidity, reveal a significant trend away from the ANSI standard, in agreement with a prior investigation.

Zuckerwar, A. J.↗

NASA NTRS1984

Mixed Layers and Satellite Retrievals

As part of the process to determine whether it is possible to retrieve boundary layer structure with the current sounding techniques, temperature retievals were performed for radiosonde profiles that showed temperature inversions. It was found that when temperature inversions exceed 8 to 10 C a retrieval will indeed show a temperature increase with height over a limited vertical distance. For weaker inversions retrieved temperatures are generally smoothly decreasing with height. It is, however, impossible to determine the actual mixed layer height from the retrievals. Whether the water vapor channels could be used in observing mixed layer structure was investigated. Temperature inversions are accompanied by significant drops in relative humidity. While this effect is very pronounced in parts of the trade wind regimes with relative humidity drops of up to 60%, it is widespread in other areas of the ocean as well. A simulation experiment was performed in which brightness temperatures were computed for smooth temperature and humidity profiles and compared with those computed from inversion profiles.

Boers, R.↗

NASA NTRS1985

Preparation of silicon carbide-silicon nitride fibers by the pyrolysis of polycarbosilazane precursors

The development of silicon carbide-silicon nitride fibers (SiC-Si3N4) by the pyrolysis of polycarbosilazane precursors is reviewed. Precursor resin, which was prepared by heating tris(N-methylamino)methylsilane or tris(N-methylamino)phenylsilane to about 520 C, was drawn into fibers from the melt and then made unmeltable by humidity conditioning at 100 C and 95 percent relative humidity. The humidity treated precursor fibers were pyrolyzed to ceramic fibers with good mechanical properties and electrical resistivity. For example, SiC-Si3N4 fibers derived from tris(N-methylamino)methylsilane had a tensile rupture modulus of 29 million psi and electrical resistivity of 6.9 x ten to the 8th power omega-cm, which is ten to the twelfth power times greater than that obtained for graphite fibers.

Penn, B. G.↗

NASA NTRS1985

Low-frequency absorption of sound in air

Zuckerwar, A. J.↗

NASA NTRS1986

Effect of additional heat treatment of 2024-T3 on the growth of fatigue crack in air and in vacuum

In order to determine the influence of ductility on the fatigue crack growth rate of aluminum alloys, fatigue tests were carried out on central notched specimens of 2024-T3 and 2024-T8 sheet material. The 2024-T8 material was obtained by an additional heat treatment applied on 2024-T3 (18 hours at 192 C), which increased the static yield strength from 43.6 to 48.9 kgf/sq mm. A change in the ultimate strength was not observed. Fatigue tests were carried out on both materials in humid air and in high vacuum. According to a new crack propagation model, crack extension is supported to be caused by a slip-related process and debonding triggered by the environment. This model predicts an effect of the ductility on the crack growth rate which should be smaller in vacuum than in humid air; however, this was not confirmed. In humid air the crack-growth rate in 2024-T8 was about 2 times faster than in 2024-T3, while in vacuum the ratio was about 2.5. Crack closure measurements gave no indications that crack closure played a significant role in both materials. Some speculative explanations are briefly discussed.

Louwaard, E. P.↗

NASA NTRS1985

Long term evaluation of grease type lubricants in selected environments

The operating life of grease-type lubricants in various environments is evaluated. The test equipment and procedures are described. The lubricants were placed in the rolling element bearings of hysteresis synchronous motors and exposed to environments of a vacuum at 60 C, a vacuum at 93.3 C, 10 psia oxygen at 90 percent relative humidity at 60 C, 14.7 psia air at 90 percent relative humidity at 60 C, start-stop operation, and low temperature start capability for one or five years. The weights of the bearings were measured before and after lubrication; the weight data for each environment are analyzed. The data reveal that the high viscosity index perfluoroalkypolyether grease performs the best in a vacuum at moderate and high temperature, in low temperature start capability, and in start-stop steps; however, the grease does not work well in oxidizing and high relative humidity environments.

Dolan, F. J.↗

NASA NTRS1987

Characterization of the LTC catalyst: Performance against common air pollutants

One of the important qualities of the Low-Temperature Catalyst (LTC) is the rapid oxidation of carbon monoxide to carbon dioxide under a wide variety of conditions. The catalytic material is a palladium-copper activated complex which reacts with various contaminant molecules through a continuous oxidation/reduction cycle. The alumina substrate enhances LTC activity with its favorable surface chemistry and very high surface area. About 10 percent surface water is necessary to facilitate the oxidation of CO. This reaction shows a log-log dependence on contact time, suggesting a Langmuir-Hinshelwood mechanism. In the tube tests, LTC removed 90 to 100 percent of contaminating carbon monoxide in the temperature region of 20 to 4000 C, and at ambient over a range of 25 to 65 percent relative humidity. In contrast, NO2 is chemisorbed by the LTC/alumina material--the amount strongly dependent on temperature increases but independent of humidity. The LTC catalyst has demonstrated excellent capability to remove an important variety of hazardous pollutant gases which are common factors to poor indoor air quality. The Instapure Air Filtration System incorporates the LTC catalyst in a 50:50 mixture with activated carbon to effectively remove particulate, odors, and hazardous gases at room temperature and humidities. The ability to remove hazardous gases is unique for the category of portable air filtration equipment. The wide variety of pollutant gases that LTC removes suggests that catalytic technology is adaptable to a considerable range of commercial and industrial applications.

Collins, Marcia F.↗