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All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Quantitative assessment of selenium diffusion and passivation in CdSeTe solar cells probed by spatially resolved cathodoluminescence

The introduction of selenium in CdSeTe/CdTe solar cells has led to improved device performances attributed to the passivation of bulk defects. In this work, high-resolution cathodoluminescence experiments are performed on a series of CdSeTe/CdTe thin films with different Se concentrations to quantify the mechanisms and the passivation role of Se. We demonstrate a universal dependence between the Se concentration and the radiative efficiency and a ten-fold enhancement of the luminescence between CdTe and CdSe 0.4 Te 0.6 . Raw luminescence maps are converted into maps of the Se concentration, revealing its graded profile within the stack. We demonstrate the diffusion of Se along CdTe grain boundaries induced by the cadmium chloride annealing treatment and determine the diffusion coefficients, which are more than eight times higher at grain boundaries than in grain interiors. These results provide microscopic insights into the distribution of Se and its impact on the passivation of CdSeTe/CdTe solar cells.

14 SOLAR ENERGY↗
DOE OSTI2012

THE SIZE EVOLUTION OF PASSIVE GALAXIES: OBSERVATIONS FROM THE WIDE-FIELD CAMERA 3 EARLY RELEASE SCIENCE PROGRAM

We present the size evolution of passively evolving galaxies at z {approx} 2 identified in Wide-Field Camera 3 imaging from the Early Release Science program. Our sample was constructed using an analog to the passive BzK galaxy selection criterion, which isolates galaxies with little or no ongoing star formation at z {approx}> 1.5. We identify 30 galaxies in {approx}40 arcmin{sup 2} to H < 25 mag. By fitting the 10-band Hubble Space Telescope photometry from 0.22 {mu}m {approx}< {lambda}{sub obs} {approx}< 1.6 {mu}m with stellar population synthesis models, we simultaneously determine photometric redshift, stellar mass, and a bevy of other population parameters. Based on the six galaxies with published spectroscopic redshifts, we estimate a typical redshift uncertainty of {approx}0.033(1 + z). We determine effective radii from Sersic profile fits to the H-band image using an empirical point-spread function. By supplementing our data with published samples, we propose a mass-dependent size evolution model for passively evolving galaxies, where the most massive galaxies (M{sub *} {approx} 10{sup 11} M{sub Sun }) undergo the strongest evolution from z {approx} 2 to the present. Parameterizing the size evolution as (1 + z){sup -{alpha}}, we find a tentative scaling of {alpha} Almost-Equal-To (- 0.6 {+-} 0.7) + (0.9 {+-} 0.4)log (M{sub *}/10{sup 9} M{sub Sun }), where the relatively large uncertainties reflect the poor sampling in stellar mass due to the low numbers of high-redshift systems. We discuss the implications of this result for the redshift evolution of the M{sub *}-R{sub e} relation for red galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

DEEP NEAR-INFRARED SPECTROSCOPY OF PASSIVELY EVOLVING GALAXIES AT z {approx}> 1.4

We present the results of new near-IR spectroscopic observations of passive galaxies at z {approx}> 1.4 in a concentration of BzK-selected galaxies in the COSMOS field. The observations have been conducted with Subaru/MOIRCS, and have resulted in absorption lines and/or continuum detection for 18 out of 34 objects. This allows us to measure spectroscopic redshifts for a sample that is almost complete to K{sub AB} = 21. COSMOS photometric redshifts are found in fair agreement overall with the spectroscopic redshifts, with a standard deviation of {approx}0.05; however, {approx}30% of objects have photometric redshifts systematically underestimated by up to {approx}25%. We show that these systematic offsets in photometric redshifts can be removed by using these objects as a training set. All galaxies fall in four distinct redshift spikes at z = 1.43, 1.53, 1.67, and 1.82, with this latter one including seven galaxies. SED fits to broadband fluxes indicate stellar masses in the range of {approx}4-40 Multiplication-Sign 10{sup 10} M{sub Sun} and that star formation was quenched {approx}1 Gyr before the cosmic epoch at which they are observed. The spectra of several individual galaxies have allowed us to measure their H{delta}{sub F} indices and the strengths of the 4000 A break, which confirms their identification as passive galaxies, as does a composite spectrum resulting from the co-addition of 17 individual spectra. The effective radii of the galaxies have been measured on the COSMOS HST/ACS i{sub F814W}-band image, confirming the coexistence at these redshifts of passive galaxies, which are substantially more compact than their local counterparts with others that follow the local effective radius-stellar mass relation. For the galaxy with the best signal-to-noise spectrum we were able to measure a velocity dispersion of 270 {+-} 105 km s{sup -1} (error bar including systematic errors), indicating that this galaxy lies closely on the virial relation given its stellar mass and effective radius.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Pd nanoparticles on ZnO-passivated porous carbon by atomic layer deposition: an effective electrochemical catalyst for Li-O 2 battery

Uniformly dispersed Pd nanoparticles on ZnO-passivated porous carbon were synthesized via an atomic layer deposition (ALD) technique, which was tested as a cathode material in a rechargeable Li-O-2 battery, showing a highly active catalytic effect toward the electrochemical reactions-in particular, the oxygen evolution reaction. Transmission electron microscopy (TEM) showed discrete crystalline nanoparticles decorating the surface of the ZnO-passivated porous carbon support in which the size could be controlled in the range of 3-6 nm, depending on the number of Pd ALD cycles performed. X-ray absorption spectroscopy (XAS) at the Pd Kedge revealed that the carbon-supported Pd existed in a mixed phase of metallic palladium and palladium oxide. The ZnO-passivated layer effectively blocks the defect sites on the carbon surface, minimizing the electrolyte decomposition. Our results suggest that ALD is a promising technique for tailoring the surface composition and structure of nanoporous supports for Li-O-2 batteries.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2017

Delayed charge recovery discrimination of passivated surface alpha events in P-type point-contact detectors

The Majorana Demonstrator searches for neutrinoless double-beta decay of 76 Ge using arrays of high-purity germanium detectors. If observed, this process would demonstrate that lepton number is not a conserved quantity in nature, with implications for grand-unification and for explaining the predominance of matter over antimatter in the universe. A problematic background in such large granular detector arrays is posed by alpha particles. In the Majorana Demonstrator, events have been observed that are consistent with energy- degraded alphas originating on the passivated surface, leading to a potential background contribution in the region-of-interest for neutrinoless double-beta decay. However, it is also observed that when energy deposition occurs very close to the passivated surface, charges drift through the bulk onto that surface, and then drift along it with greatly reduced mobility. This leads to both a reduced prompt signal and a measurable change in slope of the tail of a recorded pulse. In this contribution we discuss the characteristics of these events and the development of a filter that can identify the occurrence of this delayed charge recovery, allowing for the efficient rejection of passivated surface alpha events in analysis.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Passive radiative thermal management using phase-change metasurfaces

Abstract Realizing innovative composite materials with passive thermal management capabilities and minimal ecological footprints is a challenging but much sought-after goal that would have a transformative effect on renewable energy sciences. We demonstrate an environmentally friendly metasurface utilizing vanadium dioxide (VO 2 ) that offers responsiveness to ambient temperature and potentially long-term stability. The metasurface enables passive thermal management by self-adjusting its absorptivity and emissivity response over a broad bandwidth ranging from visible to mid-infrared (IR) wavelengths. Above the VO 2 phase transition the metasurface exhibits increased mid-IR emissivity and reduced visible/near-IR absorptivity, creating an efficient radiative emission channel in the first atmospheric transparency window with reduced absorption of solar radiation. In contrast, below VO 2 ’s transition temperature, the metasurface increasingly absorbs sun light while minimizing mid-IR radiative heat losses. Moreover, a functional silicon layer eliminates the need for an additional capping layer commonly employed to protect VO 2 from environmental degradation. The additional protective layer often impedes the use and performance of VO 2 based devices in terrestrial as well as spacecraft applications. Therefore, the proposed durable and eco-friendly metasurface will be an excellent candidate for essential passive thermal regulation systems across residential and terrestrial applications.

42 ENGINEERING↗
DOE OSTI2025

Strategies for preparing and analyzing thin passive films with atom probe tomography

Atom probe tomography provides a unique, three-dimensional map of elemental and isotopic distributions over a wide range of materials with near-atomic scale resolution and is particularly strong at analyzing buried interfaces within materials. However, it is much more difficult to apply atom probe to the analysis of nanoscale surface films, such as those formed during alloy passivation, where unique challenges persist for sample preparation and data collection. Here, we present sample preparation strategies involving the deposition of a < 100 nm capping layer that enables reliable characterization of thin passive films approximately 2–5 nm thick formed on binary and multi-principal element alloys via atom probe tomography. Several capping layer materials (Pt, Ti, Ni/Cr bi-layer) and deposition methods are contrasted. Our results indicate a sputtered Ni/Cr bi-layer enables the characterization of the entire passive film and concentration profiles that can easily be interpreted to clearly distinguish base alloy/passive film/capping layer interfaces. Lastly, we highlight ongoing challenges and opportunities for this experimental approach.

Kautz, Elizabeth J. [University of Florida]↗
DOE OSTI2011

Mean-field diffusivities in passive scalar and magnetic transport in irrotational flows

Certain aspects of the mean-field theory of turbulent passive scalar transport and of mean-field electrodynamics are considered with particular emphasis on aspects of compressible fluids. It is demonstrated that the total mean-field diffusivity for passive scalar transport in a compressible flow may well be smaller than the molecular diffusivity. This is in full analogy to an old finding regarding the magnetic mean-field diffusivity in an electrically conducting turbulently moving compressible fluid. These phenomena occur if the irrotational part of the motion dominates the vortical part, the Peclet or magnetic Reynolds number is not too large, and, in addition, the variation of the flow pattern is slow. For both the passive scalar and the magnetic cases several further analytical results on mean-field diffusivities and related quantities found within the second-order correlation approximation are presented, as well as numerical results obtained by the test-field method, which applies independently of this approximation. Particular attention is paid to nonlocal and noninstantaneous connections between the turbulence-caused terms and the mean fields. Two examples of irrotational flows, in which interesting phenomena in the above sense occur, are investigated in detail. In particular, it is demonstrated that the decay of a mean scalar in a compressible fluid under the influence of these flows can be much slower than without any flow, and can be strongly influenced by the so-called memory effect, that is, the fact that the relevant mean-field coefficients depend on the decay rates themselves.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Passivity-Short-based Stability Analysis on Electricity Market Trading System Considering Negative Price

This paper deals with a distributed decision method for determining the electricity price considering the negative price in the market trading. In addition, we analyze the stability and convergence properties for the market trading system using the concept of passivity-short. At first, mathematical models of market participants' behavior which maximize their own profits are discussed. Then, we construct a trading system based on dynamic pricing considering plug and play operation that each market participant intermittently participates in market trading. As for the optimal electricity price, even if the optimal price might be negative, we indicate the stability of the system can be guaranteed by using passivity-short which is a relaxed concept of passivity. Finally, numerical simulation results illustrate that each value decided by the market trading converges to the optimal value.

Muto, Keita↗
DOE OSTI2023

Passivity-Based Control of Grid Forming and Grid Following Converters in Microgrids

With the integration of more and more power electronics devices into the grid, it is not easy to guarantee the stability of the whole system due to the complexity of the control structure of various power converters. In this paper, we consider grid-forming and grid-following converters in one microgrid, in which the grid-forming converters support the voltage and frequency of the microgrid and the grid-following converters inject their maximum power into the microgrid. To handle the stability issue, the passivity principle is applied to guarantee the stability of the whole microgrid. We ensure every grid-following converter satisfies the passivity via the port-controlled Hamiltonian method. In addition, we apply the passivity-based proportional-resonant controller to the grid-forming converter. One of the advantages of the proposed method is that the phase lock loop system is eliminated, which may cause stability issues. Simulation results show that the proposed method can control the microgrid effectively.

Gui, Yonghao (Young)↗
DOE OSTI2018

23% efficient n-type crystalline silicon solar cells with passivated partial rear contacts

© 2018 IEEE. Over the past three years a new family of high efficiency n-type crystalline silicon cells featuring passivated partial rear contacts (PRC) has emerged. These cells take advantage of the unique contact properties obtained by introducing thin metal compound interlayers, such as TiO x and LiFx, between the metallic electrode and the silicon absorber. This paper explores the concept and potential advantages of the n-type passivated PRC cell. In particular, the recent fabrication of a cell at 23.1%, featuring a less-than 1% TiOx/LiFx /Al passivated PRC, demonstrates the compatibility of this concept with high efficiency designs.

Bullock, James↗
DOE OSTI2021

Transparent MgO for Back-Contact Passivation of CdTe-Based Solar Cells

The passivating effects of MgO have been studied by integrating into an existing superstrate CdTe thin film solar cell device architecture. When implemented as an emitter to replace the typical MZO, the device performance was below par, but improved PL and TRPL was detected with significant carrier lifetimes in comparison to the MZO devices. However, when integrated at the back, the PL signal was detected upon the illumination of excitation laser from the back. This has opened the possibility of probing the back of the CdTe thin film solar cells with transparent back contact with improved back passivation and a bifacial device structure. Further, the TRPL measurements suggests that the MgO shows passivating effects to a CdTe surface irrespective of method of deposition implemented.

bifacial↗
DOE OSTI2013

Review of passive corrosion studies of carbon steel in concrete in the context of disposal of HLW and spent fuel in Belgium

The Supercontainer (SC) design is the preferred option for the final disposal of high level nuclear waste and spent fuel in Belgium. The SC consists of a carbon steel overpack surrounded by a very thick concrete buffer, contained within a stainless steel envelope. In this highly alkaline environment of the annulus and under normal conditions (without the ingress of aggressive species), the carbon steel overpack will be protected by a passive oxide film, which is believed to result in very low and almost negligible uniform corrosion rates. This paper discusses the modeling efforts simulating the evolution of various parameters that can potentially influence the corrosion processes (temperature, pH, saturation degree and concentration of aggressive species). The outcome of the Belgian experimental program to study the passive uniform corrosion of carbon steel in concrete is also addressed. Long-term uniform corrosion rates are determined using different independent techniques (hydrogen gas measurements by means of manometric gas cells or pressure transducers, long-term passive current density measurements). (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2022

Multifunctional fiber-reinforced composites for passive sensing and energy harvesting with enhanced mechanical performance

Fiber-reinforced polymer composites (FRPCs) are valid alternatives to metals, especially in the aerospace industry, for their superior strength-to-weight ratio. FRPCs are generally manufactured by stacking layers of fibers and infusing them with epoxy-based adhesives to result in laminates. Such layer-by-layer structure often ensues a poor interlaminar property of the composites. Additionally, FRPCs can sustain complex damage modes because of their inherent anisotropic characteristics. For example, delamination can occur due to low-velocity impact at a subsurface level, which can result in premature catastrophic failures if undetected. Thus, structural monitoring is crucial to identify such damage. Point-based sensors (e.g., strain gauges, accelerometers, among many) can be embedded in the FRPCs for structural monitoring. However, their electrical power demand often embroils their usage. Therefore, the main objective of this research is to design and implement multifunctional composites that can simultaneously perform passive sensing and energy harvesting while exhibiting better mechanical performance. Previous research efforts have demonstrated that a continuous feed-through deposition of functional materials on fiber surfaces simultaneously enhanced the mechanical and sensing properties of the FRPCs. This study explores a similar approach to encode passive sensing and energy harvesting properties in the FRPCs by integrating ferroelectric microparticles on the fiber surfaces. Upon ensuring their superior interlaminar shear strength, sensing and energy harvesting properties were characterized through experimental studies. The outcome is a multifunctional composite fabricated by coating the fibers with functional microparticles through a high throughput, scalable, and low-cost approach that enables passive sensing, energy harvesting, and improved mechanical performance.

Gupta, Sumit↗
DOE OSTI2012

A real-time respiration position based passive breath gating equipment for gated radiotherapy: A preclinical evaluation

Purpose: To develop a passive gating system incorporating with the real-time position management (RPM) system for the gated radiotherapy. Methods: Passive breath gating (PBG) equipment, which consists of a breath-hold valve, a controller mechanism, a mouthpiece kit, and a supporting frame, was designed. A commercial real-time positioning management system was implemented to synchronize the target motion and radiation delivery on a linear accelerator with the patient's breathing cycle. The respiratory related target motion was investigated by using the RPM system for correlating the external markers with the internal target motion while using PBG for passively blocking patient's breathing. Six patients were enrolled in the preclinical feasibility and efficiency study of the PBG system. Results: PBG equipment was designed and fabricated. The PBG can be manually triggered or released to block or unblock patient's breathing. A clinical workflow was outlined to integrate the PBG with the RPM system. After implementing the RPM based PBG system, the breath-hold period can be prolonged to 15-25 s and the treatment delivery efficiency for each field can be improved by 200%-400%. The results from the six patients showed that the diaphragm motion caused by respiration was reduced to less than 3 mm and the position of the diaphragm was reproducible for difference gating periods. Conclusions: A RPM based PBG system was developed and implemented. With the new gating system, the patient's breath-hold time can be extended and a significant improvement in the treatment delivery efficiency can also be achieved.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2014

WE-F-16A-03: 3D Printer Application in Proton Therapy: A Novel Method to Deliver Passive-Scattering Proton Beams with a Fixed Range and Modulation for SRS and SRT

Purpose: To present a novel technique to deliver passive-scattering proton beam with fixed range and modulation using a 3D printed patient-specific bolus for proton stereotactic radiosurgery and radiotherapy. Methods: A CIRS head phantom was used to simulate a patient with a small brain lesion. A custom bolus was created in the Eclipse Treatment Planning System (TPS) to compensate for the different water equivalent depths from the patient surface to the target from multiple beam directions. To simulate arc therapy, a plan was created on the initial CT using three passive-scattering proton beams with a fixed range and modulations irradiating from different angles. The DICOM-RT structure file of the bolus was exported from the TPS and converted to STL format for 3D printing. The phantom was rescanned with the printed custom bolus and head cup to verify the dose distribution comparing to the initial plan. EBT3 films were placed in the sagital plane of the target to verify the delivered dose distribution. The relative stopping power of the printing material(ABSplus-P430) was measured using the Zebra multi-plate ion chamber. Results: The relative stopping power of the 3D printing material, ABSplus-P430 was 1.05 which is almost water equivalent. The dose difference between verification CT and Initial CT is almost negligible. Film measurement also confirmed the accuracy for this new proton delivery technique. Conclusion: Our method using 3D printed range modifiers simplify the treatment delivery of multiple passive-scattering beams in treatment of small lesion in brain. This technique makes delivery of multiple beam more efficient and can be extended to allow arc therapy with proton beams. The ability to create and construct complex patient specific bolus structures provides a new dimension in creating optimized quality treatment plans not only for proton therapy but also for electron and photon therapy.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

SU-E-J-142: Prompt Gamma Emission Measurements From a Passively Scattered Proton Beam On Targets Containing 16O, 12C and 14N

Purpose: To measure the prompt gamma emission from the important elements found in tissue ({sup 16}O,{sup 12}C and {sup 14}N) in a clinical passive-scatter treatment environment. Methods: The targets (composed of water, Perspex, graphite and liquid nitrogen) were irradiated with a 200 MeV passive-scatter proton beam and the discrete prompt gamma energy spectra was detected by a high resolution 2′ × 2′ LaBr. detector. In order to reduce the high level of radiation produced by the beam line elements, the detector was surrounded by 10 cm of lead to attenuate the scattered gamma-rays entering the detector with an extra 5 cm thick layer of lead added along the beam direction. A 10 cm thick collimator with a 5 cm × 10 cm rectangular opening was also used. Results: The prompt gamma peaks at 6.13 MeV and 4.44 MeV were clearly identified as a Result of the inelastic nuclear reaction between the protons and the 16O atoms found in the water target. The 6.13 MeV peak was 5% higher than the peak at 4.44 MeV for the water target. The 4.44 MeV peak was the only identified emission in the prompt gamma energy spectra from the graphite target ({sup 12}C). The expected 2.313 MeV peak form the{sup 14}N (liquid nitrogen target) was identified, but the other expected {sup 14}N peaks could not be resolved. Conclusion: Prompt gamma measurements with a passive-scatter proton beam are possible, but the presence of a high amount of background radiation from the patient final collimator presents a challenge at the treatment isocenter. The prominent prompt gamma peaks at 6.13 MeV and 4.44 MeV were identified from the water, Perspex and graphite targets. The prompt gammas from the liquid nitrogen target were difficult to see, but may not be significant in the in-vivo verification process.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

SU-E-T-486: In Vivo Skin Dosimetry Using the Exradin W1 Plastic Scintillation Detector for Passively Scattered Proton Beam Therapy

Purpose: To evaluate the accuracy and usefulness of plastic scintillation detectors used for skin dosimetry of patients undergoing passive scatter proton therapy. Methods: Following an IRB approved protocol, six patients undergoing passively scattered proton beam therapy for prostate cancer were selected for in vivo skin dosimetry using the Exradin W1 plastic scintillator. The detector was calibrated on a Cobalt-60 unit, and phantom measurements in the proton beam with the W1 and a calibrated parallel plate ion chamber were used to account for the under-response due to high LET at energies used for treatment. Measurements made in a heated water tank were used to account for temperature dependence. For in vivo measurements, the W1 is fixed to the patient’s skin with medical tape in the center of each of two laterally opposed treatment fields. Measurements will be performed once per week for each patient for the duration of treatment, for a total of thirty six measurements. The measured dose will be compared to the expected dose, extracted from the Eclipse treatment planning system. The average difference over all measurements and per-patient will be computed, as well as standard deviations. Results: The calibrated detector exhibited a 7% under-response in 225 and 250 MeV beams, and a 4% under-response when used at 37 °C (relative to the response at the calibration temperature of 20 °C). Patient measurements are ongoing. Conclusion: The Exradin W1 plastic scintillator detector is a strong candidate for in vivo skin dosimetry in passively scattered proton beams as PSDs are water equivalent and very small (2mm in diameter), permitting accurate measurements that do not perturb the delivered dose. This project was supported in part by award number CA182450 from the National Cancer Institute.

60 APPLIED LIFE SCIENCES↗