Search NASA⌕ Search

SEARCH · Search NASA

Results for “carbonate”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Simulation of the Thermographic Response of Near Surface Flaws in Reinforced Carbon-Carbon Panels

Thermographic inspection is a viable technique for detecting in-service damage in reinforced carbon-carbon (RCC) composites that are used for thermal protection in the leading edge of the shuttle orbiter. A thermographic technique for detection of near surface flaws in RCC composite structures is presented. A finite element model of the heat diffusion in structures with expected flaw configurations is in good agreement with the experimental measurements.

Winfree, William P.↗
NASA NTRS2009

Model for the Effect of Fiber Bridging on the Fracture Resistance of Reinforced-Carbon-Carbon

A micromechanical methodology has been developed for analyzing fiber bridging and resistance-curve behavior in reinforced-carbon-carbon (RCC) panels with a three-dimensional (3D) composite architecture and a silicon carbide (SiC) surface coating. The methodology involves treating fiber bridging traction on the crack surfaces in terms of a weight function approach and a bridging law that relates the bridging stress to the crack opening displacement. A procedure has been developed to deduce material constants in the bridging law from the linear portion of the K-resistance curve. This report contains information on the application of procedures and outcomes.

Chan, Kwai S.↗
NASA NTRS2009

Impact Testing on Reinforced Carbon-Carbon Flat Panels with Ice Projectiles for the Space Shuttle Return to Flight Program

Following the tragedy of the Orbiter Columbia (STS-107) on February 1, 2003, a major effort commenced to develop a better understanding of debris impacts and their effect on the space shuttle subsystems. An initiative to develop and validate physics-based computer models to predict damage from such impacts was a fundamental component of this effort. To develop the models it was necessary to physically characterize reinforced carbon-carbon (RCC) along with ice and foam debris materials, which could shed on ascent and impact the orbiter RCC leading edges. The validated models enabled the launch system community to use the impact analysis software LS-DYNA (Livermore Software Technology Corp.) to predict damage by potential and actual impact events on the orbiter leading edge and nose cap thermal protection systems. Validation of the material models was done through a three-level approach: Level 1--fundamental tests to obtain independent static and dynamic constitutive model properties of materials of interest, Level 2--subcomponent impact tests to provide highly controlled impact test data for the correlation and validation of the models, and Level 3--full-scale orbiter leading-edge impact tests to establish the final level of confidence for the analysis methodology. This report discusses the Level 2 test program conducted in the NASA Glenn Research Center (GRC) Ballistic Impact Laboratory with ice projectile impact tests on flat RCC panels, and presents the data observed. The Level 2 testing consisted of 54 impact tests in the NASA GRC Ballistic Impact Laboratory on 6- by 6-in. and 6- by 12-in. flat plates of RCC and evaluated three types of debris projectiles: Single-crystal, polycrystal, and "soft" ice. These impact tests helped determine the level of damage generated in the RCC flat plates by each projectile and validated the use of the ice and RCC models for use in LS-DYNA.

Melis, Matthew E.↗
NASA NTRS2009

Impact Testing on Reinforced Carbon-Carbon Flat Panels With BX-265 and PDL-1034 External Tank Foam for the Space Shuttle Return to Flight Program

Following the tragedy of the Orbiter Columbia (STS-107) on February 1, 2003, a major effort commenced to develop a better understanding of debris impacts and their effect on the space shuttle subsystems. An initiative to develop and validate physics-based computer models to predict damage from such impacts was a fundamental component of this effort. To develop the models it was necessary to physically characterize reinforced carbon-carbon (RCC) along with ice and foam debris materials, which could shed on ascent and impact the orbiter RCC leading edges. The validated models enabled the launch system community to use the impact analysis software LS-DYNA (Livermore Software Technology Corp.) to predict damage by potential and actual impact events on the orbiter leading edge and nose cap thermal protection systems. Validation of the material models was done through a three-level approach: Level 1-fundamental tests to obtain independent static and dynamic constitutive model properties of materials of interest, Level 2-subcomponent impact tests to provide highly controlled impact test data for the correlation and validation of the models, and Level 3-full-scale orbiter leading-edge impact tests to establish the final level of confidence for the analysis methodology. This report discusses the Level 2 test program conducted in the NASA Glenn Research Center (GRC) Ballistic Impact Laboratory with external tank foam impact tests on flat RCC panels, and presents the data observed. The Level 2 testing consisted of 54 impact tests in the NASA GRC Ballistic Impact Laboratory on 6- by 6-in. and 6- by 12-in. flat plates of RCC and evaluated two types of debris projectiles: BX-265 and PDL-1034 external tank foam. These impact tests helped determine the level of damage generated in the RCC flat plates by each projectile and validated the use of the foam and RCC models for use in LS-DYNA.

Melis, Matthew E.↗
NASA NTRS2010

Finned Carbon-Carbon Heat Pipe with Potassium Working Fluid

This elemental space radiator heat pipe is designed to operate in the 700 to 875 K temperature range. It consists of a C-C (carbon-carbon) shell made from poly-acrylonitride fibers that are woven in an angle interlock pattern and densified with pitch at high process temperature with integrally woven fins. The fins are 2.5 cm long and 1 mm thick, and provide an extended radiating surface at the colder condenser section of the heat pipe. The weave pattern features a continuous fiber bath from the inner tube surface to the outside edges of the fins to maximize the thermal conductance, and to thus minimize the temperature drop at the condenser end. The heat pipe and radiator element together are less than one-third the mass of conventional heat pipes of the same heat rejection surface area. To prevent the molten potassium working fluid from eroding the C C heat pipe wall, the shell is lined with a thin-walled, metallic tube liner (Nb-1 wt.% Zr), which is an integral part of a hermetic metal subassembly which is furnace-brazed to the inner surface of the C-C tube. The hermetic metal liner subassembly includes end caps and fill tubes fabricated from the same Nb-1Zr alloy. A combination of laser and electron beam methods is used to weld the end caps and fill tubes. A tungsten/inert gas weld seals the fill tubes after cleaning and charging the heat pipes with potassium. The external section of this liner, which was formed by a "Uniscan" rolling process, transitions to a larger wall thickness. This section, which protrudes beyond the C-C shell, constitutes the "evaporator" part of the heat pipe, while the section inside the shell constitutes the condenser of the heat pipe (see figure).

Juhasz, Albert J.↗
NASA NTRS2011

Fracture Mechanics Analyses of Subsurface Defects in Reinforced Carbon-Carbon Joggles Subjected to Thermo-Mechanical Loads

Coating spallation events have been observed along the slip-side joggle region of the Space Shuttle Orbiter wing-leading-edge panels. One potential contributor to the spallation event is a pressure build up within subsurface voids or defects due to volatiles or water vapor entrapped during fabrication, refurbishment, or normal operational use. The influence of entrapped pressure on the thermo-mechanical fracture-mechanics response of reinforced carbon-carbon with subsurface defects is studied. Plane-strain simulations with embedded subsurface defects are performed to characterize the fracture mechanics response for a given defect length when subjected to combined elevated-temperature and subsurface-defect pressure loadings to simulate the unvented defect condition. Various subsurface defect locations of a fixed-length substrate defect are examined for elevated temperature conditions. Fracture mechanics results suggest that entrapped pressure combined with local elevated temperatures have the potential to cause subsurface defect growth and possibly contribute to further material separation or even spallation. For this anomaly to occur, several unusual circumstances would be required making such an outcome unlikely but plausible.

Knight, Norman F., Jr.↗
NASA NTRS2016

Two Distinct Secondary Carbonate Species in OC Meteorites from Antarctica are Possible Analogs for Mars Carbonates

Meteorites falling in Antarctica are captured in ice and stored until the glacial flow transports them to the surface where they can be collected. Prior to collection, they are altered during interactions between the rock, the cryosphere, and the hydrosphere. The purpose of this study is to characterize the stable isotope values of terrestrial, secondary carbonate minerals from Ordinary Chondrite (OC) meteorites collected in Antarctica. This facilitates better understanding of terrestrial weathering in martian meteorites as well as mechanisms for weathering in cold, arid environments as an analog to Mars. OC samples were selected for analysis based upon size and collection proximity to known martian meteorites. They were also selected based on petrologic type (3+) such that they were likely to be carbonate-free before falling to Earth.

Evans, M. E.↗
NASA NTRS2015

Effect of Test Specimen Shape and Size on Interlaminar Tensile Properties of Advanced Carbon-Carbon Composites

The interlaminar tensile strength of 1000-tow T-300 fiber ACC-6 carbon-carbon composites was measured using the method of bonding the coupons to adherends at room temperature. The size, 0.70 to 1.963 inches maximum width or radius, and shape, round or square, of the test coupons were varied to determine if the test method was sensitive to these variables. Sixteen total variations were investigated and the results modeled.

Vaughn, Wallace L.↗
NASA NTRS2017

Development and Testing of Carbon-Carbon Nozzle Extensions for Upper Stage Liquid Rocket Engines

Carbon-carbon (C-C) composite nozzle extensions are of interest for use on a variety of launch vehicle upper stage engines and in-space propulsion systems. The C-C nozzle extension technology and test capabilities being developed are intended to support National Aeronautics and Space Administration (NASA) and Department of Defense (DOD) requirements, as well as those of the broader Commercial Space industry. For NASA, C-C nozzle extension technology development primarily supports the NASA Space Launch System (SLS) and NASA's Commercial Space partners. Marshall Space Flight Center (MSFC) efforts are aimed at both (a) further developing the technology and databases needed to enable the use of composite nozzle extensions on cryogenic upper stage engines, and (b) developing and demonstrating low-cost capabilities for testing and qualifying composite nozzle extensions. Recent, on-going, and potential future work supporting NASA, DOD, and Commercial Space needs will be discussed. Information to be presented will include (a) recent and on-going mechanical, thermal, and hot-fire testing, as well as (b) potential future efforts to further develop and qualify domestic C-C nozzle extension solutions for the various upper stage engines under development.

Valentine, Peter G.↗
NASA NTRS2019

Potential Improvements in Global Carbon Flux Estimates from a Network of Laser Heterodyne Radiometer Measurements of Column Carbon Dioxide

We present observing system simulation experiments (OSSEs) to evaluate the impact of a proposed network of ground-based miniaturized laser heterodyne radiometer (mini-LHR) instruments that measure atmospheric column-averaged carbon dioxide (XCO2) with a 1 ppm precision. A particular strength of this passive measurement approach is its insensitivity to clouds and aerosols due to its direct sun pointing and narrow field of view (0.2°). Developed at the NASA Goddard Space Flight Center (GSFC), these portable, low-cost mini-LHR instruments were designed to operate in tandem with the sun photometers used by the AErosol RObotic NETwork (AERONET). This partnership allows us to leverage the existing framework of AERONET's global ground network of more than 500 sites as well as providing simultaneous measurements of aerosols that are known to be a major source of error in retrievals of XCO2 from passive nadir-viewing satellite observations. We show, using the global 3-D GEOS-Chem chemistry transport model, that a deployment of 50 mini-LHRs at strategic (but not optimized) AERONET sites significantly improves our knowledge of global and regional land-based CO2 fluxes. This improvement varies seasonally and ranges 58%–81% over southern lands, 47%–76% over tropical lands, 71%–92% over northern lands, and 64%–91% globally. We also show significant added value from combining mini-LHR instruments with the existing ground-based NOAA flask network. Collectively, these data result in improved a posteriori CO2 flux estimates on spatial scales of ∼10 km2, especially over North America and Europe, where the ground-based networks are densest. Our studies suggest that the mini-LHR network could also play a substantive role in reducing carbon flux uncertainty in Arctic and tropical systems by filling in geographical gaps in measurements left by ground-based networks and space-based observations. A realized network would also provide necessary data for the quinquennial global stock takes that form part of the Paris Agreement.

Palmer, Paul I.↗
NASA NTRS2019

GEOS-Carb III: Delivering Mature Carbon Flux and Concentration Datasets in Support of NASA's Carbon Monitoring System

The GEOS-Carb project seeks to make high quality, data-driven products that support NASA's Carbon Monitoring System Program. These include bottom-up land and ocean flux estimates along with fossil fuel emissions, all informed by satellite data and the MERRA-2 reanalysis. These flux data support atmospheric carbon products that include both simulations and data assimilation products. We show examples of this work and discuss applications to future mission planning.

Ott, L.↗
NASA NTRS2020

Relative Importance of Greenhouse Gases, Sulfate, Organic Carbon, and Black Carbon Aerosol for South Asian Monsoon Rainfall Changes

The contribution of individual aerosol species and greenhouse gases to precipitation changes during the South Asian summer monsoon is uncertain. Mechanisms driving responses to anthropogenic forcings need further characterization. We use an atmosphere‐only climate model to simulate the fast response of the summer monsoon to different anthropogenic aerosol types and to anthropogenic greenhouse gases. Without normalization, sulfate is the largest driver of precipitation change between 1850 and 2000, followed by black carbon and greenhouse gases. Normalized by radiative forcing, the most effective driver is black carbon. The precipitation and moisture budget responses to combinations of aerosol species perturbed together scale as a linear superposition of their individual responses. We use both a circulation‐based and moisture budget‐based argument to identify mechanisms of aerosol and greenhouse gas induced changes to precipitation, and find that in all cases the dynamic contribution is the dominant driver to precipitation change in the monsoon region.

climate↗
DOE OSTI2020

Carbon supported single atom carbon dioxide reduction electro catalysts

Electrocatalysts composed of single atoms dispersed over porous carbon support were prepared by a lithium-melt method. The new catalysts demonstrated high selectivity, high Faradic efficiency and low overpotential toward to the electrocatalytic reduction of carbon dioxide to fuels.

Liu, Di-Jia↗
DOE OSTI2023

Aromatic Monomer Production from Lignin Through Catalytic Carbon-Carbon Bond Cleavage

The conversion of lignin, the heterogeneous aromatic polymer found in terrestrial plant cell walls, into renewable bio-derived chemicals is critical to enable a viable lignocellulose-based bioeconomy. While lignin finds some limited industrial uses today, cost-effective and robust processes for the depolymerization of lignin to aromatic monomers would substantially expand lignin applications to larger markets, such as sustainable polymers and commodity chemicals. Historically, catalytic lignin depolymerization has focused on aryl-ether bond cleavage. A large fraction of aromatics in lignin, however, is linked by various recalcitrant carbon-carbon (C-C) bonds, which present a challenging substrate for depolymerization to aromatic monomers at high yields. To increase monomer yields above those accessible through aryl-ether bond cleavage alone, here we report that autoxidation catalysis cleaves C-C bonds in various lignin substrates with high atom economy. The catalyzed autoxidations of phenol-protected reductive catalytic fractionation (RCF) oil oligomers and hydrodeoxygenation (HDO) oil are described. The stream oxygenated monomers produced from the various lignin substrates are bioavailable as demonstrated by their bioconversion to cis,cis-muconate by engineered strains of Pseudonomas putida.

autoxidation↗
DOE OSTI2021

Carbon content of soil fractions varies with season, rainfall, and soil fertility across a lowland tropical moist forest gradient

Tropical forests contain some of the largest soil carbon (C) stocks on Earth, making them broadly relevant to terrestrial-climate feedbacks, yet our understanding of how their soil organic C (SOC) fractions vary over space and time is limited. We studied effects of season, fertility, and mean annual precipitation (MAP) on the C contents of soil fractions across 14 lowland forests in Panama. We measured free-debris, occluded-debris, and mineral-associated SOC fractions, as well as soluble C associated with each fraction. We hypothesized that mineral-associated SOC would be greatest in infertile, strongly weathered soils with large reactive mineral contents. We also hypothesized that the debris SOC fractions would accumulate during the dry season, reflecting seasonal increases in litterfall. To address this, we compared soil fractions in wet and dry seasons from fertile and infertile soils across a range of 1809 – 2864 mm MAP. The C content (mg C / g soil) of all soil fractions varied with fertility and MAP: specifically, free-debris SOC was greatest in wet, high-fertility soils, and occluded-debris SOC was greater in high-fertility than low-fertility soils. The mineral-associated SOC fraction, which contained the majority of bulk soil C, showed increasing C content with greater MAP in infertile sites, presumably driving similar spatial patterns in the bulk soil. Only the free-debris SOC fraction showed strong seasonal variation, increasing in mass during the dry season. Nitrogen behaved similarly to C. In summary, soil C contents increased with MAP in infertile sites but not fertile sites, driven by the mineral-associated SOC fraction. The dry season had greater free-debris SOC, but this seasonal trend was not apparent in bulk soil C, likely because of the small size of the free-debris SOC fraction. Furthermore, changes in the quantity and seasonality of precipitation, which are projected for tropical forests, might shift spatial and temporal patterns of soil C storage, which would in turn influence forest-climate feedbacks for this C-rich biome.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

An innovative carbonated cementitious material and its printability and carbon mineralization capacity

The main goal of this research is to develop a carbonated cementitious material (CCMs) mix design and demonstrate its rapid stiffening for manufacturing 3D printed or precast elements for building construction (i.e., concrete with enhanced durability and CO 2 capture efficiency). The material development employs hydrated Ca(OH) 2 , and its distinct reaction with CO 2 to form CaCO 3 . Different formulations and additives including polymer materials enable the thermomechanical properties that give these CCMs 3D printability comparable with cement materials used for similar applications. Here, printable and castable CCM formulations were successfully developed and demonstrated to mineralize CO 2 to form up to 57% CaCO 3 .

36 MATERIALS SCIENCE↗