Search NASA⌕ Search

SEARCH · Search NASA

Results for “climate change impact”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 541 records · Page 30
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Wildfire Smoke Adjustment Factors for Low-Cost and Professional PM 2.5 Monitors with Optical Sensors

Air quality monitors using low-cost optical PM 2.5 sensors can track the dispersion of wildfire smoke; but quantitative hazard assessment requires a smoke-specific adjustment factor (AF). This study determined AFs for three professional-grade devices and four monitors with low-cost sensors based on measurements inside a well-ventilated lab impacted by the 2018 Camp Fire in California (USA). Using the Thermo TEOM-FDMS as reference, AFs of professional monitors were 0.85 for Grimm mini wide-range aerosol spectrometer, 0.25 for TSI DustTrak, and 0.53 for Thermo pDR1500; AFs for low-cost monitors were 0.59 for AirVisual Pro, 0.48 for PurpleAir Indoor, 0.46 for Air Quality Egg, and 0.60 for eLichens Indoor Air Quality Pro Station. We also compared public data from 53 PurpleAir PA-II monitors to 12 nearby regulatory monitoring stations impacted by Camp Fire smoke and devices near stations impacted by the Carr and Mendocino Complex Fires in California and the Pole Creek Fire in Utah. Camp Fire AFs varied by day and location, with median (interquartile) of 0.48 (0.44–0.53). Adjusted PA-II 4-h average data were generally within ±20% of PM 2.5 reported by the monitoring stations. Adjustment improved the accuracy of Air Quality Index (AQI) hazard level reporting, e.g., from 14% to 84% correct in Sacramento during the Camp Fire.

47 OTHER INSTRUMENTATION↗
DOE OSTI2022

Encouraging voluntary government action via a solar-friendly designation program to promote solar energy in the United States

Sustainable development requires an accelerated transition toward renewable energy. In particular, substantially scaling up solar photovoltaics (PV) adoption is a crucial component of reducing the impacts of climate change and promoting sustainable development. However, it is challenging to convince local governments to take action. This study uses a combination of propensity score matching (PSM) and difference-in-differences (DID) models to assess the effectiveness of a voluntary environmental program (VEP) called SolSmart that targets local governments to engage in solar-friendly practices to promote the local solar PV market in the United States. Via specific designation requirements and technical assistance, SolSmart simplifies the process of acting on interest in being solar friendly, has a wide coverage of basic solar-friendly actions with flexible implementation, and motivates completion with multiple levels of designation. We find that a local government’s participation in SolSmart is associated with an increased installed capacity of 18 to 19%/mo or with less statistical significance, an increased number of installations of 17%/mo in its jurisdiction. However, SolSmart has not shown a statistically significant impact on soft cost reductions to date. In evaluating the impact of the SolSmart program, this study improves our understanding of the causation between a VEP that encourages solar-friendly local government practices and multiple solar market outcomes. VEPs may be able to promote shifts toward sustainable development at the local level. Our findings have several implications for the design of VEPs that promote local sustainability.

14 SOLAR ENERGY↗
DOE OSTI2023

The cost of direct air capture and storage can be reduced via strategic deployment but is unlikely to fall below stated cost targets

Carbon dioxide removal (CDR) is necessary to minimize the impact of climate change by tackling hard-toabate sectors and historical emissions. Direct air capture and storage (DACS) is an important CDR technology, but it remains unclear when and how DACS can be economically viable. Here, we use a bottom-up engineering-economic model together with top-down technological learning projections to calculate plant-level cost trajectories for four DACS technologies. Our analysis demonstrates that the costs of these technologies can plateau by 2050 at around $\$$100-600 t-CO 2 -1 mainly via capital cost reduction through aggressive deployment, but still exceed the optimistic targets defined by countries such as the US (i.e., $\$$100 t-CO 2 -1 ). A further analysis of existing policy mechanisms indicates that strong, project-catered policy support will be required to create market opportunities, accelerate DACS scale-up and lower the costs further. Our work suggests that strategic DACS deployment and operation must be coupled with strong policies to minimise the cost of DACS and maximise the opportunity to make a planet-scale climate impact.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Increased drought and extreme events over continental United States under high emissions scenario

The frequency, severity, and extent of climate extremes in future will have an impact on human well-being, ecosystems, and the effectiveness of emissions mitigation and carbon sequestration strategies. The specific objectives of this study were to downscale climate data for US weather stations and analyze future trends in meteorological drought and temperature extremes over continental United States (CONUS). We used data from 4161 weather stations across the CONUS to downscale future precipitation projections from three Earth System Models (ESMs) participating in the Coupled Model Intercomparison Project Phase Six (CMIP6), specifically for the high emission scenario SSP5 8.5. Comparing historic observations with climate model projections revealed a significant bias in total annual precipitation days and total precipitation amounts. The average number of annual precipitation days across CONUS was projected to be 205 ± 26, 184 ± 33, and 181 ± 25 days in the BCC, CanESM, and UKESM models, respectively, compared to 91 ± 24 days in the observed data. Analyzing the duration of drought periods in different ecoregions of CONUS showed an increase in the number of drought months in the future (2023–2052) compared to the historical period (1989–2018). The analysis of precipitation and temperature changes in various ecoregions of CONUS revealed an increased frequency of droughts in the future, along with longer durations of warm spells. Eastern temperate forests and the Great Plains, which encompass the majority of CONUS agricultural lands, are projected to experience higher drought counts in the future. Drought projections show an increasing trend in future drought occurrences due to rising temperatures and changes in precipitation patterns. Our high-resolution climate projections can inform policy makers about the hotspots and their anticipated future trajectories.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Plan evaluation for heat resilience: complementary methods to comprehensively assess heat planning in Tempe and Tucson, Arizona

Abstract Escalating impacts from climate change and urban heat are increasing the urgency for communities to equitably plan for heat resilience. Cities in the desert Southwest are among the hottest and fastest warming in the U.S., placing them on the front lines of heat planning. Urban heat resilience requires an integrated planning approach that coordinates strategies across the network of plans that shape the built environment and risk patterns. To date, few studies have assessed cities’ progress on heat planning. This research is the first to combine two emerging plan evaluation approaches to examine how networks of plans shape urban heat resilience through case studies of Tempe and Tucson, Arizona. The first methodology, Plan Quality Evaluation for Heat Resilience, adapts existing plan quality assessment approaches to heat. We assess whether plans meet 56 criteria across seven principles of high-quality planning and the types of heat strategies included in the plans. The second methodology, the Plan Integration for Resilience Scorecard™ (PIRS™) for Heat, focuses on plan policies that could influence urban heat hazards. We categorize policies by policy tool and heat mitigation strategy and score them based on their heat impact. Scored policies are then mapped to evaluate their spatial distribution and the net effect of the plan network. The resulting PIRS™ for Heat scorecard is compared with heat vulnerability indicators to assess policy alignment with risks. We find that both cities are proactively planning for heat resilience using similar plan and strategy types, however, there are clear and consistent opportunities for improvement. Combining these complementary plan evaluation methods provides a more comprehensive understanding of how plans address heat and a generalizable approach that communities everywhere could use to identify opportunities for improved heat resilience planning.

Environmental Sciences & Ecology↗
DOE OSTI2022

Precipitation trends determine future occurrences of compound hot–dry events

Compound hot–dry events—co-occurring hot and dry extremes—frequently cause damages to human and natural systems, often exceeding separate impacts from heatwaves and droughts. Strong increases in the occurrence of these events are projected with warming, but associated uncertainties remain large and poorly understood. Here, using climate model large ensembles, we show that mean precipitation trends exclusively modulate the future occurrence of compound hot–dry events over land. This occurs because local warming will be large enough that future droughts will always coincide with at least moderately hot extremes, even in a 2°C warmer world. By contrast, precipitation trends are often weak and equivocal in sign, depending on the model, region and internal climate variability. Therefore, constraining regional precipitation trends will also constrain future compound hot–dry events. These results help to assess future frequencies of other compound extremes characterized by strongly different trends in the drivers.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Nutrient Inputs Stimulate Mercury Methylation by Syntrophs in a Subarctic Peatland

Climate change dramatically impacts Arctic and subarctic regions, inducing shifts in wetland nutrient regimes as a consequence of thawing permafrost. Altered hydrological regimes may drive changes in the dynamics of microbial mercury (Hg) methylation and bioavailability. Important knowledge gaps remain on the contribution of specific microbial groups to methylmercury (MeHg) production in wetlands of various trophic status. Here, we measured aqueous chemistry, potential methylation rates (k meth ), volatile fatty acid (VFA) dynamics in peat-soil incubations, and genetic potential for Hg methylation across a groundwater-driven nutrient gradient in an interior Alaskan fen. We tested the hypotheses that (1) nutrient inputs will result in increased methylation potentials, and (2) syntrophic interactions contribute to methylation in subarctic wetlands. We observed that concentrations of nutrients, total Hg, and MeHg, abundance of hgcA genes, and rates of methylation in peat incubations (k meth ) were highest near the groundwater input and declined downgradient. hgcA sequences near the input were closely related to those from sulfate-reducing bacteria (SRB), methanogens, and syntrophs. Hg methylation in peat incubations collected near the input source (FPF2) were impacted by the addition of sulfate and some metabolic inhibitors while those down-gradient (FPF5) were not. Sulfate amendment to FPF2 incubations had higher k meth relative to unamended controls despite no effect on k meth from addition of the sulfate reduction inhibitor molybdate. The addition of the methanogenic inhibitor BES (25 mM) led to the accumulation of VFAs, but unlike molybdate, it did not affect Hg methylation rates. Rather, the concurrent additions of BES and molybdate significantly decreased k meth , suggesting a role for interactions between SRB and methanogens in Hg methylation. The reduction in k meth with combined addition of BES and molybdate, and accumulation of VFA in peat incubations containing BES, and a high abundance of syntroph-related hgcAsequences in peat metagenomes provide evidence for MeHg production by microorganisms growing in syntrophy. Collectively the results suggest that wetland nutrient regimes influence the activity of Hg methylating microorganisms and, consequently, Hg methylation rates. Our results provide key information about microbial Hg methylation and methylating communities under nutrient conditions that are expected to become more common as permafrost soils thaw.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Field Study of 120-volt Heat Pump Water Heaters in the Big Easy

To meet long-term goals for reducing carbon emissions and lessen the impacts of climate change, the U.S. plans to decarbonize its building stock, which includes the replacement of fossil fuel-burning end uses with energy efficient electric alternatives. As part of this strategy, the replacement of fossil fuel water heaters with heat pump water heaters (HPWH) has the potential to avoid substantial carbon emissions. An estimated 10-15 million single-family homes with fossil fuel water heaters do not have the electrical panel capacity to install a 240-volt, 30-amp HPWH. For these homes, a technology recently introduced to the market, the 120-volt plug-in HPWH, can provide energy efficient electrification of water heating without an expensive panel and wiring retrofit. This paper presents the results of an ongoing 120-volt HPWH field study conducted in 17 homes in New Orleans, LA. Key installation scenarios are profiled for retrofitting from gas-fired water heaters to 120-volt HPWHs, accounting for space, air volume, air temperature, condensate drainage, and electrical. Each HPWH had its surrounding air temperature, relative humidity, inlet and outlet water temperature, flow, and energy consumption monitored. Using these data, hot water delivery and energy efficiency performance were analyzed based on home characteristics. Hot water run outs were investigated to understand how hot water usage, inlet water temperature, and surrounding air temperature impact the HPWH’s ability to meet load. From these results, best practices for 120-volt HPWH siting, sizing, and installation were developed. In addition, results are explored further to add insight for electrification policies and product development.

heat pump water heater, 120-volt, Residential buil↗
DOE OSTI2024

Metaproteomics-informed stoichiometric modeling reveals the responses of wetland microbial communities to oxygen and sulfate exposure

Abstract Climate changes significantly impact greenhouse gas emissions from wetland soil. Specifically, wetland soil may be exposed to oxygen (O 2 ) during droughts, or to sulfate (SO 4 2- ) as a result of sea level rise. How these stressors – separately and together – impact microbial food webs driving carbon cycling in the wetlands is still not understood. To investigate this, we integrated geochemical analysis, proteogenomics, and stoichiometric modeling to characterize the impact of elevated SO 4 2- and O 2 levels on microbial methane (CH 4 ) and carbon dioxide (CO 2 ) emissions. The results uncovered the adaptive responses of this community to changes in SO 4 2- and O 2 availability and identified altered microbial guilds and metabolic processes driving CH 4 and CO 2 emissions. Elevated SO 4 2- reduced CH 4 emissions, with hydrogenotrophic methanogenesis more suppressed than acetoclastic. Elevated O 2 shifted the greenhouse gas emissions from CH 4 to CO 2 . The metabolic effects of combined SO 4 2- and O 2 exposures on CH 4 and CO 2 emissions were similar to those of O 2 exposure alone. The reduction in CH 4 emission by increased SO 4 2- and O 2 was much greater than the concomitant increase in CO 2 emission. Thus, greater SO 4 2- and O 2 exposure in wetlands is expected to reduce the aggregate warming effect of CH 4 and CO 2 . Metaproteomics and stoichiometric modeling revealed a unique subnetwork involving carbon metabolism that converts lactate and SO 4 2- to produce acetate, H 2 S, and CO 2 when SO 4 2- is elevated under oxic conditions. This study provides greater quantitative resolution of key metabolic processes necessary for the prediction of CH 4 and CO 2 emissions from wetlands under future climate scenarios.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Optimal interpolation of global dissolved oxygen: 1965–2015

Oxygen inventory of the global ocean has declined in recent decades potentially due to the warming-induced reduction in solubility as well as the circulation and biogeochemical changes associated with ocean warming and increasing stratification. Earth System Models predict continued oxygen decline for this century with profound impacts on marine ecosystem and fisheries. Observational constraint on the rate of oxygen loss is crucial for assessing the ability of models to accurately simulate these changes. There are only a few observational assessments of the global oceanic oxygen inventory reporting a range of oxygen loss. This study develops a gridded data set of dissolved oxygen for the global oceans using optimal interpolation method. The resulting gridded product includes full-depth map of dissolved oxygen as 5-year moving average from 1965 to 2015 with uncertainty estimates. The uncertainty can come from unresolved small-scale and high-frequency variability and mapping errors. The multi-decadal trend of global dissolved oxygen is in the range of -281 to -373 Tmol/decade. This estimate is more conservative than previous works. In this study, the grid points far from the observations are essentially set equal to zero anomaly from the climatology. Calculating global inventory with this approach produces a relatively conservative estimate; thus, the results from this study likely provide a useful lower bound estimate of the global oxygen loss.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Genetic identification of avian samples recovered from solar energy installations

Renewable energy production and development will drastically affect how we meet global energy demands, while simultaneously reducing the impact of climate change. Although the possible effects of renewable energy production (mainly from solar- and wind-energy facilities) on wildlife have been explored, knowledge gaps still exist, and collecting data from wildlife remains (when negative interactions occur) at energy installations can act as a first step regarding the study of species and communities interacting with facilities. In the case of avian species, samples can be collected relatively easily (as compared to other sampling methods), but may only be able to be identified when morphological characteristics are diagnostic for a species. Therefore, many samples that appear as partial remains, or “feather spots”—known to be of avian origin but not readily assignable to species via morphology—may remain unidentified, reducing the efficiency of sample collection and the accuracy of patterns observed. To obtain data from these samples and ensure their identification and inclusion in subsequent analyses, we applied, for the first time, a DNA barcoding approach that uses mitochondrial genetic data to identify unknown avian samples collected at solar facilities to species. We also verified and compared identifications obtained by our genetic method to traditional morphological identifications using a blind test, and discuss discrepancies observed. Our results suggest that this genetic tool can be used to verify, correct, and supplement identifications made in the field and can produce data that allow accurate comparisons of avian interactions across facilities, locations, or technology types. We recommend implementing this genetic approach to ensure that unknown samples collected are efficiently identified and contribute to a better understanding of wildlife impacts at renewable energy projects.

14 SOLAR ENERGY↗
NASA NTRS2012

Optical Characterisation of Suspended Particles in the Mackenzie River Plume (Canadian Arctic Ocean) and Implications for Ocean Colour Remote Sensing

Climate change significantly impacts Arctic shelf regions in terms of air temperature, ultraviolet radiation, melting of sea ice, precipitation, thawing of permafrost and coastal erosion. Direct consequences have been observed on the increasing Arctic river flow and a large amount of organic carbon sequestered in soils at high latitudes since the last glacial maximum can be expected to be delivered to the Arctic Ocean during the coming decade. Monitoring the fluxes and fate of this terrigenous organic carbon is problematic in such sparsely populated regions unless remote sensing techniques can be developed and proved to be operational. The main objective of this study is to develop an ocean colour algorithm to operationally monitor dynamics of suspended particulate matter (SPM) on the Mackenzie River continental shelf (Canadian Arctic Ocean) using satellite imagery. The water optical properties are documented across the study area and related to concentrations of SPM and particulate organic carbon (POC). Robust SPM and POC : SPM proxies are identified, such as the light backscattering and attenuation coefficients, and relationships are established between these optical and biogeochemical parameters. Following a semi-analytical approach, a regional SPM quantification relationship is obtained for the inversion of the water reflectance signal into SPM concentration. This relationship is reproduced based on independent field optical measurements. It is successfully applied to a selection of MODIS satellite data which allow estimating fluxes at the river mouth and monitoring the extension and dynamics of the Mackenzie River surface plume in 2009, 2010 and 2011. Good agreement is obtained with field observations representative of the whole water column in the river delta zone where terrigenous SPM is mainly constrained (out of short periods of maximum river outflow). Most of the seaward export of SPM is observed to occur within the west side of the river mouth. Future work will require the validation of the developed SPM regional algorithm based on match-ups with field measurements, then the routine application to ocean colour satellite data in order to better estimate the fluxes and fate of SPM and POC delivered by the Mackenzie River to the Arctic Ocean.

Mackenzie River plume↗
NASA NTRS2022

Potential impacts of projected warming scenarios on winter wheat in the UK

The goals of this study are to analyse the impacts of 1.5 and 2.0°C scenarios on UK winter wheat using a combination of Global Climate Models (GCMs), crop models, planting dates and cultivars; to evaluate the impact of increased air temperature on winter wheat phenology and potential yield; to quantify the underlying uncertainties due to the multiple sources of variability introduced by climate scenarios, crop models and agronomic management. The data used to calibrate and evaluate three crop models were obtained from a field experiment with two irrigation amounts and two wheat cultivars that have different phenology and growth habit. After calibration, the model was applied to fifty locations across the wheat-growing area of the UK to cover all the main growing regions, with most points located in the main growing areas. Four GCMs, with two cultivars and five planting dates, were simulated at the end of the century. Results of this study showed that the UK potential wheat yield will increase by 2–8% under projected climate. Farmers will need to close such a gap in the future because it will have implications in terms of food security. Future climatic conditions might increase such a gap. Adaptation measures (e.g. moving the optimal planting time), along with climate-ready varieties bred for future conditions and with precision agriculture techniques can help to reduce this gap and ensure that the future actual UK wheat production will be close to the potential.

Climate change↗
NASA NTRS2022

Aerosol Models from the AERONET Database: Application to Surface Reflectance Validation Satellite Data

Aerosols play a critical role in radiative transfer within the atmosphere, and they have a significant impact on climate change. In this paper, we propose and implement a framework for developing an aerosol model using their microphysical properties. Such microphysical properties as the size distribution, the complex refractive index, and the percentage of sphericity are derived from the global AERosol RObotic NETwork (AERONET). These measurements, however, are typically retrieved when almucantar measurement procedures are performed (i.e., early mornings and late afternoons with clear sky) and might not have a temporal correspondence to a satellite overpass time, so a valid validation of satellite-derived products cannot be carried out. To address this problem of temporal inconsistency of satellite and ground-based measurements, we developed an approach to retrieve these microphysical properties (and the corresponding aerosol model) using the optical thickness at 440 nm, τ440, and the Ångström coefficient between 440 and 870 nm, α440–870. Such aerosol models were developed for 851 AERONET sites within the last 28 years. Obtained results suggest that empirically microphysical properties can be retrieved with uncertainties of up to 23 %. An exception is the imaginary part of the refractive index ni, for which the derived uncertainties reach up to 38 %. These specific parametric models of aerosol can be used for the studies when retrieval of microphysical properties is required as well as validation of satellite-derived products over land. Specifically, we demonstrate the usefulness of the aerosol models to validate surface reflectance records over land derived from optical remote sensing sensors. We then quantify the propagation of uncertainties in the surface reflectance due to uncertainties with the aerosol model retrieval that is used as a reference from radiative transfer simulations. Results indicate that individual aerosol microphysical properties can impact uncertainties in surface reflectance retrievals between 3.5 × 10(exp -5) to 1 × 10(exp -3) (in reflectance units). The overall impact of microphysical properties combined yields an overall uncertainty in surface reflectance <0.004 (in reflectance units). That corresponds, for example, to 1 to 3 % of the retrieved surface reflectance in the red spectral band (620–670 nm) by the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument. These uncertainty values are well below the specification (0.005 + 0.05ρ; ρ is the retrieved surface reflectance) used for the MODIS atmospheric correction.

Jean-Claude Roger↗
NASA NTRSDate not supplied

Analysis of CO Transport from Australia Fires and Its Impact to Ozone, Water Vapor and Clouds Using CrIS Single-Field-of-View Sounder Products and Other Remote Sensing and MERRA-2 Reanalysis Data

Australia’s unprecedented fire disasters at the end of 2019 to early 2020 emitted huge amounts of carbon monoxide (CO) and fire aerosol particles, and the long-range transport of the smoke plumes poses great impact to climate change, such as altering the Antarctic ozone (O3) hole. Spaceborne observations from satellites have been proven successful in monitoring CO from wildfires in the past decade and can be used to examine the associated CO transport. The primary remote sensing data used in this study is the Single Field of View (SFOV) Sounder Atmospheric Product (SiFSAP) derived from the Cross-track Infrared Sounder (CrIS) on SNPP, a new product that will be generated at NASA and released to the public in a few months. SiFSAP has a high spatial resolution of ~14 km and includes atmospheric profiles of temperature, water vapor, CO, O3, as well as cloud products, and as the SiFSAP algorithm performs both day- and night-time retrievals, it provides an additional observation for night-time in comparison to the day-time-only solar polar satellite instruments such as MOPPIT, OMPS, and TROPOMI. Most recent significant improvements in the quality of this product plus its good spatial resolution (better than most global weather and climate models) enable us to conduct process-oriented analysis of CO transport, and the variation of water vapor, O3 and clouds (optical depth, effective radius and cloud height) within and around the fire plumes. The wind fields from MERRA-2 reanalysis will be used to help characterize the transport. Other remote sensing data, such as CO from AIRS, MOPPIT and TROPOMI, O3 from OMPS and TROPOMI, as well as the UV aerosol index from OMI and OMPS, will be used and compared with SiFSAP sounder products. Cross-validation of CO and O3 from these different sensors with the corresponding MERRA-2 products will also be carried out. Along the plume transport path, some enhancement of O3 and correlation between fire aerosol, cloud optical depth and water vapor have been found but need further investigation. Using the transport of fire plumes over the Southern Pacific Ocean as a unique testbed, this study will demonstrate the trace species monitoring capability of current satellite observations, in particular, for CO and O3, and hopefully, it will provide some insight on the impacts on fire emissions on air quality and climate.

Xiaozhen (Shawn) Xiong↗
DOE OSTI2019

Subsoil organo-mineral associations under contrasting climate conditions

Climate differences can induce profound changes in organo-mineral associations in soils. However, the magnitude of these modifications, whether as a direct effect of climate conditions or an indirect effect through changes in soil mineralogy, are still not fully understood. In this study, we aimed to improve understanding of how climate and resultant changes in soil mineralogy affect subsoil (i.e., 0.4–0.9 m) organo-mineral interactions at the macro- and microscale. A set of subsoil samples were collected throughout an elevation gradient (approximately 1800 to 2400 mm precipitation year –1 and 15 to 24ºC) on Kohala Mountain, Hawaii. We carried out a combined approach of bulk soil analyses with mineral extractions and spectroscopic and spectromicroscopic analyses. Significant positive correlations (p < 0.05) between soil organic carbon (SOC) with extracted Fe and Al (dithionite citrate bicarbonate – DCB and ammonium oxalate – OX) at the bulk soil scale supported prior research showing concurrent decline of subsoil Fe, Al and SOC above a precipitation level of ~2000 - ~2200 mm year -1 . However, divergence in microscale organo-mineral associations identified using NanoSIMS allowed us to discern the relative roles of Fe and Al in promoting organo-mineral associations. At the lower precipitation range (~1800 mm year -1 ), the clay fraction < 2 µm showed higher amounts of organic matter (OM) co-localized with Fe & Al compared with the higher precipitation level (~2300 mm year -1 ), where OM was mostly unassociated or only associated with Al. While Fe contributed to approximately 40% of the microscale organo-mineral associations in the lower precipitation site (quantified by co-localizations with OM segments), this contribution at the higher rainfall regime was only 5%. In contrast, the contribution of Al was approximately the same in both rainfall levels (approximately 30%). Therefore, associations with Al may be more important than Fe for OM stabilization under reducing climate conditions. The normalized CN:C ratio based on individual pixels was found to be higher when co-localized with Al, Fe, or both, especially under the high precipitation regime. This fact points towards the importance of Fe and Al to stabilize more N-rich OM, especially at high rainfall levels. In addition, subsoil from higher rainfall conditions exhibited more reduced forms of Fe (assessed by Fe K-edge XANES) and lower proportions of carboxyl-C (5% lower in the relative abundance) as well as higher alkyl/O-alkyl ratios determined by CP-MAS 13C NMR. Such differences in composition may directly influence the organo-mineral associations at both locations, as differences in Fe reduction and the presence of carboxyl-C groups are recognized to play a role in OM stabilization. We conclude that spatial relationships between Fe and Al with SOC at the microscale show a shift towards Al-dominated SOC associations at higher precipitation that could not be ascertained from bulk measurements alone. Therefore, they are of fundamental importance to understand the impact of climate change on SOC stabilization.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Photochemically‐Driven CO 2 Release Using a Metastable‐State Photoacid for Energy Efficient Direct Air Capture

Abstract One of the grand challenges underlying current direct air capture (DAC) technologies relates to the intensive energy cost for sorbent regeneration and CO 2 release, making the massive scale (GtCO 2 /year) deployment required to have a positive impact on climate change economically unfeasible. This challenge underscores the critical need to develop new DAC processes with substantially reduced regeneration energies. Here, we report a photochemically‐driven approach for CO 2 release by exploiting the unique properties of an indazole metastable‐state photoacid (mPAH). Our measurements on simulated and amino acid‐based DAC systems revealed the potential of mPAH to be used for CO 2 release cycles by regulating pH changes and associated isomers driven by light. Upon irradiating with moderate intensity light, a ≈55 % and ≈68 % to ≈78 % conversion of total inorganic carbon to CO 2 was found for the simulated and amino acid‐based DAC systems, respectively. Our results confirm the feasibility of on‐demand CO 2 release under ambient conditions using light instead of heat, thereby providing an energy efficient pathway for the regeneration of DAC sorbents.

Premadasa, Uvinduni I.↗
DOE OSTI2023

Photochemically-Driven CO 2 Release Using a Metastable-State Photoacid for Energy Efficient Direct Air Capture

One of the grand challenges underlying current direct air capture (DAC) technologies relates to the intensive energy cost for sorbent regeneration and CO 2 release, making the massive scale (GtCO 2 /year) deployment required to have a positive impact on climate change economically unfeasible. This challenge underscores the critical need to develop new DAC processes with substantially reduced regeneration energies. Here, in this work, we report a photochemically-driven approach for CO 2 release by exploiting the unique properties of an indazole metastable-state photoacid (mPAH). Our measurements on simulated and amino acid-based DAC systems revealed the potential of mPAH to be used for CO 2 release cycles by regulating pH changes and associated isomers driven by light. Upon irradiating with moderate intensity light, a ≈55 % and ≈68 % to ≈78 % conversion of total inorganic carbon to CO 2 was found for the simulated and amino acid-based DAC systems, respectively. Our results confirm the feasibility of on-demand CO 2 release under ambient conditions using light instead of heat, thereby providing an energy efficient pathway for the regeneration of DAC sorbents.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗