Single-Iron Site Catalysts with Self-Assembled Dual-size Architecture and Hierarchical Porosity for Proton-Exchange Membrane Fuel Cells
Abstract not provided
25 ENERGY STORAGE↗
SEARCH · Search NASA
Results for “nitrogen reduction”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Efficiency of using nitrogen trifluoride as an oxidiser in a supersonic continuous-wave chemical HF laser
We report the results of an experimental study of possible ways to increase the efficiency of using NF{sub 3} nitrogen trifluoride as an oxidiser in an atomic fluorine generator of a supersonic continuous-wave chemical HF laser with a flat nozzle block corresponding to the nozzle – nozzle reagent mixing scheme. As such ways, we consider increasing the residence time of reagents in the combustion chamber and rising temperature in the chemical reaction zone. Comparison of specific energy characteristics of an HF laser operating with the use of the studied (NF{sub 3}) and ‘basic’ (F{sub 2}) oxidisers shows that the replacement of molecular fluorine with nitrogen trifluoride during the burning with deuterium in the combustion chamber of an atomic fluorine generator with allowance for the proposed measures leads to a reduction in the specific laser energy output by no more than 23 % – 24 % at high burning completeness. (paper)
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Modeling the impact of COVID-19 on air quality in southern California: implications for future control policies
Abstract. In response to the coronavirus disease of 2019 (COVID-19), California issued statewide stay-at-home orders, bringing about abrupt and dramatic reductions in air pollutant emissions. This crisis offers us an unprecedented opportunity to evaluate the effectiveness of emission reductions in terms of air quality. Here we use the Weather Research and Forecasting model with Chemistry (WRF-Chem) in combination with surface observations to study the impact of the COVID-19 lockdown measures on air quality in southern California. Based on activity level statistics and satellite observations, we estimate the sectoral emission changes during the lockdown. Due to the reduced emissions, the population-weighted concentrations of fine particulate matter (PM2.5) decrease by 15 % in southern California. The emission reductions contribute 68 % of the PM2.5 concentration decrease before and after the lockdown, while meteorology variations contribute the remaining 32 %. Among all chemical compositions, the PM2.5 concentration decrease due to emission reductions is dominated by nitrate and primary components. For O3 concentrations, the emission reductions cause a decrease in rural areas but an increase in urban areas; the increase can be offset by a 70 % emission reduction in anthropogenic volatile organic compounds (VOCs). These findings suggest that a strengthened control on primary PM2.5 emissions and a well-balanced control on nitrogen oxides and VOC emissions are needed to effectively and sustainably alleviate PM2.5 and O3 pollution in southern California.
54 ENVIRONMENTAL SCIENCES↗
Development of EPA aircraft piston engine emission standards
Piston engine light aircraft are significant sources of carbon monoxide in the vicinity of high activity general aviation airports. Substantial reductions in carbon monoxide were achieved by fuel mixture leaning using improved fuel management systems. The air quality impact of the hydrocarbon and oxides of nitrogen emissions from piston engine light aircraft were insufficient to justify the design constraints being confronted in present control system developments.
Houtman, W.↗
Xenon implantation of nanodiamond films for targeted color center emission at sub-nanosecond time scales
In this work, the lifetime of nitrogen-vacancy color centers within nanodiamonds is reduced from 550±13 ps to 297±10 ps through the implantation of xenon. Coupled-mode analysis is employed to characterize the mechanism responsible for the reduction in emission lifetime. The observed spectral lineshape is found to be consistent with a Voigt profile consisting of two Lorentzian resonant peaks at 637 nm and 811 nm that are inhomogeneously broadened by a Gaussian distribution. A convolution of the frequency-domain Lorentzian output, with linewidths less than 1 nm, from the coupled-mode system of equations with a Gaussian with standard deviation of 85 nm is performed to generate the Voigt profile. The shortened emission lifetime is found to be consistent with a coupled mode theory model incorporating coupling between nitrogen-vacancy and xenon-vacancy color centers.
36 MATERIALS SCIENCE↗
Nitrogen-Doped Carbon Flowers with Fe and Ni Dual Metal Centers for Effective Electroreduction of Oxygen
Carbon-based nanocomposites have been attracting extensive attention as high-performance catalysts in alkaline media towards the electrochemical reduction of oxygen. Herein, polyacrylonitrile nanoflowers are synthesized via a free-radical polymerization route and used as a structural scaffold and precursor, whereby controlled pyrolysis leads to the ready preparation of carbon nanocomposites (FeNi-NCF) doped with both metal (Fe and Ni) and nonmetal (N) elements. Transmission electron microscopy studies show that the FeNi-NCF composites retain the flower-like morphology, with the metal species atomically dispersed into the flaky carbon petals. Remarkably, despite a similar structure, elemental composition, and total metal content, the FeNi-NCF sample with a high Fe:Ni ratio exhibits an electrocatalytic performance towards oxygen reduction reaction (ORR) in alkaline media that is similar to that by commercial Pt/C, likely due to the Ni to Fe electron transfer that promotes the adsorption and eventual reduction of oxygen, as evidenced in X-ray photoelectron spectroscopic measurements. Results from this study underline the importance of the electronic properties of metal dopants in the manipulation of the ORR activity of carbon nanocomposites.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Electrolyte Engineering for Efficient Electrochemical Nitrate Reduction to Ammonia on a Titanium Electrode
Nitrates from agricultural runoff and industrial waste streams are a notorious waste product and hazardous pollutant. Traditional electrochemical water remediation approaches aim to solve this problem by converting nitrates to environmentally benign N 2 while minimizing the production of environmentally hazardous side products such as ammonia and nitrous oxide in a process known as “denitrification”. We modify this concept and outline an opportunity to optimize the conversion of nitrates into ammonia, which is also a key commodity product used as a fertilizer, potential fuel, and chemical precursor. The electrochemical conversion of nitrates to ammonia recycles the fixed nitrogen and offers an appealing and supplementary alternative to the energy- and resource-intensive Haber-Bosch process. In this study, we investigated the effect of varying electrochemical conditions (pH, nitrate concentration, and applied potential) on the selective reduction of nitrate to ammonia at a titanium cathode. We observed that high concentrations of both protons and nitrate ions are needed to achieve high selectivity, reaching a peak of 82% Faradaic efficiency to ammonia at an applied potential of -1 V versus RHE and a partial current density to NH 3 of -22 mA/cm 2 , using 0.4 M [NO 3 – ] at pH ~0.77. The Ti electrode, as a poor hydrogen evolution catalyst with notable corrosion resistance, provides a large window of operating conditions to achieve high selectivity in the reduction of nitrate anions. Stability of the system was evaluated, and we found a high Faradaic efficiency throughout the course of an 8 h experiment. After electrochemical testing, titanium hydride was observed at the cathode surface. We also show a preliminary technoeconomic study, indicating that it may be feasible to employ an electrochemical strategy for the production of ammonium nitrate.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Lunar missions using advanced chemical propulsion: System design issues
To provide the transportation of lunar base elements to the moon, large high-energy propulsion systems will be required. Advanced propulsion systems for lunar missions can provide significant launch mass reductions and payload increases. These mass reductions and added payload masses can be translated into significant launch cost savings for the lunar base missions. The masses in low Earth orbit (LEO) were compared for several propulsion systems: nitrogen tetroxide/monomethyl hydrazine (NTO/MMH), oxygen/methane (O2/CH4), oxygen/hydrogen (O2/H2), and metallized O2/H2/Al propellants. Also, the payload mass increases enabled with O2/H2 and O2/H2/Al systems were addressed. In addition, many system design issues involving the engine thrust levels, engine commonality between the transfer vehicle and the excursion vehicle, and the number of launches to place the lunar mission vehicles into LEO will be discussed. Analyses of small lunar missions launched from a single STS-C flight are also presented.
TRT-THEORETICAL↗
Decoupling Surface Topography from Gravitational Acceleration in Cryogenic Pool Boiling
Boiling heat transfer is governed by a complex interplay between surface conditions and gravitational acceleration. To isolate the sole effects of gravity, we investigated the pool boiling characteristics of liquid nitrogen on atomically smooth silicon dioxide (SiO 2 ) surfaces under terrestrial (1-g) and reduced gravity (0±0.02 g) conditions achieved via parabolic flight. Our results quantify a drastic reduction in the critical heat flux (CHF) in reduced gravity, decreasing from 16.15 W/cm 2 at 1-g to 5−6 W/cm 2 at μ-g due to the suppression of buoyancy. Conversely, we observed a distinct increase in the heat transfer coefficient (HTC) in the reduced gravity condition prior to CHF. By utilizing a surface with a maximum peak-to-valley height of ≈36.7 nm and low contact angle hysteresis (<10°), we confirm this HTC enhancement is an intrinsic response to the gravitational environment, decoupled from surface-defect-induced nucleation. These findings demonstrate that the influence of surface topography is significantly more prominent in reduced gravity than in terrestrial conditions, providing a critical baseline for rationalizing the design of cryogenic thermal management systems in space and quantum applications.
Liquid nitrogen↗
Cryogenic Nitrogen Thermosyphon Developed and Characterized
A two-phase nitrogen thermosyphon was developed at the NASA Glenn Research Center to efficiently integrate a cryocooler into an insulated liquid-nitrogen-filled tank as part of an advanced development zero-boiloff (ZBO) ground test. NASA Marshall Space Flight Center's (MSFC) Advanced Space Transportation Program supported this test to improve the performance of in-space propulsion system concepts. Recent studies (ref. 1) have shown significant mass reductions and other advantages when incorporating active cooling in a ZBO configuration, enabling consideration of high-performing cryogenic propellants for long-duration applications in space. Active cooling was integrated via a thermosyphon, made of copper, 42 in. (1070 mm) long with an inner diameter of 0.436 in. (11 mm). It was charged with nitrogen to 225 psia at 300 K, which provided a fill ratio of 15 percent. The temperatures and heat flows through the thermosyphon were monitored during the startup phase of the ZBO test, and steady-state tests were conducted over a range of increasing and decreasing heat flows. The results also were compared with the initial design calculations and with results for a similar thermosyphon. They show that the thermal resistance of the thermosyphon was one-half of that expected--0.2 K/W at a heat flow of 8.0 W. The design calculations also showed that this resistance can be made relatively constant over a wider range of heat flows by making the ratio of evaporator area to condenser area 3:1. The better-than-expected results will translate into reduced integration loss for the ZBO concept.
Plachta, David W.↗
Electrochemical Conversion of CO 2 to Syngas with Controllable CO/H 2 Ratios over Co and Ni Single-Atom Catalysts
The electrochemical CO 2 reduction reaction (CO 2 RR) to yield synthesis gas (syngas, CO and H 2 ) has been considered as a promising method to realize the net reduction in CO 2 emission. However, it is challenging to balance the CO 2 RR activity and the CO/H 2 ratio. To address this issue, nitrogen-doped carbon supported single-atom catalysts are designed as electrocatalysts to produce syngas from CO 2 RR. While Co and Ni single-atom catalysts are selective in producing H2 and CO, respectively, electrocatalysts containing both Co and Ni show a high syngas evolution (total current 74 mA cm -2 ) with CO/H 2 ratios (0.23-2.26) that are suitable for typical downstream thermochemical reactions. Density functional theory calculations provide insights into the key intermediates on Co and Ni single-atom configurations for the H 2 and CO evolution. The results present a useful case on how non-precious transition metal species can maintain high CO 2 RR activity with tunable CO/H 2 ratios.
25 ENERGY STORAGE↗
Urbanization and edge effects interact to drive mutualism breakdown and the rise of unstable pathogenic communities in forest soil
Temperate forests are threatened by urbanization and fragmentation, with over 20% (118,300 km 2 ) of U.S. forest land projected to be subsumed by urban land development. We leveraged a unique, well-characterized urban-to-rural and forest edge-to-interior gradient to identify the combined impact of these two land use changes—urbanization and forest edge creation—on the soil microbial community in native remnant forests. We found evidence of mutualism breakdown between trees and their fungal root mutualists [ectomycorrhizal (ECM) fungi] with urbanization, where ECM fungi colonized fewer tree roots and had less connectivity in soil microbiome networks in urban forests compared to rural forests. However, urbanization did not reduce the relative abundance of ECM fungi in forest soils; instead, forest edges alone led to strong reductions in ECM fungal abundance. At forest edges, ECM fungi were replaced by plant and animal pathogens, as well as copiotrophic, xenobiotic-degrading, and nitrogen-cycling bacteria, including nitrifiers and denitrifiers. Urbanization and forest edges interacted to generate new “suites” of microbes, with urban interior forests harboring highly homogenized microbiomes, while edge forest microbiomes were more heterogeneous and less stable, showing increased vulnerability to low soil moisture. When scaled to the regional level, we found that forest soils are projected to harbor high abundances of fungal pathogens and denitrifying bacteria, even in rural areas, due to the widespread existence of forest edges. Our results highlight the potential for soil microbiome dysfunction—including increased greenhouse gas production—in temperate forest regions that are subsumed by urban expansion, both now and in the future.
54 ENVIRONMENTAL SCIENCES↗
Kryptonate Hydrogen Detection System (Final Report)
A prototype model of a multipurpose instrument which demonstrates the applicability of the Kryptonate® technique for detecting hydrogen gas was developed. This report describes the construction of the instrument and presents a laboratory evaluation of its performance. Performance was excellent. The instrument was designed to detect hydrogen in air at concentrations of 0-3% by volume, and to detect hydrogen in nitrogen or other inert gas at concentrations of 0-10% by volume. Other detection levels (both higher and lower) could be set if required. Ultimate response times can be made of the order of 0.5 seconds. The instrument is an all solid state device operating from 120V 60 Hz power source. The instrument has been designed to enable modifications to be made with a minimum amount of difficulty.
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
Hydrogen and oxygen sensor development
A reliable and low cost gas sensor was investigated for instantaneously detecting H2 in N2, H2 in air, and O2 in N2. The major portion of the research was spent in developing a sensor which would instantaneously detect H2 to + or - 50 ppm even in the presence of trace amounts of other gases. The experimental procedures used to provide the performance characteristics for the various oscillators are discussed describing the equipment with help of schematics and photographs where applicable. The resulting performance is given in graphical form. In some cases both hydrogen and helium may be present and since both of them effect gas sensors similarly, a method was found to determine the concentration of each. The methods developed are grouped into the following four broad categories: pure metal response, variation in heat conductivity, reduction methods, and exotic processes. From the above it was decided for the present to use a copper oxide reduction process as this process was demonstrated to be capable of determining the concentrations of hydrogen and helium respectively in a gas mixture with air or nitrogen.
Farber, E. A.↗
A comparison of two transient methods of measuring thermal conductivity of particulate samples.
A comparison is made of the line source (LS) method and the differential line source (DLS) method of measuring thermal conductivity of particulate materials in vacuum. The DLS method requires more instrumentation in the measuring circuitry (an additional amplifier and a differentiating circuit), but since it does not require a stable temperature to initiate a test, it does not need a sample temperature control system. DLS tests can be taken as the temperature in the samples is rising from liquid nitrogen temperature to room temperature. This eliminates the practice of extrapolating thermal conductivity over this large temperature range. Also, the advantages of reduced test time, data reduction time, and small sample temperature rise enable the experimenter to take about 7-12 DLS tests in the time of 2 LS tests. Test data from the two methods agree very well.
Scott, R. W.↗
How Well Satellite Remote Sensing Can Inform Surface Level Ozone Production Sensitivity to Precursor Trace Gas Emissions?
Surface-level ozone (O3) pollution mitigation strategies rely on a clear understanding of the atmospheric chemical processes involving O3, NOx (nitric oxide (NO) + nitrogen dioxide (NO2)) and volatile organic compounds (VOCs). A robust spatiotemporal classification of O3 photochemical regimes with relative chemical sensitivity of local O3 formation to emission reductions of NOx (NOx-limited regime) versus VOCs (radical-limited regime) is required to design anthropogenic emission reduction policies in order to improve surface air quality. Numerous studies found that the ratio of satellite-retrieved Vertical Column Densities (VCDs) of formaldehyde (HCHO) to NO2 can diagnose O3 production sensitivity. However, uncertainty still remains about the accuracy of such estimates using satellite-based retrievals. This study conducts an investigation to identify how well satellite data can inform surface-level O3 sensitivity by validating satellite-based estimates against aircraft-based retrievals taken during the Long Island Sound Tropospheric Ozone Study (LISTOS-2018) and Ozone Water-Land Environmental Transition Study (OWLETS-2) field campaigns. For this study, we use HCHO and NO2 retrievals from the Ozone Monitoring Instrument (OMI) onboard the Aura satellite, and high spatiotemporal resolution TROPOspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor (S5P) satellite. The Community Multiscale Air Quality (CMAQ) modelling system is used to provide trace gas vertical profiles to recalculate air mass factor for deriving consistent satellite-based VCDs. To demonstrate the ability of satellites to diagnose O3 production regimes, we validate satellite-derived O3 sensitivity regimes, along with the OMI and TROPOMI products applied, using HCHO and NO2 retrievals from the aircraft-based instruments: Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) spectrometer and Geostationary Coastal and Air Pollution Events Airborne Simulator (GCAS) instruments deployed during the LISTOS-2018 and OWLETS-2 campaigns. The results of this work will advance our fundamental knowledge of the spatiotemporal evolution of the complex O3-NOx-VOC chemistry, and will advance our understanding about the quality of remote-sensing, suborbital, and satellite data for accurately observing surface-level O3 production sensitivity.
Satellite↗
Solid-State Thermodynamic Vent System for Control of Cryogenic Propellants
A Solid-State Thermodynamic Vent System (STVS) is a novel Cryogenic Fluid Management (CFM) technology for spacecraft cryogenic propellant tanks that may reduce boiloff while providing greater control over the propellent condition. By exploiting the vacuum-induced cryocooling potential of cryogen-saturated silica aerogel material, an internal STVS heat exchanger expels some sacrificial cryogenic propellant to the vacuum of space to produce cooling within the storage tank. This cooling is transferred directly to the stored fluid, thereby reducing boiloff and increasing hold times. The primary STVS project objective was to design and build a bespoke STVS heat exchanger that employed aerogel blanket material and perform a ground demonstration of the technology using liquid nitrogen (LN2) as the cryogenic propellant. This demonstration aimed to prove that an STVS can have a positive influence on the tank boiloff, shown through a reduction in mass flow rate out of the system during operation, and exercise control over the tank pressure. Testing proved the effectiveness of the concept by reducing the LN2 boiloff rate and tank pressure by roughly 70% and 77% respectively during a single pump-down cycle, which sacrificed around 1.8 kg of propellant.
Propellant Production↗
Carbon nanodot precursors enable ultrahigh-loading copper single-atom catalysts for oxygen reduction reaction
Single-atom catalysts (SACs) have attracted significant attention in electrocatalysis due to their high metal utilization and tunable electronic structures; however, their practical implementation is often limited by poor atomic dispersion, low metal loadings (typically < 1 wt%), and insufficient anchoring of single metal atoms on catalyst supports. Herein, we report a simple and versatile strategy to synthesize copper single-atom catalysts (Cu-SACs) with ultrahigh metal loading using citric-acid-derived carbon nanodots as metal-capturing precursors. Through hydrothermal treatment followed by pyrolysis in the presence of urea, atomically dispersed copper atoms coordinated with nitrogen are incorporated into a carbon framework, achieving a Cu loading of up to 20 wt% while maintaining atomic dispersion. Notably, a significant fraction of the copper single atoms exists as Cu+–N2 coordination, which provides under-coordinated and catalytically active sites. The resulting Cu-SAC exhibits promising oxygen reduction reaction (ORR) activity in alkaline media, delivering a limiting current density comparable to that of commercial 20 wt% Pt/C with a predominant four-electron reduction pathway. Despite this high intrinsic activity, durability tests reveal gradual performance degradation under prolonged electrochemical operation, which is attributed to demetallation and aggregation of copper single atoms into metallic nanoparticles. These results demonstrate the potential of carbon nanodot-based platforms for synthesizing high-loading SACs, while underscoring the critical need to simultaneously control carbon porosity and metal–nitrogen coordination to enhance active-site accessibility and durability.
Sharma, Prakhar [University of Kentucky]↗