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At least 541 records · Page 30

Frontier nonequilibrium materials science enabled by ultrafast electron methods

Most innovation in materials science and engineering resides in our ability to understand and control the intimate relationship between the structure of materials and their properties. Conventionally, the only route to discovering innovative new material properties has been to explore the structural and compositional phase space that is accessible at (or near) thermodynamic equilibrium. The characterization, manipulation and, ultimately, control of material properties far from equilibrium offers almost completely untapped possibilities for uncovering novel states and phases of materials. Investigations of materials far from equilibrium require the development of new techniques, which are capable of following dynamic processes in materials with extreme spatiotemporal resolution. Thus, ultrafast electron-based methods have become a major new frontier in materials science due to the capability of following dynamics on time scales as short as femtoseconds with the high spatial resolution and sensitivity afforded by electrons. The articles in this issue provide an exciting cross section of the novel research directions that have been enabled at this frontier. Imaging on ultrafast time scales carries critical information on phase transitions, fundamental processes involved in light-harvesting, magnetic, and plasmonic dynamics, the coupling of electronic and nuclear degrees of freedom in materials and has revealed previously hidden, nonequilibrium metastable states of matter that have no equilibrium analog.

36 MATERIALS SCIENCE↗

A Compact Airborne High Spectral Resolution Lidar for Observations of Aerosol and Cloud Optical Properties

We are in the process of developing a nadir-viewing, aircraft-based high spectral resolution lidar (HSRL) at NASA Langley Research Center. The system is designed to measure backscatter and extinction of aerosols and tenuous clouds. The primary uses of the instrument will be to validate spaceborne aerosol and cloud observations, carry out regional process studies, and assess the predictions of chemical transport models. In this paper, we provide an overview of the instrument design and present the results of simulations showing the instrument's capability to accurately measure extinction and extinction-to-backscatter ratio.

Hostetler, Chris A.↗

Analysis and improved design considerations for airborne pulse Doppler radar signal processing in the detection of hazardous windshear

High resolution windspeed profile measurements are needed to provide reliable detection of hazardous low altitude windshear with an airborne pulse Doppler radar. The system phase noise in a Doppler weather radar may degrade the spectrum moment estimation quality and the clutter cancellation capability which are important in windshear detection. Also the bias due to weather return Doppler spectrum skewness may cause large errors in pulse pair spectral parameter estimates. These effects are analyzed for the improvement of an airborne Doppler weather radar signal processing design. A method is presented for the direct measurement of windspeed gradient using low pulse repetition frequency (PRF) radar. This spatial gradient is essential in obtaining the windshear hazard index. As an alternative, the modified Prony method is suggested as a spectrum mode estimator for both the clutter and weather signal. Estimation of Doppler spectrum modes may provide the desired windshear hazard information without the need of any preliminary processing requirement such as clutter filtering. The results obtained by processing a NASA simulation model output support consideration of mode identification as one component of a windshear detection algorithm.

Lee, Jonggil↗

Studies of Antarctic Sea Ice Concentrations from Satellite Data and Their Applications

Large changes in the sea ice cover have been observed recently. Because of the relevance of such changes to climate change studies it is important that key ice concentration data sets used for evaluating such changes are interpreted properly. High and medium resolution visible and infrared satellite data are used in conjunction with passive microwave data to study the true characteristics of the Antarctic sea ice cover, assess errors in currently available ice concentration products, and evaluate the applications and limitations of the latter in polar process studies. Cloud-free high resolution data provide valuable information about the natural distribution, stage of formation, and composition of the ice cover that enables interpretation of the large spatial and temporal variability of the microwave emissivity of Antarctic sea ice. Comparative analyses of co-registered visible, infrared and microwave data were used to evaluate ice concentrations derived from standard ice algorithms (i.e., Bootstrap and Team) and investigate the 10 to 35% difference in derived values from large areas within the ice pack, especially in the Weddell Sea, Amundsen Sea, and Ross Sea regions. Landsat and OLS data show a predominance of thick consolidated ice in these areas and show good agreement with the Bootstrap Algorithm. While direct measurements were not possible, the lower values from the Team Algorithm results are likely due to layering within the ice and snow and/or surface flooding, which are known to affect the polarization ratio. In predominantly new ice regions, the derived ice concentration from passive microwave data is usually lower than the true percentage because the emissivity of new ice changes with age and thickness and is lower than that of thick ice. However, the product provides a more realistic characterization of the sea ice cover, and are more useful in polar process studies since it allows for the identification of areas of significant divergence and polynya activities. Also, heat and salinity fluxes are proportionately increased in these areas compared to those from the thicker ice areas. A slight positive trend in ice extent and area from 1978 through 2000 is observed consistent with slight continental cooling during the period. However, the confidence in this result is only moderate because the overlap period for key instruments is just one month and the sensitivity to changes in sensor characteristics, calibration and threshold for the ice edge is quite high.

Comiso, Josefino C.↗

DESPERATE: A Python Library for Processing and Denoising NMR Spectra

NMR spectroscopy is an inherently insensitive technique with respect to the amount of observable signal. A common element in all NMR spectra is random thermal noise that is often characterized by a signal-to-noise ratio (SNR). SNR can be generically improved experimentally with repetitive signal averaging or during post-processing with apodization; the former of which often results in long experimental times and the latter results in the loss of spectral resolution. Denoising techniques can instead be used during post-processing to enhance SNR without compromising resolution. The most common approach relies on the singular-value decomposition (SVD) to discard noisy components of NMR data. SVD-based approaches work well, such as Cadzow and PCA, but are computationally expensive when used for large datasets that are often encountered in NMR (e.g., Carr-Purcell/Meiboom-Gill and nD datasets). Herein, we describe the implementation of a new wavelet transform (WT) routine for the fast and robust denoising of 1D and 2D NMR spectra. Several simulated and experimental datasets are denoised with both SVD-based Cadzow or PCA and WT’s, and the resulting SNR enhancements and spectral uniformity are compared. WT denoising offers similar and improved denoising compared with SVD and operates faster by several orders-of-magnitude in some cases. Further, all denoising and processing routines used in this work are included in a free and open-source Python library called DESPERATE.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Shape from spectra

We introduce a new unified atmospheric–topographic correction approach that estimates surface geometry directly from the radiance measurement. Surface topography influences the at-sensor radiance measurement, making precise topography modeling critical in applications like vegetation or snow studies in mountainous terrain. Currently, elevation maps are used to derive topographic variables such as the slope and sky-view factor. This process is error-prone since static global digital elevation models do not generally achieve the accuracy required, and even minor mismatches in spatial resolution can introduce significant artifacts in downstream processing. Here we demonstrate that it is possible to estimate topographic parameters directly from spectral data, ensuring perfect physical consistency, temporal coincidence, and spatial alignment. We present experiments estimating topographic slope in two scenes in Southern California, with data from NASA’s Next Generation Airborne Visible/Near Infrared Imaging Spectrometer (AVIRIS-NG). We compared our radiance-based estimates against high-resolution lidar datasets. Our initial validation result showed a correlation of R 2 = 0.864 (n = 160) over the homogeneous surface of Beckman Auditorium’s cone-shaped roof on the Caltech campus in Pasadena, California. We then validate the model over a larger study site near Santa Clarita, California, finding R 2 = 0.923 (n = 40,000) in a 350 x 350m area. The accuracy of our model estimates, combined with its systematic advantages over the alternative, show the potential of the approach for use in both airborne campaigns and orbital missions.

Nimrod Carmon↗

An Integrated Modeling Framework for Sediment Dynamics During Urban Flooding: Application to Hurricane Harvey in Houston

Floodwater can mobilize and redistribute large volumes of sediment from upland to downstream urban areas, threatening infrastructure, water quality, and ecosystem health. However, existing modeling approaches often fail to capture sediment dynamics in urban floodplains due to the lack of integration between upland hydrological processes and riverine sediment transport. This study presents the first integrated modeling framework that couples the Energy Exascale Earth System Model (E3SM) land component, which simulates runoff and hillslope erosion, with TELEMAC-GAIA, a two-dimensional hydrodynamic and sediment transport model. This framework enables the fully distributed, process-based simulation of high-resolution (as fine as 30 m) sediment dynamics from hillslopes to floodplains. Applied to a highly urbanized watershed in Houston during Hurricane Harvey, this framework reproduced observed water levels at 16 USGS gauges (median R 2 = 0.83 and KGE = 0.78), key sediment dynamics such as sediment transport and deposition processes, and reproduced spatial deposition patterns consistent with LiDAR-derived data. Based on the simulation, we estimate 8.0 million m 3 of event-scale sediment deposition, including 5.7 million m 3 trapped in the flood-control reservoirs and 2.3 million m 3 deposited along major channels and floodplains. Using a representative unit removal cost, this corresponds to an estimated dredging cost of $581 million for total deposition. These results provide a first-order, physically based quantification of Harvey-scale sediment impacts. This study provides a valuable tool for the holistic analysis of sediment dynamics triggered by extreme urban flooding, supporting flood-resilience planning. More broadly, it highlights the importance of integrating physically based hydrological processes for urban flooding and sediment research.

Hurricane Harvey↗

BOREAS TE-18, 60-m, Radiometrically Rectified Landsat TM Imagery

The BOREAS TE-18 team used a radiometric rectification process to produce standardized DN values for a series of Landsat TM images of the BOREAS SSA and NSA in order to compare images that were collected under different atmospheric conditions. The images for each study area were referenced to an image that had very clear atmospheric qualities. The reference image for the SSA was collected on 02-Sep-1994, while the reference image for the NSA was collected on 2 1 Jun-1995. The 23 rectified images cover the period of 07-Jul-1985 to 18-Sep-1994 in the SSA and 22-Jun-1984 to 09-Jun-1994 in the NSA. Each of the reference scenes had coincident atmospheric optical thickness measurements made by RSS-11. The radiometric rectification process is described in more detail by Hall et al. (1991). The original Landsat TM data were received from CCRS for use in the BOREAS project. Due to the nature of the radiometric rectification process and copyright issues, the full-resolution (30-m) images may not be publicly distributed. However, this spatially degraded 60-m resolution version of the images may be openly distributed and is available on the BOREAS CD-ROM series. After the radiometric rectification processing, the original data were degraded to a 60-m pixel size from the original 30-m pixel size by averaging the data over a 2- by 2-pixel window. The data are stored in binary image-format files. The data files are available on a CD-ROM (see document number 20010000884), or from the Oak Ridge National Laboratory (ORNL) Distributed Activity Archive Center (DAAC).

Hall, Forrest G.↗

Level 1 Processing of MODIS Direct Broadcast Data From Terra

In February 2000, an effort was begun to adapt the Moderate Resolution Imaging Spectroradiometer (MODIS) Level 1 production software to process direct broadcast data. Three Level 1 algorithms have been adapted and packaged for release: Level 1A converts raw (level 0) data into Hierarchical Data Format (HDF), unpacking packets into scans; Geolocation computes geographic information for the data points in the Level 1A; and the Level 1B computes geolocated, calibrated radiances from the Level 1A and Geolocation products. One useful aspect of adapting the production software is the ability to incorporate enhancements contributed by the MODIS Science Team. We have therefore tried to limit changes to the software. However, in order to process the data immediately on receipt, we have taken advantage of a branch in the geolocation software that reads orbit and altitude information from the packets themselves, rather than external ancillary files used in standard production. We have also verified that the algorithms can be run with smaller time increments (2.5 minutes) than the five-minute increments used in production. To make the code easier to build and run, we have simplified directories and build scripts. Also, dependencies on a commercial numerics library have been replaced by public domain software. A version of the adapted code has been released for Silicon Graphics machines running lrix. Perhaps owing to its origin in production, the software is rather CPU-intensive. Consequently, a port to Linux is underway, followed by a version to run on PC clusters, with an eventual goal of running in near-real-time (i.e., process a ten-minute pass in ten minutes).

Lynnes, Christopher↗

Measuring a Precise Ultra-Lightweight Spaceflight Mirror on Earth: The Analysis of the SHARPI PM Mirror Figure Data during Mirror Processing at GSFC

The SHARPI (Solar High Angular Resolution Photometric Imager) primary mirror is a 5kg, 0.5m paraboloid, diffraction limited at FUV wavelengths when placed in a 0-G environment. The ULE sandwich honeycomb mirror and the attached mount pads were delivered by ITT (then Kodak) in 2003 to NASA s Goddard Space Flight Center (GSFC). At GSFC, we accepted, coated, mounted, and vibration tested this mirror in preparation for flight on the PICTURES (Planet Imaging Concept Testbed Using a Rocket Experiment) mission. At each step, the integrated analysis of interferometer data and FEA models was essential to quantify the 0-G mirror figure. This task required separating nanometer sized variations from hundreds of nanometers of gravity induced distortion. The ability to isolate such features allowed in-situ monitoring of mirror figure, diagnosis of perturbations, and remediation of process errors. In this paper, we describe the technical approach used to achieve these measurements and overcome the various difficulties maintaining UV diffraction-limited performance with this aggressively lightweighted mirror.

Antonille, Scott↗

The CLoud–Aerosol–Radiation Interaction and Forcing: Year 2017 (CLARIFY-2017) measurement campaign

The representations of clouds, aerosols, and cloud–aerosol–radiation impacts remain some of the largest uncertainties in climate change, limiting our ability to accurately reconstruct past climate and predict future climate. The south-east Atlantic is a region where high atmospheric aerosol loadings and semi-permanent stratocumulus clouds are co-located, providing an optimum region for studying the full range of aerosol–radiation and aerosol–cloud interactions and their perturbations of the Earth's radiation budget. While satellite measurements have provided some useful insights into aerosol–radiation and aerosol–cloud interactions over the region, these observations do not have the spatial and temporal resolution, nor the required level of precision to allow for a process-level assessment. Detailed measurements from high spatial and temporal resolution airborne atmospheric measurements in the region are very sparse, limiting their use in assessing the performance of aerosol modelling in numerical weather prediction and climate models. CLARIFY-2017 was a major consortium programme consisting of five principal UK universities with project partners from the UK Met Office and European- and USA-based universities and research centres involved in the complementary ORACLES, LASIC, and AEROCLO-sA projects. The aims of CLARIFY-2017 were fourfold: (1) to improve the representation and reduce uncertainty in model estimates of the direct, semi-direct, and indirect radiative effect of absorbing biomass burning aerosols; (2) to improve our knowledge and representation of the processes determining stratocumulus cloud microphysical and radiative properties and their transition to cumulus regimes; (3) to challenge, validate, and improve satellite retrievals of cloud and aerosol properties and their radiative impacts; (4) to improve the impacts of aerosols in weather and climate numerical models. This paper describes the modelling and measurement strategies central to the CLARIFY-2017 deployment of the FAAM BAe146 instrumented aircraft campaign, summarizes the flight objectives and flight patterns, and highlights some key results from our initial analyses.

54 ENVIRONMENTAL SCIENCES↗

DEEPEN: Newberry Volcano MT and Gravity Data - 2022 and 2023 Acquisition and Processing

As part of DEEPEN (DE-risking Exploration of geothermal Plays in magmatic ENvironments), a 3D play fairway analysis (PFA) was conducted at Newberry Volcano in Central Oregon for multiple play types (conventional hydrothermal, superhot EGS, and supercritical). For use in this PFA, combined full tensor broadband magnetotelluric (MT) and gravity data were acquired, processed, and inverted by Enthalpion Energy LLC (Enthalpion) with support from NREL staff. The data collection efforts took place from June 19th to July 24. Data were collected with the goal of gaining an improved understanding of the South Flank and the extent of the magma chamber. This GDR submission includes the raw data, single inversions, joint inversions, resolution matrices, and a report on these processes. More detailed information about the folder structure of the datasets included in this submission may be found on pages 94-97 of Magnetotelluric and Gravity Survey Report.pdf below.

15 GEOTHERMAL ENERGY↗

Digitizing Named Entities Found Within Letters of Agreement

Letters of Agreement (LOAs) are text-based air traffic control documents that contain procedures and actions agreed upon by the different parties, typically two or more FAA facilities, that are subject to an agreement. The documents contain among other things generic constraints, which are explicit and implicit combinations of procedures that limit a flight’s trajectory and affects pilot actions. For example, a controller may be required, to assign a specific altitude to an aircraft crossing the boundary between two airspaces. Although LOA generic constraints directly impact the trajectory of an aircraft, they are not currently available in a digital form that can be used for (or directly ingested into automated) flight planning. Instead, the constraints are manually input into an onboard or ground based system. LOA documents are primarily stored at a controlling facility and the generic constraints are implemented by experienced air traffic controllers and pilots primarily using voice instructions. This increases the workload of the controllers, likelihood of error (e.g., due to noisy communication) and makes it impractical for implementation with unmanned aircraft. Therefore, steps must be taken to make existing constraints machine interpretable to enable e.g., automated handoffs which in turn would reduce controller workload. With recent advances in natural language processing, especially the rise in digitization of text documents (e.g., medical documents) and automated extraction of information therein, it is now possible to extract flight specific constraints from LOAs. The goal of this work is to digitize named entities through a combination of natural language processing tasks: named entity disambiguation, toponym resolution, and numeric parsing to extract general constraint components contained within LOAs, herein referred to as Entity Enhancement (EE). Starting with a small list of named entities (e.g., ARTCC, Tower, Altitude and Speed), EE can extract the named entities while simultaneously converting the string-based output into a digital format using an ensemble of processes like rule-based gazetteers and syntactic-lexical patterns. The digital format contains a diverse set of information based on the entity label in question, ranging from standardized facility names to units of measure (e.g., feet) and other numeric information. Upon validating our approach using a truth dataset, we show an overall F1-Score of 0.71 for the extraction process. Looking beyond entity enhancement, we are also working towards the goal of completely digitizing the general constraints by performing EE and fitting them into a standardized exchange model (XM) such as the Aeronautical Information Exchange Model (AIXM). This will allow for easy distribution and dissemination of LOA constraints to air users, better searchability within documents, and enable ingestion into automated flight planning. Finally, we show a preliminary version of the proposed XM architecture and demonstrate how the model can be populated from the EE output.

Stephen S. B. Clarke↗

Super-resolution and signal separation in contact Kelvin probe force microscopy of electrochemically active ferroelectric materials

In this work, imaging mechanisms in contact Kelvin probe force microscopy (cKPFM) are explored via information theory-based methods. Gaussian processes are used to achieve super-resolution in the cKPFM signal, effectively extrapolating across the spatial and parameter space. Tensor factorization is applied to reduce the multidimensional signal to the tensor convolution of the scalar functions that show a clear trending behavior with the imaging parameters. These methods establish a workflow for the analysis of the multidimensional datasets that can then be related to the relevant physical mechanisms. We also provide an interactive Google Colab notebook that goes through all the analyses discussed in the paper.

36 MATERIALS SCIENCE↗

Fabrication Development for SPT-SLIM, a Superconducting Spectrometer for Line Intensity Mapping

Line Intensity Mapping (LIM) is a new observational technique that uses low-resolution observations of line emission to efficiently trace the large-scale structure of the Universe out to high redshift. Common mm/sub-mm emission lines are accessible from ground-based observatories, and the requirements on the detectors for LIM at mm-wavelengths are well matched to the capabilities of large-format arrays of superconducting sensors. We describe the development of an R = lambda/Delta lambda = 300 on-chip superconducting filter-bank spectrometer covering the 120-180 GHz band for future mm-LIM experiments, focusing on SPT-SLIM, a pathfinder LIM instrument for the South Pole Telescope. Radiation is coupled from the telescope optical system to the spectrometer chip via an array of feedhorn-coupled orthomode transducers. Superconducting microstrip transmission lines then carry the signal to an array of channelizing half-wavelength resonators, and the output of each spectral channel is sensed by a lumped element kinetic inductance detector (leKID). Key areas of development include incorporating new low-loss dielectrics to improve both the achievable spectral resolution and optical efficiency and development of a robust fabrication process to create a galvanic connection between ultra-pure superconducting thin-films to realize multi-material (hybrid) leKIDs. We provide an overview of the spectrometer design, fabrication process, and prototype devices.

microstrip resonators↗

Monitoring Geothermal Features in Yellowstone National Park with ATLAS Multispectral Imagery

The National Park Service (NPS) must produce an Environmental Impact Statement for each proposed development in the vicinity of known geothermal resource areas (KGRAs) in Yellowstone National Park. In addition, the NPS monitors indicator KGRAs for environmental quality and is still in the process of mapping many geothermal areas. The NPS currently maps geothermal features with field survey techniques. High resolution aerial multispectral remote sensing in the visible, NIR, SWIR, and thermal spectral regions could enable YNP geothermal features to be mapped more quickly and in greater detail In response, Yellowstone Ecosystems Studies, in partnership with NASA's Commercial Remote Sensing Program, is conducting a study on the use of Airborne Terrestrial Applications Sensor (ATLAS) multispectral data for monitoring geothermal features in the Upper Geyser Basin. ATLAS data were acquired at 2.5 meter resolution on August 17, 2000. These data were processed into land cover classifications and relative temperature maps. For sufficiently large features, the ATLAS data can map geothermal areas in terms of geyser pools and hot springs, plus multiple categories of geothermal runoff that are apparently indicative of temperature gradients and microbial matting communities. In addition, the ATLAS maps clearly identify geyserite areas. The thermal bands contributed to classification success and to the computation of relative temperature. With masking techniques, one can assess the influence of geothermal features on the Firehole River. Preliminary results appear to confirm ATLAS data utility for mapping and monitoring geothermal features. Future work will include classification refinement and additional validation.

Spruce, Joseph↗

Material condition assessment with eddy current sensors

Eddy current sensors and sensor arrays are used for process quality and material condition assessment of conducting materials. In an embodiment, changes in spatially registered high resolution images taken before and after cold work processing reflect the quality of the process, such as intensity and coverage. These images also permit the suppression or removal of local outlier variations. Anisotropy in a material property, such as magnetic permeability or electrical conductivity, can be intentionally introduced and used to assess material condition resulting from an operation, such as a cold work or heat treatment. The anisotropy is determined by sensors that provide directional property measurements. The sensor directionality arises from constructs that use a linear conducting drive segment to impose the magnetic field in a test material. Maintaining the orientation of this drive segment, and associated sense elements, relative to a material edge provides enhanced sensitivity for crack detection at edges.

Goldfine, Neil J.↗

Super resolution for root imaging

Premise High‐resolution cameras are very helpful for plant phenotyping as their images enable tasks such as target vs. background discrimination and the measurement and analysis of fine above‐ground plant attributes. However, the acquisition of high‐resolution images of plant roots is more challenging than above‐ground data collection. An effective super‐resolution (SR) algorithm is therefore needed for overcoming the resolution limitations of sensors, reducing storage space requirements, and boosting the performance of subsequent analyses. Methods We propose an SR framework for enhancing images of plant roots using convolutional neural networks. We compare three alternatives for training the SR model: (i) training with non‐plant‐root images, (ii) training with plant‐root images, and (iii) pretraining the model with non‐plant‐root images and fine‐tuning with plant‐root images. The architectures of the SR models were based on two state‐of‐the‐art deep learning approaches: a fast SR convolutional neural network and an SR generative adversarial network. Results In our experiments, we observed that the SR models improved the quality of low‐resolution images of plant roots in an unseen data set in terms of the signal‐to‐noise ratio. We used a collection of publicly available data sets to demonstrate that the SR models outperform the basic bicubic interpolation, even when trained with non‐root data sets. Discussion The incorporation of a deep learning–based SR model in the imaging process enhances the quality of low‐resolution images of plant roots. We demonstrate that SR preprocessing boosts the performance of a machine learning system trained to separate plant roots from their background. Our segmentation experiments also show that high performance on this task can be achieved independently of the signal‐to‐noise ratio. We therefore conclude that the quality of the image enhancement depends on the desired application.

Ruiz‐Munoz, Jose F.↗