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At least 541 records · Page 30

Functional soft materials from blue phase liquid crystals

Blue phase (BP) liquid crystals are chiral fluids wherein millions of molecules self-assemble into cubic lattices that are on the order of hundred nanometers. As the unit cell sizes of BPs are comparable to the wavelength of light, they exhibit selective Bragg reflections in the visible. The exploitation of the photonic properties of BPs for technological applications is made possible through photopolymerization, a process that renders mechanical robustness and thermal stability. We review here the preparation and characterization of stimuli-responsive, polymeric photonic crystals based on BPs. We highlight recent studies that demonstrate the promise that polymerized BP photonic crystals hold for colorimetric sensing and dynamic light control. We review using Landau–de Gennes simulations for predicting the self-assembly of BPs and the potential for using theory to guide experimental design. Finally, opportunities for using BPs to synthesize new soft materials, such as highly structured polymer meshes, are discussed.

36 MATERIALS SCIENCE↗

Mechanical and Structural Behavior of Granular Material Packed Beds for Space Life Support System Applications

Long-term human mission to space, such as living in International Space Station (ISS), Lunar, and Martian bases, and travel to Mars, must m ake use of Advanced Life Support Systems (ALSS) to generate and recycle critical life supporting elements like oxygen and water. Oxygen Gen eration Assembly (OGA) and Water Processor Assembly (WPA), critical c omponents of ALSS, make use of series of granular material packed beds for generation and recycling of oxygen and water. Several granular m aterials can be used for generation, recycling, processing and recovery of oxygen and water. For example, they may include soft bed media, e.g. ion exchange resins for oxygen generation assembly and hard bed media such as, activated alumina, magchem (Magnesium oxide) and activa ted carbon to remove organic species like ethanol, methanol, and urea from wastewater in Water recovery/processing assembly. These beds are generally packed using a plate-spring mechanism to provide sufficien t compaction to the bed media throughout the course of operation. This paper presents results from an experimental study of a full-scale, 3 8.1 cm (15 inches) long and 3.7 cm (1.44 inches) diameter. activated alumina bed enclosed in a cylinder determining its force-displacement behavior, friction mobilizing force, and axial normal stress distribu tion under various axially applied loads and at different levels of packing. It is observed that force-displacement behavior is non-linear for low compaction level and becomes linear with increase in compaction of the bed media. Axial normal stress distribution along the length of the bed media decreased non-linearly with increase in depth from the loading end of the granular media. This paper also presents experimental results on the amount of particulates generated corresponding to various compaction levels. Particulates generated from each of the tests were measured using standard US sieves. It was found that the p articulates and the overall displacement of the bed media increased with decrease in initial compaction of the bed media. This effect could be attributed to the greater tendency for inter-particle sliding/rub bing due to smaller internal friction angles, as seen from the shear tests, at lesser initial compacted levels. Upon unloading, it was obse rved that there was no change in displacement (especially rebounding) in the bed media. This effect could be attributed to the fact that th e porous activated alumina particles fracture/break upon increase in applied load (during loading phase) and occupy void spaces in between the material grains; thereby leading to settling of the media. The lo ad-displacement curve becomes more linear with increase in initial compaction of the bed media. It is concluded that compaction considerabl y affects the load-displacement behavior of the bed media. A series of tests were also conducted on the packed bed media to determine the f orce required to mobilize the friction between the bed media and the housing cylinder. The results from these tests showed the existence of significant friction between the bed media and the encasing stainles s steel cylinder. Further, it was found that friction effects were more pronounced for media with higher initial compaction. Internal frict ion of the granular media was measured using direct shear apparatus. It was observed that the internal friction increased with increase in initial compaction of the bed media. In this study, a computational m odel (CM) is also developed using finite element software ANSYS to verify experimental results obtained for the distribution of the axial n ormal stress and axial displacement along the length of the full-scal e activated alumina bed media. In the computational model, the granular material is considered to have appropriate failure and frictional c ontact exists between the wall and the granular media. It is observed that the model predicts results closely with the experimental method. The compational results show that the axial normal stress distribution along the length of the activated alumina media decreases non-linea rly from the loading end and is negligible beyond a certain depth. Th is can be attributed to the existence of friction between the walls and the media and that the friction takes up most of the applied load.

Malla, Ramesh B.↗

Photoinduced anisotropic lattice dynamic response and domain formation in thermoelectric SnSe

Identifying and understanding the mechanisms behind strong phonon–phonon scattering in condensed matter systems is critical to maximizing the efficiency of thermoelectric devices. To date, the leading method to address this has been to meticulously survey the full phonon dispersion of the material in order to isolate modes with anomalously large linewidth and temperature-dependence. Here we combine quantitative MeV ultrafast electron diffraction (UED) analysis with Monte Carlo based dynamic diffraction simulation and first-principles calculations to directly unveil the soft, anharmonic lattice distortions of model thermoelectric material SnSe. A small single-crystal sample is photoexcited with ultrafast optical pulses and the soft, anharmonic lattice distortions are isolated using MeV-UED as those associated with long relaxation time and large displacements. We reveal that these modes have interlayer shear strain character, induced mainly by c -axis atomic displacements, resulting in domain formation in the transient state. These findings provide an innovative approach to identify mechanisms for ultralow and anisotropic thermal conductivity and a promising route to optimizing thermoelectric devices.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Focal adhesion kinase is involved in mechanosensing during fibroblast migration

Focal adhesion kinase (FAK) is a non-receptor protein tyrosine kinase localized at focal adhesions and is believed to mediate adhesion-stimulated effects. Although ablation of FAK impairs cell movement, it is not clear whether FAK might be involved in the guidance of cell migration, a role consistent with its putative regulatory function. We have transfected FAK-null fibroblasts with FAK gene under the control of the tetracycline repression system. Cells were cultured on flexible polyacrylamide substrates for the detection of traction forces and the application of mechanical stimulation. Compared with control cells expressing wild-type FAK, FAK-null cells showed a decrease in migration speed and directional persistence. In addition, whereas FAK-expressing cells responded to exerted forces by reorienting their movements and forming prominent focal adhesions, FAK-null cells failed to show such responses. Furthermore, FAK-null cells showed impaired responses to decreases in substrate flexibility, which causes control cells to generate weaker traction forces and migrate away from soft substrates. Cells expressing Y397F FAK, which cannot be phosphorylated at a key tyrosine site, showed similar defects in migration pattern and force-induced reorientation as did FAK-null cells. However, other aspects of F397-FAK cells, including the responses to substrate flexibility and the amplification of focal adhesions upon mechanical stimulation, were similar to that of control cells. Our results suggest that FAK plays an important role in the response of migrating cells to mechanical input. In addition, phosphorylation at Tyr-397 is required for some, but not all, of the functions of FAK in cell migration.

NASA Discipline Cell Biology↗

Unveiling the Emergent Traits of Chiral Spin Textures in Magnetic Multilayers

Abstract Magnetic skyrmions are topologically wound nanoscale textures of spins whose ambient stability and electrical manipulation in multilayer films have led to an explosion of research activities. While past efforts focused predominantly on isolated skyrmions, recently ensembles of chiral spin textures, consisting of skyrmions and magnetic stripes, are shown to possess rich interactions with potential for device applications. However, several fundamental aspects of chiral spin texture phenomenology remain to be elucidated, including their domain wall (DW) structure, thermodynamic stability, and morphological transitions. Here the evolution of these textural characteristics are unveiled on a tunable multilayer platform—wherein chiral interactions governing spin texture energetics can be widely varied—using a combination of full‐field electron and soft X‐ray microscopies with numerical simulations. With increasing chiral interactions, the emergence of Néel helicity, followed by a marked reduction in domain compressibility, and finally a transformation in the skyrmion formation mechanism are demonstrated. Together with an analytical model, these experiments establish a comprehensive microscopic framework for investigating and tailoring chiral spin texture character in multilayer films.

36 MATERIALS SCIENCE↗

The LPM effect in sequential bremsstrahlung: 1/$ {\mathrm{N}}_{\mathrm{c}}^2 $ corrections

An important question concerning in-medium high-energy parton showers in a quark-gluon plasma or other QCD medium is whether consecutive splittings of the partons in a given shower can be treated as quantum mechanically independent, or whether the formation times for two consecutive splittings instead have significant overlap. Various previous calculations of the effect of overlapping formation times have either (i) restricted attention to a soft bremsstrahlung limit, or else (ii) used the large-N c limit (where N c = 3 is the number of quark colors). In this paper, we make a first study of the accuracy of the large-N c limit used by those calculations of overlap effects that avoid a soft bremsstrahlung approximation. Specifically, we calculate the 1/$ {\mathrm{N}}_{\mathrm{c}}^2 $ correction to previous N c = ∞ results for overlap g → gg → ggg of two consecutive gluon splittings g → gg. At order 1/$ {\mathrm{N}}_{\mathrm{c}}^2 $ , there is interesting and non-trivial color dynamics that must be accounted for during the overlap of the formation times.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Proppant embedment in coal and shale: Impacts of stress hardening and sorption

During methane production in CBM reservoirs, the influence of proppant embedment and permeability damage cannot be neglected – especially where the wall-rock is soft. Effective stresses are elevated during methane recovery, increasing both normal loading stress and confinement and simultaneously overprinting sorption-induced volumetric strains. Experiments and analytic modeling are conducted to define key mechanisms controlling these competitive effects. We independently measure overall sample compaction (external LVDT) and local strain (strain gauge) in the matrix to deconvolve proppant embedment in a propped fracture for different conditions of confining stress. The results show symptomatic behaviors of elastic (shale) and elastoplastic (coal) responses of embedment. Different from shale, the evolution of embedment is convex upwards with increased stress where indented depth increases more rapidly as loading stress increases under constant confinement. In addition, a stress-hardening effect is found to play a pivotal role in determining the characteristics of indentation, which are examined in terms of evolution profiles, deformation regimes, embedment slopes, curvatures, yield points and irreversible indentations. Based on the experimental observations a semianalytical model predicts indentation and the evolution of propped permeability under recreated in-situ stress conditions. A simplified case study is conducted to further illustrate the evolution of aperture and permeability of a propped fracture in CBM reservoirs. The modeling results suggest that proppant embedment is significantly overestimated if the variable stress-hardening (VSH) effect is neglected, especially when effective stress is large. Moreover, a decrease in indentation depth possibly occurs during late stage methane production, resulting in a reversal/recovery in fracture closure. This is because desorption-induced shrinkage becomes the predominant effect, causing an increase in aperture and a reduction in the indented volume of proppant. The resulting recovery in permeability implies that the propped coal fracture has the potential to optimally facilitate methane production as a pathway, even at high closure stresses generated by methane drainage.

01 COAL, LIGNITE, AND PEAT↗

Fast relaxing sustainable soft vitrimer with enhanced recyclability

Soft, fully renewable vitrimers have been introduced to circumvent the lack of recyclability of traditional elastomers with permanent cross-linked structures, while preserving the advantages of rheo-structural stability, and mechanical properties.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Relationships between the energetics of impulsive and gradual emissions from solar flares

The gradual soft X-ray emissions associated with a homogeneous set of solar flares have been investigated in the context of a thermal model proposed to explain the impulsive components. The parametric techniques which successfully characterized the hard X-ray and microwave observations are employed in an event-by-event analysis to test for quantitative and correlative relationships between the impulsive and gradual emissions. The results of this investigation are consistent with the hypothesis that the hard X-ray and microwave emissions are produced by bulk heating of a common thermal source. The quantitative relationships require an additional source to explain the soft X-ray observations, consistent with previous results. Correlations between the energetics of the impulsive and gradual emissions, identified in the present work, provide the first clear evidence that their energizing mechanisms are related.

Crannell, C. J.↗

Flare Emission Onset in the Slow-Rise and Fast-Rise Phases of an Erupting Solar Filament Observed with TRACE

We observe the eruption of an active-region solar filament of 1998 July 11 using high time cadence and high spatial resolution EUV observations from the TRACE sareiii'ce, along with soft X-ray images from the soft X-ray telescope (SXT) on the Yohkoh satellite, hard X-ray fluxes from the BATSE instrument on the (CGRO) satellite and from the hard X-ray telescope (HXT) on Yohkoh, and ground-based magnetograms. We concentrate on the initiation of the eruption in an effort to understand the eruption mechanism. First the filament undergoes slow upward movement in a "slow rise" phase with an approximately constant velocity of approximately 15 km/s that lasts about 10-min, and then it erupts in a "fast-rise" phase, reaching a velocity of about 200 km/s in about 5-min, followed by a period of deceleration. EUV brightenings begin just before the start of the filament's slow rise, and remain immediately beneath the rising filament during the slow rise; initial soft X-ray brightenings occur at about the same time and location. Strong hard X-ray emission begins after the onset of the fast rise, and does not peak until the filament has traveled a substantial altitude (to a height about equal to the initial length of the erupting filament) beyond its initial location. Our observations are consistent with the slow-rise phase of the eruption resulting from the onset of "tether cutting" reconnection between magnetic fields beneath the filament, and the fast rise resulting from an explosive increase in the reconnection rate or by catastrophic destabilization of the overlying filament-carrying fields. About two days prior to the event new flux emerged near the location of the initial brightenings, and this recently- emerged flux could have been a catalyst for initiating the tether-cutting reconnection. With the exception of the initial slow rise, our findings qualitatively agree with the prediction for erupting-flux-rope height as a function of time in a model discussed by Chen & Shibata (2000) based on reconnection between emerging flux and a flux rope.

Sterling, A. C.↗

Conformal hetero-electrolyte interface between soft oxyhalides and garnet enables low-pressure lithium-reservoir-free solid-state batteries

The operation of solid-state batteries with a lithium metal anode and a high voltage cathode requires solid electrolytes (SEs) that are chemically stable with lithium, have a wide electrochemical window, and accommodate volume changes in the electrodes. Unfortunately, no SE has exhibited satisfactory mechanical and electrochemical properties that fit these requirements to date. Dual solid electrolyte systems that use a different SE for the anolyte and catholyte present a viable solution. Here, we focus on oxyhalide SEs that demonstrate superior ionic conductivity and cathode compatibility, where their lithium metal reactivity and poor reduction stability can be resolved using a lithium garnet (Li 6.5 La 3 Zr 1.5 Ta 0.5 O 12 , LLZTO) separator. Nonetheless, this imposes a new hetero-electrolyte (H-E) interface at the anolyte|catholyte contact that defines the ion transport across the boundary. We report its promising properties, which are deconvoluted from the electrical measurements of bilayer symmetric cells, for three representative oxyhalide catholytes, LiNbOCl 4 , LiTaOCl 4 , and Li 3 Al 3 O 2 Cl 8 . Pressure-dependent measurements reveal that the relative softness of the oxyhalides (hardness ≤0.4 GPa) enables H-E resistances lower than 150 Ω cm 2 at 2–3 MPa. Mesoscale modelling reveals that the transfer-active contact area of oxyhalides with LLZTO is about 2–3-fold higher than that of argyrodite, Li 6 PS 5 Cl. The low H-E resistance of the LiNbOCl 4 |Li 6.5 La 3 Zr 1.5 Ta 0.5 O 12 dual electrolyte enables the cycling of a Li|LiNi 0.82 Mn 0.07 Co 0.11 O 2 full cell with a high discharge capacity (200 mA h g −1 ) at 60 °C and ∼7 MPa. Importantly, we demonstrate a Li-reservoir-free full cell with high Coulombic efficiency (>99.5%) and capacity at 1 MPa using this approach coupled with a garnet-silver interlayer.

Palmer, Max [University of California, Santa Barba↗

An investigation of coronal active region loop structures using AS&E rocket X-ray images

Simultaneous high spatial resolution observations at 6 cm in soft X-rays, in photospheric magnetograms, and in optical filtergrams were used to compare the most intense sources of centimetric emission in two active regions to coronal loops, sunspots, chromospheric structures, and photospheric magnetic fields. Results show that the majority of the bright microwave components are not associated with sunspots or X-ray emission. A nonthermal mechanism appears necessary to explain the brightest microwave components, discrete regions of continuous particle acceleration may be common in active regions. Studies of the plasma parameters of selected loops imply that the radio emission is consistent with gyro-resonance absorption at the third and fourth harmonic, at least from part of each loop. Results are presented for: (1) X-ray and microwave observations of active regions; (2) comparison of coronal holes observed in soft X-rays and Hel 10830 A spectrosheliograms; and (3) the reappearance of polar coronal holes and the evolution of the solar magnetic field.

Webb, D. F.↗

Quasiclassical Gluon Fields and Low’s Soft Theorem at Small Momentum-Fraction x

In the high-energy limit, soft gluons can be approximately described by quasiclassical gluon fields. It is well known that the gluon field is a pure gauge field on the transverse plane at eikonal order. We derived the complete next-to-eikonal order solutions of the classical Yang-Mills equations for soft gluons in the dense nuclear regime. Utilizing these solutions, it is shown that Low’s soft theorem at small x can be obtained by considering off-diagonal matrix elements of quasiclassical chromoelectric field between single-gluon states in the dilute regime. We further propose on extending Low’s soft theorem at small x to incorporate the effects of gluon saturation in the dense regime.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Stripe and bubble ratchets on asymmetric substrates

We show that various nonmonotonic ratchet effects can arise when mesophase pattern-forming systems, which exhibit anisotropic crystal, stripe, and bubble regimes, are coupled to one-dimensional asymmetric substrates under ac driving. The patterns emerge in the absence of a substrate when the ratio of attraction to repulsion is varied for particles with competing short-range attraction and long-range repulsion potentials. In the presence of the substrate, we find that the ratchet efficiency varies nonmonotonically with increasing attraction, depending upon how well the mesophase morphology matches the substrate spacing and periodicity. For strong repulsion, there is a weak but finite ratchet effect, while at intermediate attraction, there is a robust ratchet effect in which the system forms stripes aligned with the substrate symmetry direction. For strong attraction, large bubbles appear that have weak or no ratchet effects when the bubble width exceeds the substrate lattice spacing, causing the bubble to be only weakly coupled to the substrate. For very strong attraction, small bubbles form and undergo a strong ratchet effect with an efficiency that oscillates as a function of ac drive amplitude. Although the small bubble regime is a strongly correlated regime in which each bubble contains many particles, the system behaves as if it is in a single-particle regime since the bubble width is much smaller than the substrate lattice spacing. We map out the different rectification phases as a function of the pattern morphology, substrate strength, and ac drive amplitude. The pronounced ratchet effects that we observe in some regimes can be exploited for pattern sorting in hard and soft matter systems. Published by the American Physical Society 2024

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Logic operations with active topological defects

Logic operations performed by semiconductor-based transistors are the basis of modern computing. There is considerable interest in creating autonomous materials systems endowed with the capability to make decisions. In this work, we introduce the concept of using topological defects in active matter to perform logic operations. When an extensile active stress in a nematic liquid crystal is turned on, +1/2 defects can self-propel, in analogy to electron transport under a voltage gradient. By relying on hydrodynamic simulations of active nematics, we demonstrate that patterns of activity, when combined with surfaces imparting certain orientations, can be used to control the formation and transport of +1/2 defects. We further show that asymmetric high- and low-activity patterns can be used to create effective defect gates, tunnels, and amplifiers. The proposed active systems offer the potential to perform computations and transmit information in active soft materials, including actin-, tubulin-, and cell-based systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Scalable standard optical sources in the VUV: Emissions from electron impact on metals

The use of electron impact on metals in the development of a compact optical standard lamp in the vacuum ultraviolet is described. Two different mechanisms are exploited, transition radiation and bremsstrahlung. Transition radiation will be used as a primary standard from 1200A to 3000A using 10 keV electron impact on tungsten. Bremsstrahlung will be used in the soft X-ray region below 1200A to less than 5A as an optical transfer standard from 4 keV electron impact on tantalum or tungsten.

Hughes, R.↗

Orbital transfer rocket engine technology program: Soft wear ring seal technology

Liquid oxygen (LOX) compatibility tests, including autogenous ignition, promoted ignition, LOX impact tests, and friction and wear tests on different PV products were conducted for several polymer materials as verification for the implementation of soft wear ring seals in advanced rocket engine turbopumps. Thermoplastics, polyimide based materials, and polyimide-imide base materials were compared for oxygen compatibility, specific wear coefficient, wear debris production, and heat dissipation mechanisms. A thermal model was generated that simulated the frictional heating input and calculated the surface temperature and temperature distribution within the seal. The predictions were compared against measured values. Heat loads in the model were varied to better match the test data and determine the difference between the measured and the calculated coefficients of friction.

Lariviere, Brian W.↗

Soft-Decision-Data Reshuffle to Mitigate Pulsed Radio Frequency Interference Impact on Low-Density-Parity-Check Code Performance

This presentation briefly discusses a research effort on mitigation techniques of pulsed radio frequency interference (RFI) on a Low-Density-Parity-Check (LDPC) code. This problem is of considerable interest in the context of providing reliable communications to the space vehicle which might suffer severe degradation due to pulsed RFI sources such as large radars. The LDPC code is one of modern forward-error-correction (FEC) codes which have the decoding performance to approach the Shannon Limit. The LDPC code studied here is the AR4JA (2048, 1024) code recommended by the Consultative Committee for Space Data Systems (CCSDS) and it has been chosen for some spacecraft design. Even though this code is designed as a powerful FEC code in the additive white Gaussian noise channel, simulation data and test results show that the performance of this LDPC decoder is severely degraded when exposed to the pulsed RFI specified in the spacecraft s transponder specifications. An analysis work (through modeling and simulation) has been conducted to evaluate the impact of the pulsed RFI and a few implemental techniques have been investigated to mitigate the pulsed RFI impact by reshuffling the soft-decision-data available at the input of the LDPC decoder. The simulation results show that the LDPC decoding performance of codeword error rate (CWER) under pulsed RFI can be improved up to four orders of magnitude through a simple soft-decision-data reshuffle scheme. This study reveals that an error floor of LDPC decoding performance appears around CWER=1E-4 when the proposed technique is applied to mitigate the pulsed RFI impact. The mechanism causing this error floor remains unknown, further investigation is necessary.

Ni, Jianjun David↗