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TM 2: Assembly prototype girder

This Technical Note presents details of the successful achievement of Technical Milestone 2 in the NYSERDA contract with Brookhaven National Laboratory and Cornell University. The project { to design, build and commission the Cornell-BNL Electron Test Accelerator (CBETA) { will achieve final success when all 12 Technical Milestones are complete.

43 PARTICLE ACCELERATORS↗

CBETA Design Report

This Design Report describes the baseline design of the Cornell-BNL ERL Test Accelerator, as it exists on the date of its publication in June 2017. The Design Report will not change frequently in the future. In contrast, the parameter sheets that summarize the CBETA design will respond as quickly and as thoroughly as necessary to maintain con guration control.

43 PARTICLE ACCELERATORS↗

CBETA Design Report

This Design Report describes the baseline design of the Cornell-BNL ERL Test Accelerator, as it exists on the date of its publication in June 2017. The Design Report will not change frequently in the future. In contrast, the parameter sheets that summarize the CBETA design will respond as quickly and as thoroughly as necessary to maintain configuration control.

43 PARTICLE ACCELERATORS↗

Beam dynamics validation of the Halbach Technology FFAG Cell for Cornell-BNL Energy Recovery Linac

The Cornell-BNL Electron Test Accelerator (CBETA), a 150 MeV energy recovery linac (ERL) now in construction at Cornell, employs a fixedfield alternating gradient (FFAG) optics return loop: a single beam line comprised of quadrupole doublet cells, which accepts four recirculated energies. CBETA FFAG cell uses Halbach permanent magnet technology, its design studies have covered an extended period of time supported all the way by extensive particle dynamics simulations using computed 3-D field map models. This approach, which supported the choice of Halbach technology for CBETA FFAG ERL in 2016, is discussed and illustrated here based on the final stage in these beam dynamics studies, namely the validation of a ultimate, optimized design of the cell.

43 PARTICLE ACCELERATORS↗

Characterization of the IOTA Proton Source [Slides]

Integral-Optics Test Accelerator (IOTA) • Formed from the High Intensity Neutrino Source (HINS) • Goals – integrable optics with non-linear magnets and with electron lenses – optical stochastic cooling of particle beams – innovative emittance exchange • Storage ring – 39m in circumference – protons and ions • Focus on injection into RFQ – Duoplasmatron – Nickel filament.

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Beam Echoes in the Presence of Coupling [Slides]

Beam echoes provide a new way of measuring diffusion in particle beams. We seek to develop the theory further to understand how many factors influence the echo strength and profile. – Explore beam echoes in 2D with coupling effects – Explore beam echoes in 2D with diffusion effects – Explore beam echoes with both coupling and diffusion effects. Eventual goal is to provide recommendations to IOTA (Integrable Optics Test Accelerator) for upcoming echo experiment.

43 PARTICLE ACCELERATORS↗

Light transport and amplification for a proof-of-principle experiment of Optical Stochastic Cooling

The Optical Stochastic Cooling (OSC) is a proposed technique that holds promise for the cooling of heavy-ions and dense TeV scale hadron beams. In the OSC a particle radiates a short wave-packet in an upstream "pickup" undulator and is made to interact with its own radiation in a downstream "kicker" undulator providing a corrective energy kick. In this thesis we present formulas and wave-optics simulations to compute the single-particle kick amplitude. The wave-optics simulations are further used to model amplification of the pickup radiation in a solid-state gain medium. This research was carried out in preparation of a proof-of-principle demonstration of the OSC in Fermilab's Integrable Optics Test Accelerator (IOTA) using 100 MeV electrons.

43 PARTICLE ACCELERATORS↗

Accident Scenarios for IOTA Ring and Dose Distributions Calculated with MARS15 Code

The Integrable Optics Test Accelerator (IOTA) at Fermilab’s Accelerator Science and Technology (FAST) facility [1] is a storage ring for advanced high intensity beam physics research. Layout of the ring is shown in Fig. 1. A plan view of the ring with enclosure walls are shown in Fig. 2. The entire beam, stored in the IOTA ring, is assumed to be completely lost at either of the three locations shown in Fig. 2. Therefore, we will consider three separate corresponding accident scenarios. The maximal amount of electrons stored in the IOTA ring is estimated to be 2×10 10 electrons with energy of 150 MeV. At locations 1 and 2 the beam is lost on 60-deg dipole walls, while at location 3 the beam is lost on Lambertson magnet wall.

43 PARTICLE ACCELERATORS↗

Development and Characterization of High Performance and Robust Mixed Conducting Cathodes Supportive of Lower Cost Solid Oxide Fuel Cells (Final Report)

The objective of the proposed research is to advance an existing partnership between the University of South Carolina (USC) and LG Fuel Cell Systems, Inc. (LGFCS) to research and develop mixed electronic and ionic conducting cathode materials for durable and robust low-cost solid oxide fuel cells (SOFCs). The first task is to develop mixed ionic and electronic conducting doped (Pr,Nd)NiO 4 (PNNO)-based cathodes. This task is built on a prior collaborative work with LG Fuel Cell System, which showed that doped PNNO could exhibit phase stability at high temperatures. The initial focus will be on investigating the durability and endurance of its electrochemical performance and the temporal evolution of microstructures. In-situ high temperature neutron diffraction and x-ray diffraction will be used to study the structures of these phase stable compounds. PNNO doped with Ca and transition metal elements will be synthesized. Physical properties of these materials with respect to coefficient of thermal expansion, electrical conductivity, diffusion coefficient, and nonstoichiometry will be measured. The benefits of dense versus porous barriers will be studied and the role of barrier layer will be identified and a guideline will be provided to choose the maximum porosity for durable and robust cathode performance with co-doped PNNO as the cathodes. LSCF6428 will be used to compare its power density with that of co-doped PNNO in the absence of Cr, but some studies comparing Cr tolerance will be performed towards the end of the project. The conditions at which preferred nickelate phases are stable will be defined, including sintering temperature, operating temperature, and composition range. The second task will focus on the investigation of the location of degradation by using differential relaxation time (DRT) analysis, coupled with least squares fitting and systematical post analyses. DRT analysis can provide (1) a direct access to the kinetic parameters of the underlying processes in both cathode and anode, and (2) a clearer picture of SOFC operation, which allows loss factors to the changes of microstructures or activities of either electrode to be distinguished, and a better target fuel cell development to be enabled. The third task aims at applying the accelerated testing protocol to investigate the microstructural evolution of the cathode candidates identified in this research. Technical approaches will be developed to mitigate and improve the durability of cathode materials by choosing the right chemistry and tuning cathode microstructures.

36 MATERIALS SCIENCE↗

Summary of available data for estimating chloride-induced SCC crack growth rates for 304/316 stainless steel

The majority of existing dry storage systems used for spent nuclear fuel (SNF) consist of a welded 304 stainless steel container placed within a passively-ventilated concrete or steel overpack. More recently fielded systems are constructed with dual certified 304/304L and in some cases, 316 or 316L. In service, atmospheric salts, a portion of which will be chloride bearing, will be deposited on the surface of these containers. Initially, the stainless steel canister surface temperatures will be high (exceeding the boiling point of water in many cases) due to decay heat from the SNF. As the SNF cools over time, the container surface will also cool, and deposited salts will deliquesce to form potentially corrosive chloride-rich brines. Because austenitic stainless steels are prone to chloride-induced stress corrosion cracking (CISCC), the concern has been raised that SCC may significantly impact long-term canister performance. While the susceptibility of austenitic stainless steels to CISCC in the general sense is well known, the behavior of SCC cracks (i.e., initiation and propagation behavior) under the aforementioned atmospheric conditions is poorly understood. A literature survey has been performed to identify SCC crack growth rate (CGR) studies conducted utilizing conditions that may be relevant to existing SNF interim storage canisters, the results of which are presented in this document. The data presented here have been restricted to those representing atmospheric corrosion of stainless steels due to deliquescence of marine salts, or marine salt components, on the metal surface. A suite of experimental studies representing both long-term field tests and accelerated laboratory tests has been identified. Potentially relevant data are summarized in Figures 1-1 (304 SS) and Figure 1-2 (316 SS). In the Figures, when a particular reference utilized a series of samples, the range is shown as a bar, and the average value shown with a symbol. A summary of the test methods, sample geometry, and environmental conditions for each study is given in Table 1-1. While the surveyed studies all explore SCC of austenitic stainless steels under atmospheric conditions, the methods through which each researcher approached the problem do differ, as illustrated in Table 1-1. The surveyed studies utilized a variety of metal treatments including as-fabricated, solution annealed, welded, and sensitized material. Furthermore, different surface treatments (polished vs ground) were also used. In addition, most of these studies were accomplished using techniques that are not generally accepted for high-fidelity crack growth rate measurements, and in cases where more traditional approaches were taken, these methodologies may not be applicable to the atmospheric conditions of interest here. The wide variety of methods and materials results in the observed large scatter in measured CGRs. Each of the data sets in Figures 1-1 and 1-2 is described in more detail in the following sections. A short summary of crack growth rates based on operational experience is also presented.

36 MATERIALS SCIENCE↗

DPC Cement Filler Development (Progress Report)

The fillers research and development (R&D) program, mostly experimental, is part of a broader R&D program that includes new process modeling and performance assessment of criticality effects and the overall importance of criticality to repository performance (consequence screening). A literature research and consultation effort with experts by Hardin and Brady (2018) identified several potentially effective and workable filler materials including cements (primarily phosphate based), moltenmetal alloys, and low-temperature glasses. Filler attributes were defined, and the preliminary lists were compared qualitatively. Further comparative analysis will be done (e.g., cost estimates) after experimental screening has narrowed the list of alternatives. The following cement filler compositions were selected for experimental development work and accelerated testing in FY20: Aluminum phosphate cements (APCs); more specifically aluminum oxide / aluminum phosphate (Al 2 O 3 / AlPO 4 ) cements in which Al 2 O 3 serves as the filler material bound by an AlPO 4 binder formed by the reaction of Al 2 O 3 with H 3 PO 4 ; Calcium phosphate cements (CPCs); more specifically composed of pure or nearly pure hydroxyapatite or HAP (Ca 5 (PO 4 ) 3 (OH)); Wollastonite phosphate cements (WPC), specifically wollastonite and aluminum or calcium aluminum phosphates in which CaSiO 3 serves as the filler material and the phosphate serves as the binder. The FY20 effort focused on the optimization of compositions and subsequent processing of these three materials to achieve dense and well-consolidated monolithic samples with 30 to 40% porosity and permeabilities of 1 millidarcy. At the close of this progress report the aluminum phosphate cements (APCs) and the wollastonite phosphate cements (WPCs) appear to show the most promise for continued development. Less progress has been made with the calcium phosphate cements (CPCs); their slurry viscosities are high (and difficult to measure) and they exhibit relatively short cure times of 2 to 3 hours with concomitant and excessive volatile (e.g. CO 2 ) generation.

36 MATERIALS SCIENCE↗

Generalizable Mechanistic Understanding of Module-Level Light-Moisture and Thermal-Induced Instabilities in CIGS Photovoltaics (Final Report)

The objectives of this project are to identify the root causes of light, heat and humdity induced instabilities in the operation and accelerated testing of commercial Cu(In,Ga)Se 2 [CIGS] photovoltaic modules produced by major module manufacturers (e.g.: Solibro and MiaSolé), correlate them with module degradation/failure modes, and produce accurate service lifetime prediction models.

14 SOLAR ENERGY↗

Modeling Transverse Space Charge effects in IOTA with pyORBIT

The role and mitigation of space charge effects are important aspects of the beam physics research to be performed at the Integrable Optics Test Accelerator (IOTA) at Fermilab. The impact of nonlinear integrability (partial and complete) on space charge driven incoherent and coherent resonances will be a new feature of this accelerator and has the potential to influence the design of future low energy proton synchrotrons. In this report we model transverse space charge effects using the PIC code pyORBIT. First we benchmark the single particle tracking results against MADX with checks on symplecticity, tune footprints, and dynamic aperture in a partially integrable lattice realized with a special octupole string insert. Our space charge calculations begin with an examination of the 4D symplecticity. Short term tracking is done first with the initial bare lattice and then with a matching of the rms values with space charge. Next, we explore slow initialization of charge as a technique to establish steady state and reduce emittance growth and beam loss following injection into a mismatched lattice. We establish values of space charge simulation parameters so as to ensure numerical convergence. Finally, we compare the simulated space charge induced tune shifts and footprints against theory.

43 PARTICLE ACCELERATORS↗

Design of double- and multi-bend achromat lattices with large dynamic aperture and approximate invariants

A numerical method to design nonlinear double- and multi-bend achromat (DBA and MBA) lattices with approximate invariants of motion is investigated. The search for such nonlinear lattices is motivated by Fermilab’s Integrable Optics Test Accelerator (IOTA), whose design is based on an integrable Hamiltonian system with two invariants of motion. While it may not be possible to design an achromatic lattice for a dedicated synchrotron light source storage ring with one or more exact invariants of motion, it is possible to tune the sextupoles and octupoles in existing DBA and MBA lattices to produce approximate invariants. In our procedure, the lattice is tuned while minimizing the turn-by-turn fluctuations of the Courant-Snyder actions J x and J y at several distinct amplitudes, while simultaneously minimizing diffusion of the on-energy betatron tunes. The resulting lattices share some important features with integrable ones, such as a large dynamic aperture, trajectories confined to invariant tori, robustness to resonances and errors, and a large amplitude-dependent tune-spread. Compared to the nominal NSLS-II lattice, the single- and multi-bunch instability thresholds are increased and the bunch-by-bunch feedback gain can be reduced.

43 PARTICLE ACCELERATORS↗

Space Charge Driven Emittance Growth and the Effect of Octupoles in IOTA

The Integrable Optics Test Accelerator (IOTA) at Fermilab is a small machine dedicated to a broad frontier accelerator physics program. An important aspect of this program is to investigate the potential benefits of the resonance free tune spread achievable with integrable optics to store and accelerate high intensity proton beams for which space charge is significant. In this context, a good understanding of proton beam emittance growth and particle loss mechanisms is essential. Assuming nominal design parameters, simulations show that for a bunched beam, the bulk of emittance growth takes place immediately following injection, typically within tens of turns. We attempt to account for this growth using a simplified RMS mismatch theory; some of its limitations and possible improvements are briefly discussed. We then compare theoretical predictions to simulations performed using the PIC code pyORBIT. Further exploring ways to mitigate emittance growth and reduce particle loss, we compare two beam matching strategies: (1) matching at the injection point (2) matching at the center of the nonlinear (octupole) insertion region where $\beta_x = \beta_y$. To observe how nonlinearity affects emittance growth and whether it dominates growth due to mismatch, we track two different distributions. Finally, we explore the potential of using octupoles in a quasi-integrable configuration to mitigate growth using a variety of initial distributions both at reduced and full intensities.

43 PARTICLE ACCELERATORS↗

Evaluation of Degradation Mechanisms for Solid Secondary Waste Grout Waste Forms

The overall objective of this work is to provide defensibility for the long-term performance of grouted Hanford SSW streams when disposed in a near surface disposal facility, IDF, on the Hanford Site. Providing defensibly for the long-term performance of the grouted waste forms is consistent with the research and development activities identified in the Performance Assessment Maintenance Plan, (Westcott et al. 2019), that are necessary to address the assumptions made in the PA. Specifically, this work addresses two areas identified for further research and development activities in the plan: (1) “Evaluate ongoing research on transport characteristics of cementitious materials using accelerated tests to approximate the effects of aging/alteration/weathering”; and (2) “Evaluate ongoing research on microbial effects on transport processes in cementitious materials.” The assembled subject matter expert team evaluated a list of degradation mechanisms and supporting processes and provided rankings of areas where further research and development (R&D) are needed. From this assessment, high priority R&D areas include: (1) the effects of carbonation, Ca leaching, and SSW dimensional change in grout waste forms; (2) updated model representations of grouted waste forms; and (3) scaled testing demonstrations. Moderate priority items including a paper study on possible microbial influence, reoxidation rates, radionuclide/contaminant dissolution from SSW in the grout and freeze thaw behavior. Other processes evaluated were either deemed unlikely to occur, to have little impact on the SSW waste forms, or to occur at time frames beyond those considered (>10,000 years). The assessments and proposed R&D approaches are expected to support an update to the WRPS SSW roadmap.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

PACT Module Preconditioning Protocol (V.0.1)

The purpose of this protocol is to bring metal halide perovskite (MHP) modules to a repeatable and relevant state prior to making a performance measurement. Performance measurements are made before and after a stressor has been applied to the module to quantify the degree of loss resulting from the stressor. This procedure is intended to be carried out both before and after the accelerated test.

14 SOLAR ENERGY↗

Incoherent Dynamics of Intense Proton Beams under Electron Cooling

The minimum emittance of ion beams achieved using electron cooling is limited by the heating processes of Intra Beam Scattering and diffusion driven by resonance crossing of particles due to space-charge. We describe a new experiment to explore the intense space-charge regime with a transverse tune shift approaching -0.5 using 2.5~MeV protons at the Integrable Optics Test Accelerator (IOTA) at Fermilab. We also report on the results from PyORBIT simulations incorporating transverse space-charge and electron cooling with emphasis on the incoherent dynamics of the particles.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗