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DOE OSTI2019

The Correlation of Mesoscale Humidity Anomalies With Mesoscale Organization of Marine Stratocumulus From Observations Over the ARM Eastern North Atlantic Site

The structure of mesoscale cellular organization in marine cloud-topped boundary layers is found to be well characterized by using a novel compositing approach based on mesoscale variations in the column water vapor path (WVP). The approach is applied to ground-based observations from the Atmospheric Radiation Measurement (ARM) Eastern North Atlantic site. Based on a set of satellite and ground-based observational criteria, 381 hr of closed-cell and 227 hr of open-cell cases were selected from late 2015 to early 2018. Strong correlations are found between mesoscale-filtered cloud properties and WVP for both closed-cell and open-cell regimes. In the moist atmospheric columns, the clouds are thicker with higher tops and lower bases, and stronger precipitation compared to that in the dry columns. Overall, cloud properties of open and closed cells covary similarly with mesoscale moisture perturbations, except that the correlation of liquid water path with WVP is much weaker for open cells. The relations of subcloud properties with WVP are also examined. In the moist columns, surface equivalent potential temperature and relative humidity are higher than in the dry columns. A marginally negative correlation between mesoscale-filtered subcloud turbulence eddy dissipation rate and WVP is found for closed cells. These results are consistent with the conceptual model of closed cellular mesoscale circulations of Zhou and Bretherton (2019).

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1978

The Galilean satellites of Jupiter - Four worlds

A broad survey is presented of our current knowledge of the Galilean satellites. Attention is given to the physical properties (size, masses, densities, and rotation) and to the surface properties (albedo, surface markings, composition, and physical state) of the satellites. In particular, Io's atmosphere is considered with emphasis on the sodium, hydrogen and sulfur clouds and the ionosphere. The atmospheres of the other satellites are examined briefly and consideration is given to models of planetary origin, evolution and interior structure.

Johnson, T. V.↗

NASA NTRS1978

Laboratory analogues to cosmic dust

Results are reported for a study of the condensation of a number of solids that are likely candidates for dust formed in astronomical environments. The condensate materials were produced by vaporizing a portion of a solid target of chosen composition by a laser pulse in an atmosphere of H2, O2, or Ar at 1 atm pressure. The systems studied include olivine, pyroxene, Fe-Ni alloy, Al2O3, carbon, CaCO3, SiC, Au-olivine powders, and Au-Al2O3 powders. Possible relations among the sizes, chainlike structures, and chemistries of the condensates and of grains formed in astronomical systems are investigated. The results indicate that the laser evaporation technique is useful for providing a wide variety of grain systems that are analogous to astronomical grain systems and that the grain materials produced are useful for spectral studies of materials believed to exist in astronomical environments, both as single materials and as multicomponent grain systems

Stephens, J. R.↗

NASA NTRSDate not supplied

Enhanced Thermal Stability of High Yttria Concentration YSZ Aerogels

Aerogels demonstrate extraordinarily low thermal conductivity and low density, presenting a promising form of lightweight insulation for aerospace applications. The primary challenge is stabilization of the highly porous structure at temperatures to 1200 °C. Upon collapse of the pore structure, the favorable thermal properties and low density are diminished. Yttria-stabilized zirconia (YSZ) aerogels are synthesized to investigate the effect of composition on morphology, phase behavior, and thermal stability (specific surface area, pore size distribution). This work demonstrates the improvement in thermal stability of zirconia aerogels with increased yttria content. Furthermore, changes in structure and surface chemistry of YSZ aerogels are studied in both oxidizing and inert atmospheres. With an improved understanding of aerogel structure and performance, metal oxide aerogels can be developed to withstand the extreme environments of space exploration.

Nathaniel Olson↗

NASA NTRSDate not supplied

Development of Additive Manufacturing Technologies for 3D Printing of Spacecraft Heat Shields

Introduction: Ablative heat shields are an enabling technology for entry into planetary atmospheres. From the PICA heatshields used for several Mars rovers to the carbon phenolic material used for Galileo’s Jupiter entry probe, the heat shield manages the heat load transferred to the payload, protecting the sensitive scientific instruments carried on entry probes. The Additive Manufacturing of Thermal Protection Systems (AMTPS) project, an Early Career Initiative (ECI) funded by NASA’s Space Technology Mission Directorate and led by NASA Johnson Space Center, seeks to develop materials and processes for 3D printing ablative heat shields for spacecraft. Current methods for producing ablative heat shields are extremely labor intensive and re-quire extensive hands-on processes and quality control characterization. Additive manufacturing (AM) offers the possibility of reduced production times, improved reliability, and enhanced performance via graded compositions. Costs will also be reduced by reducing the time and labor required for heat shield production. Direct integration of the heat shield onto the structure during processing simplifies integration and reduces risk. Material Development: A critical challenge for the project is development of a material system that can (1) be printed in a near-net shape process and (2) perform well as an ablator. Achieving printability requires the material to flow under applied pressure, but maintain its shape once extruded from the printer nozzle. Ablative performance is measured by a multitude of markers, including char yield, char strength, thermal conductivity, and recession rate. Furthermore, there are several mechanical and thermal property considerations for vehicle integration including coefficient of thermal expansion (CTE) and residual stress. AM technology will be leveraged to grade the material formulation and properties through the thickness of the heat shield, an architecture not possible with current manufacturing processes. To this end, “robust” material formulations have been pre-pared with higher density for use on the surface where most ablation will occur. “Insulative” material formulations, with lower density and lower thermal conductivity, are prepared for use in the depth of the heat shield. This graded architecture will re-duce the overall mass of the heat shield and reduce costs and/or increase scientific payload capacities. To achieve a material system with the required properties, multiple resins have been investigated in collaboration with NASA Ames Research Center. To tune printability and performance, resin additives were studied to improve flexibility of the cured material while maintaining acceptable ablative performance. Material coupons were printed and studied via a suite of mechanical and thermal characterization methods. Arc jet testing was conducted at NASA Ames Research Center to evaluate ablative performance and thermal protection under conditions expected in atmospheric entry. Manufacturing Scale-Up: A partnership with Oak Ridge National Laboratory (ORNL) aims to enable full-scale fabrication of a 3D printed heat shield. Leveraging expertise in manufacturing and 3D printing at ORNL, a mid-scale manufacturing demonstration unit will be built and tested, using a dual-layer ablative system printed directly onto the titanium structure. Work on robotic system integration is ongoing and efforts to scale up material mixing with a material compound will ensure accurate and homogenous composition. Flight Test: A hypersonic sub-orbital flight test will provide a rigorous test of material performance ranging from ablation, thermal management, and mechanical integrity. Design of the capsule has taken place in collaboration with the University of Kentucky. Data collected from the flight will inform future design efforts in material formulation, printing methodology, and heat shield-capsule integration.

additive manufacturing↗

NASA NTRS2022

The Titan Haze Simulation (THS) Experiment on COSmIC. Part III. XANES Study of Laboratory Analogs of Titan Tholins

We have used the Titan Haze Simulation (THS) experimental set-up at NASA Ames’ COSmIC 19 facility to produce four laboratory analogs of Titan’s aerosols, or tholins. These tholin samples 20 were produced from four gas mixtures, representative of Titan’s atmosphere, of initial 21 compositions N2:CH4 (90:10 and 95:5) and N2:CH4:C2H2 (89.5:10:0.5 and 94.5:5:0.5) at 150 K, 22 using a plasma discharge in the stream of a jet-cooled gas expansion. Here we present an ex-situ 23 X-ray absorption near-edge structure (XANES) spectroscopy analysis of these four tholin 24 samples. The C- and N-XANES spectra show the presence of various functional groups 25 (aromatic carbon, imines, nitriles, etc.) whose abundances are correlated with (i) the relative 26 proportions between N2 and CH4, and (ii) the presence or absence of C2H2 in the initial mixtures. 27 In particular, mixtures containing C2H2 result in the formation of tholins consisting of more 28 aromatic structures and displaying larger relative amounts of imines and nitriles, but lower 29 overall nitrogen content. XANES spectroscopy also allowed for the determination of the 30 elemental C/N ratios for the four tholins, which were all found to be low (< 2.5) and consistent 31 with those measured for tholins produced in other, independent experimental set-ups. The C/N 32 ratios of tholins produced from gas mixtures that contained C2H2 (2.2–2.4) were found to be 33 about twice as large as those of tholins produced from gas mixtures that did not contain C2H234 (0.9–1.3). These new experimental results from the COSmIC/THS experiment demonstrate the 35 impact initial precursors have on the nitrogen chemistry during the formation of tholins, which 36 may help in the interpretation of observations and the development of models of Titan’s 37 atmosphere.

Titan↗

NASA NTRSDate not supplied

3D Climate Simulations of Earth-Like Planets with A Range of Atmospheric Composition, Radiative Transfer, Ocean, And Resolution Configurations, Using the New Version of ROCKE-3D

Understanding the climate of terrestrial planetary atmospheres has been increasingly the focus of research worldwide, in light of the increasing amount of rocky planet discoveries orbiting other stars in or near their habitable zone. Here we present simulations with the new version of the 3D climate model ROCKE-3D, whose version 2.0 will soon become publicly available. A wide range of configurations will be supported, compared to a handful ones in its predecessor, version 1.0 (Way et al., 2017). These include two model resolutions (4x5 and 2x2.5), two radiation schemes (GISS and SOCRATES), three atmospheric configurations (Earth-like, Earth-like without O3 and aerosols, and N2-dominated), and three ocean setups (prescribed sea-surface temperatures and ice cover, q-flux, and dynamic). Simulations of all different configuration combinations have been performed and will become available for use by the community. Key results will be presented across those configurations, together of the role of the structural uncertainty in model setup in the resulting climate calculated by the model.

climate simulations of Earth-like planets↗

NASA NTRS2015

Stratospheric Benzene and Hydrocarbon Aerosols Detected in Saturn's Auroral Regions

Context. Saturn's polar upper atmosphere exhibits significant auroral activity; however, its impact on stratospheric chemistry (i.e. the production of benzene and heavier hydrocarbons) and thermal structure remains poorly documented. Aims. We aim to bring new constraints on the benzene distribution in Saturn's stratosphere, to characterize polar aerosols (their vertical distribution, composition, thermal infrared optical properties), and to quantify the aerosols' radiative impact on the thermal structure. Methods. Infrared spectra acquired by the Composite Infrared Spectrometer (CIRS) on board Cassini in limb viewing geometry are analysed to derive benzene column abundances and aerosol opacity profiles over the 3 to 0.1 mbar pressure range. The spectral dependency of the haze opacity is assessed in the ranges 680-900 and 1360-1440 cm(exp −1). Then, a radiative climate model is used to compute equilibrium temperature profiles, with and without haze, given the haze properties derived from CIRS measurements. Results. On Saturn's auroral region (80 deg S), benzene is found to be slightly enhanced compared to its equatorial and mid-latitude values. This contrasts with the Moses & Greathouse (2005, J. Geophys. Res., 110, 9007) photochemical model, which predicts a benzene abundance 50 times lower at 80◦S than at the equator. This advocates for the inclusion of ion-related reactions in Saturn's chemical models. The polar stratosphere is also enriched in aerosols, with spectral signatures consistent with vibration modes assigned to aromatic and aliphatic hydrocarbons, and presenting similarities with the signatures observed in Titan's stratosphere. The aerosol mass loading at 80 deg S is estimated to be 1−4 × 10(exp −5) g cm(exp −2), an order of magnitude less than on Jupiter, which is consistent with the order of magnitude weaker auroral power at Saturn.We estimate that this polar haze warms the middle stratosphere by 6 K in summer and cools the upper stratosphere by 5 K in winter. Hence, aerosols linked with auroral activity can partly account for the warm polar hood observed in Saturn's summer stratosphere.

satellites↗

NASA NTRS2001

Shielded Heavy-Ion Environment Linear Detector (SHIELD): an experiment for the Radiation and Technology Demonstration (RTD) Mission

Radiological assessment of the many cosmic ion species of widely distributed energies requires the use of theoretical transport models to accurately describe diverse physical processes related to nuclear reactions in spacecraft structures, planetary atmospheres and surfaces, and tissues. Heavy-ion transport models that were designed to characterize shielded radiation fields have been validated through comparison with data from thick-target irradiation experiments at particle accelerators. With the RTD Mission comes a unique opportunity to validate existing radiation transport models and guide the development of tools for shield design. For the first time, transport properties will be measured in free-space to characterize the shielding effectiveness of materials that are likely to be aboard interplanetary space missions. Target materials composed of aluminum, advanced composite spacecraft structure and other shielding materials, helium (a propellant) and tissue equivalent matrices will be evaluated. Large solid state detectors will provide kinetic energy and charge identification for incident heavy-ions and for secondary ions created in the target material. Transport calculations using the HZETRN model suggest that 8 g cm -2 thick targets would be adequate to evaluate the shielding effectiveness during solar minimum activity conditions for a period of 30 days or more.

NASA Center LaRC↗

NASA NTRS2007

Spherical Cryogenic Hydrogen Tank Preliminary Design Trade Studies

A structural analysis, sizing optimization, and weight prediction study was performed by Collier Research Corporation and NASA Glenn on a spherical cryogenic hydrogen tank. The tank consisted of an inner and outer wall separated by a vacuum for thermal insulation purposes. HyperSizer (Collier Research and Development Corporation), a commercial automated structural analysis and sizing software package was used to design the lightest feasible tank for a given overall size and thermomechanical loading environment. Weight trade studies were completed for different panel concepts and metallic and composite material systems. Extensive failure analyses were performed for each combination of dimensional variables, materials, and layups to establish the structural integrity of tank designs. Detailed stress and strain fields were computed from operational temperature changes and pressure loads. The inner tank wall is sized by the resulting biaxial tensile stresses which cause it to be strength driven, and leads to an optimum panel concept that need not be stiffened. Conversely, the outer tank wall is sized by a biaxial compressive stress field, induced by the pressure differential between atmospheric pressure and the vacuum between the tanks, thereby causing the design to be stability driven and thus stiffened to prevent buckling. Induced thermal stresses become a major sizing driver when a composite or hybrid composite/metallic material systems are used for the inner tank wall for purposes such as liners to contain the fuel and reduce hydrogen permeation.

Arnold, Steven M.↗

NASA NTRS1977

Occultation studies of planets and satellites: The occultation of epsilon Geminorum by Mars

The occultation of epsilon Geminorum by Mars on 1976 April 8 was observed at three wavelengths and 4 ms time resolution with the 91 cm telescope. Temperature, pressure, and number density profiles of the Martian atmosphere were obtained for both the immersion and emersion events. Within the altitude range of 50 to 80 km above the mean surface, the mean temperature is 145 K, and the profiles exhibit wavelike structures with a peak to peak amplitude of 35 K and a vertical scale of about 20 km. The ratio of the refractivity of the atmosphere at 4500 A and 7500 A, determined from the time shift of the light curves for these wavelengths, is consistent with the atmospheric composition measured by Viking 1, 15 weeks later. From the central flash - a bright feature in the light curve midway between immersion and emersion - an optical depth is found at 4500 A of 3.3 plus or minus 1.7 per km atm (about 0.23 per equivalent Martian air mass) for the atmosphere about 25 km above the mean surface, near the south polar region. This large value and its weak wavelength dependence rule out Rayleigh scattering as the principal cause of the observed extinction.

Elliot, J. L.↗

NASA NTRS1991

High-efficiency heteroepitaxial InP solar cells

High-efficiency, thin-film InP solar cells grown heteroepitaxially on GaAs and Si single-crystal bulk substrates are being developed as a means of eliminating the problems associated with using single-crystal InP substrates. A novel device structure employing a compositionally graded Ga(x)In(1-x)As layer between the bulk substrate and the InP cell layers is used to reduce the dislocation density and improve the minority carrier properties in the InP. The structures are grown in a continuous sequence of steps using computer-controlled atmospheric pressure metalorganic vapor phase epitaxy (APMOVPE). Dislocation densities as low as 3 x 10(exp 7) sq cm and minority carrier lifetimes as high as 3.3 ns are achieved in the InP layers with this method using both GaAs or Si substrates. Structures prepared in this fashion are also completely free of microcracks. These results represent a substantial improvement in InP layer quality when compared to heteroepitaxial InP prepared using conventional techniques such as thermally cycled growth and post-growth annealing. The present work is is concerned with the fabrication and characterization of high-efficiency, thin-film InP solar cells. Both one-sun and concentrator cells were prepared for device structures grown on GaAs substrates. One-cell cells have efficiencies as high as 13.7 percent at 25 C. However, results for the concentrator cells are emphasized. The concentrator cell performance is characterized as a function of the air mass zero (AM0) solar concentration ratio and operating temperature. From these data, the temperature coefficients of the cell performance parameters are derived as a function of the concentration ratio. Under concentration, the cells exhibit a dramatic increase in efficiency and an improved temperature coefficient of efficiency. At 25 C, a peak conversion efficiency of 18.9 percent is reported. At 80 C, the peak AM0 efficiency is 15.7 percent at 75.6 suns. These are the highest efficiencies yet reported for InP heteroepitaxial cells. Approaches for further improving the cell performance are discussed.

Wanlass, M. W.↗

NASA NTRS2004

Application of Satellite-Derived Land Surface Temperature to Minimum Temperature Forecasting

Satellite-derived land surface temperature (LST) is studied for the purpose of understanding regional skin temperature dependency and variability, and its relationship to corresponding, site-specific air temperature. Skin temperature is highly correlated with surface-air temperature although it differs depending on land surface characteristics, terrain, and atmospheric conditions on a diurnal and seasonal scale. The high temporal resolution of the Geostationary Operational Environmental Satellite (GOES) -12 sounder is used to compare the diurnal cycles of LST and surface-air temperature. The minimum for both temperatures occurs near sunrise and LST is found to agree closely with surface-air temperatures a period of hours before sunrise on clear sky nights. The Moderate Resolution Imaging Spectroradiometer (MODIS)-derived LST renders more horizontal temperature structure - with its high spatial resolution (1 km at nadir) compared to the GOES-12 sounder (10 km). Nighttime MODIS-derived LST is extrapolated to the time of minimum temperature for a number of case study days and these are grouped by season and atmospheric conditions. These composites show that the variation in LST mirror the variation in minimum surface-air temperature under similar conditions.

Jones, P. R.↗

NASA NTRS2013

Evolution of the Stratospheric Temperature and Chemical Composition over One Titanian Year

Since the Voyager 1 (V1) flyby in 1980, Titans exploration from space and the ground has been ongoing for more than a full revolution of Saturn around the Sun (one Titan year or 29.5 Earth years was completed in May 2010). In this study we search for temporal variations affecting Titans atmospheric thermal and chemical structure within that year. We process Cassini CIRS data taken during the Titan flybys from 2006-2013 and compare them to the 1980 V1IRIS spectra (re-analyzed here). We also consider data from Earth-based and -orbiting observatories (such as from the ISO, re-visited). When we compare the CIRS 2010 and the IRIS data we find limited inter-annual variations, below the 25 or35 levels for the lower and middle, or the high latitudes, respectively. A return to the 1980 stratospheric temperatures and abundances is generally achieved from 50degN to 50degS, indicative of the solar radiation being the dominating energy source at 10 AU, as for the Earth, as predicted by GCM and photochemical models. However, some exceptions exist among the most complex hydrocarbons (C4H2 and C3H4), especially in the North. In the Southern latitudes, since 2012, we see a trend for an increase of several trace gases, possibly indicative of a seasonal atmospheric reversal. At the Northern latitudes we found enhanced abundances around the period of the northern spring equinox in mid-2009 (as in Bampasidis et al. 2012), which subsequently decreased (from 2010-2012) returning to values similar to those found in the V1 epoch a Titanian year before.

radiative transfer↗

NASA NTRS1978

The high-latitude winter F region at 300 km - Thermal plasma observations from AE-C

Results are presented for a comprehensive survey of thermal ion composition and electron temperature (Te) variations in the southern high-latitude winter F region near 300-km altitude. The data are obtained from the Atmosphere Explorer (AE-C) satellite during a magnetically quiet period centered on the June 1976 solstice. Prominent ionospheric features, including the nightside main trough, a high-latitude ionization hole, and the dayside auroral zone-cusp region, are characterized in terms of composition and Te variations. The structures under study are qualitatively interpreted in terms of known processes.

Brinton, H. C.↗

NASA NTRS1988

Surface compositional and structural aspects of Martian samples

There are many excellent reasons to examine the surface composition of a wide range of Martian samples. The existing spectral data indicate that many dust and soil particles have a thin Fe(+3) layer with a typical particle size in the 10 micrometer to 400 micrometer range. In view of the high CO2 content of the atmosphere, one might expect that surface carbonates should be present. In addition to chemisorbed material there will probably exist physisorbed atmospheric components of the atmosphere including oxygen, nitrogen and water vapor. The latter could possibly give rise to some hydrated minerals. Using ultra-high-vacuum/mass spectrographic techniques it should be possible to detect physisorbed and moderately strong chemisorbed species on the particle surfaces with a temperature programmed degassing procedure. In some instances such an approach is capable of helping distinguish between volcanic and impact generated materials by detecting the presence of fumerolic gases. Such gases typically condense on the exterior of the ejected particles. Additionally surface atomic and chemical compositions should be examined by a combination of modern surface analytical techniques. The combination we currently have in Buffalo at SUNY would appear to be one of the best available including ESCA (150 micrometer spot capability) Auger (SAM) with 300 A focussing for surface compositional surveys, SIMS for high sensitivity trace element detection and ISS for immediate surface layer analysis.

Cadenhead, D. A.↗

NASA NTRS2017

Using Advanced Mass Spectrometry Techniques to Fully Characterize Atmospheric Organic Carbon: Current Capabilities and Remaining Gaps

Organic compounds in the atmosphere vary widely in their molecular composition and chemical properties, so no single instrument can reasonably measure the entire range of ambient compounds. Over the past decade, a new generation of in-situ, field-deployable mass spectrometers has dramatically improved our ability to detect, identify, and quantify these organic compounds, but no systematic approach has been developed to assess the extent to which currently available tools capture the entire space of chemical identity and properties that is expected in the atmosphere. Reduced-parameter frameworks that have been developed to describe atmospheric mixtures are exploited here to characterize the range of chemical properties accessed by a suite of instruments. Multiple chemical spaces (e.g. oxidation state of carbon vs. volatility, and oxygen number vs. carbon number) were populated with ions measured by several mass spectrometers, with gas- and particle-phase α-pinene oxidation products serving as the test mixture of organic compounds. Few gaps are observed in the coverage of the parameter spaces by the instruments employed in this work, though the full extent to which comprehensive measurement was achieved is difficult to assess due to uncertainty in the composition of the mixture. Overlaps between individual ions and regions in parameter space were identified, both between gas- and particle-phase measurements, and within each phase. These overlaps were conservatively found to account for little (<10%) of the measured mass. However, challenges in identifying overlaps and in accurately converting molecular formulas into chemical properties (such as volatility or reactivity) highlight a continued need to incorporate structural information into atmospheric measurements.

G. Isaacman-VanWertz↗

NASA NTRS2018

Structure and Variability of the Martian Ion Composition Boundary Layer

A complex boundary layer with a variety of charged particle and electromagnetic field signatures, including a transition between plasma predominantly of solar wind origin and plasma of planetary origin, lies between the Martian bow shock and the ionosphere. In this paper, we develop and utilize algorithms to autonomously identify and characterize this ion composition boundary (ICB), using data from the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission. We find an asymmetric ICB with a larger average thickness, lower altitude, and lower velocity shear in the hemisphere where the solar wind motional electric field points outward, as a result of the asymmetry of the mass loading process. The ICB thickness scales with the magnetosheath proton gyroradius at the top of the boundary layer but does not clearly vary with external drivers. The ICB location varies with solar wind ram pressure and crustal magnetic field strength, but does not clearly respond to solar wind Mach number or extreme ultraviolet irradiance. The ICB represents a distinct boundary for ion density and flow speed, but the magnetic field strength and direction typically do not vary significantly across the ICB. The plasma density and flow speed at the ICB vary seasonally, likely in response to variations in the neutral exosphere and/or atmosphere. However, the ICB on average remains at or below the altitude where pressure balance is achieved between the piled up magnetic field (MPB) and the solar wind ram pressure, regardless of season or crustal magnetic field strength.

Electromagnetic↗