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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31

A deep learning-based direct forecasting of CO 2 plume migration

Accurate and timely forecasts of CO 2 plume evolution in geological reservoirs are crucial for CO 2 migration detection, leakage risk assessment, and operation decision support. Conventional forecasting usually adopts a two-step strategy, first calibrating reservoir model parameters against observations using iterative inverse modeling (or history matching) and then applying the calibrated model for predictions. This method impedes real-time forecasts due to the heavy computational demand in inverse modeling and may suffer from poor prediction accuracy because of the limited observation data. In this work, we propose a deep learning-based latent space mapping framework to forecast CO 2 plume migration directly by avoiding the inverse modeling. We first use the convolutional autoencoder to map the high-dimensional complex plume extents onto low-dimensional latent space. Next, we use neural networks to learn the relationship between the observation variables and the prediction latent variables. And then for given observation data, we infer the prediction values directly. This one-step direct forecasting is computationally efficient which requires a few number of parallelizable reservoir simulations and it can provide accurate predictions with limited observations by learning the observation-prediction relationship in the reduced dimension. Therefore, our proposed method enables an in-time forecast of dynamic CO 2 plume distributions. In this work, we demonstrate the effectiveness and accuracy of our method in predicting the CO 2 plume migration using four metrics such as plume area, centroid movement distance, and plume spreading in the primary and secondary directions. And the spatio-temporal evolution patterns of plume migration under diverse geological complexities are also accurately quantified.

15 GEOTHERMAL ENERGY↗

Impacts of Pore Network-Scale Wettability Heterogeneity on Immiscible Fluid Displacement: A Micromodel Study

The mixed-wet nature of reservoir formations imposes a wide range of rock wettability from strong resident-fluid wetting to strong invading-fluid wetting. The characteristics of two-phase flow in porous media composed of mixed-wetting surfaces remain poorly understood. In this study, we investigated the displacement of resident ethylene glycol (EG) by hexane in two mixed-wet micromodels of identical 2.5-D geometry heterogeneity, with uniformly or heterogeneously distributed patches strongly wetting to hexane. These patches are mixed among pores with unaltered EG-wetting surfaces. Along with control tests in the originally EG-wet micromodel, here we show the classic fingering and transitions in flow regimes at $logCa$ (capillary number) from -7.2 to -3.9. Moreover, pore-scale distributions of wettability and their spatial correlation influence displacement efficiency. In the two mixed-wet micromodels, we found (a) an increase of steady-state hexane saturation at the end of experiments by up to 0.12 in the capillary fingering regime and a decrease of at most by 0.06 in the viscous fingering regime, compared to the EG-wet micromodel, and (b) dispersed and fragmented hexane distribution after displacement. Brine drainage during supercritical CO 2 (scCO 2 ) injections in these micromodels occurs with lower wettability contrasts, and under similar viscosity ratios and interfacial tensions resulted in higher displacement efficiency relative to displacement of EG by hexane. While mixed-wettability can enhance displacement efficiency compared to uniform wettability, the dynamics of immiscible fluids in strong mixed-wet reservoirs are expected to be less pronounced in contributing to the efficiency of geological CO 2 sequestration, oil recovery, and remediation of hydrocarbon-contaminated aquifers.

2.5-D micromodel↗

High-pressure reduction of carbon dioxide in reactive liquid mixtures

Density-functional theory based molecular-dynamics simulations were used to investigate high-pressure chemical reactions in liquid mixtures of CO 2 with several elements (Si, Mn, and Fe) at high temperatures of 2000-3000 K. Our ab initio simulations indicate that these reactant elements can reduce CO 2 to C at high pressures (20 GPa) leading to the formation of C-C chains, with Si by far the most effective carbon-reducing agent. A combined chemical analysis using Bader charge analysis and Crystal Orbital Hamilton Population (COHP) on simulation snapshots shows that significant charge transfer from the reducing element to the C atoms creates instability in the C-O covalent bonds. COHP analysis further shows that Mn/Fe-O and Mn/Fe-C bonding interactions are weaker compared to the Si counterparts. These results further our understanding of the redox chemistry of CO 2 at conditions relevant to planetary mantle interiors and demonstrate the effectiveness of high pressure in the reduction of CO 2 directly to solid carbon.

Ab initio molecular dynamics↗

Radiation effects on the structure and alteration behavior of an SiO 2 –Al 2 O 3 –B 2 O 3 –Na 2 O glass

As borosilicate glasses are used in many countries to immobilize fission products and minor actinides after spent fuel reprocessing before storage in a deep geological repository, assessing that their chemical durability is of paramount importance. Here, pristine and preirradiated (952 MeV, 136Xe) SiO 2 –B2O 3 –Al2O 3 –Na 2 O glasses with the same molar ratios as in the French SON68 and ISG glasses have been subjected to aqueous corrosion in deionized water and in silica-saturated solution to measure the initial and longer term alteration rates. Pristine and preirradiated glasses corrode following the same mechanisms, but the preirradiation has a strong impact on the initial dissolution rate (increase by a factor of 5.6), and on the alteration layer depth in silica-saturated conditions (by two- to threefolds). The later result is related to the formation of a more porous, less passivating gel on the preirradiated glass specimen. Using both experimental spectroscopies (NMR, IR, and SFG) and classical molecular dynamics, the radiation effects on the glass structure and water diffusion have been assessed. After preirradiation, the density and the polymerization degree of the glass decrease, whereas the topological disorder increases. In consequence, water diffusion accelerates. These observations allow to correlate the radiation impact on the alteration behavior to the structural changes.

36 MATERIALS SCIENCE↗

Fracture Shearing in the Eau Claire Formation

This data set consists of Computed Tomographic (CT) data for five sheared Eau Claire Formation core samples with complex and heterogeneous lithology. Each sample was prefractured, housed in a specially adapted core holder, and sheared in incremental fashion. CT scans were taken before and after each shearing event.

Computed Tomography↗

CT and Scanning Data of the KGS Wellington 1-32 CarbonSAFE Core

Data described in the NETL Technical Report Series "Computed Tomography Scanning and Geophysical Measurements of the Wellington 1-32 Core", including processed and raw CT and measurements from NETL's multi-sensor core logger. Paronish, T.; Schmitt, R.; Mitchell, N; Brown, S; Crandall, D.; Moore, J.; Hasiuk, F.; Potter, N.; Holubnyak, Y.E. Computed Tomography Scanning and Geophysical Measurements of the Wellington 1-32 Core; DOE.NETL-2021.2882; NETL Technical Report Series; U.S. Department of Energy, National Energy Technology Laboratory: Morgantown, WV, 2022; p 108. DOI: https://doi.org/10.2172/1894355 https://edx.netl.doe.gov/dataset/computed-tomography-scanning-and-geophysical-measurements-of-the-wellington-1-32-core

CarbonSafe↗

RokBase - Beta

Web based tool and portal to explore and download data associated with Core Characterization Technical Report Series .

Core Characterization↗

SMART CarbonSAFE Model

The modeling work for this project built upon previous work done for the CarbonSAFE Rocky Mountain Phase I. A geologic and dynamic model was built in Petrel version 2019.3 for the area of the Colorado Plateau near Price, Utah. It is located at the north end of the San Rafael Swell in a natural gas field called Drunkards Wash. The model is 61.5 km east-west and 53 km north to south with 123x106x21 cells, giving a cell dimension of 50x50 m2. The 21 layers in the Z direction are of varying thickness depending on the formation. The Carmel, the seal layer, has 3 layers and is about 200 meters thick around the injection well. The Navajo Sandstone, the principal reservoir, has 5 layers and is about 100 meters thick. The Kayenta has 5 layers and is roughly 50 meters thick and the Wingate, a secondary reservoir, has 5 layers and is 120 meters thick. The base of the model is the Chinle Formation with 3 layers and about 120 meters of thickness..

Carbon Dioxide↗

Heart Shape to Fracture Distance: Characterizing Hydraulic Fracture Propagation before Hits

Estimating the distance from the hydraulic fracture tip to the monitor well can be useful for fracture characterization, well spacing optimization, and preventing parent-child well interference. A heart-shaped signal is referred to as the extensional precursor of a fracture hit recorded by crosswell strain measurements and can serve as a vital tool for such estimation. This study incorporates the 3D displacement discontinuity method (DDM) to understand the impact of fracture geometry and monitor well offset on the heart-shaped signal’s characteristics. Results from numerical simulation and analytical solutions reveal a strong linear correlation between the spatial extent of the heart-shaped signal and the fracture tip distance. This relationship was further developed to predict tip distance using field data from the Hydraulic Fracture Test Site 2 (HFTS2). A reasonable approximation result from field data further validates the methodology. In addition, it is worth noting that the estimation accuracy depends on the ratio between fracture dimension and tip distance. The findings of this study offer a novel approach for real-time monitoring and characterizing hydraulic fracture propagation, which can be further used for well spacing optimization in unconventional and enhanced geothermal system reservoir development, as well as caprock integrity monitoring for carbon sequestration projects.

58 GEOSCIENCES↗

Experimental Investigation of Buoyant Flow in Realistic Bedforms With Heterogeneous Wettability

Submeter-scale geologic heterogeneity greatly affects CO 2 plume migration and retention. In this work, we present meter-scale laboratory experiments that can capture the impact of realistic submeter-scale geologic heterogeneity on multiphase flow and trapping. We produce realistic sedimentary formations consisting of ripple deposits with varying grain size contrast and wettability in a meter-scale slab chamber. Then, we conduct multiphase flow experiments with analog fluids through these structures and measure the saturation patterns, capillary heterogeneity trapping (CHT), and overall trapping performance. When we alter the ripple bedform architecture, variations in trapped saturation and CHT (10–20%) increment are exhibited. Similar growth in trapping performance is also observed when grain size contrast increases. Finally, wettability changes (water- to oil-wet) can increase nonwetting saturation and CHT up to 5% and 10–20%, respectively. These results emphasize the importance of correctly characterizing the impact of small-scale heterogeneities and wettability changes. We believe this is the first time that multiphase flow experiments were conducted in meter-scale domains with realistic ripple bedforms and heterogeneous wettability to investigate plume migration and trapping.

58 GEOSCIENCES↗

The potential for New Mexico basalts to sequester CO2 with a focus on critical element mobility

This study investigates the potential for New Mexico basalts to serve as geologic CO₂ sequestration media through mineral carbonation. Batch-type experiments were conducted using crushed basalts from the Carrizozo and Taos regions at low PCO₂ (0.7–2 bar) and temperatures up to 40°C over 180 days. The experiments evaluated the kinetics of CO₂-water-rock interaction, cation release, and critical element mobility (Cu, Ni, Co, Zn). Solid and fluid samples were analyzed using SEM, EMPA, ICP-OES, and ICP-MS, and geochemical modeling was performed with GEM-Selektor and PHREEQC. Results indicated that up to 80% of the injected CO₂ was mineralized within 100 days, forming secondary carbonates such as siderite and ankerite. Additionally, significant mobilization of critical metals was observed, which has implications for resource recovery and mine-waste valorization in future CO₂ sequestration projects.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

OES CO 2 Pipeline FEED Project Design Basis Memorandum

The OES CO₂ Pipeline project will move captured carbon dioxide from two ethanol facilities near Gibson City, Illinois, roughly 7.8 miles southeast to three injection wells outside Anchor, where it will be permanently stored underground. The system is designed to handle up to 4.5 million metric tonnes per year of dense-phase CO₂ at pressures up to 2,500 psig, using 16-inch mainline pipe and 10.750-inch laterals made from API 5L X-60 and X-65 steel. Wall thicknesses vary depending on location, with thinner pipe in open country, heavier wall at road crossings, and the heaviest where the pipe passes under highways or railroads via horizontal directional drill. The pipe gets a fusion-bonded epoxy coating, with an added abrasion-resistant layer wherever it's bored or drilled. Major water crossings will use HDD rather than open trenching. The pipeline will be cathodically protected, equipped with SCADA-compatible pressure and temperature instrumentation, and monitored for leaks using a computational pipeline monitoring system per API RP 1130. Hydrostatic testing will be performed at 1.25 times design pressure, and an ILI caliper run will follow to catch any construction defects. Several items, including fracture toughness requirements, specific NDE methods, and ILI tool selection, are left for the detailed design phase. The whole system falls under 49 CFR Part 195 and ASME B31.4, and Gulf Interstate Engineering prepared this document as the FEED-level design basis under the CarbonSAFE Phase III program.

09 BIOMASS FUELS↗