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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31

Magnetic properties of Apollo 16 samples and implications for their mode of formation

The Apollo 16 crystalline rocks have a greater average percentage of metallic iron than any other lunar material and are the most reduced in terms of their metallic iron/total iron ratio. They have greater metal content than the mare basalts, the only primary igneous rocks on the moon, and more iron metal than the associated Apollo 16 breccias and soils. This fact and the relatively coarse grain size suggest reduction of the iron during the formation of the crystalline rocks, probably during melts and partial melts in an impact base surge deposit.

Pearce, G. W.↗

The electrical and magnetic properties of /TTF//I/-sub 0.71

The synthesis and transport properties of the salts (TTF) (iodine)-sub x have been investigated. These salts are quasi-one-dimensional compounds containing cation radicals only, in contrast to the cation radical-anion radical systems such as (TTF)(TCNQ). The phase diagram of (TTF)(I)-sub x is discussed, and found to consist of two nonconducting, stoichiometric phases, x = 2.0 and 3.0, and two conducting, nonstoichiometric phases, x = 0.71 and 2.3. The transport properties of (TTF)(I)-sub 0.71 are discussed in detail. This phase is highly conducting, undergoes a sharp transition to a less conducting state at 210 K, and exhibits an unusual hysteresis in some of the transport properties upon thermal cycling. The nature of the high-temperature ground state is examined.

Somoano, R. B.↗

The influence of containerless undercooling and rapid solid-state quenching on the superconductive and magnetic properties of some clustering alloy systems

The properties of clustering alloy systems and the manner in which they are influenced by rapid quenching from a containerless undercooled melt are discussed. It was postulated that rapid quenching under such conditions would result in highly disordered metastable alloys, and furthermore, that alloys in such conditions would possess physical properties characteristically different from those of alloys in the annealed equilibrium state. The scope of the program is essentially to gauge the influence of containerless undercooling on the submicrostructure of clustering-type alloys, using certain physical properties as diagnostic tools. Microstructures and macrostructures were to be examined using optical- and scanning-electron microscopy.

Collings, E. W.↗

The Influence of Containerless Undercooling and Rapid Solid-State Quenching on the Superconductive and Magnetic Properties of Some Clustering Alloy Systems

The potential of the 100-meter drop-tube for producing materials with new and important properties by their rapid solidification containerless undercooling was investigated. Materials produced exhibit evidence of very rapid quenching. The importance of rapid quenching in producing materials of considerable scientific and technological interest is emphasized. It is indicated that containerless undercooling, using at first a drop tube and eventually a space-shuttle-serviced orbiting laboratory, will provide another powerful approach for rapid quenching. A special advantage of the drop tube is that the microgravity condition is imposed ballistically; it is therefore possible to obtain either spherical samples by allowing solidification to take place in flight, or splats by allowing the sample material while still in undercooled liquid form to impact a stationary quench plate.

Collings, E. W.↗

Conduction investigations into the magnetic properties of matter

The thermal analysis of a heat exchanger for heating air to temperatures on the order of 3000 C for use in NASA's high temperature wind tunnel is presented. It was ascertained that an externally finned shell-and-tube type of heat exchanger with counterflow could be considered for this application. The methods of estimating the convective heat transfer coefficients are outlined in this report. As a part of thermal design the required size of heat exchanger was predicted. As a result of the extreme length required (approx. = 1/2 km), it was determined that a conventional heat exchanger may not be the most suitable tool for this application.

Chagini, H.↗

EM Properties of Magnetic Minerals at RADAR Frequencies

Previous missions to Mars have revealed that Mars surface is magnetic at DC frequency. Does this highly magnetic surface layer attenuate RADAR energy as it does in certain locations on Earth? It has been suggested that the active magnetic mineral on Mars is titanomaghemite and/or titanomagnetite. When titanium is incorporated into a maghemite or magnetite crystal, the Curie temperature can be significantly reduced. Mars has a wide range of daily temperature fluctuations (303K - 143K), which could allow for daily passes through the Curie temperature. Hence, the global dust layer on Mars could experience widely varying magnetic properties as a function of temperature, more specifically being ferromagnetic at night and paramagnetic during the day. Measurements of EM properties of magnetic minerals were made versus frequency and temperature (300K- 180K). Magnetic minerals and Martian analog samples were gathered from a number of different locations on Earth.

Stillman, D. E.↗

Solidifying Bi/MnBi at Low Gravity

Directional solidification of Bi/MnBi magnetic alloy under low gravity enhances magnetic properties. Magnetic properties of low-gravity Bi/MnBi alloy make attractive material for use in motors and other small electrical and electronic components.

Drauch, J.↗

Electronic structure and properties of magnetic defects in Co(1+x)Al(1-x) and Fe(1+x)Al(1-x) alloys

CoAl and FeAl compounds are developed along two directions. Magnetic susceptibility and specific heat at low temperature on (NiCo)Al and (CoFe)Al ternary alloys are in good agreement with band calculations. Results on magnetization and specific heat under field at low temperature on nonstoichiometric compounds show clearly the importance of the nearest neighbor effects. In the case of CoAl, the isolated cobalt atoms substituting aluminum are characterized by a Kondo behavior, and, for FeAl, the isolated extra iron atoms are magnetic and polarize the matrix. Moreover, for the two compounds, clusters of higher order play a considerable part in the magnetic properties for CoAl, these clusters also seem to be characterized by a Kondo behavior, for FeAl, these clusters whose moment is higher than in the case of isolated atoms, could be constituted of excess parts of iron atoms.

Abbe, D.↗

3d-Metal Induced Magnetic Ordering on U(IV) Atoms as a Route toward U(IV) Magnetic Materials

Uranium(IV) 5f 2 magnetism is dominated by a transition from a triplet to a singlet ground state at low temperatures. For the first time, we achieved magnetic ordering of U(IV) atoms in a complex fluoride through the incorporation of 3d transition metal cations. This new route allowed us to obtain an unprecedented series of U(IV) ferrimagnetic materials of the new composition Cs 2 MU 3 F 16 (M = Mn 2+ , Co 2+ , and Ni 2+ ), which were comprehensively characterized with respect to their structural and magnetic properties. Magnetic susceptibility measurements revealed ferromagnetic-like phase transitions at temperatures of ~14.0, 3.5, and 4.8 K for M = Mn 2+ , Co 2+ , and Ni 2+ , respectively. The transition is not observed when the magnetic M cations are replaced by a diamagnetic cation, Zn 2+ . Neutron diffraction measurements revealed the magnetic moments of 0.91(6)–1.97(3) μ B on the U atoms, which are only partially compensated by antiparallel moments of 1.53(14)–3.26(5) μ B on the 3 d cations. This arrangement promotes suppression of the transition to a diamagnetic ground state characteristic of U(IV), and in doing so, induces magnetic ordering on uranium via 3 d –5 f exchange coupling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Nondestructive Crack Detection in a Fuel System Component

The presentation examines the background and objective of nondestructive crack detection, flow control valve assembly and poppet post flight evaluation, poppet properties. magnetic property characterization of lab data, NDE, eddy current inspection, simulation, eddy current criteria, poppet cycle testing and NDE criteria, and the use of ultrasonic surface wave for crack detection.

Koshti, Ajay↗