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At least 559 records · Page 31

NASA'S Standard Measures During Bed Rest: Adaptations in the Cardiovascular System

Bed rest is a well-accepted analog of space flight that has been used extensively to investigate physiological adaptations in a larger number of subjects in a shorter amount of time than can be studied with space flight and without the confounding effects associated with normal mission operations. However, comparison across studies of different bed rest durations, between sexes, and between various countermeasure protocols have been hampered by dissimilarities in bed rest conditions, measurement protocols, and testing schedules. To address these concerns, NASA instituted standard bed rest conditions and standard measures for all physiological disciplines participating in studies conducted at the Flight Analogs Research Unit (FARU) at the University of Texas-Medical Branch. Investigators for individual studies employed their own targeted study protocols to address specific hypothesis-driven questions, but standard measures tests were conducted within these studies on a non-interference basis to maximize data availability while reducing the need to implement multiple bed rest studies to understand the effects of a specific countermeasure. When possible, bed rest standard measures protocols were similar to tests nominally used for medically-required measures or research protocols conducted before and after Space Shuttle and International Space Station missions. Specifically, bed rest standard measures for the cardiovascular system implemented before, during, and after bed rest at the FARU included plasma volume (carbon monoxide rebreathing), cardiac mass and function (2D, 3D and Doppler echocardiography), and orthostatic tolerance testing (15- or 30-minutes of 80 degree head-up tilt). Results to-date indicate that when countermeasures are not employed, plasma volume decreases and the incidence of presyncope during head-up tilt is more frequent even after short-duration bed rest while reductions in cardiac function and mass are progressive as bed rest duration increases. Additionally, while plasma volume loss can be corrected and cardiac mass can be prevented with properly applied countermeasures, orthostatic tolerance is more difficult to protect when supine exercise is the only countermeasure. Similar results have been observed after space flight. Plasma volume, cardiac chamber volume, and orthostatic tolerance recover relatively quickly with resumption of ambulation and normal activity levels after bed rest but restoration of cardiac mass is prolonged.

Lee, Stuart M. C.↗

Development of an Additively Manufactured Turbine Blade Tuned Mass Absorber

An innovative concept using a tuned mass absorber for resonant response reduction of turbine blades that is integrally fabricated into the blades using additive manufactured has been developed. Avoiding high resonant response and resulting high cycle fatigue failure is a major concern of the $100B worldwide turbine industry, which encompasses power generation, jet engines and rocket engine turbomachinery. Blade failure is potentially catastrophic, and although preventative measures using dampers do exist, these solutions are extremely expensive to develop and are not always effective. In addition, many of the existing techniques do not work for newer integrally bladed disks (or blisks), where there is no inherent damping in the assembly. The proposed concept, in which a tuned mass absorber re-arranges the structural dynamics and moves energy from the blade to the absorber, is designed specifically for blisks, and is intentionally linear, enabling accurate response prediction during design. Single blade prototypes have been analyzed, fabricated, and tested, and different absorber concepts have shown a reduction in response of up to 60%. After an extensive commercialization and prior art search, MSFC determined the innovation merited the generation and submission of a patent application in August ’21. Funding is now being sought to fabricate a 20-bladed blisk which would be spun at operational speeds with substantially higher and more realistic pressure loads in a special spin facility. Successful completion of this program would raise the TRL from 3/4 to 6/7, significantly improving the viability for adoption of the concept not only in rocket engines but other industrial applications as well.

Turbine Blades↗

Determining the kinetic rate constants of Fe 3 O 4 -to-Fe and FeO-to-Fe reduction by H 2

Steel production using coal accounts for ~ 8% of global carbon emissions. “Green Steel” is a new grand concept proposed recently to make steel from iron ores using renewable derived “Green Hydrogen” to achieve zero carbon emission. The kinetics and rate-limiting steps of iron ore reduction into iron with H 2 as a reducing agent is critically important to the success of this new technology. While reduction of Fe 2 O 3 into Fe by H 2 follows multiple steps, the past research on this topic mainly deals with the overall averaged kinetics, giving little information on the elemental and rate-limiting steps. In this work, we report a kinetic study specifically design to attain kinetic rate constants of one-step reduction of Fe 3 O 4 -to-Fe and FeO-to-Fe. Guided by thermodynamics, we show first how to create in situ the desirable starting oxide phases, i.e., Fe 3 O 4 and FeO, with precisely controlled the ratio of partial pressures of H 2 O and H 2 . We then show time-dependent raw H 2 O content data collected by a mass spectrometer and the processed reduction data to extract kinetic rate constants. We found that the kinetics of the two one-step reduction reactions follows nicely the Johnson-Mehl-Avrami (JMA) phase transformation model. The one-step reduction mechanisms and activation energy are also discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Temperature-dependent solid electrolyte interphase reactions drive performance in lithium-mediated nitrogen reduction to ammonia

The solid electrolyte interphase (SEI) is a vital component to control mass transport and selectivity in the lithium-mediated reduction of N 2 to NH 3 (Li-N 2 R). Finding strategies that generate the optimal SEI, a complex network of organic and inorganic species, can potentially improve Li-N 2 R performance. Here, we unravel structure-property relationships of the SEI by correlating its composition with the NH 3 faradaic efficiency (FENH3). By modifying the reaction temperature, we alter electrolyte decomposition reactions and observe changes in the SEI that explain FE NH3 trends between electrolyte solvents. We quantify a complex reaction environment at elevated temperatures where SEI formation is counteracted by etching reactions. This tradeoff leads to temporal fluctuations of FE NH3 , but the maximal FE NH3 can reach up to 40%, the highest value reported for batch cells at ambient pressure, thus far. In conclusion, our work underscores the potential of novel electrolytes that steer SEI selectivity and, ultimately, improve Li-N 2 R performance.

electrocatalytic nitrogen reduction↗

Impact of thermal energy storage properties on solar dynamic space power conversion system mass

A 16 parameter solar concentrator/heat receiver mass model is used in conjunction with Stirling and Brayton Power Conversion System (PCS) performance and mass computer codes to determine the effect of thermal energy storage (TES) material property changes on overall PCS mass as a function of steady state electrical power output. Included in the PCS mass model are component masses as a function of thermal power for: concentrator, heat receiver, heat exchangers (source unless integral with heat receiver, heat sink, regenerator), heat engine units with optional parallel redundancy, power conditioning and control (PC and C), PC and C radiator, main radiator, and structure. Critical TES properties are: melting temperature, heat of fusion, density of the liquid phase, and the ratio of solid-to-liquid density. Preliminary results indicate that even though overalll system efficiency increases with TES melting temperature up to 1400 K for concentrator surface accuracies of 1 mrad or better, reductions in the overall system mass beyond that achievable with lithium fluoride (LiF) can be accomplished only if the heat of fusion is at least 800 kJ/kg and the liquid density is comparable to that of LiF (1880 kg/cu m.

Juhasz, Albert J.↗

Impact of thermal energy storage properties on solar dynamic space power conversion system mass

A 16 parameter solar concentrator/heat receiver mass model is used in conjunction with Stirling and Brayton Power Conversion System (PCS) performance and mass computer codes to determine the effect of thermal energy storage (TES) material property changes on overall PCS mass as a function of steady state electrical power output. Included in the PCS mass model are component masses as a function of thermal power for: concentrator, heat receiver, heat exchangers (source unless integral with heat receiver, heat sink, regenerator), heat engine units with optional parallel redundancy, power conditioning and control (PC and C), PC and C radiator, main radiator, and structure. Critical TES properties are: melting temperature, heat of fusion, density of the liquid phase, and the ratio of solid-to-liquid density. Preliminary results indicate that even though overall system efficiency increases with TES melting temperature up to 1400 K for concentrator surface accuracies of 1 mrad or better, reductions in the overall system mass beyond that achievable with lithium fluoride (LiF) can be accomplished only if the heat of fusion is at least 800 kJ/kg and the liquid density is comparable to that of LiF (1800 kg/cu m).

Juhasz, Albert J.↗

Microwave Heating of Nanocrystals for Rapid, Low-Aggregation Intermetallic Phase Transformations

The use of intermetallic Pt–Co nanocrystals (NCs) for the electrocatalytic oxygen reduction reaction is quickly gaining interest thanks to the higher electrochemical stability of the intermetallic L1 o phase compared to a random alloy A1 phase. However, the thermal treatment that enables the intermetallic phase transformation also causes considerable NC aggregation, resulting in a significant loss of electrochemically active surface area. Herein, we report the use of microwave radiation to induce the intermetallic phase transformation in Cu-doped Pt–Co NCs. We demonstrate that microwave radiation reduces NC aggregation while allowing for a complete phase transformation in only 30 s. Furthermore, these microwave-treated NCs demonstrate higher mass activity for the oxygen reduction reaction while maintaining electrochemical stability similar to the thermally annealed samples.

36 MATERIALS SCIENCE↗

Lightweight Ablative and Ceramic Thermal Protection System Materials for NASA Exploration Systems Vehicles

As a collaborative effort among NASA Centers, the "Lightweight Nonmetallic Thermal Protection Materials Technology" Project was set up to assist mission/vehicle design trade studies, to support risk reduction in thermal protection system (TPS) material selections, to facilitate vehicle mass optimization, and to aid development of human-rated TPS qualification and certification plans. Missions performing aerocapture, aerobraking, or direct aeroentry rely on advanced heatshields that allow reductions in spacecraft mass by minimizing propellant requirements. Information will be presented on candidate materials for such reentry approaches and on screening tests conducted (material property and space environmental effects tests) to evaluate viable candidates. Seventeen materials, in three classes (ablatives, tiles, and ceramic matrix composites), were studied. In additional to physical, mechanical, and thermal property tests, high heat flux laser tests and simulated-reentry oxidation tests were performed. Space environmental effects testing, which included exposures to electrons, atomic oxygen, and hypervelocity impacts, was also conducted.

Valentine, Peter G.↗

Carbothermal Reduction Demonstration (CaRD)

Introduction: Lunar regolith is approximately 45% oxygen by mass. The majority of the oxygen is bound in silicate minerals. The carbothermal reduction process has been proven to be effective at removing oxygen from lunar regolith simulants. The Carbothermal Reduction Demonstration (CaRD) project aims to increase the Technology Readiness Level (TRL) of a combined solar concentrator and carbothermal reduction systemin order to demonstrate this technology on the lunar surface. The CaRD project is divided into two design cycles, a brass board and prototype. The status of both design cycles will be discussed, as well as concepts for how this technology can be applied to the Artemis program in the future. Brassboard Vacuum Test: For the brassboard demonstration, a 2 kW Nd-YAG laser was used to heat lunar regolith simulant within a carbothermal reactor developed by Sierra Space. The reactor was placed inside of a 15 ft thermal vacuum chamber at the Johnson Space Center. The resulting reaction products were analyzed using both a gas chromotograph and mass spectrometer provided by Kennedy Space Center. Thermal data was also collected. Prototype Design: For the prototype, the CaRD team will perform another thermal vacuum test at JSC using the same interfaces and assets developed for the brassboard but will test a new carbothermal reactor design that Sierra Space is developing through the Carbothermal Oxygen Production Reactor (COPR) Tipping Point project that will include a means to autonomously move regolith in and out of the reactor. In addition, a deployable solar concentrator is being developed by Glenn Research Center using mirrors produced by Carbon Mirror Applications. The solar concentrator will be used to deliver solar energy into a carbothermal reactor to melt regolith and extract oxygen. Avionics and software for the concentrator are being developed by Kennedy Space Center. Future Concepts: An ongoing task within the CaRD project is to update models that can be used to determine the mass, power, and size of In-Situ Resource Utilization concepts at various scales. These models can now be used to analyze alternatives for future applications based on the latest available data.

Aaron Paz↗

Effects of hydrogen isotope species on ITG microturbulence in LHD

Abstract The linear and nonlinear effects of hydrogen isotope species on ion temperature gradient (ITG) instability in the Large Helical Device (LHD) stellarator are studied using radially global gyrokinetic simulation. We found that the coupling range of linear toroidal harmonics depends on the ion mass of the hydrogen isotope. The growth rates of ITG mode are almost the same for H, D, and T plasmas, indicating a gyro-Bohm scaling of ion-mass dependence. The nonlinear electrostatic simulations show that the zonal flow breaks the radially elongated eigenmode structures and reduces the size of the turbulence eddies, which suppresses the turbulence and the ion heat transport in the LHD. The turbulence amplitude without the zonal flow is almost the same for H, D, and T plasmas, while it decreases with increasing ion mass of the hydrogen isotope when the zonal flow is present. The reduction of the turbulent transport with larger ion mass is mostly due to the enhancement of zonal flows by larger ion mass. The ion heat conductivity deviates from the gyro-Bohm scaling for both cases with and without the zonal flow.

Physics↗

Metabolic responses to head-down suspension in hypophysectomized rats

Rats exposed to head-down suspension (HDS) exhibit reductions in maximal O2 consumption (VO2max) and atrophy of select hindlimb muscles. This study tested the hypothesis that an endocrine-deficient rat exposed to HDS would not exhibit reductions in VO2max or hindlimb muscle mass. Hypophysectomized (HYPX) and sham-operated (SHAM) rats were tested for VO2max before and after 28 days of HDS or cage control (CC) conditions. No significant reductions in VO2max were observed in HYPX rats. In contrast, SHAM-HDS rats exhibited a significant reduction in absolute (-16%) and relative (-29%) measures of aerobic capacity. Time course experiments revealed a reduction in VO2max in SHAM-HDS rats within 7 days, suggesting that cardiovascular adjustments to HDS occurred in the 1st wk. HDS was associated with atrophy of the soleus (-42%) in SHAM rats, whereas HYPX rats exhibited atrophy of the soleus (-36%) and plantaris (-13%). SHAM-HDS rats had significantly lower (-38%) soleus citrate synthase activities per gram muscle mass than SHAM-CC, but no significant differences existed between HYPX-HDS and -CC rats. HDS rats had an impaired ability to thermoregulate, as indicated by significantly greater temperature increases per unit run time, compared with their CC counterparts. Pretreatment plasma epinephrine levels were significantly lower in HYPX than in SHAM rats. Norepinephrine concentration was similar for all groups except HYPX-HDS, in which it was significantly higher. HDS had no significant effect on thyroxine or triiodothyronine. SHAM-HDS rats had significantly lower concentrations of testosterone and growth hormone.(ABSTRACT TRUNCATED AT 250 WORDS).

NASA Discipline Number 14-10↗

Ab initio study of mechanical and thermal properties of GeTe-based and PbSe-based high-entropy chalcogenides

GeTe-based and PbSe-based high-entropy compounds have outstanding thermoelectric (TE) performance and crucial applications in mid and high temperatures. Recently, the optimization of TE performance of high-entropy compounds has been focused on reducing thermal conductivity by strengthening the phonon scattering process to improve TE performance. We report a first-principles investigation on nine GeTe-based high-entropy chalcogenide solid solutions constituted of eight metallic elements (Ag, Pb, Sb, Bi, Cu, Cd, Mn, and Sn) and 13 PbSe-based high-entropy chalcogenide solid solutions: Pb 0.99-y Sb 0.012 Sn y Se 1-2x Te x S x (x = 0.1, 0.2, 0.25, 0.3, 0.35, 0.4, 0.45, and y = 0) and Pb 0.99-y Sb 0.012 Sn y Se 1-2x Te x S x (y = 0.05, 0.1, 0.15, 0.2, 0.25 and x = 0.25). We have investigated the mechanical properties focusing on Debye temperature (Θ D ), thermal conductivity (κ), Grüneisen parameter (γ α ), dominant phonon wavelength (λ dom ), and melting temperature (T m ). We find that the lattice thermal conductivity is significantly reduced when GeTe is alloyed into the following compositions: Ge 0.75 Sb 0.13 Pb 0.12 Te, Ge 0.61 Ag 0.11 Sb 0.13 Pb 0.12 Bi 0.01 Te, and Ge 0.61 Ag 0.11 Sb 0.13 Pb 0.12 Mn 0.05 Bi 0.01 Te. This reduction is due to the mass increase and strain fluctuations. The results also show that Ge 0.61 Ag 0.11 Sb 0.13 Pb 0.12 Bi 0.01 Te solid solution has the lowest Young’s modulus (30.362 GPa), bulk and shear moduli (18.626 and 12.359 GPa), average sound velocity (1653.128 m/sec), Debye temperature (151.689 K), lattice thermal conductivity (0.574 W.m –1 .K –1 ), dominant phonon wavelength (0.692 Å), and melting temperature (535.91 K). Moreover, Ge 0.61 Ag 0.11 Sb 0.13 Pb 0.12 Bi 0.01 Te has the highest Grüneisen parameter with a reduced and temperature-independent lattice thermal conductivity. The positive correlation between Θ D and κ is revealed. Alloying of PbSe-based high-entropy by Sb, Sn, Te, and S atoms at the Se and Pb sites resulted in much higher shear strains resulted in the reduction of phonon velocity, a reduced Θ D , and a lower lattice thermal conductivity.

74 ATOMIC AND MOLECULAR PHYSICS↗

Space Exploration Applications for Development of High Capacity Cryocoolers

Long term storage of cryogens is necessary to enable NASAs long duration crewed missions to both the lunar and Martian surfaces. Such missions require in-space transport systems such as Nuclear Thermal Propulsion (NTP), and descent/ascent vehicles for transportation to and from the lunar and Martian surfaces. NTP systems and Lunar/Martian landers utilize cryogenic fluids to minimize architectural volume and mass. To further enhance the capability of these cryogenic systems, the Agency is putting emphasis on reusability, which requires the NTP and ascent/descent elements be replenished on-orbit via tankers or propellant depots, or on the lunar or Martian surface using liquefied in-situ produced propellants. NTP is one of the leading propulsion option for human Mars missions and requires liquid hydrogen to be stored on-orbit for over four years. For such a long duration mission, near “Zero Boil-Off” (ZBO) must be achieved which requires an optimized suite of passive Cryogenic Fluid Management technologies and active cooling (cryocoolers). Tens of Watts of 20K cooling is required to achieve ZBO conditions for NTP, however two-stage cooling using both 20K and 90K systems can lead to a significant reduction in both active cooling mass and power. The use of in-situ resources for lunar and Martian missions will require 150 Watts of 90K cooling for oxygen liquefaction and 300 Watts of 20K cooling for hydrogen liquefaction (lunar only). Descent/Ascent vehicles, propellant depots, and tankers will also require the use of cryocoolers to achieve ZBO conditions. To support these programs, NASA is developing high capacity 20K and 90K reverse turbo-Brayton cycle cryocoolers which offer a scalable, high efficiency, low vibration solution.

cryocooler↗

Jet Noise Reduction by Microjets - A Parametric Study

The effect of injecting tiny secondary jets (microjets ) on the radiated noise from a subsonic primary jet is studied experimentally. The microjets are injected on to the primary jet near the nozzle exit with variable port geometry, working fluid and driving pressure. A clear noise reduction is observed that improves with increasing jet pressure. It is found that smaller diameter ports with higher driving pressure, but involving less thrust and mass fraction, can produce better noise reduction. A collection of data from the present as well as past experiments is examined in an attempt to correlate the noise reduction with the operating parameters. The results indicate that turbulent mixing noise reduction, as monitored by OASPL at a shallow angle, correlates with the ratio of jet to primary jet driving pressures normalized by the ratio of corresponding diameters (p d /pjD). With gaseous injection, the spectral amplitudes decrease at lower frequencies while an increase is noted at higher frequencies. It is apparent that this amplitude crossover is at least partly due to shock-associated noise from the underexpanded jets themselves. Such crossover is not seen with water injection since the flow in that case is incompressible and there is no shock-associated noise. Centerline velocity data show that larger noise reduction is accompanied by faster jet decay as well as significant reduction in turbulence intensities. While a physical understanding of the dependence of noise reduction on p d /pjD remains unclear, given this correlation, an analysis explains the observed dependence of the effect on various other parameters.

Zaman, K. B. M. Q.↗

Modular, thermal bus-to-radiator integral heat exchanger design for Space Station Freedom

The baseline concept is introduced for the 'integral heat exchanger' (IHX) which is the interface of the two-phase thermal bus with the heat-rejecting radiator panels. A direct bus-to-radiator heat-pipe integral connection replaces the present interface hardware to reduce the weight and complexity of the heat-exchange mechanism. The IHX is presented in detail and compared to the baseline system assuming certain values for heat rejection, mass per unit width, condenser capacity, contact conductance, and assembly mass. The spreadsheet comparison can be used to examine a variety of parameters such as radiator length and configuration. The IHX is shown to permit the reduction of panel size and system mass in response to better conductance and packaging efficiency. The IHX is found to be a suitable heat-rejection system for the Space Station Freedom because it uses present technology and eliminates the interface mechanisms.

Chambliss, Joe↗

Cytometer on a Chip

A cytometer now under development exploits spatial sorting of sampled cells on a microarray chip followed by use of grating-coupled surface-plasmon-resonance imaging (GCSPRI) to detect the sorted cells. This cytometer on a chip is a prototype of contemplated future miniature cytometers that would be suitable for rapidly identifying pathogens and other cells of interest in both field and laboratory applications and that would be attractive as alternatives to conventional flow cytometers. The basic principle of operation of a conventional flow cytometer requires fluorescent labeling of sampled cells, stringent optical alignment of a laser beam with a narrow orifice, and flow of the cells through the orifice, which is subject to clogging. In contrast, the principle of operation of the present cytometer on a chip does not require fluorescent labeling of cells, stringent optical alignment, or flow through a narrow orifice. The basic principle of operation of the cytometer on a chip also reduces the complexity, mass, and power of the associated laser and detection systems, relative to those needed in conventional flow cytometry. Instead of making cells flow in single file through a narrow flow orifice for sequential interrogation as in conventional flow cytometry, a liquid containing suspended sampled cells is made to flow over the front surface of a microarray chip on which there are many capture spots. Each capture spot is coated with a thin (.50-nm) layer of gold that is, in turn, coated with antibodies that bind to cell-surface molecules characteristic of the cell species of interest. The multiplicity of capture spots makes it possible to perform rapid, massively parallel analysis of a large cell population. The binding of cells to each capture spot gives rise to a minute change in the index of refraction at the surface of the chip. This change in the index of refraction is what is sensed in GCSPRI, as described briefly below. The identities of the various species in a sample of cells is spatially encoded in the chip by the pattern of capture spots. The number of cells of a particular species is determined from the magnitude of the GCSPRI signal from that spot. GCSPRI as used here can be summarized as follows: The cytometer chip is fabricated with a diffraction grating on its front surface. The chip is illuminated with a light emitting diode (LED) from the front. By proper choice of grating parameters and of the wavelength and the angle of incidence of a laser beam, laser light can be made to be coupled into an electromagnetic mode that resonates with surface plasmons and thus couples light into surface plasmons. Coupling of light into a surface plasmon at a given location reduces the amount of incident light reflected from that location. A change in the index of refraction at the surface of a capture spot gives rise to a change in the resonance condition. Depending on the specific design, the change in the index of refraction could manifest itself as a brightening or darkening, a change in the wavelength needed to excite the plasmon at a given angle of incidence, or a change in the angle of incidence needed to excite the plasmon at a given wavelength. Whereas a multiwavelength laser system with multichannel detection would be needed to detect multiple species in conventional flow cytometry, it suffices to use an LED and a single detector channel in the GCSPRI approach: this contributes significantly to reductions in cost, complexity, size, mass, and power. GCSPRI cytometer chips could be made of plastic and could be mass-produced cheaply by use of molding and other methods adopted from the manufacture of digital video disks. These methods are amenable to a high degree of miniaturization: such additional features as fluidic channels, reaction chambers, and fluid-coupling ports could readily be incorporated into the chips, without incurring substantial additional costs.

Fernandez, Salvador M.↗

Cytometer on a Chip

A cytometer now under development exploits spatial sorting of sampled cells on a microarray chip followed by use of grating-coupled surface-plasmon-resonance imaging (GCSPRI) to detect the sorted cells. This cytometer on a chip is a prototype of contemplated future miniature cytometers that would be suitable for rapidly identifying pathogens and other cells of interest in both field and laboratory applications and that would be attractive as alternatives to conventional flow cytometers. The basic principle of operation of a conventional flow cytometer requires fluorescent labeling of sampled cells, stringent optical alignment of a laser beam with a narrow orifice, and flow of the cells through the orifice, which is subject to clogging. In contrast, the principle of operation of the present cytometer on a chip does not require fluorescent labeling of cells, stringent optical alignment, or flow through a narrow orifice. The basic principle of operation of the cytometer on a chip also reduces the complexity, mass, and power of the associated laser and detection systems, relative to those needed in conventional flow cytometry. Instead of making cells flow in single file through a narrow flow orifice for sequential interrogation as in conventional flow cytometry, a liquid containing suspended sampled cells is made to flow over the front surface of a microarray chip on which there are many capture spots. Each capture spot is coated with a thin (approximately 50-nm) layer of gold that is, in turn, coated with antibodies that bind to cell-surface molecules characteristic of one the cell species of interest. The multiplicity of capture spots makes it possible to perform rapid, massively parallel analysis of a large cell population. The binding of cells to each capture spot gives rise to a minute change in the index of refraction at the surface of the chip. This change in the index of refraction is what is sensed in GCSPRI, as described briefly below. The identities of the various species in a sample of cells is spatially encoded in the chip by the pattern of capture spots. The number of cells of a particular species is determined from the magnitude of the GCSPRI signal from that spot. GCSPRI as used here can be summarized as follows: The cytometer chip is fabricated with a diffraction grating on its front surface. The chip is illuminated with a light emitting diode (LED) from the front. By proper choice of grating parameters and of the wavelength and the angle of incidence of a laser beam, laser light can be made to be coupled into an electromagnetic mode that resonates with surface plasmons and thus couples light into surface plasmons. Coupling of light into a surface plasmon at a given location reduces the amount of incident light reflected from that location. A change in the index of refraction at the surface of a capture spot gives rise to a change in the resonance condition. Depending on the specific design, the change in the index of refraction could manifest itself as a brightening or darkening, a change in the wavelength needed to excite the plasmon at a given angle of incidence, or a change in the angle of incidence needed to excite the plasmon at a given wavelength. Whereas a multiwavelength laser system with multichannel detection would be needed to detect multiple species in conventional flow cytometry, it suffices to use an LED and a single detector channel in the GCSPRI approach: this contributes significantly to reductions in cost, complexity, size, mass, and power. GCSPRI cytometer chips could be made of plastic and could be mass-produced cheaply by use of molding and other methods adopted from the manufacture of digital video disks. These methods are amenable to a high degree of miniaturization: such additional features as fluidic channels, reaction chambers, and fluid-coupling ports could readily be incorporated into the chips, without incurring substantial additional costs.

Fernandez, Salvador M.↗