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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Measuring Hydrogen Concentrations in Metals

Commercial corrosion-measurement system adapted to electrochemical determination of hydrogen concentrations in metals. New technique based on diffusion of hydrogen through foil specimen of metal. In sample holder, hydrogen produced on one side of foil, either by corrosion reaction or by cathodic current. Hydrogen diffused through foil removed on other side by constant anode potential, which leads to oxidation of hydrogen to water. Anode current is measure of concentration of hydrogen diffusing through foil. System used to study hydrogen uptake, hydrogen elimination by baking, effect of heat treatment, and effect of electroplating on high-strength steels.

Danford, M. D.↗
NASA NTRS1973

The 5-kwe reactor thermoelectric system summary

Design of the 5-kwe reactor thermoelectric system was initiated in February 1972 and extended through the conceptual design phase into the preliminary design phase. Design effort was terminated in January, 1973. This report documents the system and component requirements, design approaches, and performance and design characteristics for the 5-kwe system. Included is summary information on the reactor, radiation shields, power conversion systems, thermoelectric pump, radiator/structure, liquid metal components, and the control system.

Vanosdol, J. H.↗
NASA NTRS2005

Materials Chemistry Issues in the Development of a Single-Crystal Solar/Thermal Refractive Secondary Concentrator

A translucent crystal concentrates and transmits energy to a heat exchanger, which in turn heats a propellant gas, working gas of a dynamic power system, or a thermopile. Materials are the limiting issue in such a system. Central is the durability of the crystal, which must maintain the required chemical, physical/optical, and mechanical properties as it is heated and cooled. This report summarizes available data to date on the materials issues with this system. We focus on the current leading candidate materials, which are sapphire (Al2O3) for higher temperatures and silica (SiO2) for lower temperatures. We use data from thermochemical calculations; laboratory coupon tests with silica and sapphire; and system tests with sapphire. The required chemical properties include low-vapor pressure and interfacial stability with supporting structural materials. Optical properties such as transmittance and index of refraction must be maintained. Thermomechanical stability is a major challenge for a large, single-crystal ceramic and has been discussed in another report. In addition to the crystal, other materials in the proposed system include refractory metals (Nb, Ta, Mo, W, and Re), carbon (C), and high-temperature ceramic insulation. The major issue here is low levels of oxygen, which lead to volatile refractory metal oxides and rapid consumption of the refractory metal. Interfacial reactions between the ceramic crystal and refractory metal are also discussed. Finally, high-temperature ceramic insulating materials are also likely to be used in this system. Outgassing is a major issue for these materials. The products of outgassing are typically reactive with the refractory metals and must be minimized.

Jacobson, Nathan S.↗
NASA NTRS1987

Calculation of the surface tension of liquid metals using a one-component-plasma reference system

The one-component-plasma (OCP) model is used as a reference system instead of the traditional hard-sphere fluid to calculate the liquid-vapor interfacial surface tension of liquid metals within the density functional formalism. The calculated surface tensions of the alkali metals are in excellent agreement with experiment. For the polyvalent metal Al, the result obtained is larger than experimental measurements. It is concluded that the OCP system is not suitable to describe the liquid-vapor phase transition in simple metals which have a nominal plasma parameter larger than the usual freezing value of about 178. The calculated interfacial widths in all cases are narrower than the expected experimental values.

Zeng, X. C.↗
NASA NTRS2011

Assessment of the Use of Nanofluids in Spacecraft Active Thermal Control Systems

The addition of metallic nanoparticles to a base heat transfer fluid can dramatically increase its thermal conductivity. These nanofluids have been shown to have advantages in some heat transport systems. Their enhanced properties can allow lower system volumetric flow rates and can reduce the required pumping power. Nanofluids have been suggested for use as working fluids for spacecraft Active Thermal Control Systems (ATCSs). However, there are no studies showing the end-to-end effect of nanofluids on the design and performance of spacecraft ATCSs. In the present work, a parametric study is performed to assess the use of nanofluids in a spacecraft ATCSs. The design parameters of the current Orion capsule and the tabulated thermophysical properties of nanofluids are used to assess the possible benefits of nanofluids and how their incorporation affects the overall design of a spacecraft ATCS. The study shows that the unique system and component-level design parameters of spacecraft ATCSs render them best suited for pure working fluids. The addition of nanoparticles to typical spacecraft thermal control working fluids actually results in an increase in the system mass and required pumping power.

Ungar, Eugene K.↗
NASA NTRS1975

Aerothermal performance and structural integrity of a Rene 41 thermal protection system at Mach 6.6

A flightweight panel based on a metallic thermal-protection-system concept for hypersonic and reentry vehicles was subjected repeatedly to thermal cycling by quartz-lamp radiant heating using a thermal history representative of a reentry heat pulse and to aerodynamic heating at heating rates required to sustain a surface temperature of 1089 K (1960 R). The panel consisted of a corrugated heat shield and support members of 0.05-cm (0.02-in.) thick Rene 41 of riveted construction and 5.08-cm (2-in.) thick silica fibrous insulation packages covered by Rene 41 foil and inconel screening. All tests were conducted in the Langley 8-foot high-temperature structures tunnel with the heat shield corrugations alined in the stream direction. The panel sustained 5.33 hr of intermittent radiant heating and 6.5 min of intermittent aerodynamic heating of up to 1-min duration for differential pressures up to 6.2 kPa (0.9 psi) with no apparent degradation of thermal or structural integrity, as indicated by temperature distributions and results from load deflection tests and vibration surveys of natural frequencies.

Deveikis, W. D.↗
NASA NTRS1976

Initiation with an electron beam of chemical reactions of interest for visible wavelength lasers

A description is given of the first results obtained with a new shock tube-electron beam facility designed to provide a versatile means for the systematic search for laser operation among several candidate metal atom-oxidizer systems. According to the current experimental approach, metal atoms are obtained in the vapor phase by the dissociation of metal compounds. A shock tube is employed to provide a short duration flow through an array of 29 supersonic flow-mixing nozzles. A high energy electron accelerator is used for the rapid initiation of chemical reaction in a mixed flow of encapsulated metal and oxidizer.

Whittier, J. S.↗
NASA NTRS1986

Testing metals and alloys for use in oxygen systems

When oxygen is present in high concentrations or large quantities, as in oxygen-based life-support systems, the likelihood of combustion and the probable intensity of a conflagration increase, together with the severity of the damage caused. Even stainless steel will burn vigorously when ignited in a 1000-psi oxygen environment. The hazards involved in the use of oxygen increase with system operation at the elevated temperatures typical of propulsion systems. Fires in oxygen systems are generally catastrophic, causing a threat to life in manned vehicles. When mechanical components of a mechanism generate friction heat in the presence of oxygen, many commonly used metal alloys ignite and burn. Attention is presently given to frictional heating, particle impact, and flame propagation tests conducted in oxygen environments.

Stoltzfus, Joel M.↗
NASA NTRS2019

Electron Beam Welding of Pure Tungsten Hex Cans for Nuclear Thermal Propulsion Engines

Nuclear thermal propulsion (NTP) is an in-space propulsion method currently being developed at the NASA Marshall Space Flight Center (MSFC). NTP systems are a high specific impulse (750–1,100 s), high thrust (15,000–250,000 lbf ) method of propulsion which have the potential to allow for faster transit times when optimizing for high ΔV. In the nuclear rocket engine, the heat from the nuclear fission reaction is transferred to a low molecular mass propellant (such as hydrogen). Hot propellant is expanded through a nozzle to generate thrust. Development of ceramic metal (cermet) fuel systems for NTP applications is currently ongoing at MSFC. In cermet fuel systems, ceramic fissile fuel particles such as uranium nitride or uranium dioxide are dispersed within a net-shaped, high-density structural matrix. The composite material is cladded by a protective metal structure to make up an NTP fuel element. Cladding materials must be able to withstand the demanding operating conditions required of the engine as well as retain a hermetic seal to allow for retention of fuel element structural integrity, prevent hydrogen attack or migration of the ceramic fuel, and limit release of fission products during operation. For NTP applications, tungsten is a prime material for both the metal matrix and cladding in cermet fuel systems because of its high melting point, high temperature strength, and compatibility with hot hydrogen. If a weld in tungsten with the capability of holding a hermetic seal is achievable, tungsten becomes a strong candidate for NTP applications. This Technical Memorandum focuses on determining the weldability of pure tungsten using electron beam welding (EBW). Tungsten appears well suited for NTP applications, but it has a high ductile to brittle transition temperature (DBTT) dependent upon chemical composition, structure/stress distribution, and mechanical conditions. Therefore, it is highly subject to brittle fracture. Because of its high susceptibility to brittle fracture, it is very difficult to weld. EBW was chosen for joining pure tungsten because of its low heat input compared to gas tungsten arc welding. Reduced heat input can be directly correlated with an increase in ductility of a tungsten weld. EBW is a high energy density welding process in which a stream of electrons penetrates a weld joint in a deep, narrow spike in contrast to a broad gas tungsten arc weld pool. The investigation initially focused on EBW of tungsten plates of both 0.01 in and 0.03 in thickness to determine if EBW could weld pure tungsten without the presence of visual defects—particularly cracking—in the welds. Variation in the weld procedure and post-weld heat treatment (PWHT) was used to improve the surface appearance of flat EBWs on a pure tungsten sheet. The investigation moved on to weld 0.05-in-thick hexagonal tungsten cans with a weld joint thickness of 0.025 in. The goal for welding the pure tungsten hex cans was to avoid any visual surface defects and generate a weld capable of a hermetic seal. This proved difficult. Cold welds commonly exhibited porosity that leaked air. Hot welds exhibited cracks, typically observed immediately after welding. Later welds were preheated to increase ductility and decrease the likelihood of through-thickness cracking. PWHT was used to arrest microcrack growth both in the flat weld samples and hexagonal weld samples.

Courtright, Z. S.↗
NASA NTRS1999

The Use of Metal Filled Via Holes for Improving Isolation in LTCC RF and Wireless Multichip Packages

LTCC MCMs (Low Temperature Cofired Ceramic MultiChip Module) for RF and wireless systems often use metal filled via holes to improve isolation between the stripline and microstrip interconnects. In this paper, results from a 3D-FEM electromagnetic characterization of microstrip and stripline interconnects with metal filled via fences for isolation are presented. It is shown that placement of a via hole fence closer than three times the substrate height to the transmission lines increases radiation and coupling. Radiation loss and reflections are increased when a short via fence is used in areas suspected of having high radiation. Also, via posts should not be separated by more than three times the substrate height for low radiation loss, coupling, and suppression of higher order modes in a package.

Ponchak, George E.↗
NASA NTRS1975

Water hyacinths for removal of cadmium and nickel from polluted waters

Removal of cadmium and nickel from static water systems utilizing water hyacinths (Eichhornia crassipes (Mart.) Solms) was investigated. This aquatic plant demonstrated the ability to rapidly remove heavy metals from aqueous systems by root absorption and concentration. Water hyacinths demonstrated the ability to absorb and concentrate up to 0.67 mg of cadmium and 0.50 mg of nickel per gram of dry plant material when exposed for a 24-hour period to waters polluted with from 0.578 to 2.00 ppm of these toxic metals. It is found that one hectare of water hyacinths has the potential of removing 300 g of cadmium or nickel from 240,000 liters of water polluted with these metals during a 24-hour period.

Wolverton, B. C.↗
NASA NTRS2002

Automation of NDE on RSRM Metal Components

An automated eddy current system has been designed and built, and is being implemented to inspect RSRM (Space Shuttle) metal components. The system provides a significant increase in inspection reliability, as well as other benefits such as data storage, chemical waste reduction and reduction in overall process time. This paper is in viewgraph form.

Hartman, John↗
NASA NTRS1996

Cosmic Metal Production and the Contribution of QSO Absorption Systems to the Ionizing Background

The recent discovery by Cowie et al. (1995) and Tytler et al. (1995) of metals in the Ly alpha clouds shows that the intergalactic medium (IGM) at high redshift is contaminated by the products of stars and suggests that ionizing photons from massive star formation may be a significant contributor to the UV background radiation at early epochs. We assess the validity of the stellar photoionization hypothesis. Based on recent computations of metal yields and 0-star Lyman continuum (Lyc) fluxes, we find that 0.2 percent of the rest-mass energy of the metals produced is radiated as Lyc. By modeling the transfer of ionizing radiation through the IGM and the rate of chemical enrichment, we demonstrate that the background intensity of photons at 1 ryd that accompanies the production of metals in the Ly alpha forest clouds may be significant, approaching 0.5 x 10(exp -21) ergs cm squared s(-1) Hz(-1) sr(-1) at z approximately equals 3 if the Lyc escape fraction is greater than of equal to 0.25. Together with quasars, massive stars could then, in principle, provide the hydrogen and helium Lyc photons required to ionize the universe at high redshifts. We propose that observations of the He2 Gunn-Peterson effect and of the metal ionization states of the Ly alpha forest and Lyman-limit absorbers should show the signature of a stellar spectrum. We also note that the stellar photoionization model fails if a large fraction of the UV radiation emitted from stars cannot escape into the IGM, as suggested by the recent Hopkins Ultraviolet Telescope observations by Leitherer et al. (1995) of low-redshift starburst galaxies, or if most of the metals observed at z is approximately 3 were produced at much earlier epochs.

Madau, Piero↗
NASA NTRS1993

Damped Lyman-alpha absorption by disk galaxies with large redshifts. IV - More intermediate-resolution spectroscopy

Intermediate-resolution spectra of six QSOs exhibiting seven Ly-alpha absorption troughs that are candidates for damped Ly-alpha absorption lines are presented. The metal content of the confirmed damped systems is investigated by examining the metal-line velocity profiles, and by performing curve-of-growth analyses for four of the six confirmed damped systems. The low-ionization lines associated with the z(metals) = 2.0399 damped system toward Q0458-020 have velocity widths up to 10 times wider than the width of the 21-cm absorption feature found at the same redshift. Since the 21-cm absorption arises in a low velocity dispersion layer of H I that extends more than 8/h kpc transverse to the line of sight, the H I absorption cannot arise from the same clouds responsible for the bulk of the metal-line absorption. This is strong evidence for a two-component model consisting of high column density 'quiescent' gas which gives rise to damped Ly-alpha and 21-cm absorption, and low column density 'turbulent' gas which dominates equivalent widths of saturated metal lines.

Wolfe, Arthur M.↗