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Optimization of residual stresses in MMC's through the variation of interfacial layer architectures and processing parameters

The objective of this work was the development of efficient, user-friendly computer codes for optimizing fabrication-induced residual stresses in metal matrix composites through the use of homogeneous and heterogeneous interfacial layer architectures and processing parameter variation. To satisfy this objective, three major computer codes have been developed and delivered to the NASA-Lewis Research Center, namely MCCM, OPTCOMP, and OPTCOMP2. MCCM is a general research-oriented code for investigating the effects of microstructural details, such as layered morphology of SCS-6 SiC fibers and multiple homogeneous interfacial layers, on the inelastic response of unidirectional metal matrix composites under axisymmetric thermomechanical loading. OPTCOMP and OPTCOMP2 combine the major analysis module resident in MCCM with a commercially-available optimization algorithm and are driven by user-friendly interfaces which facilitate input data construction and program execution. OPTCOMP enables the user to identify those dimensions, geometric arrangements and thermoelastoplastic properties of homogeneous interfacial layers that minimize thermal residual stresses for the specified set of constraints. OPTCOMP2 provides additional flexibility in the residual stress optimization through variation of the processing parameters (time, temperature, external pressure and axial load) as well as the microstructure of the interfacial region which is treated as a heterogeneous two-phase composite. Overviews of the capabilities of these codes are provided together with a summary of results that addresses the effects of various microstructural details of the fiber, interfacial layers and matrix region on the optimization of fabrication-induced residual stresses in metal matrix composites.

Pindera, Marek-Jerzy↗

Crack Growth Behavior in the Threshold Region for High Cycle Fatigue Loading

This presentation describes results obtained from a research project conducted at the NASA Johnson Space Center (JSC) that was jointly supported by the FAA Technical Center and JSC. The JSC effort was part of a multi-task FAA program involving several U.S. laboratories and initiated for the purpose of developing enhanced analysis tools to assess damage tolerance of rotorcraft and aircraft propeller systems. The research results to be covered in this presentation include a new understanding of the behavior of fatigue crack growth in the threshold region. This behavior is important for structural life analysis of aircraft propeller systems and certain rotorcraft structural components (e.g., the mast). These components are often designed to not allow fatigue crack propagation to exceed an experimentally determined fatigue crack growth threshold value. During the FAA review meetings for the program, disagreements occurred between the researchers regarding the observed fanning (spread between the da/dN curves of constant R) in the threshold region at low stress ratios, R. Some participants believed that the fanning was a result of the ASTM load shedding test method for threshold testing, and thus did not represent the true characteristics of the material. If the fanning portion of the threshold value is deleted or not included in a life analysis, a significant penalty in the calculated life and design of the component would occur. The crack growth threshold behavior was previously studied and reported by several research investigators in the time period: 1970-1980. Those investigators used electron microscopes to view the crack morphology of the fatigue fracture surfaces. Their results showed that just before reaching threshold, the crack morphology often changed from a striated to a faceted or cleavage-like morphology. This change was reported to have been caused by particular dislocation properties of the material. Based on the results of these early investigations, a program was initiated at JSC to repeat these examinations on a number of aircraft structural alloys that were currently being tested for obtaining fatigue crack growth properties. These new scanning electron microscope (SEM) examinations of the fatigue fracture faces confirmed the change in crack morphology in the threshold crack tip region. In addition, SEM examinations were further performed in the threshold crack-tip region before breaking the specimens open (not done in the earlier published studies). In these examinations, extensive crack forking and even 90-degree crack bifurcations were found to have occurred in the final threshold crack-tip region. The forking and bifurcations caused numerous closure points to occur that prevented full crack closure in the threshold region, and thus were the cause of the fanning at low-R values. Therefore, we have shown that the fanning behavior was caused by intrinsic dislocation properties of the different alloy materials and were not the result of a plastic wake that remains from the load-shedding test phase. Also, to accommodate the use of da/dN data which includes fanning at low R-values, an updated fanning factor term has been developed and will be implemented into the NASGRO fatigue crack growth software. The term can be set to zero if it is desired that the fanning behavior is not be modeled for particular cases, such as when fanning is not a result of the intrinsic properties of a material.

Forman, Royce G.↗

A Moderate D/H Ratio for a Surficial Water Reservoir on Mars

Martian surface morphology implies that Mars was once warm enough to maintain persistent liquid water on its surface and that water played a significant role in the formation of weathered/altered terrains [e.g., 1, 2, 3]. Volatiles exhaled by volcanic activity would have been the dominant greenhouse gases and would have significantly affected the Martian climate. The enrichment of some volatile elements in the atmosphere, which would have dissolved in surface water, could also have influenced water chemistry (e.g., acidity) and played a significant role in weathering and aqueous alteration processes. While much of this picture is qualitative, Martian meteorites contain records of major Martian volatile reservoirs. This study characterizes Martian surficial volatile reservoirs based on in situ ion microprobe analyses of volatile abundances and H-isotopes of glassy phases (groundmass glass [GG] and impact melt [IM]) in Martian basalts (shergottites). Although these meteorites are of igneous origin, some glassy phases underwent impact-induced modification that trapped surficial and atmospheric volatile components [4, 5]; e.g., inert gases contained in IMs from EETA79001 (EETA79) match the relative abundances of modern Martian atmosphere [6]. Analyses of these glassy phases demonstrate that surficial volatile reservoirs have distinct D/H ratios from their magmatic volatiles.

Usui, Tomohiro↗

The Prelude to and Aftermath of the Giant Flare of 2004 December 27: Persistent and Pulsed X-ray Properties of SGR 1806-20 from 1993 to 2005

We report on the evolution of key spectral and temporal parameters of SGR 1806-20 prior to and following the highly energetic giant flare of 2004 December 27. Using RXTE, we track the pulse frequency of the SGR and find that the spin-down rate varied erratically in the months before and after the flare. Contrary to the giant flare in SGR 1900+14, we find no evidence for a discrete jump in spin frequency at the time of the December 27th flare (Absolute value of (Delta * upsilon/upsilon) < 5 10 (exp -6)). In the months surrounding the flare, we find a strong correlation between pulsed flux and torque consistent with the model for magnetar magnetosphere electrodynamics proposed. As with the flare in SGR 1900+14, the pulse morphology of SGR 1806-20 changes drastically following the flare. Using Chandra and other publicly available imaging X-ray detector observations, we construct a spectral history of SGR 1806-20 from 1993 to 2005. The usual magnetar persistent emission spectral model of a power law plus a blackbody provides an excellent fit to the data. We confirm the earlier finding of increasing spectral hardness of SGR 1806-20 between 1993 and 2004. However, our results indicate significant differences in the temporal evolution of the spectral hardening. Rather than a direct correlation between torque and spectral hardness, we find evidence for a sudden torque change that preceded a gradual hardening of the energy spectrum on a timescale of years. Interestingly, the spectral hardness, spin-down rate, phase-averaged flux, and pulsed flux of SGR 1806-20 all peak months before the flare epoch.

Woods, Peter M.↗

A Multiwavelength Dynamical State Analysis of ACT-CLJ0019.6+0336

In our study, we show a multiwavelength view of ACT-CL J0019.6+0336 (which hosts aradio halo), to investigate the cluster dynamics, morphology, and ICM. We use a combination ofXMM-Newton images, Dark Energy Survey (DES) imaging and photometry, SDSS spectroscopicinformation, and 1.16 GHz MeerKAT data to study the cluster properties. Various X-ray and opticalmorphology parameters are calculated to investigate the level of disturbance. We find disturbancesin two X-ray parameters and the optical density map shows elongated and axisymmetric structureswith the main cluster component southeast of the cluster centre and another component northwest ofthe cluster centre. We also find a BCG offset of∼950 km/s from the mean velocity of the cluster, anda discrepancy between the SZ mass, X-ray mass, and dynamical mass (MX,500andMSZ,500lies>3σaway fromMdyn,500), showing that J0019 is a merging cluster and probably in a post-merging phase.

Denisha S Pillay↗

Metallicities of Emission-Line Galaxies from HST ACS PEARS and HST WFC3 ERS Grism Spectroscopy at 0.6 is less than z is less than 2.4

Galaxies selected on the basis of their emission line strength. show low metallicities, regardless of their redshifts. We conclude this from a sample of faint galaxies at redshifts between 0.6 < z < 2.4, selected by their prominent emission lines in low resolution grism spectra in the optiCa.i with the Advanced Camera for Surveys (ACS) on the Hubble Space Telescope (HST) and in the near-infrared using Wide-Field Camera 3 (WFC3). Using a sample of 11 emission line galaxies (ELGs) at 0.6 < z < 2.4 with luminosities of -22 approx < MB approx -19 which have [OII], H-Beta, and [OIII] line flux measurements from the combination of two grism spectral surveys, we use the R23 method to derive the gas-phase oxygen abundances: 7.5 <12+log(0/H)<8.5. The galaxy stellar masses are derived using Bayesian based Markov Chain Monte Carlo (pi MC(exp 2)) fitting of their Spectral Energy Distribution (SED), and span the mass range 8.1 < log(M(stellar)/M(solar)) < 10.1. These galaxies show a mass-metal1icity (M-L) and Luminosity-Metallicity (LZ) relation, which is offset by -<J.6 dex in meta1licity at given absolute magnitude and stellar mass relative to the local SDSS galaxies, as well as continuum selected DEEP2 samples at similar redshifts. The emission-line selected galaxies most resemble the local "green peas" galaxies and Lyman-alpha galaxies at z approx = 0.3 and z approx = 2.3 in the M-Z and L-Z relations and their morphologies. The G - M(sub 20) morphology analysis shows that 10 out of 11 show disturbed morphology, even as the star-forming regions are compact. These galaxies may be intrinsically metal poor, being at early stages of formation, or the low metallicities may be due to gas infall and accretion due to mergers.

Xia, Lifang↗

Mass loss during the RR Lyrae phase of the horizontal branch: Mass dispersion on the horizontal branch and RR Lyrae period changes

Mass loss on the horizontal branch has been invoked in the literature to explain such phenomena as the color (mass) dispersion of the horizontal branch and the observed distribution of period changes in RR Lyrae stars. To test these claims, the Yale stellar evolution code was used to evolve horizontal branch models of masses 0.64, 0.66, 0.68, 0.70, and 0.72 solar mass with Z of 0.001, core mass of 0.4893, main-sequence helium abundance of 0.23, and constant mass loss rates of 0, 10(exp -10), 5 x 10(exp -10), and 10(exp -9) solar mass/yr. Mass loss was assumed to occur only in the instability strip, where a mechanism is most likely to exist. Synthetic horizontal branches, constructed from the models, show that mass loss on the horizontal branch cannot produce the observed color dispersion even for the highest mass-loss rate of 10(exp -9) solar mass/yr. Mass loss is unlikely to occur at a higher rate without significant effects on the horizontal branch morphology, which would destroy the good agreement between standard synthetic models without mass loss and observed horizontal branches. Periods and period changes were calculated for all models. The period changes are not significantly larger for models with mass loss. The effect of mass loss in clusters of other metallicities is discussed.

Koopmann, Rebecca A.↗

Multispectral Imaging Broadens Cellular Analysis

Amnis Corporation, a Seattle-based biotechnology company, developed ImageStream to produce sensitive fluorescence images of cells in flow. The company responded to an SBIR solicitation from Ames Research Center, and proposed to evaluate several methods of extending the depth of field for its ImageStream system and implement the best as an upgrade to its commercial products. This would allow users to view whole cells at the same time, rather than just one section of each cell. Through Phase I and II SBIR contracts, Ames provided Amnis the funding the company needed to develop this extended functionality. For NASA, the resulting high-speed image flow cytometry process made its way into Medusa, a life-detection instrument built to collect, store, and analyze sample organisms from erupting hydrothermal vents, and has the potential to benefit space flight health monitoring. On the commercial end, Amnis has implemented the process in ImageStream, combining high-resolution microscopy and flow cytometry in a single instrument, giving researchers the power to conduct quantitative analyses of individual cells and cell populations at the same time, in the same experiment. ImageStream is also built for many other applications, including cell signaling and pathway analysis; classification and characterization of peripheral blood mononuclear cell populations; quantitative morphology; apoptosis (cell death) assays; gene expression analysis; analysis of cell conjugates; molecular distribution; and receptor mapping and distribution.

Source record↗

Multiscale and Multiphysics Modeling of Additive Manufacturing of Advanced Materials

The objective of this proposed project is to research and develop a prediction tool for advanced additive manufacturing (AAM) processes for advanced materials and develop experimental methods to provide fundamental properties and establish validation data. Aircraft structures and engines demand materials that are stronger, useable at much higher temperatures, provide less acoustic transmission, and enable more aeroelastic tailoring than those currently used. Significant improvements in properties can only be achieved by processing the materials under nonequilibrium conditions, such as AAM processes. AAM processes encompass a class of processes that use a focused heat source to create a melt pool on a substrate. Examples include Electron Beam Freeform Fabrication and Direct Metal Deposition. These types of additive processes enable fabrication of parts directly from CAD drawings. To achieve the desired material properties and geometries of the final structure, assessing the impact of process parameters and predicting optimized conditions with numerical modeling as an effective prediction tool is necessary. The targets for the processing are multiple and at different spatial scales, and the physical phenomena associated occur in multiphysics and multiscale. In this project, the research work has been developed to model AAM processes in a multiscale and multiphysics approach. A macroscale model was developed to investigate the residual stresses and distortion in AAM processes. A sequentially coupled, thermomechanical, finite element model was developed and validated experimentally. The results showed the temperature distribution, residual stress, and deformation within the formed deposits and substrates. A mesoscale model was developed to include heat transfer, phase change with mushy zone, incompressible free surface flow, solute redistribution, and surface tension. Because of excessive computing time needed, a parallel computing approach was also tested. In addition, after investigating various methods, a Smoothed Particle Hydrodynamics Model (SPH Model) was developed to model wire feeding process. Its computational efficiency and simple architecture makes it more robust and flexible than other models. More research on material properties may be needed to realistically model the AAM processes. A microscale model was developed to investigate heterogeneous nucleation, dendritic grain growth, epitaxial growth of columnar grains, columnar-to-equiaxed transition, grain transport in melt, and other properties. The orientations of the columnar grains were almost perpendicular to the laser motion's direction. Compared to the similar studies in the literature, the multiple grain morphology modeling result is in the same order of magnitude as optical morphologies in the experiment. Experimental work was conducted to validate different models. An infrared camera was incorporated as a process monitoring and validating tool to identify the solidus and mushy zones during deposition. The images were successfully processed to identify these regions. This research project has investigated multiscale and multiphysics of the complex AAM processes thus leading to advanced understanding of these processes. The project has also developed several modeling tools and experimental validation tools that will be very critical in the future of AAM process qualification and certification.

Liou, Frank↗

Observed On-Orbit Background of the ACIS Detector on the Chandra X-Ray Observatory

We have analyzed calibration data acquired during the Orbital Activation and Checkout (OAC) phase of the Chandra X-ray Observatory (CXO) mission in order to characterize the background of the Advanced CCD Imaging Spectrometer (ACIS) produced by charged particles and non-cosmic X-rays. The ACIS instrument contains 8 Front-Illuminated (FI) CCDs and 2 Back-Illuminated (BI) CCDs. The FI and BI CCD)s exhibit dramatically different responses to enhancements in the particle flux. The F1 CCDs show relatively little increase in the overall count rate, typical increases are 1 - 3 counts/s; the BI CCDs show large excursions to as high as 100 counts/s. The duration of these intervals of enhanced background are highly variable ranging from 100 s to 5000 s. The spatial distribution of these background events is relatively flat across the power-law. The events produce morphologies which are similar to cosmic X-ray events, so that morphology alone cannot be used as a rejection criterion. We explore the correlation of these times of high background with the data from Chandra's on-board radiation monitor, the EPHIN (Electron, Proton, Helium Instrument particle detector) instrument and archival data from the Advanced Composition Explorer (ACE) satellite. We discuss strategies for observers to identify and exclude times of high background and to model and subtract the background events from their data.

Plucinsky, P. P.↗

Prominence Eruption Initiated by Helical Kink Instability of an Embedded Flux Rope

We study the triggering mechanism of a limb-prominence eruption and the associated coronal mass ejection (CME) near AR 12342 using Solar Dynamics Observatory and Large Angle and Spectrometric Coronagraph/Solar Heliospheric Observatory observations. The prominence is seen with an embedded flux thread (FT) at one end and bifurcates from the middle to a different footpoint location. The morphological evolution of the FT is similar to that of an unstable flux rope (FR), which we regard as a prominence-embedded FR. The FR twist exceeds the critical value. In addition, the morphology of the prominence plasma in 304 Å images marks the helical nature of the magnetic skeleton, with a total of 2.96 turns along arc length. The potential field extrapolation model indicates that the critical height of the background magnetic field gradient falls within the inner corona (105 Mm), which is consistent with the extent of coronal plasma loops. These results suggest that the helical kink instability in the embedded FR caused the slow rise of the prominence to the height of the torus instability domain. Moreover, the differential emission measure analysis unveils heating of the prominence plasma to coronal temperatures during an eruption, suggesting reconnection-related heating underneath the upward rising embedded FR. The prominence starts with a slow rise motion of 10 km s(exp. -1), which is followed by fast and slow acceleration phases that have an average acceleration of 28.9 m s(exp. -2) and 2.4 m s(exp. -2) in C2 and C3 field of view, respectively. As predicted by previous numerical simulations, the observed synchronous kinematic profiles of the CME leading edge and the core support the involved FR instability in the prominence initiation.

Vemareddy, P.↗

Ionospheric response to the sustained high geomagnetic activity during the March '89 great storm

A simulation was conducted to model the high-latitude ionospheric to the sustaied level of high geomagnetic activity for the great magnetic storm period of March 13-14, 1989. The geomagnetic and solar activity indices and the Defense Meterological Satellite Program (DMSP) F8 and F9 satellite data for particle precipitation and high-latitude convection were used as inputs to a time-dependent ionospheric model (TDIM). The results of the TDIM were compared to both DMSP plasma density data and ground-based total electron content (TEC) measurements for the great storm period as well as with earlier storm observations. The comparisons show that the overall structure of the high-latitude ionosphere was dominated by an increased convection speed within the polar cap that led to increased ion temperatures. In turn, this enhanced the NO(+) density, raised the atomic-to-molecular ion transition height to over 300 km, decreased N(sub m)F(sub 2), increased h(sub m)F(sub 2), and in places either increased n(sub e) at 800 km or slightly decreased it. The morphology of the ionosphere under these extreme conditions was considerably different than that modeled for less distributed intervals. These differences included the character of the dayside tongue of ionization that no longer extended deep into the polar cap. Instead, as a result of the ion heating and consequent reduction in N(sub m)F(sub 2), a large polar hole occupied much of the polar region. This polar hole extended beyond the auroral oval and merged with the night sector midatitude trough. The limitaions associated with the applicability of the TDIM to the geomagnetic conditions present on March 13 and 14 are discussed. The primary limitations of the TDIM derive from the limited temporal resolution of the model input parameters and the lack of suitably dynamic thermospheric specification for the great storm conditions. These limitations leads to midlatitude ionospheric storm phases that do no follow those observed.

Sojka, J. J.↗

Geometry and physical conditions in the stellar wind of AG Carinae

AG Carinae is one of the prototypes of the class of Luminous Blue Variables (LBVs). Since 1990 the star has continuously brightened in its visual continuum. We report on a multi-instrument and -wavelength observing campaign to monitor the current activity phase of AG Car. Ground-based photometry, polarimetry, spectroscopy, and space-ultraviolet spectroscopy and spectropolarimetry have been obtained. From the variability of the polarization at ultraviolet and optical wavelengths we detect significant intrinsic polarization. P(sub int) greater than or equal to 0.5% is a large value for a hot, luminous star, suggesting departure from spherical symmetry in the wind of AG Car. The intrinsic polarization is variable on a timescale of 2 months or less. The measured ultraviolet polarization (intrinsic + interstellar) dropped to 0.5% in 1992 May and returned to 1% in 1992 July. The results are interpreted in terms of a variable outflow with a density enhancement in the equatorial plane. A similar model was suggested for the related object R127 in the Large Magellanic Cloud (LMC). This geometry is reminiscent of the large-scale morphology of the gas nebula and dust 'jet' surrounding AG Car. It is therefore likely that physical conditions close to the stellar surface are responsible for the geometry of the spatially resolved circumstellar material around AG Car. Despite the drastic change of the photospheric conditions, the mass-loss rate did not increase. We find no evidence for a positive correlation between wind density and stellar radius. This makes models that explain the radius increase by opacity effects in the outflow unlikely. The mechanism responsible for the temperature and radius variations is still unknown but most likely has its origin in subphotospheric regions.

Leitherer, Claus↗

Probing for Exoplanets Hiding in Dusty Debris Disks: Disk Imaging, Characterization, and Exploration with HST-STIS Multi-roll Coronagraphy

Spatially resolved scattered-light images of circumstellar debris in exoplanetary systems constrain the physical properties and orbits of the dust particles in these systems. They also inform on co-orbiting (but unseen) planets, the systemic architectures, and forces perturbing the starlight-scattering circumstellar material. Using HST/STIS broadband optical coronagraphy, we have completed the observational phase of a program to study the spatial distribution of dust in a sample of ten circumstellar debris systems, and one "mature" protoplanetrary disk all with HST pedigree, using PSF-subtracted multi-roll coronagraphy. These observations probe stellocentric distances greater than or equal to 5 AU for the nearest systems, and simultaneously resolve disk substructures well beyond corresponding to the giant planet and Kuiper belt regions within our own Solar System. They also disclose diffuse very low-surface brightness dust at larger stellocentric distances. Herein we present new results inclusive of fainter disks such as HD92945 (F (sub disk) /F (sub star) = 5x10 (sup -5) confirming, and better revealing, the existence of a narrow inner debris ring within a larger diffuse dust disk. Other disks with ring-like sub-structures and significant asymmetries and complex morphologies include: HD181327 for which we posit a spray of ejecta from a recent massive collision in an exo-Kuiper belt; HD61005 suggested to be interacting with the local ISM; HD15115 and HD32297, discussed also in the context of putative environmental interactions. These disks, and HD15745, suggest that debris system evolution cannot be treated in isolation. For AU Mic's edge-on disk we find out-of-plane surface brightness asymmetries at greater than or equal to 5 AU that may implicate the existence of one or more planetary perturbers. Time resolved images of the MP Mus proto-planetary disk provide spatially resolved temporal variability in the disk illumination. These and other new images from our HST/STIS GO/12228 program enable direct inter-comparison of the architectures of these exoplanetary debris systems in the context of our own Solar System.

stellocentric distances↗

Fiber-matrix interphase characterization in composites using ultrasonic velocity data

A nondestructive method is introduced to determine the effective elastic of fiber-matrix interphases from measured composite moduli. The composite moduli are obtained by measuring the angular dependences of ultrasonic longitudinal and transverse phase velocities in planes along and perpendicular to the fibers. Three independent interphase effective moduli are found using micromechanical multiphase models which were applied after averaging composite transverse moduli to account for the composite orthotropy. Sensitivity analysis shows that errors in the calculated interphasial moduli are approximately ten times those in the composite moduli. Experiments are performed on Si3N4 ceramic and Ti-24Al-11Nb intermetallic matrix composites reinforced with carbon coated silicon carbide fibers. The experimental interphasial moduli for the intermetallic composites agree with literature data after accounting for the interphase microstructure. The interphasial moduli for ceramic composites are lower than those for the intermetallic composite due to imperfect mechanical contact between the interphase and the porous matrix. The use of the method to assess the interphase degradation is demonstrated for interphasial oxidation damage. The analysis helps to determine the morphology of the damaged interphase.

Chu, Y. C.↗

The Observed On-Orbit Background of the ACIS Instrument of the Chandra X-Ray Observatory

We have analyzed calibration data acquired during the Orbital Activation and Checkout (OAC) phase of the Chandra X-ray Observatory (CXO) mission in order to characterize the background of the Advanced CCD Imaging Spectrometer (ACIS) produced by charged particles and non-cosmic x-rays. The ACIS instrument contains eight Front-Illuminated (FI) CCDs and two Back-Illuminated (BI) CCDs. The FI and BI CCDs exhibit dramatically different responses to enhancements in the particle flux. The FI CCDs show relatively little increase in the overall count rate, typical increases are 1-3 counts/s; the BI CCDs show large excursions to as high as 100 counts/s. The directions of these intervals of enhanced background are highly variable ranging from 100 s to 5000 s. The spatial distribution of these background events is relatively flat across the detectors. The spectral distribution can be characterized by a simple power law. The events produce morphologies which are similar to cosmic x-ray events, so that morphology alone cannot be used as a rejection criterion. We explore the correlation of these times of high background with the data from Chandra's on-board radiation monitor, the EPHIN (Electron, Proton, Helium Instrument particle detector) instrument and archival data from the Advanced Composition Explorer (ACE) satellite. We discuss strategies for observers to identify and exclude times of high background and to model and subtract the background events from their data.

Plucinsky, Paul P.↗

An Evolutionary System of Mineralogy. Part I: Stellar Mineralogy (>13 to 4.6 Ga)

Minerals preserve records of the physical, chemical, and biological histories of their origins and subsequent alteration, and thus provide a vivid narrative of the evolution of Earth and other worlds through billions of years of cosmic history. Mineral properties, including trace and minor elements, ratios of isotopes, solid and fluid inclusions, external morphologies, and other idiosyncratic attributes, represent information that points to specific modes of formation and subsequent environmental histories—information essential to understanding the co-evolving geosphere and biosphere. This perspective suggests an opportunity to amplify the existing system of mineral classification, by which minerals are defined solely on idealized end-member chemical compositions and crystal structures. Here we present the first in a series of contributions to explore a complementary evolutionary system of mineralogy—a classification scheme that links mineral species to their paragenetic modes. The earliest stage of mineral evolution commenced with the appearance of the first crystals in the universe at >13 Ga and continues today in the expanding, cooling atmospheres of countless evolved stars, which host the high-temperature (T > 1000 K), low-pressure (P < 10-2 atm) condensation of refractory minerals and amorphous phases. Most stardust is thought to originate in three distinct processes in carbon- and/or oxygen-rich mineral-forming stars: (1) condensation in the cooling, expanding atmospheres of asymptotic giant branch stars; (2) during the catastrophic explosions of supernovae, most commonly core collapse (Type II) supernovae; and (3) classical novae explosions, the consequence of runaway fusion reactions at the surface of a binary white dwarf star. Each stellar environment imparts distinctive isotopic and trace element signatures to the micro- and nanoscale stardust grains that are recovered from meteorites and micrometeorites collected on Earth’s surface, by atmospheric sampling, and from asteroids and comets. Although our understanding of the diverse mineral-forming environments of stars is as yet incomplete, we present a preliminary catalog of 41 distinct natural kinds of stellar minerals, representing 22 official International Mineralogical Association (IMA) mineral species, as well as 2 as yet unapproved crystalline phases and 3 kinds of non-crystalline condensed phases not codified by the IMA.

Robert M. Hazen↗

Micro and Macro Segregation in Alloys Solidifying with Equiaxed Morphology

To understand macro segregation formation in Al-Cu alloys, experiments were run under terrestrial gravity (1g) and under low gravity during parabolic flights (10(exp -2) g). Alloys of two different compositions (2% and 5% Cu) were solidified at two different cooling rates. Systematic microscopic and SEM observations produced microstructural and segregation maps for all samples. These maps may be used as benchmark experiments for validation of microstructure evolution and segregation models. As expected, the macro segregation maps are very complex. When segregation was measured along the central axis of the sample, the highest macro segregation for samples solidified at 1g was obtained for the lowest cooling rate. This behavior is attributed to the longer time available for natural convection and shrinkage flow to affect solute redistribution. In samples solidified under low-g, the highest macro-segregation was obtained at the highest cooling rate. In general, low-gravity solidification resulted in less segregation. To explain the experimental findings, an analytical (Flemings-Nereo) and a numerical model were used. For the numerical model, the continuum formulation was employed to describe the macroscopic transports of mass, energy, and momentum, associated with the microscopic transport phenomena, for a two-phase system. The model proposed considers that liquid flow is driven by thermal and solutal buoyancy, and by solidification shrinkage. The Flemings-Nereo model explains well macro segregation in the initial stages of low-gravity segregation. The numerical model can describe the complex macro segregation pattern and the differences between low- and high-gravity solidification.

Stefanescu, Doru M.↗