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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31

ERAD: A Graph-Based Tool for Energy Resilience Analysis of Electric Distribution Systems

Understanding the impact of extreme events on people's ability to access energy is crucial for designing resilient energy systems. In the event of a disaster, damage to the electric system and related infrastructure (e.g., downed power lines, flooded equipment, hacked communication systems, damaged roads, etc.) can impact people's access to critical services, including not just electricity but also shelter, food, healthcare, and more. There is a key need to understand such impacts better and evaluate options to improve energy resilience. The Energy Resilience Analysis for Electric Distribution Systems (ERAD) tool is a free and open-source software package designed to help researchers and decision-makers analyze and improve energy system resilience.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Recovery and Enhanced Upgrading of Rare Earth Elements from Coal-Based Resources: Bioleaching and Precipitation

Rare earth elements (REEs) are of great importance to modern society and their reliable supply is a major concern of many industries that utilize them in metal alloys, semiconductors, electrical equipment, and defense equipment. REEs in the coal waste have been revealed to be an alternative resource for REEs production. In this study, the extraction, recovery, and upgrading of the REEs from coal waste has been realized with the bioleaching and precipitation processes. Reliable and sustainable acid and oxidant production from the oxidation of the pyrite with Acidithiobacillus ferrooxidans to generate acid for leaching were realized in this research. The acidified bioleaching solution was used to extract REEs from coal waste, with 13–14% yields for most REE elements (~72 h of leaching). However, recovery for longer duration tests was significant higher (varies from 40–60% for individual REEs). After extraction, precipitation and separation processes were designed with the aid of Visual Minteq calculations and modeling to concentrate the REEs. With the procedures designed in this research, a final REEs precipitate product containing 36.7% REEs was produced.

01 COAL, LIGNITE, AND PEAT↗

Innovating the next generation of commercial smart building software

Nearly 30% of commercial building energy use is wasted due to equipment faults and HVAC controls problems. The result is increased emissions, compromised comfort and productivity, and less reliable coordination of building power needs with a clean grid. The energy impact alone represents $17 billion in potential savings. Today’s smart building software provides a robust solution to address these operational deficiencies. Energy management and information systems (EMIS) are saving up to 9% on average, with two-year paybacks. They are being incorporated into energy management processes, commissioning services, and utility programs. As effective as they are, two barriers prevent even deeper benefits; limited personnel to fix problems once they are identified, and the expense and time to manually implement changes in control systems. In partnership with the research community, the EMIS industry is developing new capabilities to overcome these barriers. Moving beyond siloed products for either fault detection and diagnostics, or optimal control, these new capabilities empower users to not only automatically identify faults, but also to push corrective action, and control improvements to their buildings. In this paper, several areas for enhancements are documented: ‘one-time’ correction of faults such as setpoints, schedules, and economizer lockouts; short-term active testing for automated proportional integral derivative (PID) loop tuning and functional testing; and continuous supervisory control for demand flexibility and year-round efficiency. Results are presented from a pair of partner implementations out of a dozen providers integrating these enhancements into their products, including field tests from across the country, and insights into operator acceptance and integration into operations and maintenance practices.

Casillas, Armando↗

Research on oxygen solubility in aqueous amine solvents with common additives used for CO 2 chemical absorption

Oxidative degradation in amine based post-combustion carbon capture (PCCC) leads to solvent losses and decreased solvent performance. Oxygen (O 2 ) in the flue gas is dissolved into the aqueous solvent and can reactively degrade the amine component. Advanced aqueous amine solvents are designed to contain additional surfactant and anti-foam additives as well as two types of corrosion inhibitors. These additives contribute to improve the solvent performance while reducing foaming and corrosion of expensive equipment. This work examines the impact of these additives on oxygen solubility (or dissolved oxygen - DO) in various aqueous amines used in PCCC including ethanolamine (MEA), 1-amino-2-propanol (A2P), 2-amino-1-propanol (2A1P), 2-(methylamino)-ethanol (NMEA), 2-(ethylamine)-ethanol (2EAE), diethanolamine (DEA), methyl-diethanolamine (MDEA), dimethylethanolamine (DMEA), piperazine (PZ), 1,2-ethyldiamine (EDA), and 1,6 hexadiamine (HDA). Further, the impact of carbon loading on oxygen solubility with and without these additives was also examined. The surfactant and anti-foam additives had minimal impact on DO for all the solvents investigated. The two anticorrosion additives had opposite effects in the measured DO, 2- mercaptobenzothiazole (MBT) decreased the DO concentration, and sodium metavanadate showed an increase. These results indicate that several of these common additives can be expected to minimally affect DO related oxidative degradation in these advance amine solvents.

60 APPLIED LIFE SCIENCES↗

Brief Update on Advancements by Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction

In 2011, Pacific Northwest National Laboratory (PNNL), working as a partner in the National Advanced Biofuels Consortium, issued a report assessing the viable industrial feed system and pump options for a 2000 dry metric tons per day production-scale hydrothermal liquefaction (HTL) plant (Berglin et al. 2012). This report was issued as PNNL-21981, Review and Assessment of Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction, and will be referred to as “Pump Survey” for reference. It had the following scope: • Identify relevant applications and industries operating at comparable scales • Interact with commercial vendors and pursue integration between vendors • Take advantage of commercial off-the-shelf (COTS) technology • Supply and support vendor needs for biomass feedstock rheology characterization • Provide vendors with process requirements to support selection of conceptual design for feedstock handing and pump system • Obtain cost data to the extent possible from equipment vendors to support the technical economic analysis (TEA) • Identify issues associated scale-up. The current document represents an update to the prior report in order to: 1. Identify advancements in vendor-reported technologies 2. List reports of new experience or trials with biomass pumping applications 3. Determine if technology/application gaps identified in the prior report have been filled 4. Capture ideas on future research.

09 BIOMASS FUELS↗

Using Residential and Office Building Archetypes for Energy Efficiency Building Solutions in an Urban Scale: A China Case Study

Building energy consumption accounts for 36% of the overall energy end use worldwide and is growing rapidly as developing countries continue to urbanize. Understanding the energy use at urban scale will lay the foundation for identification of energy efficiency opportunities to be deployed at speed. China has almost half of global new constructions and plays an important role in building suitability. However, an open source national building energy consumption database is not available in China. To provide data support for building energy consumptions, this paper used a simulation method to develop an urban building energy consumption database for a pilot city in Wuhan, China. First, residential, small, and large office building archetype energy models were created in EnergyPlus to represent typical building energy consumption in Wuhan. The baseline reference model simulation results were further validated using survey data from the literature. Second, stochastic simulations were conducted to consider different design parameters and occupants’ energy usage intensity scenarios, such as thermal properties of the building envelope, lighting power density, equipment power density, HVAC (heating, ventilation and air conditioning) schedule, etc. A building energy consumption database was generated for typical building archetypes. Third, data-driven regression analysis was conducted to support quick building energy consumption prediction using key high- level building information inputs. Finally, a web-based urban energy platform and an interface were developed to support further third-party application development. The research is expected to provide fast energy efficiency building design solutions for urban planning, new constructions as well as building retrofits.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Weather effects on the lifecycle of U.S. Department of Defense equipment replacement (WELDER)

Extreme weather has a direct and significant impact on buildings and infrastructure, resulting in billions of dollars of damage each year. This problem continues to grow as climate patterns change and buildings are exposed to new and different hazards than what they were designed to withstand. In order to better plan for the long-range sustainment, restoration, modernization, and eventual recapitalization of these buildings, organizations with large building portfolios, such as the U.S. Department of Defense (DoD), must have an awareness of the risks that these extreme weather events present. This research aimed to develop an approach to estimate condition loss and reduction in service life for the components of a building due to extreme weather hazards, to understand the risks that may be present in certain buildings and building systems. To achieve this objective, a damage association matrix was developed that categorizes climate hazards, the damage modes that they produce, and the individual component types impacted. This damage matrix formally links state-of-the-art climate model output, which provides projections of the probability of various climate hazards with a damage effects model that quantifies the consequence on component-level condition and service life. This method is applied to an actual portfolio of buildings in a particular geographic location and with a pre-defined component inventory that comprises the building. This approach can be aggregated to the system-, facility-, and site-level thus helping support billions of dollars in recapitalization decisions related to restoration/modernization of facilities.

54 ENVIRONMENTAL SCIENCES↗

Building Large-Scale U.S. Synthetic Electric Distribution System Models

Rapid increases in distributed energy resources on distribution systems are prompting research efforts to improve and evaluate electric power distribution algorithms; however, there is a shortage of realistic, large-scale, U.S.-style test systems for the evaluation of such advanced algorithms. Some available tools to build large-scale test systems are of European style, and their application to studies focused on the United States might not be desirable given very different characteristics between the European and U.S. distribution designs. Motivated by this need, this paper develops detailed algorithms to build large-scale U.S. distribution systems and incorporates them in a new Reference Network Model, RNM-US. The approach starts with information from street maps and a catalog with electric equipment that includes power lines, transformers, voltage regulators, capacitors, and switching devices. The paper presents the algorithms through an illustrative case study of the different steps that comprise the process of building a synthetic distribution grid. Finally, the paper presents a medium- and a large-scale data set covering 10 million electrical nodes and 120,000 km of power lines, demonstrating the applicability of the proposed method to build very large-scale synthetic distribution systems.

27 ARPA - Advanced Research Projects Agency-Energy↗

A study on the creep behavior of alloy 709 using in-situ scanning electron microscopy

In this research, an experimental evaluation of creep properties of Alloy 709 in the temperature range of 750–850 °C was undertaken. Alloy 709 is a novel austenitic stainless steel with 20% Cr and 25% Ni by wt% that was developed for application in structural components of nuclear power plants. Creep rupture tests were conducted in an in-situ heating-loading and Scanning Electron Microscope (SEM) unit equipped with Electron Backscatter Diffraction (EBSD) detector and Energy Dispersive Spectroscopy (EDS). “Real-time” creep damage mechanisms of Alloy 709 at various stresses and temperatures using a flat, un-notched sample with continuously reducing cross-section is studied so that the failure and maximum creep damage occurred at the center of the sample where the in-situ SEM imaging could be focused. Accelerated creep tests at temperatures and stresses above service conditions were performed by employing multiple blocks of constant loads where the loads were increased once the sample attained constant creep rate, indicating a secondary creep regime. This technique ensures multiple data points can be obtained from the same test, saves the time required for an otherwise long-term creep test and usage of SEM. Further, Coincident Site Lattice (CSL) boundary maps were collected as control maps before testing, and the grain boundaries were observed during the creep test to understand the effect of grain boundary character on the creep damage mechanism. Void growth, grain boundary separation, and sliding were found to be the main creep mechanisms whose rate is dependent on stress and temperature. Failure mechanisms studied on the fracture surface using SEM fractography were correlated to the sample surface observations to create complementary information to better understand the underline creep mechanism of Alloy 709.

36 MATERIALS SCIENCE↗

Additively Manufactured Tamper Evident Container (TEC)

The protection of sensitive data, proprietary information, and physical assets from adversarial disclosure is a high priority in today’s environment of government and industrial espionage. Furthermore, knowledge of the security history and monitoring for potential acquisition or disclosure of the protected assets from oppositional sources is equally important. In 2016, as part of an LANL Institute for Materials Science (IMS) rapid response research initiative, the investigators of this technology demonstration project developed the concept of an additively manufactured tamper resistant container that possessed tamper evident features. Tamper evident seals and detection technologies have a long history in protecting consumers from product tampering, recording the installation and activation of mechanical safety panels and fasteners on dangerous electro-mechanical systems, and serving as a warranty void indicator on expensive electronic equipment. Examples of such tamper evident seals range from “no-tech” versions, e.g., the paper seals under medicine caps, to “high-tech” seals that are radio frequency-active and include encryption capabilities used by the International Atomic Energy Agency (IAEA) to monitor stored nuclear materials in support of safeguards missions. The tamper evident container (TEC) technology would have many uses.

36 MATERIALS SCIENCE↗

LA100 Equity Strategies. Chapter 12: Distribution Grid Upgrades for Equitable Resilience and Solar, Storage, and Electric Vehicle Access

The LA100 Equity Strategies project integrates community guidance with robust research, modeling, and analysis to identify strategy options that can increase equitable outcomes in Los Angeles' clean energy transition. As Los Angeles transitions toward clean energy, existing distribution grid infrastructure will need to be updated and expanded to support reliable service during routine operations, enable interconnection with distributed energy resources and electrified loads, and provide access to energy-related services during disasters. This chapter focuses on equity in distribution grid upgrades, reliability, and resilience in Los Angeles. Specifically, NREL performed grid upgrade and resilience analyses using a detailed model of the distribution grid and income-differentiated household load profiles, electric vehicle (EV) adoption patterns, distributed solar adoption, and grid reliability to explore two key questions to inform how the City of Los Angeles can ensure a resilient and reliable distribution grid for all communities during the clean energy transition: Where can distribution system upgrades can be prioritized to enable equitable access to, and adoption of, clean energy technologies and how can Los Angeles provide equitable, resilient access to electricity-related services (e.g., health care, food) during disaster events like earthquakes and flooding? The electric distribution system is the "last mile" of the grid, linking the multistate bulk power system with customers; new loads, including EVs; and distributed energy resources, such as customer and community solar and storage. This analysis focuses on the 4.8-kilovolt (kV) system, including service transformers that represent the utility-side of the grid connection for most residential customers. Chapter 17 looks at the customer-side of the grid connection with a focus on electric panel upgrade needs. The transition toward clean energy can put additional stress on the distribution system from distributed energy resources and electrification - especially EVs and increased use of electricity for heating, cooling, cooking, and hot water. This stress, measured here as the number of equipment overloads and voltage violations, correlates strongly to grid reliability and therefore is used as a proxy for understanding additional upgrades needed and to help ensure equitable access to electrification and distributed energy resources. NREL also conducted community resilience analysis to examine customer-level access to both electricity and a larger range of services, such as hospitals and grocery stores during a disaster. This analysis explicitly considers equity to understand differences in current resilience and resilience strategies to effectively improve critical services access for all Angelenos. Research was guided by input from the community engagement process, and associated equity strategies are presented in alignment with that guidance.

14 SOLAR ENERGY↗

Hydrogen Compatible Materials Workshop

This report serves as the proceedings of the Hydrogen Compatible Materials Workshop held virtually by Sandia National Laboratories on December 2-3, 2020. The purpose of the workshop was to assemble subject matter experts at Sandia and its national laboratory partners within the U.S. Department of Energy's (DOE) Hydrogen Materials Compatibility (H-Mat) Consortium with public and private stakeholders in the research, development and deployment of hydrogen technologies to discuss the topic of hydrogen compatible materials. This workshop was designed to build on past events and current research and development (R&D) efforts to develop a forward-looking vision that identifies gaps and challenges for the next decade. In particular, the workshop organizers sought to expand their understanding of hydrogen compatible materials needs for power, manufacturing and other industrial uses to enable deeper impact and widespread use of hydrogen while continuing to address open questions in hydrogen-powered transportation of concern to Original Equipment Manufacturers, hydrogen producers, materials & component suppliers and other private entities. The workshop was primarily organized as a series of panel-led discussions on the topics of hydrogen-enabled transportation, heating and power, and industrial uses. Each panel consisted of 2-3 subject matter experts who relayed their perspectives on a set of framing questions developed to facilitate discussion by the broader group of workshop participants. By the workshop's conclusion, the participants identified and prioritized a list of technical challenges for each panel topic where further R&D is warranted.

08 HYDROGEN↗

GRACE Final Technical Report

The GRACE project (Grid that is Risk-Aware for Clean Electricity) was a five-year research initiative funded by the U.S. Department of Energy's Advanced Research Projects Agency- Energy (ARPA-E) under the PERFORM program. Led by Duke University's Nicholas School of the Environment, with contributions from The Ohio State University, North Carolina State University, Dartmouth College, and Pacific Northwest National Laboratory, the project addressed a fundamental challenge in grid management: conventional software plans for a single most-likely outcome and relies on reserves as a buffer, leaving utilities poorly equipped for the growing variability introduced by renewable energy. GRACE demonstrated a better approach: explicitly representing thousands of plausible future scenarios and choosing operating schedules that perform well across all of them.

14 SOLAR ENERGY↗

CPAP Ventilators Needed for Rapid Response to COVID-19 by Modification of CPAP Equipment

Early on in the COVID-19 pandemic, potential ventilator shortages were a critical issue identified by national health care providers. Capacity modeling at the time suggested patient demand may exceed ventilator supply. Thus, the challenge became finding an urgent interim solution to meet health care needs. Our initial hypothesis was that CPAP technology could be modified to provide similar functionality to a ventilator, relieving demand and allowing physicians to decide which patients need high end machines, ultimately saving lives. In conjunction with medical experts and pulmonologists, we were able to identify three key thrusts associated with this research problem: (1) modification of CPAP technology to allow for 02 input that would be capable of providing ventilation; (2) development of an alarming function that would provide real-time audible alarms to alert medical personnel to critical conditions, which would be used inline with CPAP technology; and (3) a method of sterilizing expiratory air from such a system in order to protect medical personnel from biohazard, since CPAPs vent to the atmosphere. We were unable to realize results for thrust 1 (CPAP modification for 02); we identified potential safety issues associated with utilizing medical grade oxygen with a common CPAP device. In order to characterize and mitigate these issues, we would need to partner closely with a device manufacturer; such a partnership could not be achieved in the timeframe needed for this rapid response work. However, we determined that some medical grade BiPAP devices do not need this modification and that the significant progress on thrusts 2 and 3 would be sufficient to buy down risk of a massive ventilator shortage. Our team built a prototype alarm system that can be utilized with any assistive respiratory device to alert on all key conditions identified by medical personnel (high pressure, low pressure, apnea, loss of power, low battery). Finally, our team made significant progress in the rapid prototyping and demonstration of an inline UV air purifier device. The device is cost efficient and can be manufactured at scale with both commercially available and additively manufactured parts. Initial tests with SARS-CoV-2 analog bacteriophage MS2 show 99% efficacy at reducing bioburden. Following a successful demonstration of the prototype device with medical personnel, we were able to obtain follow-on (non-LDRD) funding to provide additional device characterization, validation, and production in order to respond to an immediate regional need.

42 ENGINEERING↗

Lessons Learned—Fluoride Exposure and Response

Laboratory research can expose workers to a wide variety of chemical hazards. Researchers must not only take personal responsibility for their safety but also inevitably rely on coworkers to also work safely. The foundations for protocols, requirements, and behaviors come from our history and lessons learned from others. For that reason, here, a recent incident is examined in which a researcher suffered hydrofluoric acid (HF) burns while working with an inorganic digestion mixture of aqueous HF (8%) and nitric acid (HNO 3 , 58%). HF education is critical for workers because delays in treatment, improper treatment, and delay of symptoms are all factors in unfavorable outcomes in case reports. Furthermore, while the potential severity of the incident was elevated due to bypassed engineered controls and lack of proper personal protective equipment, only minor injuries were sustained. We discuss the results of a causal analysis of the incident that revealed areas of improvement in protocols, personal protective equipment, and emergency response that could help prevent similar accidents from occurring. We also present simple improvements that anyone can implement to reduce the potential consequences of an accident, based upon our lessons learned.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Optimizing Process Conditions during Catalytic Fast Pyrolysis of Pine with Pt/TiO 2 —Improving the Viability of a Multiple-Fixed-Bed Configuration

Catalytic fast pyrolysis (CFP) has been identified as a promising pathway for the production of renewable fuels and co-products. However, continued technology development is needed to increase process efficiency and reduce process costs. This report builds upon previous research in which a bifunctional metal–acid Pt/TiO 2 catalyst was utilized in a fixed-bed reactor operated with co-fed H 2 to improve product yield and reduce coke generation compared to conventional CFP methods. Here, we report further process optimization, in which we achieved similar CFP oil carbon efficiency (>35%) and CFP oil oxygen content (<20 wt %) to our previous report while reducing catalyst and equipment costs by increasing time-on-stream between regenerations by 40–95% and decreasing required regeneration time by more than a factor of 2. These process improvements were achieved by conducting parameter sweeps to determine optimum conditions for CFP and regeneration with key variables including pyrolysis temperature, catalytic upgrading temperature, hydrogen partial pressure, and regeneration oxygen concentration. Coupled with comprehensive oil analyses, these data provide foundational insight into the deoxygenation and coking chemistries for CFP under realistic process conditions while also advancing the technology through applied engineering.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Next Generation Integrated PV Products Cost and Workflow Analysis (Final Report)

Residential photovoltaic (PV) costs have fallen consistently for over a decade (Ardani et al. 2018). DOE has subsequently developed a new residential PV cost target for 2030 of $0.05/kilowatt hour (SETO 2023). Ardani et al. (2018) conclude that integrated roofing and PV (RIPV) products may be key to achieving the residential target for both new construction and retrofit residential PV. In RIPV, the PV product is incorporated into or replaces the roofing material. RIPV systems can use conventional crystalline or thin-film technologies, may be aesthetically attractive alternatives to traditional racked and mounted PV systems, and may increase building property values (Cook et al. 2023). These products also have the potential to provide customer acquisition, labor, and equipment cost savings over traditional, racked and mounted residential rooftop PV and several companies have recently introduced integrated roofing and PV (RIPV) products (Cook et al. 2023). In 2022, Tesla was the market leader, representing 94% of RIPV capacity installed in 2022 through its Solar Roof offering, while GAF Energy and its Timberline Solar product was second capturing 3% (Feldman et al. 2023). In this project, NREL analyzed three research questions: (1) How do current RIPV products compare to racked and mounted PV in terms of costs, install times and processes? (2) How are RIPV products installed and are there opportunities for cost savings? (3) What are the key barriers to expanding market opportunities for integrating solar and roofing products? In this project, we explored residential RIPV cost reduction opportunities by analyzing installation processes. Our study documented residential RIPV installations at two reroofing sites (20.52 kilowatts) and the equivalent of nine new construction sites (71.75 kW) in California through a methodology known as time and motion study. We also conducted 15 interviews with subject-matter experts to identify barriers and solutions to maximize these products' market penetration.

14 SOLAR ENERGY↗

Model Reduction for Steady Hypersonic Aerodynamics via Conservative Manifold Least-Squares Petrov–Galerkin Projection

High-speed aerospace engineering applications rely heavily on computational fluid dynamics (CFD) models for design and analysis. This reliance on CFD models necessitates performing accurate and reliable uncertainty quantification (UQ) of the CFD models, which can be very expensive for hypersonic flows. Additionally, UQ approaches are many-query problems requiring many runs with a wide range of input parameters. One way to enable computationally expensive models to be used in such many-query problems is to employ projection-based reduced-order models (ROMs) in lieu of the (high-fidelity) full-order model (FOM). In particular, the least-squares Petrov–Galerkin (LSPG) ROM (equipped with hyper-reduction) has demonstrated the ability to significantly reduce simulation costs while retaining high levels of accuracy on a range of problems, including subsonic CFD applications. This allows LSPG ROM simulations to replace the FOM simulations in UQ studies, making UQ tractable even for large-scale CFD models. This work presents the first application of LSPG to a hypersonic CFD application, the Hypersonic International Flight Research Experimentation 1 (HIFiRE-1) in a three-dimensional, turbulent Mach 7.1 flow. This paper shows the ability of the ROM to significantly reduce computational costs while maintaining high levels of accuracy in computed quantities of interest.

42 ENGINEERING↗