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At least 559 records · Page 31

A Development of Critical Components for the Modular Staged Pressurized Oxy-Combustion Power Plant

DOE's Coal FIRST (Flexible, Innovative, Resilient, Small, Transformative) Initiative was implemented to encourage the development of the coal plant of the future, which will be capable of flexible operation to meet the needs of the grid; using innovative and cutting-edge components that improve efficiency and reduce emissions; providing resilient power to Americans; being small compared to today's conventional utility-scale coal power plants; and transforming how coal power plant technologies are designed and manufactured. The modular Staged, Pressurized Oxy-Combustion (SPOC) process envisioned by and under development at Washington University in St. Louis (WUSTL) has the potential to achieve these goals. The process offers: 1) a modular plant design for improved operational flexibility; 2) fuel-staging combined with pressurized oxy-combustion, which leads to smaller plant size, higher plant efficiency, and lower cost for pollutant and greenhouse gases removal compared with traditional carbon-capture equipped coal power plants; and 3) small modular boilers and pollutant removal units that can be fabricated in shop and assembled on site, further reducing plant capital costs. Under DOE's support (DE-FE0031925), WUSTL is advancing the development of the critical components for the SPOC power plant, including the integrated combustion system and the direct contact cooler (DCC) from TRL 4 to TRL-5, which would allow them to be subsequently incorporated into a pilot plant. These units are the only two components that are not commercially available for a SPOC plant, and hence, their development is a key step toward the commercialization of SPOC. This work presents the objectives, task descriptions, and current progress of the project. So far, the fabrication of a new combustor design and the convective heat transfer boiler has been completed, and the integration of the combustor, boiler, and DCC is underway. Recent results obtained with the newly designed combustor show a stable coal/methane flame while dry-feeding PRB coal under oxy-combustion conditions.

Magalhaes, Duarte↗

Small Business Voucher Program: Scaling-Up of Bio-Based C5 Building Block Production: Cooperative Research and Development Final Report, CRADA Number CRD-16-00611

Visolis, Inc. is an early stage industrial biotechnology company developing next generation of processes for producing building blocks for bulk polymers and fuels. The company is developing low-cost routes to the chemicals of the future in support of DOE, EERE and BETO goals to grow the U.S. bioeconomy. NREL has capabilities in scale-up of fermentation processes from bench top through pilot scales and also has expertise and technologies related to production of lignocellulosic sugars from cellulosic feedstocks. NREL's Integrated Biorefinery Research Facility (IBRF) houses multiple fermentation vessels/systems ranging in size from 0.5 to 9,000 L along with ancillary capabilities in compositional analysis, separations, and purification. NREL's role will be to scale-up the Visolis process to produce an intermediate product, mevalonic acid, from both dextrose and biomass derived sugars. The goals of the project are to: 1) transfer and reproduce one of Visolis's proprietary fermentation processes at bench top and pilot scale at NREL's IBRF using dextrose as the feedstock, 2) carry out bench-scale fermentations using Visolis's organism and cellulosic sugars, and 3) produce mevalonic acid from the bench top and pilot scale runs for catalyst lifetime testing and conversion to isoprene.

09 BIOMASS FUELS↗

Small-Scale Recycling of Irradiated Uranium and Transuranic Elements (Np, Pu) Using 3D-Printed Centrifugal Contactors

Niowave’s technology employs super-conducting linear accelerators to induce fission on low-enriched uranium targets followed by subsequent radiochemical processing to purify 99 Mo as well as a number of other fission products. Argonne’s Radiochemistry group (CFCT), in partnership with Niowave and UNLV, will be managing the TCF project to develop a closed-cycle loop for Niowave’s uranium targets. The roles of the DOE national laboratory partner will be to 1) develop a basic chemical understanding of the separations and purifications required to meet industry standards, 2) initiate the additive manufacturing (AM) of the centrifugal contactors, 3) develop a process flowsheet using Argonne computer codes.

43 PARTICLE ACCELERATORS↗

Near ground level sensing for spatial analysis of vegetation

Measured changes in vegetation indicate the dynamics of ecological processes and can identify the impacts from disturbances. Traditional methods of vegetation analysis tend to be slow because they are labor intensive; as a result, these methods are often confined to small local area measurements. Scientists need new algorithms and instruments that will allow them to efficiently study environmental dynamics across a range of different spatial scales. A new methodology that addresses this problem is presented. This methodology includes the acquisition, processing, and presentation of near ground level image data and its corresponding spatial characteristics. The systematic approach taken encompasses a feature extraction process, a supervised and unsupervised classification process, and a region labeling process yielding spatial information.

Sauer, Tom↗

Centrifugal Sieve for Gravity-Level-Independent Size Segregation of Granular Materials

Conventional size segregation or screening in batch mode, using stacked vibrated screens, is often a time-consuming process. Utilization of centrifugal force instead of gravity as the primary body force can significantly shorten the time to segregate feedstock into a set of different-sized fractions. Likewise, under reduced gravity or microgravity, a centrifugal sieve system would function as well as it does terrestrially. When vibratory and mechanical blade sieving screens designed for terrestrial conditions were tested under lunar gravity conditions, they did not function well. The centrifugal sieving design of this technology overcomes the issues that prevented sieves designed for terrestrial conditions from functioning under reduced gravity. These sieves feature a rotating outer (cylindrical or conical) screen wall, rotating fast enough for the centrifugal forces near the wall to hold granular material against the rotating screen. Conventional centrifugal sieves have a stationary screen and rapidly rotating blades that shear the granular solid near the stationary screen, and effect the sieving process assisted by the airflow inside the unit. The centrifugal sieves of this new design may (or may not) have an inner blade or blades, moving relative to the rotating wall screen. Some continuous flow embodiments would have no inner auger or blades, but achieve axial motion through vibration. In all cases, the shearing action is gentler than conventional centrifugal sieves, which have very high velocity differences between the stationary outer screen and the rapidly rotating blades. The new design does not depend on airflow in the sieving unit, so it will function just as well in vacuum as in air. One advantage of the innovation for batch sieving is that a batch-mode centrifugal sieve may accomplish the same sieving operation in much less time than a conventional stacked set of vibrated screens (which utilize gravity as the primary driving force for size separation). In continuous mode, the centrifugal sieves can provide steady streams of fine and coarse material separated from a mixed feedstock flow stream. The centrifugal sieves can be scaled to any desired size and/or mass flow rate. Thus, they could be made in sizes suitable for small robotic exploratory missions, or for semi-permanent processing of regolith for extraction of volatiles of minerals. An advantage of the continuous-mode system is that it can be made with absolutely no gravity flow components for feeding material into, or for extracting the separated size streams from, the centrifugal sieve. Thus, the system is capable of functioning in a true microgravity environment. Another advantage of the continuous-mode system is that some embodiments of the innovation have no internal blades or vanes, and thus, can be designed to handle a very wide range of feedstock sizes, including occasional very large oversized pieces, without jamming or seizing up.

Walton, Otis R.↗

Modeling and Characterization of Damage Processes in Metallic Materials

This paper describes a broad effort that is aimed at understanding the fundamental mechanisms of crack growth and using that understanding as a basis for designing materials and enabling predictions of fracture in materials and structures that have small characteristic dimensions. This area of research, herein referred to as Damage Science, emphasizes the length scale regimes of the nanoscale and the microscale for which analysis and characterization tools are being developed to predict the formation, propagation, and interaction of fundamental damage mechanisms. Examination of nanoscale processes requires atomistic and discrete dislocation plasticity simulations, while microscale processes can be examined using strain gradient plasticity, crystal plasticity and microstructure modeling methods. Concurrent and sequential multiscale modeling methods are being developed to analytically bridge between these length scales. Experimental methods for characterization and quantification of near-crack tip damage are also being developed. This paper focuses on several new methodologies in these areas and their application to understanding damage processes in polycrystalline metals. On-going and potential applications are also discussed.

Glaessgen, E. H.↗

Exploiting nonionic surfactants to enhance fatty alcohol production in Rhodosporidium toruloides

Fatty alcohols (FOHs) are important feedstocks in the chemical industry to produce detergents, cosmetics, and lubricants. Microbial production of FOHs has become an attractive alternative to production in plants and animals due to growing energy demands and environmental concerns. However, inhibition of cell growth caused by intracellular FOH accumulation is one major issue that limits FOH titers in microbial hosts. In addition, identification of FOH-specific exporters remains a challenge and previous studies towards this end are limited. To alleviate the toxicity issue, we exploited nonionic surfactants to promote the export of FOHs in Rhodosporidium toruloides, an oleaginous yeast that is considered an attractive next-generation host for the production of fatty acid-derived chemicals. Our results showed FOH export efficiency was dramatically improved and the growth inhibition was alleviated in the presence of small amounts of tergitol and other surfactants. As a result, FOH titers increase by 4.3-fold at bench scale to 352.6 mg/L. With further process optimization in a 2-L bioreactor, the titer was further increased to 1.6 g/L. The method we show here can potentially be applied to other microbial hosts and may facilitate the commercialization of microbial FOH production.

59 BASIC BIOLOGICAL SCIENCES↗

Athermal glass work at the nanoscale: Engineered electron-beam-induced viscoplasticity for mechanical shaping of brittle amorphous silica

Amorphous silica deforms viscoplastically at elevated temperatures, which is common for brittle glasses. The key mechanism of viscoplastic deformation involves interatomic bond switching, which is thermally activated. Here, for this study, we precisely control the mechanical shaping of brittle amorphous silica at the nanoscale via engineered electron–matter interactions without heating. We observe a ductile plastic deformation of amorphous silica under a focused scanning electron beam with low acceleration voltages (few to tens of kilovolts) during in-situ compression studies, with unique dependence on the acceleration voltage and beam current. By simulating the electron–matter interaction, we show that the deformation of amorphous silica depends strongly on the volume where inelastic scattering occurs. The electron–matter interaction via e-beam irradiation alters the Si–O interatomic bonds, enabling the high-temperature deformation behavior of amorphous silica to occur athermally. Finally, by systematically controlling the electron–matter interaction volume, it is possible to mechanically shape the brittle amorphous silica on a small scale at room temperature to a level comparable to glass shaping at high temperatures. The findings can be extended to develop new fabrication processes for nano- and microscale brittle glasses.

36 MATERIALS SCIENCE↗

Chemical Analysis of the Ultrafaint Dwarf Galaxy Grus II. Signature of High-mass Stellar Nucleosynthesis

We present a detailed abundance analysis of the three brightest member stars at the top of the giant branch of the ultrafaint dwarf (UFD) galaxy Grus II. All stars exhibit a higher than expected [Mg/Ca] ratio compared to metal-poor stars in other UFD galaxies and in the Milky Way (MW) halo. Nucleosynthesis in high-mass ( 20 M ⊙) core-collapse supernovae has been shown to create this signature. The abundances of this small sample (three) stars suggests the chemical enrichment of Grus II could have occurred through substantial high-mass stellar evolution, and is consistent with the framework of a top-heavy initial mass function. However, with only three stars it cannot be ruled out that the abundance pattern is the result of a stochastic chemical enrichment at early times in the galaxy. The most metal-rich of the three stars also possesses a small enhancement in rapid neutron-capture (r-process) elements. The abundance pattern of the r-process elements in this star matches the scaled r-process pattern of the solar system and r-process enhanced stars in other dwarf galaxies and in the MW halo, hinting at a common origin for these elements across a range of environments. All current proposed astrophysical sites of r-process element production are associated with high-mass stars, thus the possible top-heavy initial mass function of Grus II would increase the likelihood of any of these events occurring. The time delay between the α and r-process element enrichment of the galaxy favors a neutron star merger as the origin of the r-process elements in Grus II.

79 ASTRONOMY AND ASTROPHYSICS↗

A review of some aspects of inferring the ozone profile by inversion of ultraviolet radiance measurements

The mathematical inversion of light-scattering observations to obtain the atmospheric ozone profile is discussed in terms of the filtering properties of the physical and mathematical processes for different spatial scales. Within this context, it is shown that the physical process of scattering acts as a low pass filter; which transfers large-scale profile information efficiently to radiance observations but very strongly attenuates small- or fine-scale profile information. To avoid domination of the mathematical inversion by the random error of radiance measurements, an equivalent spatial-scale filtering in the inversion procedure is essential. The available evidence suggests that mathematical inversion to obtain the low level ozone profile below 25 to 30 km is either inferior to or no better than the statistical estimation of the profile using total ozone as predictor. However, inversion profiles for high level ozone above 25 to 30 km appear to have moderately good accuracy.

Mateer, C. L.↗

Stochastic simulation of vertically nonhomogeneous gusts

The small-scale horizontal gust structure of detailed wind profiles along the vertical in the first 20 km of the atmosphere is a vertically nonhomogeneous process. A linear stochastic model was developed based on the process covariance function. This model was formulated through the use of a scaling hypothesis which transforms the nonhomogeneous gust process into a nondimensional gust process which is homogeneous in a nondimensional gust height coordinate. The velocity scaling parameter for the gust process is the gust standard deviation, and the length scale used to nondimensionalize the altitude is the vertical space lag associated with the first zero of the gust covariance function. State space theory was used to derive a digital filter from the model, which can be readily used to simulate gusts for space vehicle design applications.

Fichtl, G. H.↗

Stochastic simulation of vertically nonhomogeneous gusts

The small-scale horizontal gust structure of detailed wind profiles along the vertical in the first 20 km of the atmosphere is a vertically nonhomogeneous process. A linear stochastic model is developed for the process based on the process covariance function. This model is formulated through the use of a scaling hypothesis that transforms the nonhomogeneous gust process into a nondimensional gust process which is homogeneous in a nondimensional height coordinate. The velocity scaling parameter for the gust process is the gust standard deviation, and the length scale used to nondimensionalize the altitude is the vertical space lag associated with the first zero of the gust covariance function. State space theory is used to derive a digital filter from the model, which can be readily used to simulate gusts for space vehicle design applications.

Fichtl, G. H.↗

Separation processes during binary monotectic alloy production

Observation of microgravity solidification processes indicates that outside of sedimentation, at least two other important effects can separate the phases: critical-point wetting and spreading; and thermal migration of second-phase droplets due to interfacial tension gradients. It is difficult to study these surface tension effects while in a unit gravity field. In order to investigate the processes occurring over a temperature range, i.e., between a consolute point and the monotectic temperature, it is necessary to use a low-gravity environment. The MSFC drop tube (and tower), the ballistic trajectory KC-135 airplane, and the Space Shuttle are ideal facilities to aid formation and testing of hypotheses. Much of the early work in this area focuses on transparent materials so that process dynamics may be studied by optical techniques such as photography for viewing macro-processes; holography for studying diffusional growth; spinodal decomposition and coalescence; ellipsometry for surface wetting and spreading effects; and interferometry and spectroscopy for small-scale spatial resolution of concentration profiles.

Frazier, D. O.↗

A passive infrared ice detection technique for helicopter applications

A technique has been developed, and successfully tested, to detect icing remotely on helicopter rotor blades. Using passive infrared (IR) thermometry it is possible to detect the warming caused by latent heat released as supercooled water freezes. During icing, the ice accretion region on the leading edge of the blade is found to be warmer than the uniced trailing edge resulting in a chordwise temperature profile characteristic of icing. Preliminary tests, using an IR Thermal video system, were conducted on a static model in the NASA Icing Research Tunnel (IRT) for a variety of wet (glaze) and dry (rime) ice conditions. A prototype detector system was built consisting of a single point IR pyrometer, and experiments were run on a small scale rotor model. Using this prototype detector, the characteristic chordwise temperature profiles were again observed for a range of icing conditions. Several signal processing methods were investigated, to allow automatic recognition of the icing signature. Additionally, several implementation issues were considered. Based on both the static and subscale rotor tests, where ice was successfully detected, the passive IR technique appears to be promising for rotor ice detection.

Dershowitz, Adam L.↗

Transition from Pool to Flow Boiling: The Effect of Reduced Gravity

Applications of boiling heat transfer in space can be found in the areas of thermal management, fluid handling and control, power systems, on-orbit storage and supply systems for cryogenic propellants and life support fluids, and for cooling of electronic packages for power systems associated with various instrumentation and control systems. Recent interest in exploration of Mars and other planets, and the concepts of in-situ resource utiliLation on Mars highlights the need to understand the effect of gravity on boiling heat transfer at gravity levels varying from 1>= g/g(sub e) >=10(exp -6). The objective of the proposed work was to develop a mechanistic understanding of nucleate boiling and critical heat flux under low and micro-gravity conditions when the velocity of the imposed flow is small. For pool boiling, the effect of reduced gravity is to stretch both the length scale as well as the time scale for the boiling process. At high flow velocities, the inertia of the liquid determines the time and the length scales and as such the gravitational acceleration plays little role. However, at low velocities and at low gravity levels both liquid inertia and buoyancy are of equal importance. At present, we have little understanding of the interacting roles of gravity and liquid inertia on the nucleate boiling process. Little data that has been reported in the literature does not have much practical value in that it can not serve as a basis for design of heat exchange components to be used in space. Both experimental and complete numerical simulations of the low velocity, low-gravity nucleate boiling process were carried out. A building block type of approach was used in that first the growth and detachment process of a single bubble and flow and heat transfer associated with the sliding motion of the bubble over the heater surface after detachment was studied. Liquid subcooling and flow velocity were varied parametrically. The experiments were conducted at 1 g(sub e), while varying the orientation of surface with respect to the gravity vector. In the laboratory experiments, holographic interferometry was used to obtain data on velocity and temperature fields associated with a bubble prior to, and after detachment and during sliding motion. A test rig for conducting experiments in the KC-135 was developed, but experiments could not be conducted due to the unavailability of the aircraft prior to completion of the project. Numerical simulations modeling the micro and macro regions of the bubble were carried out in three dimensions. The results of the experiments were used to validate analytical/numerical models.

Dhir, Vijay K.↗

Control and Identification of Turbulent Boundary Layer Separation

Effective delay of turbulent boundary layer separation could be achieved via closed-loop control. Constructing such a system requires that sensor data be processed, real-time, and fed into the controller to determine the output. Current methods for detection of turbulent boundary layer separation are lacking the capability of localized, fast and reliable identification of the boundary layer state. A method is proposed for short-time FFT processing of time series, measured by hot-film sensors, with the purpose of identifying the alternation of the balance between small and large scales as the boundary layer separates, favoring the large scales. The method has been validated by comparison to other criteria of separation detection and over a range of baseline and controlled flow conditions on a simplified high-lift system, incorporating active flow control.

Seifert, Avi↗

Laboratory Studies of Fischer-Tropsch-Type Reactions and Their Implications for Organics in Asteroids and Comets

We have been studying Fischer-Tropsch type (FTT) reactions as a source for organic materials both in the gas phase of the solar nebula and incorporated into primitive comets and asteroids for almost 10 years, and over this time our concept has evolved greatly from the standard "catalytic" model to a much more robust chemical scenario. Our simulations have been conducted at temperatures that are much higher than we like, primarily for practical reasons such as the timescale of individual reactions, and we are just starting a series of measurements to allow us to measure reaction rates at temperatures from 873K down to as low as 373K. We have preliminary data on the carbon (d13C = -50) & nitrogen (d15N = +9.5) isotopic fractionation at 873K, but not on materials produced at lower temperature. Isotope values are on the VPDB scale for carbon and vs. Air for nitrogen. We have also investigated the noble gas trapping efficiency of the FTT process by adding a small amount of a noble gas mix to our standard synthesis mix. The noble gas ratio is 49:49:1:1::Ne:Ar:Kr:Xe. Xe and Kr are trapped at 873K and are more efficiently trapped at 673K with no isotopic fractionation at either temperature. Ar trapping is detected at 673K, but not at 873K. Ne has not yet been observed in our samples. The solar nebula was an extremely complex system, mixing materials from the innermost regions out to well into the zones where comets formed and thus mixing highly processed nebular materials with grains and coatings formed before the nebula began to collapse. Laboratory studies may provide the means to separate such diverse components based on carbon or nitrogen isotopic fractionation or the quantities of noble gases trapped in grain coatings and their thermal release patterns, among other observables. The ultimate goal of laboratory synthesis of nebular analogs is to provide the means to identifY the conditions under which natural samples were formed and the signatures of subsequent metamorphic events.

Nuth, Joseph↗

Validation & Verification of CFD Models for Cryogenic Fluid Management of Propellant Tanks in Space

This article describes the need and the strategy for CFD model development, validation, and verification for Cryogenic Fluid Management (CFM) of Propellant Tanks in Space. It describes the type of CFD models that must be developed to address the future needs of Space CFM. It also discusses the two classes of experiments currently used to validate the fidelity of the CFD models. These two experiment classes are: (a) the small-scale simulant fluid science experiments that are equipped with scientific diagnostics to elucidate the underlying two-phase fluid physics of the CFM processes; and (b) the large-scale cryogenic experiments that assess the engineering performance of the propellant tank for storage and transfer. The current status of the CFD model development and validation is briefly assessed by presenting examples of segregated two-phase flow problems that have been successfully modeled. The future model development directions for CFM situations involving more complex interpenetrating phases are also defined.

Cryogenic Fluid Management↗