Thermal cycling of thin-film cadmium sulfide solar cells
Thermal cycling of thin-film cadmium sulfide solar cells
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Thermal cycling of thin-film cadmium sulfide solar cells
Solar thermal energy can be effectively collected, transported, stored, and utilized by means of a chemical storage and transport system employing the reversible SO2 oxidation reaction. A solar chemical receiver for SO3 thermal decomposition to SO2 and oxygen was analyzed. Bench tests of a ten foot section of a receiver module were conducted with dissociated sulfuric acid (SO3 and H2O) in an electrical furnace. Measured percent conversion of SO3 was 85% of the equilibrium value. Methods were developed to fabricate and assemble a complete receiver module. These methods included applying an aluminide coating to certain exposed surfaces, assembling concentric tubes with a wire spacer, applying a platinum catalyst to the tubing wall, and coiling the entire assembly into the desired configuration.
The thermal disappearance of solar prominences under strong perturbations due to wave heating, Ohmic heating, viscous heating or conduction was investigated. Specifically, how large a thermal perturbation is needed to destroy a stable thermal equilibrium was calculated. It was found that the prominence plasma appears to be thermally very rugged. Its cold equilibrium may most likely be destroyed by either strong magnetic heating or conduction in a range of parameters which is relevant to flares.
Thermal anisotropy of electrons and instability of circularly polarized electromagnetic waves propagating along magnetic field in solar wind
Phenolic Impregnated Carbon Ablator–Domestic (PICA‑D) has been selected as the heatshield thermal protection system (TPS) material for two upcoming NASA planetary science missions: the Dragonfly mission to Titan and the Mars Sample Retrieval Lander (SRL). Early testing revealed differences between PICA‑D and heritage PICA, particularly in in‑plane (IP) tensile stiffness and thermal expansion. Thermostructural analyses using Finite Element Method (FEM) tools subsequently predicted the potential for IP compressive failure in the near‑surface layers of PICA‑D under both Dragonfly and SRL flight environments. Over the past three years, the Dragonfly and SRL teams have carried out an extensive thermostructural qualification campaign to address these concerns and validate PICA‑D for flight. This effort began with a comprehensive mechanical property characterization program at Kratos test laboratories, which significantly improved understanding of PICA‑D mechanical behavior and increased the fidelity of FEM predictions. The teams also conducted six large‑scale test entries at the National Solar Thermal Test Facility (NSTTF) solar tower, exposing PICA‑D articles—including gap fillers and representative design features or flaws—to combined thermal and mechanical loads. The talk will summarize key findings from these mechanical and thermostructural test campaigns and present the current status of PICA‑D qualification for NASA’s planetary science missions.
Energy technology concerning photovoltaic conversion, solar thermal conversion systems, and electrical power distribution processing is discussed. The manufacturing processes involving solar cells and solar array production are summarized. Resource issues concerning gallium arsenides and silicon alternatives are reported. Collector structures for solar construction are described and estimates in their service life, failure rates, and capabilities are presented. Theories of advanced thermal power cycles are summarized. Power distribution system configurations and processing components are presented.
Under the Department of Energy's (DOE) Solar Thermal Technology Program, Sandia National Laboratories is evaluating heat engines for terrestrial Solar Distributed Heat Receivers. The Stirling engine has been identified by Sandia as one of the most promising engines for terrestrial applications. The Stirling engine also has the potential to meet DOE's performance and cost goals. The NASA Lewis Research Center is conducting Stirling engine technology development activities directed toward a dynamic power source for space applications. Space power systems requirements include high reliability, very long life, low vibration and high efficiency. The free-piston Stirling engine has the potential for future high power space conversion systems, either nuclear or solar powered. Although both applications appear to be quite different, their requirements complement each other. Preliminary designs feature a free-piston Stirling engine, a liquid metal heat transport system, and a means to provide nominally 25 kW electric power to a utility grid while meeting DOE's performance and long term cost goals. The Cummins design incorporates a linear alternator to provide the electrical output, while the STC design generates electrical power indirectly through a hydraulic pump/motor coupled to an induction generator. Both designs for the ASCS's will use technology which can reasonably be expected to be available in the early 1990's
Under the Department of Energy's (DOE) Solar Thermal Technology Program, Sandia National Laboratories is evaluating heat engines for terrestrial Solar Distributed Heat Receivers. The Stirling engine has been identified by Sandia as one of the most promising engines for terrestrial applications. The Stirling engine also has the potential to meet DOE's performance and cost goals. The NASA Lewis Research Center is conducting Stirling engine technology development activities directed toward a dynamic power source for space applications. Space power systems requirements include high reliability, very long life, low vibration and high efficiency. The free-piston Stirling engine has the potential for future high power space conversion systems, either nuclear or solar powered. Although both applications appear to be quite different, their requirements complement each other. Preliminary designs feature a free-piston Stirling engine, a liquid metal heat transport system, and a means to provide nominally 25 kW electric power to a utility grid while meeting DOE's performance and long term cost goals. The Cummins design incorporates a linear alternator to provide the electrical output, while the STC design generates electrical power indirectly through a hydraulic pump/motor coupled to an induction generator. Both designs for the ASCS's will use technology which can reasonably be expected to be available in the early 1990's.
A unique solar thermal chamber has been designed and fabricated to produce the maximum concentration of solar energy and higher temperature possible. Its primary purpose was for solar plasma propulsion experiments and related material specimen testing above 3000 K. The design not only maximized solar concentration, but also, minimized infrared heat loss. This paper provides the underlying theory and operation of the chamber and initial optical correlation to the actual fabricated hardware. The chamber is placed at the focal point of an existing primary concentrator with a 2.74 m (9 ft) focal length. A quartz lens focuses a small sun image at the inlet hole of the mirrored cavity. The lens focuses two image planes at prescribed positions; the sun at the cavity's entrance hole and the primary concentrator at the junction plane of two surfaces that form the cavity chamber. The back half is an ellipsoid reflector that produces a 1.27 cm diameter final sun image. The image is "suspended in space," 7.1 cm away from the nearest cavity surface, to minimize thermal and contaminate damage to the mirror surfaces. A hemisphere mirror makes up the front chamber and has its center of curvature at the target image, where rays leaving the target are reflected back upon themselves, minimizing radiation losses.
A pseudoheat-pipe heat transfer mechanism has been demonstrated effective in terms of both total heat removal efficiency and rate, on the one hand, and system isothermal characteristics, on the other, for solar thermal energy storage systems of the kind being contemplated for spacecraft. The selection of appropriate salt and alkali metal substances for the system renders it applicable to a wide temperature range. The rapid heat transfer rate obtainable makes possible the placing of the thermal energy storage system around the solar receiver canister, and the immersing of heat transfer fluid tubes in the phase change salt to obtain an isothermal heat source.
The development of low cost thermal energy storage technologies is discussed in terms of near term oil savings, solar energy applications, and dispersed energy systems for energy conservation policies. Program definition and assessment and research and technology development are considered along with industrial storage, solar thermal power storage, building heating and cooling, and seasonal thermal storage. A bibliography on seasonal thermal energy storage emphasizing aquifer thermal energy is included.
Under the Department of Energy's (DOE) Solar Thermal Technology Program, Sandia National Laboratories (SNLA) is developing heat engines for terrestrial Solar Distributed Heat Receivers. SNLA has identified the Stirling to be one of the most promising candidates for the terrestrial applications. The free-piston Stirling engine (FPSE) has the potential to meet the DOE goals for both performance and cost. The National Aeronautics and Space Administration (NASA) Lewis Research Center (LeRC) is conducting free-piston Stirling activities which are directed toward a dynamic power source for space applications. Space power system requirements include high efficiency, very long life, high reliability and low vibration. The FPSE has the potential for future high power space conversion systems, either solar or nuclear. Generic free-piston technology is currently being developed by LeRC for DOE/ORNL for use with a residential heat pump under an Interagency Agreement. Since 1983, the SP-100 Program (DOD/NASA/DOE) is developing dynamic power sources for space. Although both applications (heat pump and space power) appear to be quite different, their requirements complement each other. A cooperative Interagency Agreement (IAA) was signed in 1985 with NASA Lewis to provide technical management for an Advanced Stirling Conversion System (ASCS) for SNLA. Conceptual design(s) using a free-piston Stirling (FPSE), and a heat pipe will be discussed. The ASCS will be designed using technology which can reasonably be expected to be available in the 1980's.
A detailed analysis of the annealing of thermally diffused InP solar cells fabricated by the Nippon Mining Co. is presented. The cells were irradiated with 1 MeV electrons, and the induced degradation is measured using deep level transient spectroscopy and low temperature (86 K) IV measurements. Clear recovery of the photovoltaic parameters is observed during low temperature (T is less than 300 K) solar illuminations (1 sun, AMO) with further recovery at higher temperatures (300 less than T less than 500 K). For example, the output of a cell which was irradiated up to a fluence of 1 x 10(exp 16) cm(sup -2) was observed to recover to within 5 percent of the pre-irradiation output. An apparent correlation between the recovery of I(sub sc) and the annealing of the H4 defect and of the minority carrier trapping centers is observed. An apparent correlation between the recovery of VO, and the annealing of the H5 defect is also observed. These apparent correlations are used to develop a possible model for the mechanism of the recovery of the solar cells.
Concentrating solar thermal power (CSP) technology development has recently focused on high efficiency power cycles and chemical reactions that require high operating temperatures. An increase in receiver operating temperatures relative to current commercial CSP technology is necessary to support more efficient, high temperature power cycles or thermochemical processes. Solar receivers operating with heat transfer media temperatures >700 degrees C face various challenges including thermal performance, scalability, thermal-mechanical issues, and receiver service life. In addition, heat transfer media selection for high-temperature processes has been moving towards inert solid particles in Gen3 CSP, and reactive solid media and/or gases in solar thermochemical processes. To overcome the shortcomings and limitations of conventional designs for molten salt or particle receivers and receiver reactors, we introduce a unique light-trapping, planar cavity receiver (LTPCR) configuration and will present the current development progresses to demonstrate receiver feasibility through modeling, testing, and prototype demonstration.
The Heliostat Consortium for Concentrating Solar-Thermal Power (HelioCon) began in 2021, funded by the U.S. Department of Energy's Solar Energy Technologies Office to advance U.S. heliostat technologies over the next five years. This report provides detailed information on progress the HelioCon team has made since its founding, including expanding the number of partnerships with industry, research, education, and other institutions; increasing our staff; providing information to a growing audience through our web presence; and participating in national and international conferences with industry leaders.
Thermal models for hard X-ray bursts consisting of a one-dimensional flux tube whose central electrons are heated to about 400 million K are examined. It is found that the evolution of a thermal X-ray source is a sensitive function of the electron-ion thermal coupling and the state of the plasma into which the source expands. When this coupling is weak, the heated electrons separate into a region of high temperature of about 400 million K and a region of lower temperature of about 100 million K, a process which leads to a power-law X-ray spectrum. In the case of strong coupling there is only one dominant temperature, about 200 million K, and the X-ray spectrum resembles a true thermal spectrum.
The laboratory scale testing of a modified anhydrous NaOH latent heat storage concept for small solar thermal power systems such as total energy systems utilizing organic Rankine systems is discussed. A diagnostic test on the thermal energy storage module and an investigation of alternative heat transfer fluids and heat exchange concepts are specifically addressed. A previously developed computer simulation model is modified to predict the performance of the module in a solar total energy system environment. In addition, the computer model is expanded to investigate parametrically the incorporation of a second heat exchange inside the module which will vaporize and superheat the Rankine cycle power fluid.
Engineering studies for an International Energy Agency project for the design and construction of a 500 kW solar thermal electric power generation system of the distributed collector system (DCS) type are reviewed. The DCS system design consists of a mixed field of parabolic trough type solar collectors which are used to heat a thermal heat transfer oil. Heated oil is delivered to a thermocline storage tank from which heat is extracted and delivered to a boiler by a second heat transfer loop using the same heat transfer oil. Steam is generated in the boiler, expanded through a steam turbine, and recirculated through a condenser system cooled by a wet cooling tower.