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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Spectroscopic characterization of titanium 6-4 surfaces after chemical pretreatments

Several techniques have been used to study pretreated Ti 6-4 surfaces including scanning electron microscopy (SEM), electron spectroscopy of chemical analysis (ESCA), and, reflectance visibile spectroscopy. Each pretreatment type gives a characteristic surface morphology as seen by SEM. Elemental analysis of the Ti 6-4 surfaces was done using ESCA. Trace residual contaminants from particular chemical pretreatments are identified readily. Reflectance visible spectroscopy using indicator dyes placed on Ti 6-4 surfaces appears to be a feasible approach to establish surface acidity. Differences in surface acidity have been observed using bromthymol blue on Ti 6-4 surfaces pretreated by two different methods.

Chen, W.↗
NASA NTRS1981

Simultaneous spectroscopic determination of the latitudinal, seasonal, and diurnal variability of stratospheric N2O, NO, NO2, and HNO3

A program for the measurement of latitudinal, seasonal, and diurnal variations in stratospheric N2O, NO, NO2 and HNO3 is described, which uses airborne Fourier transform absorption spectroscopy to simultaneously determine columns, above 12 km, of the four molecules. The data may prove useful for comparison with two-dimensional models of stratospheric chemistry, since simultaneous measurement of several species with the same technique provides an inherently more reliable set for model comparisons, by eliminating uncorrelated atmospheric variability and reducing differences in instrumental biases.

Coffey, M. T.↗
NASA NTRS1981

A spectroscopic, photometric, and magnetic study of the starspot on II Pegasi

A description is presented of extensive observations of II Peg during 1977 and 1978, taking into account multicolor broad-band photometry, high-dispersion spectroscopy, low-dispersion spectrophotometry, and Zeeman analysis. During this time the star showed periodic light variations in excess of a 0.4 mag range attributable to the presence of a large starspot or an equivalent nonuniform surface brightness distribution. The high-precision multicolor photometry, which differed greatly from previous photometric results, illustrates that the starspots on II Peg are continually evolving on time scales of approximately 1 year or less. A low-dispersion spectrum of the large spot showed pronounced VO and TiO molecular adsorption features. A high-resolution, high signal-to-noise Reticon spectrum at lambda 6707 does not show any compelling evidence of previously reported lithium in this star.

Vogt, S. S.↗
NASA NTRS1981

Changes in the high state of AM Herculis - A simultaneous X-ray, optical, polarimetric, and spectroscopic study

Simultaneous UBVR photometry, circular polarimetry, and high resolution spectroscopy observations (during May, 1979), coordinated with a monitor proportional counter and a solid state spectrometer, are reported for the cataclysmic variable AM Her, when it was in its normal 'high' state, where the mean visual magnitude was 12.5 mag versus 15 mag for the infrequent 'low' state. The circular polarization was always negative and had the smallest peak to peak amplitude yet reported. The emission lines He II 4686, H-beta, N III 4634, N III 4640-4641, C III 4650-4651, and He I 4713 present at least two components identified with the broad and sharp components of Greenstein at al. (1977). The radial velocity curve of the broad component shows a 50% reduction of amplitude in comparison to their values, and a third very broad component in 4686 is identified. No correlation between the optical photometry and 1-10 keV X-ray intensity was found on flickering time scales. Results of the observations are discussed within the framework of models with accretion onto one or both magnetic poles of the white dwarf.

Crosa, L.↗
NASA NTRS1981

Airborne simultaneous spectroscopic detection of laser-induced water Raman backscatter and fluorescence from chlorophyll a and other naturally occurring pigments

The airborne laser-induced spectral emission bands obtained simultaneously from water Raman backscatter and the fluorescence of chlorophyll and other naturally occurring waterborne pigments are reported here for the first time. The importance of this type data lies not only in its single-shot multispectral character but also in the application of the Raman line for correction or calibration of the spatial variation of the laser penetration depth without the need for in situ water attenuation measurements. The entire laser-induced fluorescence and Raman scatter emissions resulting from each separate 532-nm 10-nsec laser pulse are collected and spectrally dispersed in a diffraction grating spectrometer having forty photomultiplier tube detectors. Results from field experiments conducted in the North Sea and the Chesapeake Bay/Potomac River are presented. Difficulties involving the multispectral resolution of the induced emissions are addressed, and feasible solutions are suggested together with new instrument configurations and future research directions.

Hoge, F. E.↗
NASA NTRS1981

A spectroscopic study of the high excitation nebula NGC 6302

The wonderfully intricate irregular gaseous nebula NGC 6302 shows a great range of excitation from the S I to Fe VII forbidden lines. Data obtained with the International Ultraviolet Explorer (IUE) covering the spectral range of wavelengths 1200-3203 and with the image-photon counting system at the Anglo-Australian telescope emphasizing the region of wavelengths 3200-4880 are used for a new determination of the chemical composition of this object. No simple theoretical model can represent the observed intensities. Helium and nitrogen are enhanced in abundance, as noted by previous observers, but the enrichment of nitrogen is a whole order of magnitude. Carbon and oxygen are decreased in abundance, neon and heavier elements show a 'normal' abundance pattern, but calcium and possibly silicon are depleted; presumably they are concentrated in grains.

Aller, L. H.↗
NASA NTRS1982

Spectroscopic observations of comets

Development of a spectrograph using a microchannel plate intensifier for observing faint comets is described. The spectrograph is capable of obtaining useful spectra of objects as faint as M(2) = 18. The increased guiding efficiency achieved by the optical coupling of the ISIT vidicon of the 154 cm telescope has resulted in a better signal to noise ratio. The ability to take a direct image of the comet aids in the interpretation of the spatial profile of the emissions. Spectra of comets Schwassmann-Wachmann 1, Bradfield, Encke, Tuttle, and Stephen-Oterma are discussed.

Source record↗
NASA NTRS1981

A High Resolution Spectroscopic Study of the Nu2 Band of Hydrogen Sulfide and the 1-0 Band of Hydrogen Iodide

A tunable diode laser spectrometer was constructed and used to study: (1) the effects of centrifugal distortion on the transition frequencies and strengths of the nu sub 2 band of H2S, and (2) nuclear quadrupole hyperfine structure in the 1-0 band of HI. A total of 126 line frequencies and 94 line strengths in the nu sub 2 band of H2S were measured. The average accuracy of the line frequency measurements was + or - 0.0016 cm. The line strengths were measured to an average accuracy of about 3 percent. The effect of the finite spectral width of the diode laser on the measurement of line strengths is discussed. The observed H2S line frequencies were fit to Watson's AS and NS reduced Hamiltonian in both the Ir and IIIr coordinate representations in order to determine the best set of rotation distortion constants for the upper state of the nu sub 2 band. Comparisons of the observed line strengths in this band to rigid rotor line strengths are also presented. Nuclear quadrupole hyperfine structure in the low J lines of the 1-0 band of HI was observed. The upper vibrational state nuclear quadrupole coupling constant, determined from the observed splittings, was -1850 MHz + or - 12 MHz or 1.2 percent + or - 0.7 percent larger than the ground state coupling constant.

Strow, L. L.↗
NASA NTRS1980

Spectroscopic studies of water and water/regolith mixtures on planetary surfaces at low temperatures

New reflectance spectra of Ganymede, Europe, Callisto, Io, Saturn's rings, and Mars were obtained. The new data is combined with data covering other spectral regions for compositional interpretation. The spectral properties of water and mixtures of water plus other minerals were studied in the laboratory at the low temperatures typical of Mars, the Galilean satellites, and Saturn's rings. High precision reflectance spectra of water ice were studied.

Clark, R. N.↗
NASA NTRS1982

Spectroscopic requirements for HALOE: An analysis of the HCl and HF channels

Spectral line parameters that have absorption features within the HCl and HF channels of the Halogen Occultation Experiment (HALOE) were evaluated. Line positions and identification of stratospheric and solar absorption features in both channels are presented based on an analysis of high-resolution, balloon-borne solar occultation spectra. For the relevant HCl and HF lines and for transitions of the interfering species, the accuracy of the following spectral parameters was assessed: line positions, line strengths, lower state energies, air-broadened collisional half-widths, and temperature dependence of the air-broadened half-widths. In addition, since the HALOE instrument and calibration cells are filled with mixtures of HCl in N2 and HF in N2, the self-broadened and N2-broadened HF and HCl half-widths were also considered.

Rinsland, C. P.↗
NASA NTRS1982

Spectroscopic measurements of Mars and Venus with heterodyne techniques

Measurements were made of the exact shape of CO2 absorption lines in Mars and Venus to determine the vertical pressure temperature structure using high resolution heterodyne spectroscopy. Accurate measurements of absolute wind velocities in both the mesosphere and stratosphere of Venus were made from Doppler shifts of narrow CO2 lines, and searches were made for minor molecular species of interest in modeling the stratospheric photochemistry for Mars and Venus.

Betz, A.↗
NASA NTRS1981

X-ray spectroscopic observations and modeling of supernova remnants

The X-ray observations of young remnants and their theoretical interpretation are described. A number of questions concerning the nature of the blast wave interaction with the interstellar gas and grains and of atomic processes in these hot plasmas are considered. It is concluded that future X-ray spectrometers with high collecting area, moderate spectral resolution and good spatial resolution can make important contributions to the understanding of supernova remnants in the Milky Way and neighboring galaxies and of their role in the global chemical and dynamical evolution of the interstellar medium.

Shull, J. M.↗
NASA NTRS1982

H2 and HD Spectroscopic Status

HD spectra was studied in the UV about as thoroughly as those of H2. The vibration-rotation line positions are known. However, the theory does not do well in calculating the absorption strengths. These tend to be stronger than the quadrupole strengths for H2 and so more lines were measured. The state of knowledge of the HD line positions of vibration-rotation constants is summarized. The HD absorption strength measurements are also summarized. A summary of absorption strengths for HD is tabulated.

Margolis, J. S.↗
NASA NTRS1982

Performing spectroscopic and specific heat studies of improper ferroelectrics

The results of infrared measurements on Ni-Br, Cu-Cl, and Fe-I boracite improper ferroelectrics and far infrared measurements of Ni-Br boracite are presented. The boracites have the general formula X3B7O3Y, where X = divalent metal and Y = halogen. They undergo a first order phase transition from a high temperature paraelectric phase with cubic symmetry to a ferroelectric phase with orthorhombic symmetry. The boracites are "improper ferroelectrics" since the spontaneous polarization is not the primary order parameter in the cubic-orthorhombic phase transition. Current understanding of these materials is that the primary order parameter is associated with a doubly degenerate zone-boundary phonon in the cubic phase. The degenerate critical modes become homogeneous and split into the A sub 1 and A sub 2 modes in the orthorhombic phase, doubling the volume of the primitive cell. An harmonic coupling between the softing A sub 1 and a low frequency A sub 1 optic mode induces a spontaneous polarization as a secondary effect in the ferroelectric phase. This secondary non-critical nature of the ferroelectric mode earns these materials the "improper" title and is responsible for their unique properties and high figure of merit in detector use.

Coleman, L. B.↗
NASA NTRS1982

IUE spectroscopic investigation of interacting binary systems

The IUE observations of binaries consisting of at least one early type star, to the Algol systems, and to W Serpentis systems are discussed. The OB close binaries almost invaribly show a stellar wind. The difference between an unevolved early type system and a slightly evolved system is difficult to discern observationally and probably not meaningful in terms of Roche lobes. the zeta Aur stars show complex gas motions and shocks. Many of the Algol systems show peculiarities in their ultraviolet continua and the resonance lines, particularly Si IV, are of abnormal and variable strength. Emission lines were detected in several systems during the total eclipse. The W Ser stars are characterized by numerous strong emission lines in their ultraviolet spectra. It appears that these systems may be related to beta Lyrae as they seem to be in a phase of rapid mass transfer and their spectra show similarities to that of beta Lyrae.

Mccluskey, G. E., Jr.↗
NASA NTRS1981

Spectroscopic detection of stratospheric hydrogen cyanide

A number of features have been identified as absorption lines of hydrogen cyanide in infrared spectra of stratospheric absorption obtained from a high-altitude aircraft. Column amounts of stratospheric hydrogen cyanide have been derived from spectra recorded on eight flights. The average vertical column amount above 12 kilometers is 7.1 + or - 0.8 x 10 to the 14th molecules per square centimeter, corresponding to an average mixing ratio of 170 parts per trillion by volume.

Coffey, M. T.↗
NASA NTRS1982

Recent spectroscopic measurements of NOx in the lower stratosphere

High resolution (0.02 and 0.06 per cm) Fourier transform airborne systems were used for measurements of long path atmospheric absorption spectra, covering many of the NOx infrared bands. Atmospheric emission measurements with liquid helium cooled grating spectrometer systems at 0.5 per cm resolution were also carried out from different altitudes in the NOx bands region. Analysis of the absorption and emission spectra provides quantification of NOx in the lower stratosphere at different latitudes and seasons, as well as diurnal variability.

Goldman, A.↗
NASA NTRS1982

Mars residual north polar cap - Earth-based spectroscopic confirmation of water ice as a major constituent and evidence for hydrated minerals

A description is presented of new earth-based reflectance spectra of the Martian north residual polar cap. The spectra indicate that the composition is at least mostly water ice plus another component with a 'gray' reflectance. The other minerals in the ice cap appear to be hydrated. The data were obtained with a cooled circular variable filter spectrometer on February 20, 1978, using the 2.2-m telescope on Mauna Kea, Hawaii. It is pointed out that the identification of water ice in the north polar cap alone does not indicate that water makes up all or even most of the bulk of the cap. Kieffer (1970) has shown that a small amount of water will mask the spectral features of CO2.

Clark, R. N.↗