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At least 559 records · Page 31

The Use of Thermal Remote Sensing to Study Thermodynamics of Ecosystem Development

Thermal remote sensing can provide environmental measuring tools with capabilities for measuring ecosystem development and integrity. Recent advances in applying principles of nonequilibrium thermodynamics to ecology provide fundamental insights into energy partitioning in ecosystems. Ecosystems are nonequilibrium systems, open to material and energy flows, which grow and develop structures and processes to increase energy degradation. More developed terrestrial ecosystems will be more effective at dissipating the solar gradient (degrading its energy content). This can be measured by the effective surface temperature of the ecosystem on a landscape scale. A series of airborne thermal infrared multispectral scanner data were collected from several forested ecosystems ranging from a western US douglas-fir forest to a tropical rain forest in Costa Rica. These data were used to develop measures of ecosystem development and integrity based on surface temperature.

Luvall, Jeffrey C.↗

ISS and Space Environment Interactions in Event of Plasma Contactor Failure

The International Space Station (ISS), illustrated in Figure 1, will be the largest, highest power spacecraft placed in orbit. Because of this the design of the electrical power system diverged markedly from previous systems. The solar arrays will operate at 160 V and the power distribution voltage will be 120 V. The structure is grounded to the negative side of the solar arrays so under the right circumstances it is possible to drive the ISS potential very negative. A plasma contactor has been added to the ISS to provide control of the ISS structure potential relative to the ambient plasma. The ISS requirement is that the ISS structure not be greater than 40 V positive or negative of local plasma. What are the ramifications of operating large structures with such high voltage power systems? The application of a plasma contactor on ISS controls the potential between the structure and the local plasma, preventing degrading effects. It is conceivable that there can be situations where the plasma contactor might be non-functional. This might be due to lack of power, the need to turn it off during some of the build-up sequences, the loss of functionality for both plasma contactors before a replacement can be installed, and similar circumstances. A study was undertaken to understand how important it is to have the contactor functioning and how long it might be off before unacceptable degradation to ISS could occur.

Carruth, M. R., Jr.↗

Thermal Remote Sensing and the Thermodynamics of Ecosystems Development

Thermal remote sensing can provide environmental measuring tools with capabilities for measuring ecosystem development and integrity. Recent advances in applying principles of nonequilibrium thermodynamics to ecology provide fundamental insights into energy partitioning in ecosystems. Ecosystems are nonequilibrium systems, open to material and energy flows, which grow and develop structures and processes to increase energy degradation. More developed terrestrial ecosystems will be more effective at dissipating the solar gradient (degrading its energy content). This can be measured by the effective surface temperature of the ecosystem on a landscape scale. A series of airborne thermal infrared multispectral scanner data were collected from several forested ecosystems ranging from a western US douglas-fir forest to a tropical rain forest in Costa Rica. Also measured were agriculture systems. These data were used to develop measures of ecosystem development and integrity based on surface temperature.

Luvall, Jeffrey C.↗

Thermal Evaluation of Fiber Bragg Gratings at Extreme Temperatures

The development of integrated fiber optic sensors for use in aerospace health monitoring systems demands that the sensors be able to perform in extreme environments. In order to use fiber optic sensors effectively in an extreme environment one must have a thorough understanding of the sensor's capabilities, limitations, and performance under extreme environmental conditions. This paper reports on our current sensor evaluation examining the performance of freestanding fiber Bragg gratings (FBG) at extreme temperatures. While the ability of FBGs to survive at extreme temperatures has been established, their performance and long term survivability is not well documented. At extreme temperatures the grating structure would be expected to dissipate, degrading the sensors performance and eventually ceasing to return a detectable signal. The fiber jacket will dissipate leaving a brittle, unprotected fiber. For FBGs to be used in aerospace systems their performance and limitations need to be thoroughly understood at extreme temperatures. As the limits of the FBGs performance are pushed the long term survivability and performance of the sensor comes into question. We will not only examine the ability of FBGs to survive extreme temperatures but also look at their performance during many thermal cycles. This paper reports on test results of the performance of thermal cycling commercially available FBGs, at temperatures up to 1000 C, seen in aerospace applications. Additionally this paper will report on the performance of commercially available FBGs held at 1000 C for hundreds of hours. Throughout the evaluation process, various parameters of the FBGs performance were monitored and recorded. Several test samples were subjected to identical test conditions to allow for statistical analysis of the data. Test procedures, calibrations, referencing techniques, performance data, and interpretations and explanations of results are presented in the paper along with directions for future research.

Juergens, Jeffrey↗

Hydrogen Effects on GaAs Device Reliability

It has been observed that GaAs devices mounted in hermetically sealed packages, and exposed to burn-in and lifetest temperatures as low as 125 C, exhibit performance degradation in both RF and DC characteristics after relatively short periods of test time (500 hours). This paper will provide a discussion and summary of the general understanding of the failure mechanisms associated with this.

GaAs devices degradation gate metallization struct↗

Nondestructive Evaluation and Monitoring Results from COPV Accelerated Stress Rupture Testing, NASA White Sands Test Facility (WSTF)

Develop and demonstrate NDE techniques for real-time characterization of CPVs and, where possible, identification of NDE capable of assessing stress rupture related strength degradation and/or making vessel life predictions (structural health monitoring or periodic inspection modes). Secondary: Provide the COPV user and materials community with quality carbon/epoxy (C/Ep) COPV stress rupture progression rate data. Aid in modeling, manufacturing, and application of COPVs for NASA spacecraft.

Saulsberry Regor↗

Thermal Remote Sensing and the Thermodynamics of Ecosystem Development

Thermal remote sensing can provide environmental measuring tools with capabilities for measuring ecosystem development and integrity. Recent advances in applying principles of nonequilibrium thermodynamics to ecology provide fundamental insights into energy partitioning in ecosystems. Ecosystems are nonequilibrium systems, open to material and energy flows, which grow and develop structures and processes to increase energy degradation. More developed terrestrial ecosystems will be more effective at dissipating the solar gradient (degrading its exergy content) and can be measured by the effective surface temperature of the ecosystem on a landscape scale. Ecosystems are viewed as open thermodynamic systems with a large gradient impressed on them by the exergy flux from the sun. Ecosystems, according to the restated second law, develop in ways that systematically increases their ability to degrade the incoming solar exergy, hence negating it's ability to set up even larger gradients. Thus it should be expected that more mature ecosystems degrade the exergy they capture more completely than a less developed ecosystem. The degree to which incoming solar exergy is degraded is a function of the surface temperature of the ecosystem. If a group of ecosystems receives the same amount of incoming radiation, we would expect that the most mature ecosystem would reradiate its energy at the lowest quality level and thus would have the lowest surface temperature (coldest black body temperature). Initial development work was done using NASA's airborne Thermal Infrared Multispectral Scanner (TIMS) followed by the use of a multispectral visible and thermal scanner-Airborne Thermal and Land Applications Sensor (ATLAS). Luvall and his coworkers have documented ecosystem energy budgets, including tropical forests, midlatitude varied ecosystems, and semiarid ecosystems. These data show that under similar environmental conditions (air temperature, relative humidity, winds, and solar irradiance) and within a given biome type, the more developed the ecosystem, the cooler it's surface temperature and the more degraded the quality of it's reradiated energy. HyspIRI is a hyperspectral visible/Near IR and multispectral thermal future global satellite mission that will collect data to study the world's ecosystems and will provide a benchmark on the state of the worlds ecosystems against which future changes can be assessed. HyspIRI will provide global data sets that will provide a means for measuring ecosystem development and integrity.

Luvall, Jeffrey C.↗

Thermal Remote Sensing and the Thermodynamics of Ecosystem Development

Thermal remote sensing can provide environmental measuring tools with capabilities for measuring ecosystem development and integrity. Recent advances in applying principles of nonequilibrium thermodynamics to ecology provide fundamental insights into energy partitioning in ecosystems. Ecosystems are nonequilibrium systems, open to material and energy flows, which grow and develop structures and processes to increase energy degradation. More developed terrestrial ecosystems will be more effective at dissipating the solar gradient (degrading its exergy content) and can be measured by the effective surface temperature of the ecosystem on a landscape scale. Ecosystems are viewed as open thermodynamic systems with a large gradient impressed on them by the exergy flux from the sun. Ecosystems, according to the restated second law, develop in ways that systematically increases their ability to degrade the incoming solar exergy, hence negating it's ability to set up even larger gradients. Thus it should be expected that more mature ecosystems degrade the exergy they capture more completely than a less developed ecosystem. The degree to which incoming solar exergy is degraded is a function of the surface temperature of the ecosystem. If a group of ecosystems receives the same amount of incoming radiation, we would expect that the most mature ecosystem would reradiate its energy at the lowest quality level and thus would have the lowest surface temperature (coldest black body temperature). Initial development work was done using NASA's airborne Thermal Infrared Multispectral Scanner (TIMS) followed by the use of a multispectral visible and thermal scanner- Airborne Thermal and Land Applications Sensor (ATLAS). Luvall and his coworkers have documented ecosystem energy budgets, including tropical forests, midlatitude varied ecosystems, and semiarid ecosystems. These data show that under similar environmental conditions (air temperature, relative humidity, winds, and solar irradiance) and within a given biome type, the more developed the ecosystem, the cooler it's surface temperature and the more degraded the quality of it's reradiated energy. HyspIRI is a hyperspectral visible/Near IR and multispectral thermal future global satellite mission that will collect data to study the world's ecosystems and will provide a benchmark on the state of the worlds ecosystems against which future changes can be assessed. HyspIRI will provide global data sets that will provide a means for measuring ecosystem development and integrity.

Luvall, Jeffrey C.↗

12Cao-7Al2o3 Electride Hollow Cathode

The use of the electride form of 12CaO-7Al.sub.2O.sub.3, or C12A7, as a low work function electron emitter in a hollow cathode discharge apparatus is described. No heater is required to initiate operation of the present cathode, as is necessary for traditional hollow cathode devices. Because C12A7 has a fully oxidized lattice structure, exposure to oxygen does not degrade the electride. The electride was surrounded by a graphite liner since it was found that the C12A7 electride converts to it's eutectic (CA+C3A) form when heated (through natural hollow cathode operation) in a metal tube.

Rand, Lauren P.↗

Ice Accretions and Full-Scale Iced Aerodynamic Performance Data for a Two-Dimensional NACA 23012 Airfoil

This report documents the data collected during the large wind tunnel campaigns conducted as part of the SUNSET project (StUdies oN Scaling EffecTs due to ice) also known as the Ice-Accretion Aerodynamics Simulation study: a joint effort by NASA, the Office National d'Etudes et Recherches Aérospatiales (ONERA), and the University of Illinois. These data form a benchmark database of full-scale ice accretions and corresponding ice-contaminated aerodynamic performance data for a two-dimensional (2D) NACA 23012 airfoil. The wider research effort also included an analysis of ice-contaminated aerodynamics that categorized ice accretions by aerodynamic effects and an investigation of subscale, low- Reynolds-number ice-contaminated aerodynamics for the NACA 23012 airfoil. The low-Reynolds-number investigation included an analysis of the geometric fidelity needed to reliably assess aerodynamic effects of airfoil icing using artificial ice shapes. Included herein are records of the ice accreted during campaigns in NASA Glenn Research Center's Icing Research Tunnel (IRT). Two different 2D NACA 23012 airfoil models were used during these campaigns; an 18-in. (45.7-cm) chord (subscale) model and a 72-in. (182.9-cm) chord (full-scale) model. The aircraft icing conditions used during these campaigns were selected from the Federal Aviation Administration's (FAA's) Code of Federal Regulations (CFR) Part 25 Appendix C icing envelopes. The records include the test conditions, photographs of the ice accreted, tracings of the ice, and ice depth measurements. Model coordinates and pressure tap locations are also presented. Also included herein are the data recorded during a wind tunnel campaign conducted in the F1 Subsonic Pressurized Wind Tunnel of ONERA. The F1 tunnel is a pressured, high- Reynolds-number facility that could accommodate the full-scale (72-in. (182.9-cm) chord) 2D NACA 23012 model. Molds were made of the ice accreted during selected test runs of the full-scale model in the IRT. From these molds, castings were made that closely replicated the features of the accreted ice. The castings were then mounted on the full-scale model in the F1 tunnel, and aerodynamic performance measurements were made using model surface pressure taps, the facility force balance system, and a large wake rake designed specifically for these tests. Tests were run over a range of Reynolds and Mach numbers. For each run, the model was rotated over a range of angles-of-attack that included airfoil stall. The benchmark data collected during these campaigns were, and continue to be, used for various purposes. The full-scale data form a unique, ice-accretion and associated aerodynamic performance dataset that can be used as a reference when addressing concerns regarding the use of subscale ice-accretion data to assess full-scale icing effects. Further, the data may be used in the development or enhancement of both ice-accretion prediction codes and computational fluid dynamic codes when applied to study the effects of icing. Finally, as was done in the wider study, the data may be used to help determine the level of geometric fidelity needed for artificial ice used to assess aerodynamic degradation due to aircraft icing. The structured, multifaceted approach used in this research effort provides a unique perspective on the aerodynamic effects of aircraft icing. The data presented in this report are available in electronic form upon formal approval by proper NASA and ONERA authorities.

Addy, Harold E., Jr.↗

12CaO-7Al2O3 Electride Hollow Cathode

The use of the electride form of 12CaO-7Al2O3, or C12A7, as a low work function electron emitter in a hollow cathode discharge apparatus is described. No heater is required to initiate operation of the present cathode, as is necessary for traditional hollow cathode devices. Because C12A7 has a fully oxidized lattice structure, exposure to oxygen does not degrade the electride. The electride was surrounded by a graphite liner since it was found that the C12A7 electride converts to it's eutectic (CA+C3A) form when heated (through natural hollow cathode operation) in a metal tube.

Rand, Lauren P.↗

The fate of organic carbon in marine sediments - New insights from recent data and analysis

Organic carbon in marine sediments is a critical component of the global carbon cycle, and its degradation influences a wide range of phenomena, including the magnitude of carbon sequestration over geologic timescales, the recycling of inorganic carbon and nutrients, the dissolution and precipitation of carbonates, the production of methane and the nature of the seafloor biosphere. Although much has been learned about the factors that promote and hinder rates of organic carbon degradation in natural systems, the controls on the distribution of organic carbon in modern and ancient sediments are still not fully understood. In this review, we summarize how recent findings are changing entrenched perspectives on organic matter degradation in marine sediments: a shift from a structurally-based chemical reactivity viewpoint towards an emerging acceptance of the role of the ecosystem in organic matter degradation rates. That is, organic carbon has a range of reactivities determined by not only the nature of the organic compounds, but by the biological, geochemical, and physical attributes of its environment. This shift in mindset has gradually come about due to a greater diversity of sample sites, the molecular revolution in biology, discoveries concerning the extent and limits of life, advances in quantitative modeling, investigations of ocean carbon cycling under a variety of extreme paleo-conditions (e.g. greenhouse environments, euxinic/anoxic oceans), the application of novel analytical techniques and interdisciplinary efforts. Adopting this view across scientific disciplines will enable additional progress in understanding how marine sediments influence the global carbon cycle.

Organic carbon↗

Investigating Fifth Oxide Effect on CMXAS Glass Properties

Coatings for hot section aero turbine engine structural materials are subject to thermochemical degradation after interacting with calcium-magnesium-aluminosilicates (CMAS). Molten CMAS viscosity is the primary glass property of importance, correlating with coating infiltration and reaction depth. CMAS viscosity was measured using a spindle-dipped viscometer at temperatures between 1300-1550°C in 25°C increments. Experimental data were compared to Thermo-Calc and FactSage computational models, which showed good agreement with experimental trends. CMXAS compositions, where X denotes a fifth oxide, of Ca30.75-Mg9-X5-Al13-Si42.25 (single cation oxide mol%) for X = Fe2+, Fe3+, Gd3+, Hf4+, Na1+, Ti4+, Y3+, Yb3+, Zr4+ additions were used. Oxide precipitation was observed in X = Hf4+ , Zr4+ CMXAS specimens, indicating coating dissolution is an increased threat for T ≥ 1390°C. Molten CMAS and CMXAS viscosity measurements were shown to correlate with net cation field strength, offering an alternative in property prediction where thermodynamic data are unavailable.

Clark Avery Luckhardt↗

Small scale tensile testing technique for measuring grain boundary strength of neutron-irradiated materials in focused ion beam systems

Irradiation induced defects on grain boundaries (GBs) can lead to GB strength degradation and cause intergranular cracking in structural materials, affecting the safe operation and service life of nuclear reactors. Establishing the quantitative relationship between the strength and character/microchemistry for individual GB in an effort of integrating experimental measurements and multiscale simulations.

36 MATERIALS SCIENCE↗

Self-Learning Kinetic Monte Carlo Simulations of Radiation Damage in Nuclear Fuels

Understanding how irradiation affects the thermo-physical and mechanical properties of nuclear materials, such as thermal conductivity degradation in fuels and embrittlement of structural components, is critical to the safety and efficiency of nuclear reactors. These effects are largely governed by the formation and evolution of atomic-scale point defects and defect clusters. Due to their small sizes, however, these defects are invisible under high-resolution scanning transmission electron microscopy. This project aims to fill this experimental knowledge gap by integrating density functional theory (DFT), machine learning interatomic potential (MLIP), and kinetic Monte Carlo (KMC) techniques to predict longtime evolution of irradiation-induced defects in nuclear fuels.

36 - MATERIALS SCIENCE↗

Chemo-Mechanical Instabilities in Lithium Cobalt Oxide at Higher State-Of-Charge in Li-Ion Batteries

Transition metal oxide cathodes are widely used in commercial Li-ion batteries. However, their practical charge capacity is limited due to severe chemo-mechanical instabilities at higher charge voltage, and state-of-charge condition. Here, in situ stress and strain measurements were synchronized to probe mechanical deformations in the lithium cobalt oxide (LCO) cathode via a multi-beam stress sensor and digital image correlation, respectively. In situ mechanical measurements revealed how Li removal from the electrode structure induces deformations on the LCO composite cathodes during cycling. The structure and morphology of the LCO cathodes were further investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM) studies. Two distinct electrochemical and mechanical behaviors were identified when the LCO was charged up to 4.65 V. The LCO undergoes a compressive stress generation when charged up to 4.2 V and surface fractures on the LCO particles were detected by SEM. LCO cathode experienced significantly large contractions (negative strains) when charged up to 4.65 V, where intergranular crack formation and phase transformation were detected on the LCO particles via SEM and XRD, respectively. Overall, the study bridges complicated structural deformations with in situ analysis of mechanical degradations in LCO cathodes charged at higher voltages. The correlation is vital to understanding instability mechanisms in transition metal oxides at high voltages for alkali metal ion batteries.

higher state-of-charge↗

User-Defined Material Model for Progressive Failure Analysis

An overview of different types of composite material system architectures and a brief review of progressive failure material modeling methods used for structural analysis including failure initiation and material degradation are presented. Different failure initiation criteria and material degradation models are described that define progressive failure formulations. These progressive failure formulations are implemented in a user-defined material model (or UMAT) for use with the ABAQUS/Standard1 nonlinear finite element analysis tool. The failure initiation criteria include the maximum stress criteria, maximum strain criteria, the Tsai-Wu failure polynomial, and the Hashin criteria. The material degradation model is based on the ply-discounting approach where the local material constitutive coefficients are degraded. Applications and extensions of the progressive failure analysis material model address two-dimensional plate and shell finite elements and three-dimensional solid finite elements. Implementation details and use of the UMAT subroutine are described in the present paper. Parametric studies for composite structures are discussed to illustrate the features of the progressive failure modeling methods that have been implemented.

Knight, Norman F. Jr.↗

Two-Photon Fluorescence Microscopy Developed for Microgravity Fluid Physics

Recent research efforts within the Microgravity Fluid Physics Branch of the NASA Glenn Research Center have necessitated the development of a microscope capable of high-resolution, three-dimensional imaging of intracellular structure and tissue morphology. Standard optical microscopy works well for thin samples, but it does not allow the imaging of thick samples because of severe degradation caused by out-of-focus object structure. Confocal microscopy, which is a laser-based scanning microscopy, provides improved three-dimensional imaging and true optical sectioning by excluding the out-of-focus light. However, in confocal microscopy, out-of-focus object structure is still illuminated by the incoming beam, which can lead to substantial photo-bleaching. In addition, confocal microscopy is plagued by limited penetration depth, signal loss due to the presence of a confocal pinhole, and the possibility of live-cell damage. Two-photon microscopy is a novel form of laser-based scanning microscopy that allows three-dimensional imaging without many of the problems inherent in confocal microscopy. Unlike one-photon microscopy, it utilizes the nonlinear absorption of two near-infrared photons. However, the efficiency of two-photon absorption is much lower than that of one-photon absorption because of the nonlinear (i.e., quadratic) electric field dependence, so an ultrafast pulsed laser source must typically be employed. On the other hand, this stringent energy density requirement effectively localizes fluorophore excitation to the focal volume. Consequently, two-photon microscopy provides optical sectioning and confocal performance without the need for a signal-limiting pinhole. In addition, there is a reduction in photo-damage because of the longer excitation wavelength, a reduction in background fluorescence, and a 4 increase in penetration depth over confocal methods because of the reduction in Rayleigh scattering.

Fischer, David G.↗