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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31

Changes in Soil Carbon Dynamics in Response to Long-Term Soil Warming - Integration Across Scales from Cells to Ecosystems

This project produced a series of papers documenting the effects of soil warming on fluxes of carbon dioxide between soils and the atmosphere, and the temporal changes in structure and function of soil microbial community. A diversity of techniques was used in the study including: pyrolysis–GC/MS to analyze soil chemistry; isotopically–labeled organic compounds to estimate microbial carbon use efficiency; and Illumina sequencing of the 16S ribosomal RNA gene to study bacterial community composition. We found that soil warming resulted in a four–phase pattern of soil organic matter decay and carbon dioxide fluxes to the atmosphere, with phases of substantial soil carbon loss alternating with phases of no detectable loss. Several factors combined to affect the timing, magnitude, and thermal acclimation of soil carbon loss. These include depletion of microbially accessible carbon pools, reductions in microbial biomass, a shift in microbial carbon use efficiency, and changes in microbial community composition. Our results support projections of a long–term, self–reinforcing carbon feedback from mid–latitude forests to the climate system as the world warms.

54 ENVIRONMENTAL SCIENCES↗

Symposium on Machine Processing of Remotely Sensed Data, Purdue University, West Lafayette, Ind., June 29-July 1, 1976, Proceedings

Papers are presented on the applicability of Landsat data to water management and control needs, IBIS, a geographic information system based on digital image processing and image raster datatype, and the Image Data Access Method (IDAM) for the Earth Resources Interactive Processing System. Attention is also given to the Prototype Classification and Mensuration System (PROCAMS) applied to agricultural data, the use of Landsat for water quality monitoring in North Carolina, and the analysis of geophysical remote sensing data using multivariate pattern recognition. The Illinois crop-acreage estimation experiment, the Pacific Northwest Resources Inventory Demonstration, and the effects of spatial misregistration on multispectral recognition are also considered. Individual items are announced in this issue.

Source record↗

Early adaptation to altered gravitational environments in the squirrel monkey

The feeding behavior of two squirrel monkeys flown in Spacelab 3 is compared to that of six monkeys exposed to 1.5 G through centrifugation. The monkeys in the centrifugation study were housed unrestrained in cages, maintained at 25 C + or - 1 C, exposed to a 12:12 light/dark cycle, and had unrestrained access to food and water. The Spacelab monkeys were maintained at 26 C, exposed to a 12:12 light/dark cycle and had unlimited food and water. It is observed that the centrifuge rats displayed a change in feeding behavior for 4 days prior to resuming a normal pattern; one Spacelab monkey exhibited a 6 day depression before recover to control levels, and the feeding pattern of the second monkey was not influenced by the environment. It is noted that the effect of an altered dynamic environment is variable on the feeding behavior of individual monkeys.

Fuller, C. A.↗

High throughput parallel backside contacting and periodic texturing for high-efficiency solar cells

Disclosed are configurations of long-range ordered features of solar cell materials, and methods for forming same. Some features include electrical access openings through a backing layer to a photovoltaic material in the solar cell. Some features include textured features disposed adjacent a surface of a solar cell material. Typically the long-range ordered features are formed by ablating the solar cell material with a laser interference pattern from at least two laser beams.

14 SOLAR ENERGY↗

EVI-Equity

EVI-Equity (Electric Vehicle Infrastructure for Equity) is a $200k project, started around in June of 2021, with a funding from the Vehicle Technologies Office (VTO). The motivation was to create a new analytical capability that can enable us to quantify and investigate equitable access to and distribution of existing and future deployment of PEVs and EVSEs in neighborhoods, cities, states, and the nation. EVI-Equity is a bottom-up equity-focused analysis model, built upon individual (synthetic) households, aggregated by census block groups. It consists of four core components - community engagement, environmental profiling, household expenditures, and network design. Although there are some commonalities, EVI-Equity is not a vehicle choice model, charging simulation model, or transportation demand model. EVI-Equity is rather a cross-cutting analysis tool, dedicated for evaluating equitable EV adoption and EVSE deployment, encompassing and bridging a wide variety of related tools, models, and frameworks. Some of the results indicate the importance of used vehicle market for low-income households. The presentation also highlights similarities and variations as to preferred public charging locations. For example, regardless of household income, retail spots are the most preferred location for public charging, followed by curbside/street. However, the results also imply that the importance of workplace charging may vary with income - the lower the income, the less important. Environmental profiling results, with an example of ground-level ozone in Atlanta area, show that the contrast between the haves and the have nots of plug-in electric vehicles depends on location. The assessment of household expenditures illustrates the economic impact of home charging access on an individual household level - the lower the income, the greater the impact is. Lastly, Denver metro area and the state of South Dakota are used to showcase the impact of different network design of charging infrastructure, as well as alternative (vs. baseline/existing) electric vehicle adoption pattern.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

Stochastic derivative-free optimization using a trust region framework

This study presents a trust region algorithm to minimize a function f when one has access only to noise-corrupted function values f¯. The model-based algorithm dynamically adjusts its step length, taking larger steps when the model and function agree and smaller steps when the model is less accurate. The method does not require the user to specify a fixed pattern of points used to build local models and does not repeatedly sample points. If f is sufficiently smooth and the noise is independent and identically distributed with mean zero and finite variance, we prove that our algorithm produces iterates such that the corresponding function gradients converge in probability to zero. As a result, we present a prototype of our algorithm that, while simplistic in its management of previously evaluated points, solves benchmark problems in fewer function evaluations than do existing stochastic approximation methods.

97 MATHEMATICS AND COMPUTING↗

Imaging Changes in Cell Walls of Engineered Poplar by Stimulated Raman Scattering and Atomic Force Microscopy

Lignin is a major impediment in the deconstruction of plant biomass to its soluble monomeric constituents. Modification of the lignin biosynthetic pathway has proven to be an effective means of reducing biomass recalcitrance but can often result in impaired growth. As one of the successful instances of “designer” biomass, “Zip-lignin” has been generated in poplar to introduce ester linkages into the lignin backbone. The resulting plants grow normally and have improved biomass deconstructability, especially under mild alkaline conditions that can effectively cleave the uniquely introduced ester bonds. In order to further understand the structural and chemical features that may be associated with the observed improved processing efficiency, we used hyperspectral stimulated Raman scattering (hsSRS) to map the Zip-lignin in planta using lignin conjugated α–β carbon double bonds as the proxy. Such double bonds are introduced in all types of lignin, but unique structures in Zip-lignins experience a ~20 cm –1 shift from 1650 to 1630 cm –1 in their Raman spectra due to the conjugation between the double bond and an associated ester carbonyl group. Analysis of the hsSRS images has revealed that the Raman signal specifically representing Zip-lignin can be estimated. Moreover, it exhibits a distribution pattern in cell wall layers similar to that of the native lignin, but its intensity varies in different transgenic poplar lines. In addition, when the cell walls are imaged by atomic force microscopy and Simons’ staining, we found that the poplar containing the Zip-lignin had increased accessible areas, which may be beneficial to the chemical penetration during pretreatment and substrate accessibility during enzymatic hydrolysis. Our work indicates that both physical and chemical modification of cell wall in Zip-lignin poplar could contribute to the observed improvements in sugar yields.

09 BIOMASS FUELS↗

Three-dimensional coherent Bragg imaging of spontaneously rotating nanoparticles

This dataset contains spontaneous rocking curves of individual 60 nm gold particles, measured as CDI patterns in the Bragg geometry. The dataset provides a higher-quality alternative to ID 151, and is collected at lower energy, shorter detector distance (~120 mm) and using a He-filled flight tube. Additionally, this data includes measurements along the (111), (200), and (220) directions, providing access to multiple strain directions.

60 nm truncated-octrahedral gold nanoparticles↗

Big Data Analytics for Long-Term Meteorological Observations at Hanford Site

A growing number of physical objects with embedded sensors with typically high volume and frequently updated data sets has accentuated the need to develop methodologies to extract useful information from big data for supporting decision making. This study applies a suite of data analytics and core principles of data science to characterize near real-time meteorological data with a focus on extreme weather events. To highlight the applicability of this work and make it more accessible from a risk management perspective, a foundation for a software platform with an intuitive Graphical User Interface (GUI) was developed to access and analyze data from a decommissioned nuclear production complex operated by the U.S. Department of Energy (DOE, Richland, USA). Exploratory data analysis (EDA), involving classical non-parametric statistics, and machine learning (ML) techniques, were used to develop statistical summaries and learn characteristic features of key weather patterns and signatures. The new approach and GUI provide key insights into using big data and ML to assist site operation related to safety management strategies for extreme weather events. Specifically, this work offers a practical guide to analyzing long-term meteorological data and highlights the integration of ML and classical statistics to applied risk and decision science.

54 ENVIRONMENTAL SCIENCES↗

Surface flow visualization requirements for testing in NTF

Surface flow visualization is required to be correlated at all the facilities to allow the following: (1) an understanding of the chordwise and spanwise extent of laminar flow; (2) the change in shock location for various trip configurations; (3) the effectiveness of the chosen boundary layer trip (since its specifications will change as a function of Reynolds number); and (4) a comparison of the separation patterns at the buffet conditions. A requirement to tunnel-to-tunnel correlation testing involving the NTF is pointed out. A specification for a surface flow visualization system to be used in the NTF is defined. Recognition of the special limitations in the NTF including physical and visual accessibility, high operating cost, flow contamination requirements, as well as the need for on-line review of the results to develop the final trip configurations in a timely manner, leads to the listed requirements.

Bengelink, R. L.↗

The Application of Remote Sensing Data to GIS Studies of Land Use, Land Cover, and Vegetation Mapping in the State of Hawaii

A land cover-vegetation map with a base classification system for remote sensing use in a tropical island environment was produced of the island of Hawaii for the State of Hawaii to evaluate whether or not useful land cover information can be derived from Landsat TM data. In addition, an island-wide change detection mosaic combining a previously created 1977 MSS land classification with the TM-based classification was produced. In order to reach the goal of transferring remote sensing technology to State of Hawaii personnel, a pilot project was conducted while training State of Hawaii personnel in remote sensing technology and classification systems. Spectral characteristics of young island land cover types were compared to determine if there are differences in vegetation types on lava, vegetation types on soils, and barren lava from soils, and if they can be detected remotely, based on differences in pigments detecting plant physiognomic type, health, stress at senescence, heat, moisture level, and biomass. Geographic information systems (GIS) and global positioning systems (GPS) were used to assist in image rectification and classification. GIS was also used to produce large-format color output maps. An interactive GIS program was written to provide on-line access to scanned photos taken at field sites. The pilot project found Landsat TM to be a credible source of land cover information for geologically young islands, and TM data bands are effective in detecting spectral characteristics of different land cover types through remote sensing. Large agriculture field patterns were resolved and mapped successfully from wildland vegetation, but small agriculture field patterns were not. Additional processing was required to work with the four TM scenes from two separate orbits which span three years, including El Nino and drought dates. Results of the project emphasized the need for further land cover and land use processing and research. Change in vegetation composition was noted in the change detection image.

Hogan, Christine A.↗

Size and Distribution of Parr Produced from Natural‐ and Hatchery‐Origin Steelhead Spawning Naturally in a Small Pacific Northwest Coastal Stream

Abstract Recent studies suggest that steelhead Oncorhynchus mykiss produced from local hatchery‐origin (HOR) adults have lower lifetime fitness than their natural‐origin (NOR) counterparts. To increase our understanding of this pattern, we compared age‐1 parr size and distribution produced by a local integrated population of HOR and NOR adults spawning naturally across a range of environmental conditions. Across 8 years, we used genetic parentage assignments and field measurements of parr in conjunction with creek temperature and flow data to find small, nonbiologically significant differences in size between parr of different parent origins. This suggests that parr produced by HOR adults are acquiring enough resources to grow at a rate similar to that of parr produced by NOR adults. In contrast to origin, we found strong positive associations between mean size of parr and annual mean water temperature and summer flow. Additionally, the distribution of parr was similar and HOR‐produced parr were not skewed relative to the location of the hatchery. Parr occupying the full extent of accessible and suitable habitat might be a positive outcome for hatchery programs seeking to supplement an existing population or replace an extirpated population. However, these results also imply that HOR fish could be competing with NOR fish for food and space, which might be less desirable if the goal of the hatchery program is harvest and not supplementation. Our results highlight the importance of clearly articulated goals for the hatchery program, as the observed pattern could be deemed a benefit or a risk depending on the hatchery's purpose. Lastly, projections for higher water temperatures and reduced summer flows, when considered in the context of the correlations we observed for size of parr, imply that coastal steelhead populations could start experiencing negative climate impacts with respect to steelhead parr growth metrics during the summer in the next few decades.

Kennedy, Benjamen M.↗

A Dynamic Optimization Technique for Siting the NASA-Clark Atlanta Urban Rain Gauge Network (NCURN)

NASA satellites and ground instruments have indicated that cities like Atlanta, Georgia may create or alter rainfall. Scientists speculate that the urban heat island caused by man-made surfaces in cities impact the heat and wind patterns that form clouds and rainfall. However, more conclusive evidence is required to substantiate findings from satellites. NASA, along with scientists at Clark Atlanta University, are implementing a dense, urban rain gauge network in the metropolitan Atlanta area to support a satellite validation program called Studies of PRecipitation Anomalies from Widespread Urban Landuse (SPRAWL). SPRAWL will be conducted during the summer of 2003 to further identify and understand the impact of urban Atlanta on precipitation variability. The paper provides an. overview of SPRAWL, which represents one of the more comprehensive efforts in recent years to focus exclusively on urban-impacted rainfall. The paper also introduces a novel technique for deploying rain gauges for SPRAWL. The deployment of the dense Atlanta network is unique because it utilizes Geographic Information Systems (GIS) and Decision Support Systems (DSS) to optimize deployment of the rain gauges. These computer aided systems consider access to roads, drainage systems, tree cover, and other factors in guiding the deployment of the gauge network. GIS and DSS also provide decision-makers with additional resources and flexibility to make informed decisions while considering numerous factors. Also, the new Atlanta network and SPRAWL provide a unique opportunity to merge the high-resolution, urban rain gauge network with satellite-derived rainfall products to understand how cities are changing rainfall patterns, and possibly climate.

Shepherd, J. Marshall↗

Linking human-building interactions in shared offices with personality traits

Occupant behavior influences office building energy performance. The level of human-building interactions (HBIs) in shared offices strongly influences building energy use and occupant well-being. This study explored the link between occupant personality types and their behaviors of sharing energy and environment control systems and interactions with their colleagues. Inspired by the Five-Factor Model (FFM), we classified HBI behaviors into four dimensions: willingness to share control, knowledge of control, group decision behavior, and adaptive strategies. These four variables can be mapped to the four personality traits proposed by the FFM: agreeableness, openness, extraversion, and conscientiousness. Our cluster analysis identified six behavioral patterns: average (17.7%), reserved (15.3%), environmentally friendly (16.6%), role model (24.2%), self-centered (17.2%), and mechanist (9.0%). We further applied association rules, a widely utilized machine learning technique, to discover how demographics, building-related contextual factors, and perception-attitudinal factors influence HBI behaviors. Country, control feature accessibility, and group dynamics were found to be the three most influential factors that determine occupants’ HBI behaviors. Finally, the study provides insights about building design and operation, as well as policy to promote socially and environmentally desirable HBI behaviors in a shared office environment.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Implementation and assessment of resolution-dependent elastic incoherent neutron scattering measurements at a backscattering spectrometer for probing relaxations in complex systems

We introduce the use of a higher-order reflection, Si(333), of the silicon analyzer crystals at a backscattering spectrometer to implement analysis of the relaxation dynamics in the samples. Here, this is achieved by monitoring the temperature dependence of the neutron scattering intensity perceived as elastic when measured using Si(111), Si(311), and Si(333) reflections. As a test case, we use a sample with well-characterized, but complex, relaxation pattern, where the non-Lorentzian relaxation function is known to exhibit a set of parameters specific to each temperature point and scattering momentum transfer (Q) value. Even for this very general relaxation pattern, characterized by no constrains on the relaxation function parameters, we successfully map the relaxation times measured using the present approach onto those previously obtained from the full analysis of the quasielastic neutron scattering signal. Analysis of the Q-specific activation energies becomes possible for the Q values accessible simultaneously through Si(111), Si(311), and Si(333) reflections (in the present case, 0.9 Å –1 < Q < 1.9 Å –1 ). While the dedicated neutron spectrometers for this type of analysis are yet to be constructed, we show that the present-day backscattering spectrometers can be employed, under certain conditions, to analyze temperature dependence of the relaxation time in the samples not amenable to traditional full analysis of the quasielastic neutron scattering signal.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Adsorption Hysteresis Under Control: Tuning Host–Guest Interactions via a Genetic Algorithm

Mesoporous adsorbent materials offer a large volumetric capacity; however, cyclic adsorption/desorption processes in these systems often suffer from hysteresis and may require a significant pressure swing to access this capacity. To mitigate hysteresis, a proposed strategy is to include nucleation sites on the walls of the mesoporous material to facilitate droplet and bubble formation, lowering the free energy barriers to the respective phase transitions. It is unclear, however, what combination of adsorbate− adsorbent interactions and spatial patterning would be beneficial for a given application, considering that improvements to some sorption properties may come at the expense of other attributes. To understand these interconnected observables, we examine two model systems, planar-slit and cylindrical pores with tunable interaction sites, using GPU-accelerated transition matrix Monte Carlo simulations. The simulations provide a free energy map of the pressure−adsorption space in a matter of minutes, which we use to track adsorption isotherm characteristics as a function of adsorbent properties. We then leverage the rapid acquisition of simulation data to construct a genetic algorithm to iteratively modify interaction sites of the slit-pore wall to minimize the hysteresis of this system without sacrificing uptake. We find that the adsorption branch of the isotherm is easily modulated via the average host−guest interaction strength, but desorption is only adjustable if there is a suitable bubble nucleation site. Within the context of a slit-pore system, we identify relative interaction strengths and patch sizes required to gain control over both branches of the hysteresis loop.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Photonic spin Hall effect in bilayer graphene moiré superlattices

The formation of a superstructure—with a related moiré pattern—plays a crucial role in the extraordinary optical and electronic properties of twisted bilayer graphene, including the recently observed unconventional superconductivity. Here we present an interdisciplinary approach to determine the moiré angle in twisted bilayer graphene based on the photonic spin Hall effect. Here, we show that the photonic spin Hall effect exhibits clear fingerprints of the underlying moiré pattern, and the associated light beam shifts are well beyond current experimental sensitivities in the near-infrared and visible ranges. By discovering the dependence of the frequency position of the maximal photonic spin Hall effect shift on the moiré angle, we argue that the latter could be unequivocally accessed via all-optical far-field measurements. We also disclose that, when combined with the Goos-Hänchen effect, the spin Hall effect of light enables the complete determination of the electronic conductivity of the bilayer. Altogether our findings demonstrate that subwavelength spin-orbit interactions of light provide an unprecedented toolset for investigating optoelectronic properties of multilayer two-dimensional van der Waals materials.

36 MATERIALS SCIENCE↗

Study of shot noise in photoresists for extreme ultraviolet lithography through comparative analysis of line edge roughness in electron beam and extreme ultraviolet lithography

In this paper, the influence of the absorption shot noise on line edge roughness (LER) of photoresists for extreme ultraviolet (EUV) lithography is studied experimentally through the comparative analysis of LER obtained by EUV (92 eV photons) and 100 keV e-beam lithography. Techniques for performing EUV and e-beam lithography with a matched image log slope for a fair comparison of LER values are described. Measurements of absorption of 100 keV electrons estimated through a transmissive electron energy loss spectroscopy measurement with a 120 keV electron beam showed that despite having access to core levels in the material (e.g., 284 eV edge in carbon), these electrons mostly just excite the energy levels less than 100 eV in the resist, with a mean deposited energy of 35 eV. By combining the incident flux and the absorption probabilities, the absorbed quanta for patterning of 50 nm half-pitch line/space features was found to be similar between the two patterning technologies.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗