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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1972

Hypersonic transitional boundary layers.

Surface thin-film gages have been used to determine the extent of the transition region, intermittency distribution, and disturbance convection velocities in the boundary layer on a sharp 5-deg half angle cone at Mach 7.4 in the Ames 3.5-ft Hypersonic Wind Tunnel. In addition, extensive hot wire space-time correlation measurements have been obtained in the wind-tunnel freestream and in the transitional hypersonic boundary layer on a cone-ogive-cylinder in the same facility. Disturbance convection velocities have been obtained from the longitudinal cross correlation measurements as a function of fluctuation scale and distance from the wall. The results of normal cross correlation measurements are also discussed.

Owen, F. K.↗
NASA NTRS1994

High-angle-of-attack yawing moment asymmetry of the X-31 aircraft from flight test

Significant yawing moment asymmetries were encountered during the high-angle-of-attack envelope expansion of the two X-31 aircraft. These asymmetries led to position saturations of the thrust vector vanes and trailing-edge flaps during some of the dynamic stability axis rolling maneuvers at high angles of attack. This slowed the high-angle-of-attack envelope expansion and resulted in maneuver restrictions. Several aerodynamic modifications were made to the X-31 forebody with the goal of minimizing the asymmetry. A method for determining the yawing moment asymmetry from flight data was developed and an analysis of the various configuration changes completed. The baseline aircraft were found to have significant asymmetries above 45 deg angle of attack with the largest asymmetry typically occurring around 60 deg angle of attack. Applying symmetrical boundary layer transition strips along the forebody sides increased the magnitude of the asymmetry and widened the angle-of-attack range over which the largest asymmetry acted. Installing longitudinal forebody strakes and rounding the sharp nose of the aircraft caused the yawing moment asymmetry magnitude to be reduced. The transition strips and strakes made the asymmetry characteristic of the aircraft more repeatable than the clean forebody configuration. Although no geometric differences between the aircraft were known, ship 2 consistently had larger yawing moment asymmetries than ship 1.

Cobleigh, Brent R.↗
DOE OSTI2024

Higgs-confinement transitions in QCD from symmetry protected topological phases

In gauge theories with fundamental matter there is typically no sharp way to distinguish confining and Higgs regimes, e.g. using generalized global symmetries acting on loop order parameters. It is standard lore that these two regimes are continuously connected, as has been explicitly demonstrated in certain lattice and continuum models. We point out that Higgsing and confinement sometimes lead to distinct symmetry protected topological (SPT) phases -- necessarily separated by a phase transition -- for ordinary global symmetries. We present explicit examples in 3+1 dimensions, obtained by adding elementary Higgs fields and Yukawa couplings to QCD while preserving parity P and time reversal T. In a suitable scheme, the confining phases of these theories are trivial SPTs, while their Higgs phases are characterized by non-trivial P- and T-invariant theta-angles θ f , θ g = π for flavor or gravity background gauge fields, i.e. they are topological insulators or superconductors. Finally, we consider conventional three-flavor QCD (without elementary Higgs fields) at finite U(1) B baryon-number chemical potential μ B , which preserves P and T. At very large μ B , three-flavor QCD is known to be a completely Higgsed color superconductor that also spontaneously breaks U(1) B . We argue that this high-density phase is in fact a gapless SPT, with a gravitational theta-angle θ g = π that safely co-exists with the U(1) B Nambu-Goldstone boson. We explain why this SPT motivates unexpected transitions in the QCD phase diagram, as well as anomalous surface modes at the boundary of quark-matter cores inside neutron stars.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2015

Dynamics of Hydrophobic Core Phenylalanine Residues Probed by Solid-State Deuteron NMR

We conducted a detailed investigation of the dynamics of two phenylalanine side chains in the hydrophobic core of the villin headpiece subdomain protein (HP36) in the hydrated powder state over the 298–80 K temperature range. We utilized static deuteron NMR measurements of longitudinal relaxation and line shapes supplemented with computational modeling. The temperature dependence of the relaxation times reveals the presence of two main mechanisms that can be attributed to the ring-flips, dominating at high temperatures, and small-angle fluctuations, dominating at low temperatures. The relaxation is non- exponential at all temperatures with the extent of non-exponentiality increasing from higher to lower temperatures. This behavior suggests a distribution of conformers with unique values of activation energies. The central values of the activation energies for the ring-flipping motions are among the smallest reported for aromatic residues in peptides and proteins and point to a very mobile hydrophobic core. The analysis of the widths of the distributions, in combination with the earlier results on the dynamics of flanking methyl groups (Vugmeyster et al., J. Phys. Chem. 2013, 117, 6129–6137), suggests that the hydrophobic core undergoes concerted fluctuations. There is a pronounced effect of dehydration on the ring-flipping motions, which shifts the distribution toward more rigid conformers. The cross-over temperature between the regions of dominance of the small-angle fluctuations and ring-flips shifts from 195 K in the hydrated protein to 278 K in the dry one. This result points to the role of solvent in the onset of the concerted fluctuations of the core and highlights aromatic residues as markers of the protein dynamical transitions.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2018

Sulfur Hydrides: Phase Diagram and the Transition into the Record-High T{sub c} State

Remarkable feature of the phase diagram of sulfur hydrides, the record-high T{sub c} superconductors, is a sharp increase near P ≈ 150 GPa from T{sub c} ≈ 120 to ≈ 200 K. This increase is a signature of the structural transition. The present study is concerned with the nature of this phase transition. One can demonstrate that the symmetry analysis along with an analysis of the impact of lattice deformations lead to the conclusion that we are dealing with the first-order transition. Such a transition is manifested in an abrupt appearance of small pockets on the Fermi surface and, correspondingly, the two-gap energy spectrum.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Mineralogical effects on the detectability of the postperovskite boundary

The discovery of a phase transition in Mg-silicate perovskite (Pv) to postperovskite (pPv) at lowermost mantle pressure-temperature (P - T) conditions may provide an explanation for the discontinuous increase in shear wave velocity found in some regions at a depth range of 200 to 400 km above the core-mantle boundary, hereafter the D{double_prime} discontinuity. However, recent studies on binary and ternary systems showed that reasonable contents of Fe{sup 2+} and Al for pyrolite increase the thickness (width of the mixed phase region) of the Pv - pPv boundary (400-600 km) to much larger than the D{double_prime} discontinuity ({le} 70 km). These results challenge the assignment of the D{double_prime} discontinuity to the Pv - pPv boundary in pyrolite (homogenized mantle composition). Furthermore, the mineralogy and composition of rocks that can host a detectable Pv {yields} pPv boundary are still unknown. Here we report in situ measurements of the depths and thicknesses of the Pv {yields} pPv transition in multiphase systems (San Carlos olivine, pyrolitic, and midocean ridge basaltic compositions) at the P - T conditions of the lowermost mantle, searching for candidate rocks with a sharp Pv - pPv discontinuity. Whereas the pyrolitic mantle may not have a seismologically detectable Pv {yields} pPv transition due to the effect of Al, harzburgitic compositions have detectable transitions due to low Al content. In contrast, Al-rich basaltic compositions may have a detectable Pv - pPv boundary due to their distinct mineralogy. Therefore, the observation of the D{prime} discontinuity may be related to the Pv {yields} pPv transition in the differentiated oceanic lithosphere materials transported to the lowermost mantle by subducting slabs.

Grocholski, Brent↗
DOE OSTI2013

Synthesis and structural studies of praseodymium doped silver borate glasses

Praseodymium doped silver borate glasses with nominal composition xPr{sub 6}O{sub 11}-(25-x)Ag{sub 2}O-75B{sub 2}O{sub 3} (x=0, 1, 2, 3, 4, 5) were prepared by melt quench technique. XRD pattern shows that there is no sharp peak it confirms the amorphous nature of the present glasses. The glass transition temperature (T{sub g}) of this glass system have been studied using the Matac MBS-8000 Digital Signal Processing and Conventional Thermal Analysis (DTA) method. The T{sub g} of these glasses increases with increase in concentration of Pr{sub 6}O{sub 11} except at 0.2 mol%, T{sub g} value is lower. {sup 11}B MAS-NMR shows the presence of sharp peak around 0.306 ppm. Chemical shift of these glasses decreases with mol% of rare earth oxide. FTIR spectra recorded in the region of 400 to 4000 cm{sup -1}. This studies revealed that the progressive addition Ag{sub 2}O and Pr{sub 6}O{sub 11} leads to modification of B{sub 2}O{sub 3} into BO{sub 4} groups. Raman measurements of these glasses support the proposed interpretations of the experimental results.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Phase separation in LuFeO{sub 3} films

The structural transition at about 1000 °C, from the hexagonal to the orthorhombic phase of LuFeO{sub 3}, has been investigated in thin films of LuFeO{sub 3}. Separation of the two structural phases of LuFeO{sub 3} occurs on a length scale of micrometer, as visualized in real space using X-ray photoemission electron microscopy. The results are consistent with X-ray diffraction and atomic force microscopy obtained from LuFeO{sub 3} thin films undergoing the irreversible structural transition from the hexagonal to the orthorhombic phase of LuFeO{sub 3}, at elevated temperatures. The sharp phase boundaries between the structural phases are observed to align with the crystal planes of the hexagonal LuFeO{sub 3} phase. The coexistence of different structural domains indicates that the irreversible structural transition, from the hexagonal to the orthorhombic phase in LuFeO{sub 3}, is a first order transition, for epitaxial hexagonal LuFeO{sub 3} films grown on Al{sub 2}O{sub 3}.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Observation of an intermediate state during lithium intercalation of twisted bilayer MoS2

Abstract Lithium intercalation of MoS 2 is generally believed to introduce a phase transition from H phase (semiconducting) to T phase (metallic). However, during the intercalation process, a spatially sharp boundary is usually formed between the fully intercalated T phase MoS 2 and non-intercalated H phase MoS 2 . The intermediate state, i.e ., lightly intercalated H phase MoS 2 without a phase transition, is difficult to investigate by optical-microscope-based spectroscopy due to the narrow size. Here, we report the stabilization of the intermediate state across the whole flake of twisted bilayer MoS 2 . The twisted bilayer system allows the lithium to intercalate from the top surface and enables fast Li-ion diffusion by the reduced interlayer interaction. The E 2g Raman mode of the intermediate state shows a peak splitting behavior. Our simulation results indicate that the intermediate state is stabilized by lithium-induced symmetry breaking of the H phase MoS 2 . Our results provide an insight into the non-uniform intercalation during battery charging and discharging, and also open a new opportunity to modulate the properties of twisted 2D systems with guest species doping in the Moiré structures.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Superconducting Performance, Structure, Microstructure, and Trapped Field of Top-Seeded Melt-Processed Bulk Y{sub 3}Ba{sub 5}Cu{sub 8}O{sub x}

The sintering temperature for the production of Y{sub 3}Ba{sub 5}Cu{sub 8}O{sub 18} (Y-358) preform powders synthesized in sol-gel spontaneous combustion technique was optimized. A large single-grain bulk Y-358 crystal was fabricated employing a top-seeded melt-growth technique utilizing the optimally sintered preform powders (i.e., at 900 {sup ∘}C for 12 h). Structural, microstructural, elemental, and magnetic properties were investigated by means of X-ray diffraction, scanning electron microscopy, and SQUID, respectively. The structural characterization indicated that the sample is highly textured in (00l) direction. The Y-358 phase fractions were estimated in both preform powders and bulk sample using Rietveld refinement. The onset of superconducting transition is observed at 92.5 K, and the curve is very sharp indicative of the high quality of the produced bulk sample. The field dependence of critical current density (J{sub c}) was determined at 77 K, and the self-field J{sub c} was found to be ∼26 kA/cm{sup 2}. A magnetic field of 0.27 T was trapped by the sample at 77 K.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Effect of Cesium Substitution on the Superconducting Properties of Bi-2212 Samples Prepared Via Solid-State Reaction and Laser Floating Zone Technique

In this work, the effect of cesium substitution on the structural and superconducting properties of Bi{sub 2}Sr{sub 2}Ca{sub 1-x}Cs{sub x}Cu{sub 2}O{sub +y} (where x = 0.0, 0.025, 0.050, 0.075, 0.10, 0.125, and 0.15) samples prepared by the solid-state reaction route and by directional growth using the laser floating zone (LFZ) technique has been studied. X-ray diffraction has shown that both kinds of samples present the 2212 phase as the major one, with pseudo tetragonal structure, accompanied by minor amounts of (Sr,Ca)CuO{sub 2} and Bi{sub 2}(Sr,Ca){sub 4}O{sub 6 + d} secondary phases. SEM-EDX results indicate that Bi-2212 phase is the major one, with small amounts of secondary phases. Cs substitution diminishes the size and content of secondary phases. Magnetization measurements reflect different behavior for sintered and LFZ grown samples. Although the diamagnetic transition is very wide for the former samples, it is very sharp for the last ones. The critical onset temperatures, T{sub C}, are around 80 and 90 K, for sintered and LFZ grown samples, respectively. Moreover, M–H measurements indicate that LFZ grown samples exhibit larger areas than the sintered ones. The intragranular critical current, J{sub C}, calculated from the M–H loops and Bean’s formula, is maximum for x = 0.025Cs sintered and x = 0.05Cs LFZ grown samples. The maximum pinning forces, F{sub Pmax}, determined in these samples are higher than those obtained in undoped ones, reaching 9 × 10{sup 7} Oe*A/cm{sup 2} and 10 × 10{sup 8} Oe*A/cm{sup 2}, at 10 K, for sintered and LFZ grown samples, respectively.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Single crystal growth and variation of thermodynamic and magnetic properties of Pr1−xLaxAlO3 (x = 0, 0.8)

Highlights: • The perovskite Pr{sub (1-x)}La{sub (x)}AlO{sub 3} was grown by two different protocols to control the P{sup 4+} concentration. • Low temperature magnetic properties in bulk single crystals are sensitive to annealing protocols. • Post growth annealing in a reducing atmosphere leads to closest Pr{sub 0.2}La{sub 0.8}AlO{sub 3} stoichiometry. • A possible new magnetic transition for single crystal PrAlO{sub 3} is observed at 6 K. - Abstract: Two approaches to using optical floating zone (OFZ) technique for single crystal growth of the perovskite Pr{sub 1−x}La{sub x}AlO{sub 3} are discussed, along with the influence on the physical properties of the resulting single crystals due to oxidizing and reducing post anneals. In method one (M1) we used pre-reduced Pr{sub 2}O{sub 3} powder starting material, while in the other method, M2, we employed an argon 5% hydrogen reducing environment during the floating zone single crystal growth. Magnetic susceptibility of the low temperature monoclinic phase of Pr{sub 0.2}La{sub 0.8}AlO{sub 3} is shown to be sensitive to the precise annealing protocol followed. For the post-growth reduced single crystal the magnetic susceptibility is flat across the R-3c to C2/m structural transition, whereas the oxidized and as-grown samples display a sharp upturn and downturn, respectively. We attribute the low temperature susceptibility differences to relative proportions of Pr{sup 3+} and Pr{sup 4+}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Resonant tunneling of fluctuation Cooper pairs

Superconducting fluctuations have proved to be an irreplaceable source of information about microscopic and macroscopic material parameters that could be inferred from the experiment. According to common wisdom, the effect of thermodynamic fluctuations in the vicinity of the superconducting transition temperature, T c , is to round off all of the sharp corners and discontinuities, which otherwise would have been expected to occur at T c . Here we report the current spikes due to radiation-induced resonant tunneling of fluctuation Cooper pairs between two superconductors which grow even sharper and more pronounced upon approach to T c . This striking effect offers an unprecedented tool for direct measurements of fluctuation Cooper pair lifetime, which is key to our understanding of the fluctuation regime, most notably to nature of the pseudogap state in high-temperature superconductors. Lastly, our finding marks a radical departure from the conventional view of superconducting fluctuations as a blurring and rounding phenomenon.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

RADIO MONITORING OF THE TIDAL DISRUPTION EVENT SWIFT J164449.3+573451. II. THE RELATIVISTIC JET SHUTS OFF AND A TRANSITION TO FORWARD SHOCK X-RAY/RADIO EMISSION

We present continued multi-frequency radio observations of the relativistic tidal disruption event Swift J164449.3+573451 (Sw 1644+57) extending to t Almost-Equal-To 600 days. The data were obtained with the JVLA and AMI Large Array as part of our on-going study of the jet energetics and the density structure of the parsec-scale environment around the disrupting supermassive black hole. We combine these data with public Swift/XRT and Chandra X-ray observations over the same time-frame to show that the jet has undergone a dramatic transition starting at Almost-Equal-To 500 days, with a sharp decline in the X-ray flux by about a factor of 170 on a timescale of {delta}t/t {approx}< 0.2 (and by a factor of 15 in {delta}t/t Almost-Equal-To 0.05). The rapid decline rules out a forward shock origin (direct or reprocessing) for the X-ray emission at {approx}< 500 days, and instead points to internal dissipation in the inner jet. On the other hand, our radio data uniquely demonstrate that the low X-ray flux measured by Chandra at Almost-Equal-To 610 days is consistent with emission from the forward shock. Furthermore, the Chandra data are inconsistent with thermal emission from the accretion disk itself since the expected temperature of {approx}30-60 eV and inner radius of {approx}2-10 R{sub s} cannot accommodate the observed flux level or the detected emission at {approx}> 1 keV. We associate the rapid decline with a turn off of the relativistic jet when the mass accretion rate dropped below {approx} M-dot{sub Edd}{approx}0.006 M{sub Sun} yr{sup -1} (for a 3 Multiplication-Sign 10{sup 6} M{sub Sun} black hole and order unity efficiency) indicating that the peak accretion rate was about 330 M-dot{sub Edd}, and the total accreted mass by t Almost-Equal-To 500 days is about 0.15 M{sub Sun }. From the radio data we further find significant flattening in the integrated energy of the forward shock at t {approx}> 250 days with E{sub j,iso} Almost-Equal-To 2 Multiplication-Sign 10{sup 54} erg (E{sub j} Almost-Equal-To 10{sup 52} erg for a jet opening angle, {theta}{sub j} = 0.1) following a rise by about a factor of 15 at Almost-Equal-To 30-250 days. Projecting forward, we predict that the emission in the radio and X-ray bands will evolve in tandem with similar decline rates.

36 MATERIALS SCIENCE↗
DOE OSTI2012

A HIGH-RESOLUTION ISOTOPIC STUDY OF THE ROTATIONAL SPECTRUM OF c-C{sub 3}H{sub 2}

The rotational spectra of the normal and seven isotopic species of cyclopropenylidene c-C{sub 3}H{sub 2} have been measured at high spectral resolution by Fourier transform microwave spectroscopy of a supersonic molecular beam between 10 and 43 GHz. Deuterium quadrupole coupling and carbon-13 spin-rotation hyperfine constants were determined in addition to the rotational constants. Quartic and sextic centrifugal distortion constants derived from 28 lines between 150 and 316 GHz of the doubly deuterated species c-C{sub 3}D{sub 2} allow the rotational spectrum to be calculated to 0.5 km s{sup -1} or better in equivalent radial velocity up to 500 GHz. Spectroscopic constants determined from four centimeter-wave and 19 millimeter-wave lines of the normal species c-C{sub 3}H{sub 2}, including 15 with sharp Lamb-dips, allow prediction of the most important astronomical transitions (i.e., those with {Delta}J = 1 and K{sub a} {<=} 3) to 0.05 km s{sup -1} or better at 500 GHz. The doubly deuterated species is a good candidate for detection in cold dark clouds, because deuterium fractionation is high in c-C{sub 3}H{sub 2} and lines of C{sub 3}HD are fairly intense in these sources. An accurate empirical equilibrium structure of c-C{sub 3}H{sub 2}, derived from the experimental rotational constants of normal and isotopic c-C{sub 3}H{sub 2}, corrected for zero-point vibrational effects, is compared with previously reported structures.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

Helical magnetic order and Fermi surface nesting in noncentrosymmetric ScFeGe

Here, an investigation of the structural, magnetic, thermodynamic, and charge transport properties of noncentrosymmetric hexagonal ScFeGe reveals it to be an anisotropic metal with a transition to a weak itinerant incommensurate helimagnetic state below T N =36 K. Neutron diffraction measurements discovered a temperature and field independent helical wave vector k = (0 0 0.193) with magnetic moments of 0.53 μ B per Fe confined to the ab-plane. Density functional theory calculations are consistent with these measurements and find several bands that cross the Fermi level along the c-axis with a nearly degenerate set of flat bands just above the Fermi energy. The anisotropy found in the electrical transport is reflected in the calculated Fermi surface, which consists of several warped flat sheets along the c-axis with two regions of significant nesting, one of which has a wave vector that closely matches that found in the neutron diffraction. The electronic structure calculations, along with a strong anomaly in the c-axis conductivity at TN, signal a Fermi surface driven magnetic transition, similar to that found in spin density wave materials. Magnetic fields applied in the ab-plane result in a metamagnetic transition with a threshold field of ≈ 6.7 T along with a sharp, strongly temperature dependent discontinuity and a change in sign of the magnetoresistance for in-plane currents. Thus, ScFeGe is an ideal system to investigate the effect of in-plane magnetic fields on a helimagnet with a c-axis propagation vector, where the relative strength of the magnetic interactions and anisotropies determine the topology and magnetic structure.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2026

Contrasting decays of 3-quasiparticle isomers in 173 W: A discerning test of 𝐾 conservation and 𝐾 mixing

Two isomers with K π = 19/2 + at 1876 keV with a half-life of 21(1) ns, and K π = 23/2− at 2159 keV with a half-life of 93(6) ns have been identified in 173 W, the lightest tungsten isotope to exhibit this phenomenon. An unusually high number of 13 branches have been established in the decay of the K π = 23/2 − isomer. This decay is associated with transitions involving significantly higher degrees of K forbiddenness and is in sharp contrast with the usual preferential deexcitation through branches, which are less forbidden, as is evident for the K π = 19/2 + state in 173 W. The inclusion of K-mixing effects, arising from band crossings in the sequences to which decays with larger degrees of K forbiddenness are observed, can qualitatively account for this contrasting behavior. These results provide a striking illustration of the competition between K conservation and K mixing in the decay of such isomers.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1973

Positive ions in the mesosphere.

Positive ions have been measured using the parachute borne blunt probe, a subsonic system launched on meteorological rockets, which measures polar electrical conductivities in the 30 to 80 km altitude range. A central feature of the daytime positive conductivity profiles is a sharp break occurring between 60 and 70 km which indicates the transition from galactic cosmic ray to solar ultraviolet ionization, and, hence provides information about the nitric oxide density. In the 50-60 km region the positive ion conductivity is relatively constant with altitude and correlates well with atmospheric temperature down to 35 km. Using temperature and pressure profiles and a reduced mobility, the conductivity profiles may be converted to density profiles. The average mid-latitude daytime profile at intermediate solar zenith angles showed a minimum at 63.5 km.

Hale, L. C.↗